Patents Represented by Attorney, Agent or Law Firm Matthew D. Rabdau
  • Patent number: 6673220
    Abstract: A method for fabricating silicon tiles and silicon tile targets has been provided, such as may be used in the sputter deposition of thin film transistor (TFT) silicon films. The method describes processes of cutting the tiles, beveling the tiles edges, etching the tiles to minimize residual damage caused by cutting the tiles, polishing the tiles to a specified flatness, and attaching the tiles to a backing plate. All these processes are performed with the aim of minimizing contamination and particle formations when the target is used for sputter deposition.
    Type: Grant
    Filed: May 21, 2001
    Date of Patent: January 6, 2004
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Apostolos Voutsas, John Hartzell
  • Patent number: 6673691
    Abstract: A method of changing the resistance of a perovskite metal oxide thin film device with a resistance-change-producing pulse includes changing the resistance of the device by varying the duration of a resistance-change-producing pulse.
    Type: Grant
    Filed: September 26, 2002
    Date of Patent: January 6, 2004
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Wei-Wei Zhuang, Sheng Teng Hsu
  • Patent number: 6673664
    Abstract: A method of making a self-aligned ferroelectric memory transistor includes preparing a substrate, shallow trench isolation, n the polysilicon; and forming a gate stack, including: depositing a layer of silicon nitride; selectively etching the silicon nitride, the bottom electrode and the polysilicon; selectively etching the polysilicon to the level of the first dielectric layer; and implanting and activating ions to form a source region and a drain region; forming a sidewall barrier layer; depositing a layer of ferroelectric material; forming a top electrode structure on the ferroelectric material; and finishing the structure, including passivation, oxide depositing and metallization.
    Type: Grant
    Filed: October 16, 2001
    Date of Patent: January 6, 2004
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Sheng Teng Hsu, Tingkai Li, Fengyan Zhang
  • Patent number: 6669870
    Abstract: A Cu(hfac) precursor with a substituted phenylethylene ligand has been provided. The substituted phenylethylene ligand includes bonds to molecules selected from the group consisting of C1 to C6 alkyl, C1 to C6 haloalkyl, C1 to C6 phenyl, H and C1 to C6 alkoxyl. One variation, the &agr;-methylstyrene ligand precursor has proved to be stable a low temperatures, and sufficiently volatile at higher temperatures. Copper deposited with this precursor has low resistivity and high adhesive characteristics. A synthesis method has been provided which produces a high yield of the above-described precursor.
    Type: Grant
    Filed: March 28, 2001
    Date of Patent: December 30, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Wei-Wei Zhuang, Tue Nguyen, Lawrence J. Charneski, David R. Evans, Sheng Teng Hsu
  • Patent number: 6664117
    Abstract: A method of forming a multi-layered, spin-coated perovskite thin film on a wafer includes preparing a perovskite precursor solution including mixing solid precursor material into acetic acid forming a mixed solution; heating the mixed solution in air for between about one hour to six hours; and filtering the solution when cooled; placing a wafer in a spin-coating mechanism; spinning the wafer at a speed of between about 500 rpm to 3500 rpm; injecting the precursor solution onto the wafer surface; baking the coated wafer at a temperature of between about 100° C. to 300° C.; annealing the coated wafer at a temperature of between about 400° C. to 650° C. in an oxygen atmosphere for between about two minutes to ten minutes; repeating the spinning, injecting, baking and annealing steps until a perovskite thin film of desired thickness is obtained; and annealing the perovskite thin film at a temperature of between about 500° C. to 750° C.
    Type: Grant
    Filed: September 26, 2002
    Date of Patent: December 16, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Wei-Wei Zhuang, Sheng Teng Hsu, Jong-Jan Lee
  • Patent number: 6664147
    Abstract: A method is provided to produce thin film transistors (TFTs) on polycrystalline films having a single predominant crystal orientation. A layer of amorphous silicon is deposited over a substrate to a thickness suitable for producing a desired crystal orientation. Lateral-seeded excimer laser annealing (LS-ELA) is used to crystallize the amorphous silicon to form a film with a preferred crystal orientation. The crystallized film is then polished to a desired thickness. A gate is formed overlying the polycrystalline film. The polycrystalline film is doped to produce source and drain regions.
    Type: Grant
    Filed: February 28, 2001
    Date of Patent: December 16, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventor: Apostolos Voutsas
  • Patent number: 6664116
    Abstract: A method of forming a ferroelectric thin film on a high-k layer includes preparing a silicon substrate; forming a high-k layer on the substrate; depositing a seed layer of ferroelectric material at a relatively high temperature on the high-k layer; depositing a top layer of ferroelectric material on the seed layer at a relatively low temperature; and annealing the substrate, the high-k layer and the ferroelectric layers to form a ferroelectric thin film.
    Type: Grant
    Filed: December 12, 2001
    Date of Patent: December 16, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Tingkai Li, Sheng Teng Hsu
  • Patent number: 6660628
    Abstract: A method of forming a titanium-based barrier metal layer includes preparing a substrate, including forming IC elements on the substrate; forming a titanium-based barrier metal precursor using a solution of about 5% by volume tetrakis (methylethylamino) titanium (TMEAT) and about 95% by volume octane; and depositing a titanium-based barrier layer on the substrate by MOCVD.
    Type: Grant
    Filed: March 17, 2003
    Date of Patent: December 9, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Wei Pan, Wei-Wei Zhuang, David R. Evans, Sheng Teng Hsu
  • Patent number: 6660576
    Abstract: A substrate and a method for fabricating variable quality substrate materials are provided. The method comprises: selecting a first mask having a first mask pattern; projecting a laser beam through the first mask to anneal a first area of semiconductor substrate; creating a first condition in the first area of the semiconductor film; selecting a second mask having a second mask pattern; projecting the laser beam through the second mask to anneal a second area of the semiconductor film; and, creating a second condition in the second area of the semiconductor film, different than the first condition. More specifically, when the substrate material is silicon, the first and second conditions concern the creation of crystalline material with a quantitative measure of lattice mismatch between adjacent crystal domains.
    Type: Grant
    Filed: March 11, 2002
    Date of Patent: December 9, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Apostolos Voutsas, Yasuhiro Mitiani, Mark A. Crowder
  • Patent number: 6654210
    Abstract: A solid-state inductor and a method for forming a solid-state inductor are provided. The method comprises: forming a bottom electrode; forming a colossal magnetoresistance (CMR) thin film overlying the bottom electrode; forming a top electrode overlying the CMR thin film; applying an electrical field treatment to the CMR thin film in the range of 0.4 to 1 megavolts per centimeter (MV/cm) with a pulse width in the range of 100 nanoseconds (ns) to 1 millisecond (ms); in response to the electrical field treatment, converting the CMR thin film into a CMR thin film inductor; applying a bias voltage between the top and bottom electrodes; and, in response to the applied bias voltage, creating an inductance between the top and bottom electrodes. When the applied bias voltage is varied, the inductance varies in response.
    Type: Grant
    Filed: April 22, 2002
    Date of Patent: November 25, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Wei Pan, Sheng Teng Hsu, Wei-Wei Zhuang
  • Patent number: 6649963
    Abstract: A method of forming a semiconductor memory device on a silicon substrate includes implanting doping impurities of a first type in the silicon substrate to form a conductive channel of a first type for use as a gate junction region, forming a MOS capacitor on the conductive channel of the first type, depositing an FEM capacitor over less than the entire area of the MOS capacitor, thereby forming a stacked gate unit, implanting doping impurities of a second type in the silicon substrate on either side of the gate junction region to form a conductive channel of a second type for use as a source junction region and a drain junction region, and depositing an insulating structure about the FEM gate unit.
    Type: Grant
    Filed: December 6, 1999
    Date of Patent: November 18, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Sheng Teng Hsu, Jong Jan Lee
  • Patent number: 6649957
    Abstract: A polycrystalline memory structure is described for improving reliability and yield of devices employing polycrystalline memory materials comprising a polycrystalline memory layer, which has crystal grain boundaries forming gaps between adjacent crystallites overlying a substrate. An insulating material is located at least partially within the gaps to at least partially block the entrance to the gaps. A method of forming a polycrystalline memory structure is also described. A layer of material is deposited and annealed to form a polycrystalline memory material having gaps between adjacent crystallites. An insulating material is deposited over the polycrystalline memory material to at least partially fill the gaps, thereby blocking a portion of each gap.
    Type: Grant
    Filed: January 15, 2003
    Date of Patent: November 18, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Sheng Teng Hsu, Tingkai Li, Fengyan Zhang, Wei-Wei Zhuang
  • Patent number: 6649457
    Abstract: A method of isolating a CMOS device on a silicon on insulator substrate, wherein the substrate includes an insulating layer of top silicon formed thereon, includes growing a gate oxide layer on the top silicon layer; depositing a first layer of material on the gate oxide layer; removing the first layer of material, the gate oxide layer and the top silicon layer from a device field region; forming an insulating cup about the first layer of material, the gate oxide layer and the top silicon layer; depositing a second layer of material over the first layer of material and the insulating cup; etching the first layer of material and the second layer of material to form a gate electrode; implanting ions to form a source region and a drain region; passivating the structure; and metallizing the structure.
    Type: Grant
    Filed: September 24, 2001
    Date of Patent: November 18, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventor: Sheng Teng Hsu
  • Patent number: 6649032
    Abstract: A method has been provided for forming a polycrystalline silicon (p-Si) film with a small amount of hydrogen. Such a film has been found to have excellent sheet resistance, and it is useful in the fabrication of liquid crystal display (LCD) panels made from thin film transistors (TFTs). The low hydrogen content polycrystalline silicon films are made from introducing a small amount of hydrogen gas, with Ar, during the sputter deposition of an amorphous silicon film. The hydrogen content in the film is regulated by controlling the deposition temperatures and the volume of hydrogen in the gas feed during the sputter deposition. The polycrystalline silicon film results from annealing the low hydrogen content amorphous silicon film thus formed.
    Type: Grant
    Filed: May 21, 2001
    Date of Patent: November 18, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventor: Apostolos Voutsas
  • Patent number: 6645454
    Abstract: A method is provided for maintaining a planar surface as crystal grains are laterally grown in the fabrication of crystallized silicon films. The method comprises: forming a film of amorphous silicon with a surface and a plurality of areas; irradiating each adjacent areas of the silicon film with a first sequence of laser pulses; and, in response to the first sequence of laser pulses, controlling the planarization of the silicon film surface between adjacent areas of the silicon film as the crystal grains are laterally grown. By controlling the number of laser pulses in the sequence, the temporal separation between pulses, and the relative intensity of the pulses, the lateral growth length characteristics of the crystal grains can be traded against the silicon film flatness. A silicon film formed by a pulsed laser sequence crystallization process is also provided.
    Type: Grant
    Filed: June 28, 2001
    Date of Patent: November 11, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventor: Apostolos Voutsas
  • Patent number: 6642092
    Abstract: A method for is provided forming a thin-film transistor (TFT) on a flexible substrate. The method comprises: supplying a metal foil substrate such as titanium (Ti), Inconel alloy, stainless steel, or Kovar, having a thickness in the range of 10 to 500 microns; depositing and annealing amorphous silicon to form polycrystalline silicon; and, thermally growing a gate insulation film overlying the polycrystalline. The silicon annealing process can be conducted at a temperature greater than 700 degrees C. using a solid-phase crystallization (SPC) annealing process. Thermally growing a gate insulation film includes: forming a polycrystalline silicon layer having a thickness in the range of 10 to 100 nanometers (nm); and, thermally oxidizing the film at temperature in the range of 900 to 1150 degrees for a period of time in the range of 2 to 60 minutes. Alternately, a plasma oxide layer is deposited over a thinner thermally oxidized layer.
    Type: Grant
    Filed: July 11, 2002
    Date of Patent: November 4, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Apostolos T. Voutsas, John W. Hartzell, Masahiro Adachi
  • Patent number: 6642138
    Abstract: A method is provided to deposit and pattern a sacrificial polymer, and form metal layers. A double hard mask is used to pattern and etch the sacrificial polymer. The double hard mask may be formed at temperatures below 400° C. The sacrificial polymer is capable of being decomposed to become air gaps during annealing.
    Type: Grant
    Filed: March 29, 2002
    Date of Patent: November 4, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Wei Pan, Sheng Teng Hsu
  • Patent number: 6635555
    Abstract: A method is provided to produce thin polycrystalline films having a single predominant crystal orientation. The method is well suited to the production of films for use in production of thin film transistors (TFTs). A layer of amorphous silicon is deposited over a substrate to a thickness suitable for producing a desired crystal orientation. Lateral-seeded excimer laser annealing (LS-ELA) is used to crystallize the amorphous silicon to form a film with a preferred crystal orientation. The crystallized film is then polished to a desired thickness for subsequent processing.
    Type: Grant
    Filed: February 28, 2001
    Date of Patent: October 21, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventor: Apostolos Voutsas
  • Patent number: 6632731
    Abstract: A method of fabricating a sub-micron MOS transistor includes preparing a substrate, including isolating an active region therein; depositing a gate oxide layer; depositing a first selective etchable layer over the gate oxide layer; depositing a second selective etchable layer over the first selective etchable layer; etching the structure to undercut the first selective etchable layer; implanting ions in the active region to form a source region and a drain region; depositing and planarizing the oxide; removing the remaining first selective etchable layer and the second selective etchable layer; depositing a gate electrode; and depositing oxide and metallizing the structure. A sub-micron MOS transistor includes a substrate; and an active region, including a gate region having a length of less than one micron; a source region including a LDD source region; and a drain region including a LDD drain region.
    Type: Grant
    Filed: February 14, 2001
    Date of Patent: October 14, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Yanjun Ma, David Russell Evans, Yoshi Ono, Sheng Teng Hsu
  • Patent number: 6630396
    Abstract: A plasma enhanced chemical vapor deposition (PECVD) process is provided for depositing one or more dielectric material layers on a substrate for use in interconnect structures of integrated circuits. The method comprises the steps of depositing a fluorinated amorphous carbon (a-F:C) layer on a substrate by providing a fluorine containing gas, preferably octafluorocyclobutane, and a carbon containing gas, preferably methane, in ratio of approximately 5.6, so as to deposit a a-F:C layer having an internal compressive stress of approximately 28 MPa. After deposition the film is annealed at approximately 400° C. for approximately two hours. An adhesion promoter layer of relatively hydrogen-free hydrogeneated silicon carbide is then deposited on the a-F:C layer using silane (SiH4) and methane (CH4) as the deposition gases.
    Type: Grant
    Filed: August 27, 2002
    Date of Patent: October 7, 2003
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Hongning Yang, Tue Nguyen