Abstract: A process for the production of epoxide ring opening products having a defined residual epoxide oxygen content by reaction of epoxides with nucleophiles in the presence of medium-strength acids is provided. The products have a defined residual epoxide oxygen content of 10 to 80% by weight based on the epoxide. In the process, aliphatic epoxidized olefins or aliphatic epoxidized esters are reacted with nucleophiles in the presence of 1 to 4 g phosphoric acid, phosphorous acid, or hypophosphorous acid per mol epoxide and the ring opening product is directly obtained without neutralization of the catalyst acid.
Type:
Grant
Filed:
November 4, 1993
Date of Patent:
January 10, 1995
Assignee:
Henkel Kommanditgesellschaft Auf Aktien
Inventors:
Peter Daute, Roland Gruetzmacher, Nicole Mertscheit
Abstract: The following water soluble materials are all satisfactory internal accelerators for otherwise conventional zinc phosphate conversion coating solutions: reducing sugars, starch, urea, and poly{acrylates and methacrylates}. Concentrates including these ingredients and otherwise conventional constituents of zinc phosphate conversion coating compositions, except for excluding conventional accelerators other than nitrate, are stable in composition during storage, unlike most conversion coating compositions containing conventional accelerators. Thus concentrates according to the invention are practical single-package concentrates that can be made into working phosphating compositions by dilution with water only.
Abstract: A combination of phosphonoinidazoline at surfactant, soluble polyvalent metal ions, and a metal etching component, which is tolerant of aluminum cations and aluminate anions, when used as the Stage 4 rinse for aluminum cans provides good can mobility and good resistance to loss of mobility during heating of the treated cans to a greater extent than is normal during high speed processing. A concentrate of the active ingredients of such a Stage 4 treatment also maintains its effectiveness for longer than do similar produels when stored at high ambient temperatures.
Abstract: Methods of use of carbonic acid esters corresponding to general formula I: ##STR1## in which R.sup.1 is an alkyl radical derived from an aliphatic saturated primary alcohol containing 1 to 22 carbon atoms and R.sup.2 is an alkyl radical derived from an aliphatic, saturated primary alcohol containing 1 to 8 carbon atoms and/or has the same meaning as R.sup.1 and n is a number of 2 to 20 while m is 0 or has the same meaning as n, as foam control agents for the sugar beet or potato-processing food industry and/or in fermentation processes are provided. In the industrial processing of sugar-containing plant juices, as carried out on an industrial scale in the case of sugar beet, particular difficulties are caused by excessive foaming in the defecation units, during transport of the beet, in the diffusors and in the carbonizing tanks and before the evaporators, thus, use of the esters in these processes is advantageous.
Type:
Grant
Filed:
August 17, 1993
Date of Patent:
January 3, 1995
Assignee:
Henkel Kommanditgesellschaft Auf Aktien
Inventors:
Ulrike Mahler, Alfred Westfechtel, Hans-Juergen Sladek, Sylke Kielmann
Abstract: An apparatus and method is provided wherein the foam inhibiting effectiveness of defoaming and antifoaming additives on various types of foamable liquid mediums is measured. A single generally cylindrical foam cell having openings at both ends is provided wherein an interchangeable foam cell insert having varied geometry is longitudinally disposed within the foam cell. The foam cell insert is provided with a plurality of centralizer walls extending into the foam cell with an agitator member being carried by the centralizer walls. Foamable liquid medium is introduced into the foam cell and recirculated therethrough to form a dynamic fluid-flow system. As the liquid medium passes through both the foam cell and the foam cell insert, it comes into contact with the agitator member carried by the centralizer walls of the foam cell insert forming foam which accumulates in the foam cell.
Type:
Grant
Filed:
December 13, 1993
Date of Patent:
December 27, 1994
Assignee:
Henkel Corporation
Inventors:
Richard Gerke, Jose M. Rodriguez, John J. Palmer
Abstract: A process for the production of surface-active alkyl glycosides which is carried out by the transacetalization method with butanol, leads to a new alkyl glycoside as end product which is characterized by high color-stability in alkaline medium; besides a high proportion of alkyl monoglycoside, the product also contains polyglycoside on polyglycose and butyl glucoside.
Type:
Grant
Filed:
April 27, 1990
Date of Patent:
December 20, 1994
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Manfred Biermann, Karlheinz Hill, Willi Wuest, Rainer Eskuchen, Josef Wollmann, Andreas Bruns, Guenter Hellmann, Karl-Heinz Ott, Walter Winkle, Klaus Wollmann
Abstract: A one-component moulding and sealing compound based on prepolymers with terminal silyl groups with at least one hydrolyzable substituent on the Si atom, organo-metallic tin compounds as the catalyst and also inorganic fillers containing a polyvinyl chloride and fatty acid amide having thixotropic effect to reduce surface tackiness.
Type:
Grant
Filed:
July 14, 1993
Date of Patent:
December 13, 1994
Assignee:
Teroson GmbH
Inventors:
Gabriele Bride, Gisbert Kern, Wolfgang Lepka, Michael Schatzle
Abstract: A latex which affords a film having superior heat resistance, gloss, and transparency is comprised of: (1) water; (2) a styrene-maleic anhydride copolymer solubilized by a solubilizing amount of ammonium hydroxide; (3) a graft copolymer which is comprised of a portion of the solubilized styrenemaleic anhydride copolymer onto which is grafted a polymer formed from the polymerization of one or more polymerizable ethylenically unsaturated monomers selected from the group consisting of an acrylate, a methacrylate, an aromatic alkenyl monomer, an aliphatic alkenyl monomer, and combinations thereof; (4) a polymer dispersed in the water which is comprised of one or more ethylenically unsaturated monomers selected from the group consisting of an acrylate, a methacrylate, an aromatic alkenyl monomer, an aliphatic alkenyl monomer, and combinations thereof dispersed in the water; (5) a nonionic or anionic surfactant, or a combination thereof; and, (6) optionally, zinc or zirconyl ammonium carbonate.
Type:
Grant
Filed:
January 13, 1994
Date of Patent:
December 13, 1994
Assignee:
Henkel Corporation
Inventors:
George A. Smith, Steven P. Boucher, Reuben H. Grinstein
Abstract: A process of retaining or enhancing corrosion resistance of autodeposited coatings on metallic surfaces by contacting the uncured coating on the metallic surface with a rinse solution containing hydrofluorozirconic acid or a salt thereof, such as nickel or cobalt salt. The metallic surface may be cold rolled steel or galvanized steel. The resinous autodeposited coatings are poly{vinylidene chloride} polymers. Copolymers containing at least 50% by weight poly{vinylidene chloride} are suitable. Because the protective properties of the autodeposited coatings are improved on both types of steel, both may be processed simultaneously, providing practical and economic advantages.
Abstract: In a process for phosphatizing electrolytically and/or hot-dip galvanized steel strip, the steel strip is briefly treated with acidic phosphatizing solutions which contain, in addition to zinc and phosphate ions, manganese and nickel cations and anions of oxygen-containing acids with an accelerator effect. The weight ratio of nickel cations to nitrate anions is adjusted to between 1:10 and 1:60 and the weight ratio of manganese cations nitrate anions is adjusted to between 1:1 and 1:40.
Abstract: Addition of alkyl and/or alkenyl polyalkylene glycol ethers as filtration aids in the filtration and/or dehydration of mineral or coal suspensions reduces the dehydration time, and filter cakes with a low residual moisture content are obtained.
Type:
Grant
Filed:
December 15, 1992
Date of Patent:
December 13, 1994
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Rita Koester, Horst Speckmann, Wolfgang von Rybinski, Dieter Koeppl
Abstract: The invention is a two-component film-forming reactive system for heat-sealable materials. The composition contains at least one resin which is curable with an epoxide and an epoxide compound as a curing agent. The resin which is curable with the epoxide is a mixture of a carboxyl or hydroxyl terminated polyurethane with an acrylate or methacrylate polymer or copolymer having hydroxyl or carboxyl groups.
Abstract: A corrosion resistant film with a low coefficient of friction that facilitates automatic conveying can be formed on the surface of tin-plated steel or of aluminum, particularly DI cans of one of these types of metal, by contacting the aluminum or the tin plated steel with an aqueous liquid composition having a pH in the range from 2.0 to 6.5 and containing:(A) from 1 to 30 g/L of phosphate ions,(B) from 0.1 to 10 g/L of condensed phosphate ions, and(C) from 0.1 to 20 g/L as solids of water-soluble polymers of N-vinylphenol substituted on the phenolic rings with dialkylaminomethyl groups.
Abstract: A process for the preparation of polyether polyamines comprising the steps ofA) reacting a polyol with an epihalohydrin in the presence of a catalyst;B) adding an at least equimolar quantity of an aqueous alkali metal hydroxide, based on the weight of catalyst, to the reaction mixture formed in step A);C) distilling volatile constituents from the reaction mixture from step B) at a temperature below about 150.degree. C. and under a pressure below about 1.33.times.10.sup.4 Pa.;D) filtering the reaction mixture remaining after step C) at a temperature in the range of from about 80.degree. C. to about 100.degree. C. to remove insoluble components thereof from the bishalohydrin reaction product; andE) reacting the bishalohydrin reaction product with ammonia and/or an amine in the presence of an alkaline catalyst to form a polyether polyamine.
Abstract: The invention addressed the problem of improving the adhesive strength of a dimensionally stable, soft-rubbing adhesive stick consisting of an aqueous preparation of a synthetic polymer and a soap gel as gel-forming component and, optionally, other auxiliaries. This problem was solved by the use of an at least substantially solvent-free aqueous polyurethane dispersion as the aqueous preparation of a synthetic polymer.
Type:
Grant
Filed:
February 19, 1992
Date of Patent:
December 6, 1994
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Gerhard Gierenz, Wolfgang Klauck, Rainer Hoefer, Roland Gruetzmacher
Abstract: The invention is an aqueous softening filler for leather and a process for softening leather which utilizes the softening filler. The softening filler comprises thermoexpansible microcapsules. The thermoexpansible microcapsules are impregnated into the leather from an aqueous dispersion or from a mixture containing the thermoexpansible microcapsules and fat liquor. After the leather is impregnated with the thermoexpansible microcapsules, the leather is heated to a temperature above which the thermoexpansible microcapsules expand. The process improves the softness of the leather.
Abstract: An effective lubricant for cold working of metals is provided by a combination of a water soluble copolymer of styrene with maleic anhydride, maleic acid, and/or an ammonium or substituted ammonium maleate salt with an ethoxylated alcohol, preferably an alcohol with at least 40 carbon atoms before ethoxylation and about 50% of its mass in the polyoxyethylene block in the molecule.
Abstract: A plastic container package for bulk materials, such as liquids or pourable fine granules or the like, is surrounded on the outside by a close-fitting cardboard or paper jacket. The container has, at least in regions, an upper stopping edge for the cardboard jacket. To fit the container with a printable and easily removable streamer, the plastic container includes catch ramps in the form of stopping shoulders protruding from a transition region between a bottom face and associated side faces. In the position of use, the cardboard jacket is designed as a closed streamer which is fixed between the stopping shoulders by pushing it over the catch ramps.
Abstract: A chromating composition including hexavalent and trivalent chromium, phosphate ions, silica, and a silane coupling agent and with ratios among its components within certain specified ranges produces a protective layer on the surface of zinc coated steel treated with the composition that has an excellent alkali resistance, corrosion resistance, coatability, and welding tolerance.
Type:
Grant
Filed:
April 7, 1993
Date of Patent:
November 22, 1994
Assignee:
Henkel Corporation
Inventors:
Takao Ogino, Arata Suda, Takayuki Aoki, Mitsuyuki Koga
Abstract: A wet strength resin composition is comprised of an aminopolyamide-epichlorohydrin acid salt resin having a total organically bound chlorine of up to 0.7% by weight of the resin. The amount of total organically bound chlorine present is controlled by the process parameters.