Abstract: The present invention relates to carboxylic acid esters of 2-hydroxy-5-isoalkyl-beta-methylstyrenes wherein the said isoalkyl substituent comprises 8-18 carbon atoms.
Abstract: A polyester composition for use in facilitating separation of blood serum or plasma from a cellular portion of blood, the composition containing: (a) a multifunctional acid component comprising: (i) a benzene polycarboxylic acid, and derivatives thereof; and (ii) an aliphatic polycarboxylic acid having from about 16 to about 40 carbon atoms; and (b) a diol component, and wherein the multifunctional acid component and diol component are employed in an equivalent ratio ranging from about 0.8:1.1 to about 1.0:1.3.
Type:
Grant
Filed:
November 3, 1999
Date of Patent:
June 6, 2000
Assignee:
Henkel Corporation
Inventors:
William L. O'Brien, Dean A. Oester, Jeffrey A. Barnhorst, Lidia Kupczyk-Subotkowska, John P. Fisher
Abstract: Polyamides and process for their preparation comprising eitherA) epoxidizing an unsaturated or partially hydrogenated fatty acid glyceride;B) transesterifying the epoxidized glyceride with a C.sub.1-4 alkanol to obtain epoxidized fatty acid C.sub.1-4 alkyl esters;C) ring opening and dimerizing the epoxidized fatty acid C.sub.1-4 alkyl esters; andD) reacting the dimerized fatty acid C.sub.1-4 alkyl esters with a polyamine to obtain a polyamide; orA) transesterifying an unsaturated or partially hydrogenated glyceride with a C.sub.14 alkanol to obtain olefinically unsaturated fatty acid C.sub.1-4 alkyl esters;B) epoxidizing the unsaturated fatty acid C.sub.1-4 alkyl esters;C) ring opening and dimerizing the epoxidized fatty acid C.sub.1-4 alkyl esters; andD) reacting the dimerized fatty acid C.sub.1-4 alkyl esters with a polyamine to obtain a polyamide.
Type:
Grant
Filed:
July 21, 1998
Date of Patent:
June 6, 2000
Assignee:
Henkel Corporation
Inventors:
Setsuo Sato, Ramiro Carielo Bueno, Wanderson Bueno De Almeida
Abstract: A process for making a superfatted personal cleansing bar involving the steps of: (a) providing a solid-form superfatting agent consisting of: (i) a fatty component selected from the group consisting of C.sub.6 -C.sub.22 free fatty acids, C.sub.6 -C.sub.22 fatty alcohols, and mixtures thereof; and (ii) a nonionic sugar surfactant selected from the group consisting of an alkyl polyglycoside of formula I:R.sub.1 O(Z).sub.a Iwherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; and a is a number having a value from 1 to about 6, a polyhydroxy fatty acid amide, and mixtures thereof; (b) providing a solid-form neutralized tallow/coco fatty acid soap mixture; (c) mixing components (a) and (b) to form a superfatted soap bar stock; and (d) stamping the superfatted soap bar stock into a finished personal cleansing bar.
Type:
Grant
Filed:
April 15, 1999
Date of Patent:
May 30, 2000
Assignee:
Henkel Corporation
Inventors:
Timothy J. Cassady, Robert R. Schoettker
Abstract: A surface is disinfected with a solution containing a fully or partially neutralized orthophosphate and optionally one or more surfactants. The method provides a safe and effective means of sanitizing surfaces such as cutting boards by removing, reducing or retarding the growth of pathogenic microorganisms without the use of substances that are toxic to humans.
Abstract: Improvement in the process of extracting metals, particularly copper, from aqueous ammoniacal solutions with beta-diketone extractants dissolved in a water immiscible hydrocarbon diluent, such as a kerosene, in which the improvement comprises application of a voltage potential across the interface of the aqueous and organic layers of an extraction circuit with an electrostatic coalescer, and maintaining the voltage potential until the layers have been separated, to control entrainment of the aqueous layer into the organic layer, thereby significantly reducing metal production cost and providing improved metal quality by minimizing ammonia entrapment and carry over to the aqueous stripping solution from which the metal is recovered, typically by electrowinning of the aqueous acid strip solution.
Type:
Grant
Filed:
April 21, 1999
Date of Patent:
May 9, 2000
Assignee:
Henkel Corporation
Inventors:
Michael J. Virnig, G. Timothy Fisher, Gary A. Kordosky
Abstract: A translucent personal cleansing bar containing: (a) an alkyl polyglycoside of formula I:R.sub.1 O(Z).sub.a (I)wherein R.sub.1 is a monovalent organic radical having from about 8 to 10 carbon atoms, and a is a number having a value of from about 1.40 to 1.55; (b) a soap component; and (c) water.
Type:
Grant
Filed:
September 9, 1998
Date of Patent:
May 9, 2000
Assignee:
Henkel Corporation
Inventors:
Timothy J. Cassady, Robert R. Schoettker
Abstract: A liquid cleaning composition containing: (a) at least one surfactant, other than a nonionic sugar surfactant; (b) an antibacterial agent; (c) a nonionic sugar surfactant; and (d) a glyceride component.
Abstract: A method of controlling or preventing foam in an aqueous system is provided, wherein an effective amount of an alkoxylated, epoxidized fatty compound that has been ring-opened with a nucleophile is determined and added to the system. After ring opening with the nucleophile, the epoxidized fatty compound is alkoxylated with an alkylene oxide selected from the group consisting of ethylene oxide, propylene oxide, and butylene oxide.
Type:
Grant
Filed:
September 2, 1997
Date of Patent:
May 2, 2000
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Horst-Werner Wollenweber, Klaus Hornfeck, Dieter Kaps, Bernhard Nellessen, Rita Koester, Wolfgang Drees, Peter Daute
Abstract: An adjuvant containing: (a) a fatty alcohol carbonate; and (b) a component selected from the group consisting of nonionic surfactants, anionic surfactants, cationic surfactants, alkyl esters, phytobland mineral oils, water soluble silicone surfactants, fatty acid dialkyl ethers, fatty acid dialkyl carbonates, vegetable oils, and mixtures thereof.
Abstract: A water-based composition for treating hair wherein the composition contains(a) a polymer selected from cationic, amphoteric, zwitterionic and nonionic polymers,(b) an alkyl polglycoside corresponding to formula (I):RO--(Z).sub.x (I)in whichR is an alkyl radical containing 6 to 22 carbon atoms,Z is a mono- or oligosaccharide,x is a number of 1.1 to 5,or adducts thereof with 1 to 10 moles of ethylene oxide or propylene oxide, and(c) a fatty alcohol.
Type:
Grant
Filed:
August 2, 1996
Date of Patent:
May 2, 2000
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Joerg Kahre, Hermann Hensen, Thomas Mueller-Kirschbaum, Dagmar Goebels, Holger Tesmann
Abstract: A process of preparing a concentrate which is useful as a thickener for aqueous compositions is provided. The process comprises obtaining a solution of an associative thickener compound in an organic solvent capable of forming a low boiling azeotrope with water. The solution is essentially free of water at this point and is at a temperature above the boiling point of said low boiling azeotrope. Water is added to said solution and an azeotrope of water and said organic solvent is distilled. The rate of addition of water is sufficient to replace said azeotrope with water, but is insufficient to cause a second phase to form in the resulting mixture of said solution and said water. The process yields a concentrate of an associative thickener in water, which concentrate is essentially free of volatile organic solvents.
Type:
Grant
Filed:
January 20, 1999
Date of Patent:
May 2, 2000
Assignee:
Henkel Corporation
Inventors:
Michael Wiggins, Dipak Shah, Reuben H. Grinstein
Abstract: A process for reducing foam in an alkyl polyglycoside-containing cleaning composition by adding a defoaming-effective amount of an alkyl polyglycoside having the general formula I:R.sub.1 O(Z).sub.a Iwherein R.sub.1 is a monovalent organic radical having from 16 to 18 carbon atoms; Z is a glucose residue having 5 or 6 carbon atoms; a is a number having a value of from 1 to about 6, to a cleaning composition containing an alkyl polyglycoside having the general formula II:R.sub.2 O(Z).sub.a IIwherein R.sub.2 is a monovalent organic radical having from 8 to 16 carbon atoms; Z is a glucose residue having 5 or 6 carbon atoms; a is a number having a value of from 1 to about 6.
Type:
Grant
Filed:
June 16, 1997
Date of Patent:
April 18, 2000
Assignee:
Henkel Corporation
Inventors:
Stephen F. Gross, John Frederick Hessel
Abstract: Diketo dinitriles are produced from the reaction of a diester and a nitrile in the presence of an alkali metal base. Polymers derived from the diketo dinitriles are useful as molding resins.
Abstract: The invention relates to a process for working up charged aqueous solutions, more especially etching solutions, which contain ammonia, at least one ammonium salt and metal ions in dissolved form and which accumulate in the treatment of substrates containing valuable metals, more especially copper-containing electronic sub-assemblies by contacting the aqueous solution with an organic water-immiscible extractant in one or more extraction stages to form an organic phase containing valuable metals and an aqueous phase, (b) washing the organic phase with a water-containing liquid in one or more successive washing stages wherein the water-containing liquid has a pH above 6.5 in the first washing stage and after said washing stage contacting the washing water before reuse with an organic extraction solution, and (c) conducting one or more stripping stages to transfer the valuable metals from the organic phase to an aqueous phase.
Abstract: A process for producing a polyurethane resin having an extended gel time by reacting a polyol component with a polyisocyanate in an NCO:OH ratio of from 10:1 to 1:10 wherein the polyol component contains from 0.1% to 100% by weight of a randomized castor oil prepared by heating castor oil for between about 0.1 and 15 hours at a temperature of between about 100.degree. C. and 280.degree. C. in the presence of a basic lithium salt.
Type:
Grant
Filed:
September 15, 1998
Date of Patent:
April 4, 2000
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Bernd Beuer, Roland Gruetzmacher, Andreas Heidbreder, Johann Klein
Abstract: A surfactant composition consisting essentially of: (a) from about 20 to about 63% by weight of an acyl isethionate; (b) from about 3 to about 52% by weight of a nonionic sugar surfactant selected from the group consisting of alkyl glucose esters, aldobionamides, gluconamides, glyceramides, glyceroglycolipids, polyhydroxy fatty acid amides, alkyl polyglycosides having the general formula I:R.sub.1 O(R.sub.2 O).sub.b (Z).sub.a Iwherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is a divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6, and mixtures thereof; (c) from about 7 to about 23% by weight of a free fatty acid; and (d) remainder, water, all weights being based on the weight of the surfactant composition.
Type:
Grant
Filed:
July 14, 1997
Date of Patent:
April 4, 2000
Assignee:
Henkel Corporation
Inventors:
Timothy J. Cassady, Robert R. Schoettker
Abstract: Detergent compositions comprised of an alkyl polyglycoside and an ester quat corresponding to formula (II) ##STR1## wherein R.sup.2 CO is an aliphatic acyl radical containing 12 to 22 carbon atoms and 0, 1, 2 or 3 double bonds, n=2 or 3 and X stands for halide, methosulfate or methophosphate ion are provided which are useful for the production of surface-active agents and for the enhanced recovery of crude oil.
Type:
Grant
Filed:
September 11, 1998
Date of Patent:
March 28, 2000
Assignees:
Henkel Kommanditgesellschaft auf Aktien, Pulcra S.A., Henkel Corporation
Inventors:
Allen D. Urfer, Oriol Ponsati Obiols, Nuria Bonastre
Abstract: A process for controlling microwave heating rates involving: (a) providing a microwavable substrate; (b) combining the microwavable substrate with an additive consisting essentially of an aliphatic polyol to form a modified microwavable substrate; and (c) subjecting the modified microwavable substrate to microwave energy.