Abstract: The present invention relates to a process for forming a composition comprising oligomeric alkylaluminoxane, e.g., preferably methylaluminoxane, and moieties having the structure--OC(R).sub.3, where R is, for example, methyl, which comprises initially treating a composition comprising trialkylaluminum with a reagent containing a carbon-oxygen double bond, such as, carbon dioxide, followed by hydrolysis of the resulting composition with water.Another embodiment of the invention a composition comprising oligomeric methylaluminoxane and greater than 10 mole % of moieties of the structure --OC(R).sub.3, where R is methyl, which, when such composition is hydrolyzed, there is an evolution of hydrolysis products of methane and at least one C.sub.2 or higher alkane, such as t-butane.

Abstract: Process for the batchwise preparation of poly-p-phenylene terephthalamide polymer by means of reacting approximately equimolar amounts of p-phenylene diamine and terephthaloyl dichloride in a solution containing N-methyl-2-pyrrolidone and calcium chloride, with the reaction being carried out in a cylindrical reaction vessel equipped with a single mixing gear used as stirrer and granulator, the contents of the reaction vessel being whirlingly mixed as terephthaloyl dichloride is added, the formed polymer being crumbled, and the reaction and the crumbling taking place in one and the same reaction vessel. The whirling miming ensures that the terephthaloyl dichloride is very thoroughly mixed into the solution of N-methyl-2-pyrrolidone, calcium chloride, and p-phenylene diamine before the reaction between the reactants causes a very rapid increase in viscosity. The quality of She product obtained by this process is very high.

Abstract: Catalyst residues are removed from polyketone compositions by use of a beta diketone compound, e.g., an acetylacetone reagent.

Abstract: The durability of a supported noble metal hydrodechlorination catalyst can be improved by (1) treating the supported catalyst, which comprises support and catalytic noble metal, with a non-elemental halide compound, which is not a mineral acid (such as an alkali metal halide, an ammonium halide, an alkaline earth metal halide, and/or a halogenated hydrocarbon); and (2) then using the treated catalyst in a hydrodechlorination reaction. Suitable treatment compounds include ammonium chloride, lithium chloride, or a chlorinated hydrocarbon. The treated catalyst is a novel composition of matter comprising at least one platinum group metal supported by an oxidic support wherein the metal, which is in the zero valent state, predominantly resides adjacent the surface of the support and is predominantly visible under a microscope having a resolution of about 5 .ANG..

Abstract: Essentially mesoporous titanium oxide materials, having an average pore diameter of no more than about 100 .ANG. (e.g., from about 20 .ANG. to about 50 .ANG.) and an average surface area of no less than about 300 m.sup.2 /gm, preferably no less than about 500 m.sup.2 /gm are disclosed which optionally can contain an effective amount of at least one transition metal (e.g., a rare earth metal, iron, or the like) for stabilization. These materials can be formed by treating a titanium source, which is derived from a titanium alkoxide, in an organic-aqueous solution, with an organic structure directing agent (e.g., higher alkyl amine, optionally in the presence of an alcohol cosolvent) to form meso-sized micelles and hydrothermally treating the resulting composition.

Abstract: A process for the synthesis of a catalyst for the polymerization of carbon monoxide and at least one olefin which comprises treating a mixture of a compound of palladium, such as tetrakis(acetonitrile) palladium, and a Lewis acid anion, such as a fluoride of a metal selected from Group III to Group V of the Periodic Table (e.g., boron trifluoride), with carbon monoxide and an olefin followed by reaction of the resulting composition with a bidentate ligand reagent, such as a 1,3-bis(diphenyl-phosphino) alkane (e.g., 1,3-bis(diphenyl-phosphino) propane).

Abstract: Benzene phosphorus dichloride can be prepared by the reaction of benzene and phosphorus trichloride in the presence of a catalytically effective amount of a Friedel-Crafts catalyst, such as aluminum trichloride or ferric trichloride, at elevated temperature, such as from about 200.degree. C. to about 250.degree. C., and superatmospheric pressure, such as no less than the vapor pressure of the components at the chosen reaction temperature, to insure a liquid reaction medium.

Abstract: The invention pertains to a non-linear optically active (NLO) side chain polycarbonate and to NLO active waveguides containing said polycarbonate. Waveguides containing this NLO polycarbonate have a low loss of signal. Polycarbonates based on bischloroformates of hexafluorobisphenol A, hexafluorotetrabromobisphenol A and bisphenol S or deuterated bisphenol A or sulphonylbiphenol are especially preferred within the framework of the invention: they were found to give an exceptionally low loss of signal. The invention further pertains to cross-linkable and already cross-linked polycarbonates. Especially preferred polycarbonates according to the invention are those where the diol comprises a rigid donor group. These polycarbonates have a high Tg, which renders them thermally stable.

Abstract: The disclosure teaches a blend of a predominant amount of a polyphosphate flame retardant and an effective amount of a liquid crystalline additive for viscosity reduction and compatibilization when blended with a thermoplastic polymer, as compared to use of just the polyphosphate flame retardant alone. The polyphosphate can comprise resorcinol bis(diphenyl phosphate) and/or its higher oligomers. The liquid can be a liquid crystalline segmented block copolymer or a liquid crystalline oligomer.

Abstract: The invention relates to a polymeric optical amplifier doped with lanthanide ions, which are present in the amplifier in the form of a complex.The invention also relates to novel electrically neutral lanthanide complexes which can be applied with advantage in the above-described polymeric optical amplifiers. These complexes comprise host molecules which readily complex with the lanthanide and fully encapsulate it.

Abstract: The present invention is a flame retardant polyketone polymer composition which comprises: (a) a bicyclic phosphorus flame retardant compound, such as one containing one or more pentaerythritol phosphate alcohol moieties, as exemplified by bis(pentaerythritol phosphate alcohol) carbonate; (b) an intumescent flame retardant compound containing nitrogen and phosphorus, such as melamine phosphate; and (c), optionally, a monophosphate ester compound to enhance the compatibility of the composition in the polymer substrate, such as a liquid aryl-group containing phosphate ester compound or melamine phosphate, and the monophosphate ester compound is triphenyl phosphate.

Abstract: A process for manufacturing a multi-layer printed wire board, also referred to as a multilayer, comprising at least two electrically insulating substrates with electrically conductive traces or layers provided on at least three surfaces thereof, in which process, by means of lamination under pressure, a cured basic substrate based on a UD-reinforced synthetic material, provided on either side with traces, is combined with and bonded to a back-up substrate, wherein during the laminating process the back-up substrate is added to the basic substrate, the back-up substrate comprising a UD-reinforced cured core layer provided at least on the side facing the conducting traces of the basic substrate with a still plastically deformable (flowable) adhesive layer, and such a pressure is exerted on the laminate as to bring said cured core layer of the back-up substrate into contact or practically into contact with the conducting traces of the basic substrate, and the space between these traces is filled with the adhesiv

Abstract: The present application relates to a flame retarded polycarbonate resin composition containing for flame retardancy a hydroxy-terminated aromatic oligomeric phosphate composition of the formula: ##STR1## where R is a hydrocarbyl group derived from an aliphatic or aromatic diol, Ar is an alkyl-substituted or unsubstituted phenyl group, n is from about 0 to about 10, and the phosphate composition contains a predominant amount of phosphate where n ranges from 0 to 1.

Abstract: Novel flame retardant compounds for polymers are disclosed that include 1,4-cyclohexanedimethanol bis(diphenyl phosphate)s. These can be synthesized by reacting 1,4-cyclohexanedimethanol and a diphenyl halophosphate, such as diphenyl chlorophosphate, in the presence of a catalyst, such as magnesium chloride, in an appropriate solvent, such as hexane.

Abstract: A composition, adapted to be used in the beneficiation of coarse potash ore fractions in the substantial absence of extender oil, which consists essentially of: (a) water; and (b) a long chain primary aliphatic amine, for example, a tallow-based amine, having an iodine value of from about 20 to about 70 cg/g, preferably from about 40 to about 60 cg/g. The composition may further contain an acid to assist in the dispersion of the amine in water.

Abstract: Nitrogen-containing polymers can be formed by the reaction of a polyketone, such as a copolymer of carbon monoxide and propylene, and an amino acid or derivative thereof, such as aspartic acid or glycine.

Abstract: A process for manufacturing a multi-layer printed wire board, also referred to as a multilayer, comprising at least two electrically insulating substrates with electrically conductive traces or layers provided on at least three surfaces thereof, in which process, by means of lamination under pressure, a cured basic substrate based on a UD-reinforced synthetic material, provided on either side with traces, is combined with and bonded to a back-up substrate, wherein during the laminating process the back-up substrate is added to the basic substrate, the back-up substrate comprising a UD-reinforced cured core layer provided at least on the side facing the conducting traces of the basic substrate with a still plastically deformable (flowable) adhesive layer, and such a pressure is exerted on the laminate as to bring said cured core layer of the back-up substrate into contact or practically into contact with the conducting traces of the basic substrate, and the space between these traces is filled with the adhesiv

Abstract: The invention pertains to a non-linear optically active (NLO) side chain polycarbonate and to NLO active waveguides containing said polycarbonate. Waveguides containing this NLO polycarbonate have a low loss of signal. Polycarbonates based on bischloroformates of hexafluorobisphenol A, hexafluorotetrabromobisphenol A and bisphenol S or deuterated bisphenol A or sulphonylbiphenol are especially preferred within the framework of the invention: they were found to give an exceptionally low loss of signal. The invention further pertains to cross-linkable and already cross-linked polycarbonates. Especially preferred polycarbonates according to the invention are those where the diol comprises a rigid donor group. These polycarbonates have a high Tg, which renders them thermally stable.

Abstract: The invention relates to a polymeric optical amplifier doped with lanthanide ions, which are present in the amplifier in the form of a complex. The invention also relates to novel electrically neutral lanthanide complexes which can be applied with advantage in the above-described polymeric optical amplifiers. These complexes comprise host molecules which readily complex with the lanthanide and fully encapsulate it.

Abstract: The present invention is in the field of retardation layers for liquid crystalline displays, more particularly in the field of retardation layers based on super-twisted nematic (STN) liquid crystalline layer. In the retardation layers of the present invention the liquid crystalline polymer is placed between glass substrates wherein at least one substrate has a thickness of 20-500 micrometers. The use of such thin glass substrates reduces the weight and thickness of the retardation layer.The LC polymer film may also be placed between the substrate of the display cell and a thin glass substrate or between the polarizer and a thin glass substrate. In these embodiments of the invention a second thin glass substrate is not necessary and the thickness and weight of the retardation layer is further reduced.