Abstract: A method of breaking oil-in-water and water-in-oil emulsions in crude oil processing systems in which copolymers incorporating a hydrophilic cationic monomer subunit and a lipophilic nonionic monomer subunit or dispersions or emulsions of cationic polymers and obverse demulsifiers are employed.
Type:
Grant
Filed:
December 31, 1997
Date of Patent:
July 13, 1999
Assignee:
BetzDearborn Inc.
Inventors:
Paul R. Hart, Fu Chen, Wen P. Liao, Walter J. Burgess
Abstract: A method for inhibiting foam formation in a stripper of an amine unit is disclosed. The addition of non-foaming demulsifiers to the liquid, compressed hydrocarbon stream entering or the aqueous organic amine stream entering or exiting an absorber of an amine unit effectively inhibits foam formation in the amine unit stripper. Foam formation in the stripper is inhibited by controlling the entrainment of hydrocarbon in the alkaline amine stream entering the stripper through demulsification treatment in the absorber.
Abstract: An anionic polyacrylamide pretreatment for a metal surface which enhances corrosion resistance and surface adhesion properties is described. The pretreatment is stable at extreme pH's and compatible with other water soluble polymers. The anionic polyacrylamide includes mono- or di-alkyl substitutions on the N group of the polyacrylamide.
Abstract: A method of removing layers of heat cured paint buildup on supporting hangers is disclosed. The method includes coating support hangers with a layer of a thermally expandable material in a water soluble carrier and thereafter applying a water insoluble coating layer. The thermally expandable material, the carrier and the water insoluble coating are all selected so as to be relatively unaffected by the curing temperatures of the paint line where the hangers are to be used. When an undesirably thick coating of cured paint has built-up on the hangers, it is removed by heating to a temperature sufficient to expand the thermally expandable material thereby cracking the paint layers. Thereafter, the hangers are soaked in a hot aqueous solution to dissolve the carrier layer and remove the cracked, cured paint layers.
Type:
Grant
Filed:
October 22, 1997
Date of Patent:
May 18, 1999
Assignee:
BetzDearborn Inc.
Inventors:
David B. Mitchell, Ralph L. Minnis, Gene V. Wayman, Steven M. DeBoo, Mark J. Deschryver
Abstract: A composition for of controlling scale formation and deposition and corrosion in aqueous systems is described wherein a treatment solution of a substoichiometric amount of a composition comprising a scale/corrosion inhibitor in combination with a substituted alkylpolycarboxylate is employed. The scale/corrosion inhibitor can be a phosphonate such as hydroxyethylidene diphosphonic acid, 2-phosphonobutane-1,2,4-tricarboxylic acid, hydroxyphosphonoacetic acids, amino phosphonates; terpolymers, copolymers and homopolymers of acrylic acid, maleic acid, epoxysuccinic acids such as polyepoxysuccinic acid or mixtures thereof. The substituted alkylpolycarboxylates are compounds of the general structure: R--X.sub.m --Y.sub.n wherein R is a hydrocarbon functionality having 4 to 18 carbons; X, when present, is --NH--, --NY.sup.1 --, --N-->O, --N--OC--Y.sup.1, --O-- or --S--; n is greater than or equal to 1; m=O or 1; and Y and Y.sup.
Type:
Grant
Filed:
November 18, 1997
Date of Patent:
February 2, 1999
Assignee:
BetzDearborn Inc.
Inventors:
William S. Carey, Libardo A. Perez, Donald T. Freese, Judith L. Barron
Abstract: The use of halo-benzotriazoles as corrosion inhibitors in aqueous systems is disclosed. Halo-benzotriazoles such as chloro-tolyltriazole and bromo-tolyltriazole were found to be more effective corrosion inhibitors than tolyltriazole in the presence of chlorine.
Type:
Grant
Filed:
June 10, 1998
Date of Patent:
January 26, 1999
Assignee:
BetzDearborn Inc.
Inventors:
David W. Reichgott, Sydia B. Anderson, Michael A. Cady, Roger C. May, Anita G. Monino
Abstract: The use of halo-benzotriazoles as corrosion inhibitors in aqueous systems is disclosed. Halo-benzotriazoles such as chloro-tolyltriazole and bromo-tolyltriazole were found to be more effective corrosion inhibitors than tolyltriazole in the presence of chlorine.
Type:
Grant
Filed:
February 27, 1998
Date of Patent:
January 26, 1999
Assignee:
BetzDearborn Inc.
Inventors:
David W. Reichgott, Sydia B. Anderson, Michael A. Cady, Roger C. May, Anita G. Monino
Abstract: An alpha-tocopherol is disclosed as a polymerization inhibitor effective against vinyl monomer polymerization. Alpha-tocopherol was found to inhibit polymerization of acrylonitrile and diolefines such as isoprene and butadiene. Alpha-tocopherol was found to interact synergistically with hydroquinone in inhibiting polymerization of acrylonitrile.
Abstract: Positive static electricity charges in air flow from an air washer generated by an industrial process are reduced and controlled to a desired level by treatment of the water circulating in the air washer with an anionic polymeric material such as water soluble, neutralized polyacrylate.
Type:
Grant
Filed:
April 22, 1997
Date of Patent:
December 22, 1998
Assignee:
BetzDearborn Inc.
Inventors:
Bobby J. Brown, Bruce K. Fillipo, David M. Polizzotti, Gregory J. Pomrink
Abstract: Methods and compositions for breaking oil and water emulsions are disclosed. Oil and water emulsions are broken by treating the emulsion with a copolymer of tannin and a cationic monomer. The preferred composition is an aqueous solution of a copolymer of tannin and a cationic monomer, a water soluble organic multivalent salt and a glycol. The preferred salt is aluminum chlorohydrate and the preferred glycol is hexylene glycol.
Type:
Grant
Filed:
July 24, 1997
Date of Patent:
December 22, 1998
Assignee:
BetzDearborn Inc.
Inventors:
Paul R. Hart, Jen-Chi Chen, Fu Chen, Thai H. Duong
Abstract: A method of preparing halo-benzotriazoles is disclosed. The method involves mixing an aqueous solution of sodium hypohalite with an aqueous slurry or suspension of a benzotriazole. Preferred sodium hypohalites are sodium hypochlorite or sodium hypobromite and the preferred benzotriazole is tolyltriazole.
Abstract: Compositions and methods for passivating galvanized metal surfaces are disclosed. The addition of a paraffin wax, preferably emulsified with nonionic surfactants to commercial passivation treatment (chrome or non-chrome) enhances passivation.
Abstract: The use of halo-benzotriazoles as corrosion inhibitors in aqueous systems is disclosed. Halo-benzotriazoles such as chloro-tolyltriazole and bromo-tolyltriazole were found to be more effective corrosion inhibitors than tolyltriazole in the presence of chlorine.
Type:
Grant
Filed:
January 3, 1997
Date of Patent:
June 30, 1998
Assignee:
BetzDearborn Inc.
Inventors:
David W. Reichgott, Sydia B. Anderson, Michael A. Cady, Roger C. May, Anita G. Monino
Abstract: The separation of black liquor, containing lignin, from tall oil is enhanced by the addition of a separation aid. The separation aid is an alkylphenol-formaldehyde resin alkoxylate, a poly (proplyene oxide) ethoxylate, an alkanol amine condensate, or combination thereof.
Abstract: A controlled-release supplement coolant additive for use in diesel engine coolant systems comprising a core containing at least one supplemental coolant additive (SCA) active component and a polymeric coating material encapsulating said core. The controlled released supplement coolant additive slowly releases the SCA active components to a diesel engine coolant system, thereby delivering an effective concentration level of SCA active components over an extended period. The controlled-release supplement coolant additive maintains a minimum concentration level of active SCA components in the coolant system. Additionally, the controlled-release supplemental coolant additive prevents overdosing the coolant system with particular SCA active components such as nitrates.
Type:
Grant
Filed:
June 21, 1996
Date of Patent:
April 21, 1998
Assignee:
BetzDearborn Inc.
Inventors:
Wayne A. Mitchell, Kurt D. Heinz, Clifford Alvin Ferrin, Jr., Narender Pal Luthra
Abstract: Oil-in-water (reverse) and water-in-oil (obverse) emulsions in crude oil production and processing systems are resolved by addition of a treatment solution comprising a copolymer of acryloxyethyltrimethyl ammonium chloride (AETAC) and acrylamide. The mole percent of AETAC is above about 20% and the molecular weight (grams per mole) of the copolymer is above about 2 million. The treatment solution is effective in matrix which include high percentages of oil and at high temperatures.
Type:
Grant
Filed:
June 21, 1994
Date of Patent:
March 24, 1998
Assignee:
BetzDearborn Inc.
Inventors:
Paul R. Hart, J. Michael Brown, Edward J. Connors
Abstract: A polymer and method of controlling corrosion and the formation and deposition of scale imparting compounds in water systems is disclosed. The polymer has the general structure: ##STR1## wherein E.sup.1 comprises the repeat unit obtained after polymerization an .alpha.,.beta. ethylenically unsaturated carboxylic acid monomers, lower alkyl (C.sub.1 -C.sub.6) ester or a hydroxylated lower alkyl (C.sub.1 -C.sub.6) ester of such carboxylic acid, or amide forms thereof; E.sup.2 comprises the repeat unit obtained after polymerization of an .alpha.,.beta. ethylenically unsaturated monomer containing a sulfonic acid functionality; R.sup.1 is a hydrogen or a lower (C.sub.1 -C.sub.3) alkyl; R.sup.2 is --CH.sub.2 --O-- or --C(.dbd.O)--O--; R.sup.3 is --?--CH.sub.2 --CH(--CH.sub.2 --OH)--O--!--.sub.n ; n is an integer greater than 1; and R.sup.
Abstract: Compositions and methods for passivating galvanized metal surfaces are disclosed. The addition of a paraffin wax, preferably emulsified with nonionic surfactants to commercial passivation treatment (non-chrome) enhances passivation.
Abstract: A boom system having a flexible barrier is supported by floats on offset arms. The offset arms and floats thereon are mounted to the barrier in a manner which allows the angle between the barrier and the offset arms to be easily varied. The orientation of the barrier with respect to the surface the boom system is disposed on can thus be easily varied to account for variations in wind, waves and currents. Furthermore, the orientation of the barrier is controlled without the use of ballast weights.
Type:
Grant
Filed:
July 19, 1995
Date of Patent:
December 9, 1997
Assignee:
BetzDearborn Inc.
Inventors:
James F. Echols, Marvin Echols, deceased
Abstract: Methods and compositions for breaking oil and water emulsions are disclosed. Oil and water emulsions are broken by treating the emulsion with a copolymer of tannin and a cationic monomer. The preferred composition is an aqueous solution of a copolymer of tannin and a cationic monomer, a water soluble organic multivalent salt and a glycol. The preferred salt is aluminum chlorohydrate and the preferred glycol is hexylene glycol.
Type:
Grant
Filed:
June 3, 1996
Date of Patent:
December 2, 1997
Assignee:
BetzDearborn Inc.
Inventors:
Paul R. Hart, Jen-Chi Chen, Fu Chen, Thai H. Duong