Patents Represented by Attorney, Agent or Law Firm Wayne C. Jaeschke
  • Patent number: 5439953
    Abstract: Disclosed are materials and/or shaped articles based on a starch which has been thermomechanically digested at elevated pressures and temperatures and with the addition of water and/or lower molecular weight plasticizing agents, said starch containing thermoplastic synthetic polymer compounds in an at least largely homogeneous mixture. The materials and/or shaped articles according to the invention are characterized in that their contents of synthetic thermoplastic polymer compounds is derived from aqueous polymer dispersions comprising a disperse polymer phase in an aqueous phase and that the synthetic thermoplastic polymer compounds have been incorporated in the starch in combination with the aqueous phase in such a manner that the starch digestion has been effected by the concomitant use of the aqueous phase of the polymer dispersions.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: August 8, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wolfgang Ritter, Rainer Bergner, Wolfgang Kempf
  • Patent number: 5439671
    Abstract: Process for the production of a neutral-tasting paste of an alkyl ether sulfate in glycerol, comprising the steps of:A) forming an aqueous paste of at least one alkyl ether sulfate wherein the aqueous paste contains from about 25 to about 75% by weight of alkyl ether sulfate;B) adding glycerol to the aqueous paste from step A) in from about 1 to about 4 times the quantity by weight of the aqueous paste;C) distilling off substantially all of the water present in the mixture resulting from step B) to produce a substantially ambydrous paste; andD) passing steam heated to a temperature above 100.degree. C. through skid paste with intensive whirling of the paste and steam phases.
    Type: Grant
    Filed: March 28, 1994
    Date of Patent: August 8, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Achim Ansmann, Willi Breitzke, Karl-Heinz Gantke
  • Patent number: 5439709
    Abstract: The invention relates to the use of C.sub.8-22 fatty acid methyl esters in lubricants for card spinning, to a process for lubricating textile fibers for the production of carded yarns and to lubricants containing C.sub.8-22 fatty acid methyl esters and (meth)acrylates having limiting viscosities below 400 ml .multidot.g.sup.-1, as measured in tetrahydrofuran at 20.degree. C.
    Type: Grant
    Filed: January 26, 1994
    Date of Patent: August 8, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wolfgang Becker, Raymond Mathis, Ulrich Eicken, Karin Robrahn, Silvia Stapper-Druyen
  • Patent number: 5435845
    Abstract: Compositions and methods relating to cementitious compositions are provided. The use of a glucoheptonate in the alpha form to prolong the workability of cementitious compositions is provided. The alpha form of glucoheptonate (found to have properties superior to the beta form when used to retard the hydration of cementitious compositions) can be used in combination with a plasticizing resin, e.g. a naphthalenesulfonate/formaldehyde condensate resin, to prolong the workability of a cementitious composition, without unacceptably delaying green strength development. Also provided are mixtures of a glucoheptonate in the alpha form and a naphthalenesulfonate/formaldehyde condensate resin plasticizer.
    Type: Grant
    Filed: November 2, 1993
    Date of Patent: July 25, 1995
    Assignee: Henkel Corporation
    Inventors: Jose L. Villa, Zvi Grauer
  • Patent number: 5435841
    Abstract: This invention relates generally to insolubilizers for use with binders in paper coating compositions. There is provided a process for preparing both an insolubilizer and paper coating composition containing the insolubilizer and a binder which, when applied onto paper products, significantly enhances their wet-rub resistance.The insolubilizer is prepared by:(a) forming a glyoxal-urea adduct by reacting from about 1.0 to about 4.0 moles of glyoxal with about 1.0 mole of urea, at an elevated temperature,(b) cooling the glyoxal-urea adduct to room temperature,(c) adding from about 0.5 to about 2.0 moles of free glyoxal to the glyoxal-urea adduct to form an oligomer, and(d) adjusting the pH of the oligomer to from about 5 to about 7.
    Type: Grant
    Filed: May 25, 1994
    Date of Patent: July 25, 1995
    Assignee: Henkel Corporation
    Inventors: Nancy Clungeon, Gregory J. Flynn, Zhentao He, Jose M. Rodriguez
  • Patent number: 5434230
    Abstract: Compositions containing a radical-polymerizable olefinically unsaturated compound and a hydrazone of an aromatic aldehyde or ketone are provided. Also provided are methods for the production of such compositions and methods for the use of such compositions as an adhesive and sealing compound or its use for the coating and production of plastic moldings. The compositions polymerize radically at room temperature upon exposure to ambient air.
    Type: Grant
    Filed: January 11, 1994
    Date of Patent: July 18, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Thomas Huver, Petra P. Kremeyer, Wolfgang Klauck, Christian Nicolaisen, Lothar Kammer
  • Patent number: 5434301
    Abstract: A process for recovering sulfuric acid from a mixture containing sulfuric acid and organic sulfonation products is provided. The process comprises contacting a mixture comprised of sulfuric acid and (i) a naphthalene-based material selected from the group consisting of naphthalenesulfonic acids, lower-alkyl substituted naphthalenesulfonic acids, and mixtures of two or more of such materials, or (ii) an aromatic-based carbonyl condensate (preferably a material selected from the group consisting of formaldehyde condensates of naphthalenesulfonic acids, formaldehyde condensates of lower-alkyl substituted naphthalenesulfonic acids, and mixtures of two or more of such materials), with a basic anion exchange resin in essentially the sulfate form (and preferably in the form of essentially non-porous particles) to provide a raffinate liquid phase enriched with respect to said mixture in said naphthalene-based material and depleted with respect to said mixture in sulfuric acid.
    Type: Grant
    Filed: December 1, 1993
    Date of Patent: July 18, 1995
    Assignee: Henkel Corporation
    Inventor: William G. Kozak
  • Patent number: 5433775
    Abstract: The invention relates to a dimensionally stable, soft-rubbing adhesive stick consisting of a water-based preparation of starch derivatives and a soap gel as the shaping gel-forming component and, optionally, other auxiliaries. To obtain an adhesive stick which is largely based on natural raw materials and which may therefore be regarded as safe from ecological and toxicological standpoints, the invention is characterized in that viscosity-reduced starch ethers are present as the starch derivatives.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: July 18, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl-Josef Gardenier, Gerhard Gierenz, Wolfgang Klauck, Bernd Peters, Horst Donothek, Norbert Doering
  • Patent number: 5431840
    Abstract: In the new process, cleaning and care preparations for floors, shoes, leather and furniture are produced by mixing a wax emulsion containing alkyl glycoside as emulsifier with the other constituents of the preparation. The alkyl glycosides correspond to the following general formulaR--O(--G).sub.n Iin which R is a long-chain C.sub.8-22 alkyl radical, G is a glycoside-bonded residue of a monosaccharide and n has a value of 1 to 10. The wax emulsions are distinguished by particular particle fineness and extremely good compatibility with the other constituents of the preparations.
    Type: Grant
    Filed: June 21, 1993
    Date of Patent: July 11, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz-Dieter Soldanski, Bernd-Dieter Holdt, Juergen Noglich
  • Patent number: 5432275
    Abstract: A continuous method of bleaching an alkylpolyglycoside, substantially free of alcohol, with peroxy compounds, preferably hydrogen peroxide, which is highly efficient to provide an unexpected high degree of color reduction from a dark brown to a light, which product, from an extinction coefficient color respectively of about 10 to about 15 to about 0.025 to about 0.15. The bleaching is carried out at controlled pH and temperature, under pressure preferably in the presence of Mg. The use of a prebleached heel or feed prior to introduction of the unbleached material to be bleached results in a faster approach to equilibrium, steady state, bleaching conditions which results in minimum chemical usage and more rapid production of low color.
    Type: Grant
    Filed: February 25, 1994
    Date of Patent: July 11, 1995
    Assignee: Henkel Corporation
    Inventors: Patrick M. McCurry, Jr., James D. Beaulieu
  • Patent number: 5431729
    Abstract: Compositions and methods relating to cementitious compositions are provided. The use of a blend of a rosin and a tannin to entrain air into cementitious compositions is provided. A blend of a rosin and a tannin in a weight ratio of 10:1 to 1:10 are added to a wet cementitious composition at levels of less than 1% by weight based on the weight of the cement and air is mixed into the cement. The resulting cement will contain, e.g. 5% to 10% by volume air which improves the resistance of the set cement to freeze damage. Also provided is a method of entraining air into a cementitious composition which employs such a blend.
    Type: Grant
    Filed: April 12, 1994
    Date of Patent: July 11, 1995
    Assignee: Henkel Corporation
    Inventor: Timothy Hegge
  • Patent number: 5431780
    Abstract: The process of producing particulate, solid, pourable and free-flowing useful materials from water-containing preparations thereof by spray-drying in a hot gas stream under normal pressure wherein the hot gas stream is superheated steam, terminating the spray-drying of the materials before they are completely dry or damaged by heat effects, and then (a) mixing the spray-dried materials with an auxiliary component which is capable of binding residual quantities of water from the materials, or (b) further drying the spray-dried materials under conditions that will not damage the materials, or (c) post-treating the spray-dried materials in a manner as to homogenize the residual moisture in the materials.
    Type: Grant
    Filed: July 16, 1993
    Date of Patent: July 11, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wilfried Raehse, Volker Bauer
  • Patent number: 5429684
    Abstract: A water-based carpet cleaning composition containing 10% to 80% by weight of an alkali metal or ammonium salt of sulfonated oleic acid, up to 40% by weight of additional surfactant, up to 10% by weight of water-miscible organic solvent, up to 10% by weight of heavy metal complexing agent, 2 to 30% by weight of resoiling inhibitor, up to 1% by weight of antistatic agent, up to 3% by weight of preservatives, dyes and fragrances, and the balance, water.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: July 4, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Rainer Osberghaus, Karl-Heinz Rogmann, Herta Tuchermann, Ansgar Behler
  • Patent number: 5430131
    Abstract: Glycoside products having a propensity to discolor and/or to exhibit haze under aqueous alkaline or neutral pH conditions can be stabilized to substantially reduce the extent of discoloration and to essentially eliminate any haze which might also be present by adjusting the pH of a hydrogen peroxide-free aqueous solution of the alkyl glycoside product to about 7 prior to treatment with a metal borohydride material which at the end of the reaction period is consumed resulting in a stabilized alkyl polyglycoside product which does not exhibit a haze in an aqueous solution at a pH of about 7.
    Type: Grant
    Filed: June 8, 1994
    Date of Patent: July 4, 1995
    Assignee: Henkel Corporation
    Inventors: Patrick M. McCurry, Jr., Janet R. Varvil
  • Patent number: 5427632
    Abstract: A chromium free conversion coating at least equivalent in corrosion protective quality to conventional chromate conversion coatings can be formed on metals, particularly cold rolled steel, by a dry-in-place aqueous acidic liquid comprising:(A) a component of anions, each of said anions consisting of (i) at least four fluorine atoms and (ii) at least one atom of an element selected from the group consisting of titanium, zirconium, hafnium, silicon, and boron, and, optionally, (iii) ionizable hydrogen atoms, and, optionally, (iv) one or more oxygen atoms;(B) a component of cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, zirconium, iron, and copper; the ratio of the total number of cations of this component to the total number of anions of component (A) being at least 1:5;(C) sufficient free acid to give the composition a pH in the range from 0.5 to 5.
    Type: Grant
    Filed: July 30, 1993
    Date of Patent: June 27, 1995
    Assignee: Henkel Corporation
    Inventor: Shawn E. Dolan
  • Patent number: 5427687
    Abstract: Process for carrying out an equilibrium reaction in which one or more products are separated off by vapor permeation comprising the steps of:A) forming a reaction mixture comprising the reactants to be reacted in at least one reaction zone at a reaction temperature and reaction pressure selected so as to provide a reaction temperature above the boiling temperature of at least the product or products to be removed, wherein at least the product or products to be removed enters the resulting vapor phase in vapor form;B) passing the vapor phase containing the product or products to be removed to a zone remote from the reaction zone, which remote zone contains a semi-permeable membrane permeable to the product or products to be removed;C) carrying out vapor permeation in said remote zone to remove at least a portion of the product or products to be removed from said vapor phase; andD) returning the resulting vapor retentate from step C) to a reaction zone in step A).
    Type: Grant
    Filed: December 15, 1992
    Date of Patent: June 27, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Stephan Blum, Bernhard Gutsche, Lutz Jeromin, Levent Yueksel
  • Patent number: 5427863
    Abstract: The corrosion resistance, and also often the heat resistance, of a autodeposited coating in which the organic binders are predominantly copolymers of vinylidene chloride containing at least 50% vinylidene chloride can be improved by including another type of organic resin binder in the autodeposition bath in sufficient amount to constitute at least 2 up to as much as about 40% of the total of the PVDC and the other organic resin binder. Results can be further improved by rinsing the uncured autodeposited coating with an aqueous treatment solution that has a pH between 7 and 11 and contains between 0.01 and 5% of anions derived from multifunctional organic acids, preferably anions of 1-hydroxyethylidene-1,1-diphosphonic acid, citric acid, tartaric acid, and/or oxalic acid before drying the coating.
    Type: Grant
    Filed: September 23, 1992
    Date of Patent: June 27, 1995
    Assignee: Henkel Corporation
    Inventor: Elizabeth J. Siebert
  • Patent number: 5428115
    Abstract: An activator for cyanoacrylate adhesives based on N,N-dialkyl aniline derivatives is provided. The activators are characterized by a molecular weight of more than 200 and by at most 3 carbon atoms for both N,N-dialkyl substituents together. Also provided are methods of production and use of the activator and to the combination product of the activator and the cyanoacrylate adhesive.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: June 27, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Thomas Huver, Christian Nicolaisen, Susanne Camp
  • Patent number: 5421907
    Abstract: 2-Ethylhexyl esters of fatty acids, optionally mixed with emulsifiers, solubilizers, corrosion inhibitors, and/or water, are useful as low viscosity agents for the cold cleaning of metal surfaces contaminated mainly with oil. Such agents are non-toxic when inhaled and completely biodegradable.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: June 6, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Claus Nieendick, Karl Schmid, Heinz Mueller, Claus-Peter Herold
  • Patent number: 5420317
    Abstract: Olefinically unsaturated adducts of propylene on polyunsaturated fatty acids with 18 to 22 carbon atoms or on esters of these fatty acids with C.sub.1 -C.sub.36 alkanols in molar ratios of propylene to fatty acids or fatty acid esters in the range from 1:1 to 2:1, obtainable by reacting the fatty acids or fatty acid esters with propylene at elevated temperature and pressure in the presence of compounds of the transition metals Ru, Rh, Pd, Ir and Pt as catalysts to form an olefinically unsaturated adduct.
    Type: Grant
    Filed: July 24, 1992
    Date of Patent: May 30, 1995
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Alfred Laufenberg, Arno Behr