Patents Represented by Attorney, Agent or Law Firm Wayne C. Jaeschke
  • Patent number: 4945177
    Abstract: Novel 2,2-dibromo-3-oxonitriles of Formula I,R--CO--CBr.sub.2 --CN (I)in which R represents in each case a possibly substituted or unsubstituted aliphatic, cycloaliphatic, aromatic or heterocyclic group, with the exception of a phenyl group substituted with 1 to 3 chlorine atoms, can be obtained in that a carboxylic acid ester of Formula IIR--CO--OR' (II)in which R has the significance indicated for Formula I, and in which R' represents a straight chain or branched alkyl group with 1 to 4 carbon atoms, is reacted with acetonitrile in the presence of a strong base, the 3-oxonitrile produced is isolated from the reaction mixture and reacted in a solvent inert with respect to bromine and in the presence of a hydrogen bromide acceptor, possibly under cooling, and the 2,2-dibromo-3-oxonitrile of Formula I obtained is isolated from the reaction mixture.
    Type: Grant
    Filed: December 23, 1986
    Date of Patent: July 31, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Horst-Juergen Krause, Hans-Theo Leinen, Rudolf Lehmann
  • Patent number: 4944812
    Abstract: A vegetable tannin is condensed with formaldehyde and an amine to provide an acid soluble product which is useful in a metal treatment solution to enhance corrosion resistance and paint adhesion characteristics of a metal surface.
    Type: Grant
    Filed: November 16, 1988
    Date of Patent: July 31, 1990
    Assignee: Henkel Corporation
    Inventors: Andreas Lindert, Stephen M. Wolpert
  • Patent number: 4943458
    Abstract: The invention is a hollow body of plastic having a glossy surface, which is formed from a two-layer parison by an extrusion blow molding process, without need for exact temperature control during production, the hollow body being ecologically safe, inexpensive and, has a particularly glossy surface. The parison comprises a HDPE (high-density polyethylene) inner layer (5) and an unpigmented polyethylene outer layer (6) with additives.
    Type: Grant
    Filed: December 21, 1988
    Date of Patent: July 24, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Herbert Buecheler
  • Patent number: 4943393
    Abstract: Compounds of the formula ##STR1## wherein X and Y are different and are OH or SO.sub.3 M wherein M is selected from the group consisting of hydrogen, an alkali metal ion, an alkaline earth metal ion, NR.sub.4 wherein R is hydrogen, an alkyl or hydroxy alkyl radical having from 1 to 4 carbon atoms; a and c are integers having a value of from 0 to 18; b is an integer having a value of from 0 to 2 such that the sum of a+b+c is from 12 to 18; Z is an oxyethylene, oxypropylene, or oxybutylene group; n is an integer having a value of from 0 to 30 reduce the viscosity of highly concentrated, aqueous pastes of alkali metal salts of .alpha.-sulfonated fatty acid alkyl esters by as much as 90% of their original value.
    Type: Grant
    Filed: February 13, 1989
    Date of Patent: July 24, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Bernd Fabry, Robert Piorr
  • Patent number: 4942266
    Abstract: A process for the catalytic hydrogenation of liquid fatty acid triglycerides and the simultaneous recovery of fatty alcohols and C.sub.3 diols in the presence of gaseous hydrogen and hydrogenation catalysts under pressures of from 50 to 300 bar and at temperatures in the range from 160.degree. to 250.degree. C., to produce fatty alcohols in at least 99% of the theoretical yield and of 1,2-propanediol in at least 80% of the theoretical yield and a maximum paraffin content of 0.5% of the theoretical yield is disclosed. The hydrogenation reaction is carried out in a tube bundle reactor operated under isothermal conditions through a cooling or heating fluid, the liquid phase being passed as co-current trickle phase with the gaseous phase over catalyst packings in the individual reactor tubes without back-mixing, and in that the load per unit volume of the reactor is selected between 0.2 and 2.5 l starting material per 1 reactor volume per hour and the load per unit area of each individual reactor tube between 1.
    Type: Grant
    Filed: March 17, 1989
    Date of Patent: July 17, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Theo Fleckenstein, Gerd Goebel, Franz-Josef Carduck, Norbert Bremus, Reinhard Eicher
  • Patent number: 4942041
    Abstract: The use of compositions containing bis- or oligo-bis-guanides, alcohols, hydrogen peroxide, carboxylic acids, and water, applied externally, provides for the effective control of eggs of the threadworm Enterobius vermicularis on the skin.
    Type: Grant
    Filed: December 20, 1988
    Date of Patent: July 17, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Walter Guhl, Klaus Bansemir
  • Patent number: 4942174
    Abstract: Novel alkyl aryl ether derivatives corresponding to the formula: ##STR1## in which R.sup.1 is a C.sub.8 -C.sub.20 alkyl group with one or more branches, E is a group --CH.sub.2 --CH.sub.2 -- or --CH.dbd.CH-- and R.sup.2 is a C.sub.1 -C.sub.4 alkyl group, a C.sub.2 -C.sub.4 hydroxyalkyl group, an alkoxyalkyl group containing 1 to 4 C atoms in the alkoxy group and 2 to 4 C atoms in the alkyl group, hydrogen or a salt-forming cation, are highly effective sebosuppressive agents in cosmetic or pharmaceutical preparations for topical application to the hair and to the skin.
    Type: Grant
    Filed: November 10, 1988
    Date of Patent: July 17, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hinrich Moeller, Siegfried Wallat
  • Patent number: 4942049
    Abstract: Terminally blocked polyethoxylated fatty alcohols of the formula:R--O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.1 (I)wherein R is a linear or branched alkyl or alkenyl group having from 6 to 28 carbon atoms, R.sub.1 is a linear alkyl group having from 1 to 8 carbon atoms, and n is an integer having a value of from 2 to 12 are used as anti-foaming additives in the manufacture and/or processing of food stuffs as well as in fermentation processes.
    Type: Grant
    Filed: January 11, 1989
    Date of Patent: July 17, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl H. Schmid, Alfred Meffert, Gilbert Schenker, Adolf Asbeck
  • Patent number: 4940544
    Abstract: A process for the treatment of wastewaters heavily polluted by fats, proteins and/or carbohydrates of vegetable or animal origin or their processing products by degradation by microorganisms in a continuous flow reactor without separation of fats and/or sludges, comprising passing the wastewasters through a first part of a reactor containing aerobic and anaerobic microorganisms to consume the free oxygen present in the water, with at least partial degradation of the pollutants to fermentation products, and on flowing through another, adjoining part of the reactor, the fermentation products and any pollutants still present are coverted in the presence of the anaerobic microorganisms into--predominantly--digester gas and biomass. Optionally, fertilizing and/or pH-stabilizing substances or other auxiliaries are added in order to reduce the susceptibility of the system to failure.
    Type: Grant
    Filed: July 14, 1988
    Date of Patent: July 10, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Peter Gode, Jens P. Riebe, Lutz Jeromin
  • Patent number: 4940808
    Abstract: A process for the ozonization of unsaturated organic compounds in a reaction column through which the unsaturated compounds--in solution in a protic solvent--and an ozone-containing carrier gas and an inert coolant are passed downward in co-current flow to provide for an improved coolant effect and an increased ozonization yield where the coolant comprises a compound gaseous or liquid at ambient temperature with a boiling point preferably in the range from +20.degree. C. to -200.degree. C. The boiling point of the coolant is preferably at least 5.degree. C. below the ozonization temperature.
    Type: Grant
    Filed: July 7, 1988
    Date of Patent: July 10, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Paul Schulz, Michael J. Virnig, Franz J. Carduck
  • Patent number: 4939245
    Abstract: The invention is a process for preparing a glycoside product by reacting an alcohol having 4 to 30 carbon atoms with a saccharide or oligosaccharide in the presence of an acid catalyst wherein an undissolved phase comprising the saccharide or oligosaccharide is present in the reaction mixture during the process.
    Type: Grant
    Filed: December 21, 1988
    Date of Patent: July 3, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: John F. Rasche, Carl E. Pickens, Patrick M. McCurry, Jr.
  • Patent number: 4938779
    Abstract: The efficiency of chromium utilization in chrome tanning of hides to make leather is greatly improved by performing the preliminary neutralization of the acid tanning liquor in the presence of an aldehydo or keto acid, before conventional subsequent neutralization with an alkali aluminum silicate. Most preferably, a combination of glyoxylic acid and magnesium oxide is used for the preliminary neutralization.
    Type: Grant
    Filed: July 6, 1989
    Date of Patent: July 3, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hans-Herbert Friese, Emil Ruscheinsky, Rudolf Zauns
  • Patent number: 4939001
    Abstract: In the process of sealing decorative anodized aluminum oxide coatings in hot aqueous solutions, superior results are obtained when the sealing solutions contain 1-phosphonopropane-1,2,3-tricarboxylic acid, 1,1-diphosphonopropane-2,3-dicarboxylic acid, and/or alkali metal and/or alkanolamine salts of these acids. The presence of these acids or their salts prevents the formation of bloom and allows shorter sealing times with equivalent quality, and the addition of as little as 1 ppm of aluminum ions to such solutions also prevents iridescence.
    Type: Grant
    Filed: June 14, 1989
    Date of Patent: July 3, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Dieter Brodalla, Winfried Kirchhoff, Willi Wuest, Helmut Blum, Wolfgang Riedel
  • Patent number: 4939171
    Abstract: Alkyl and alkenyl aryl ether derivatives corresponding to the formula: ##STR1## in which R.sup.1 is a saturated cycloaliphatic C.sub.6 -C.sub.20 alkyl group or a mono- or polyunsaturated, linear, branched or cycloaliphatic C.sub.6 -C.sub.20 alkyl group and R.sup.2 is a C.sub.1 -C.sub.4 hydroxyalkyl group, a C.sub.3 or C.sub.4 hydroxyalkenyl group, a group --COOR.sup.3, --CH.sub.2 --COOR.sup.3, --CH.sub.2 --CH.sub.2 --COOR.sup.3 or --CH.dbd.CH--COOR.sup.3, are suitable as sebosuppressive agents in cosmetic or pharmaceutical preparations for topical application to the hair and to the skin.
    Type: Grant
    Filed: November 10, 1988
    Date of Patent: July 3, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Hinrich Moeller, Norbert Banduhn
  • Patent number: 4938889
    Abstract: A granular, storable bleach mixture suitable for addition to a detergent composition or to a wash liquor comprising a mixture of (a) from 5 to 35% by weight sodium perborate, preferably as monohydrate, (b) from 5 to 30% by weight tetra-acetyl ethylene-diamine and (c) from 90 to 50% by weight of a carrier material. The latter comprises a salt optionally containing water of crystallization or urea or mixtures thereof with anhydrous sodium sulfate, wherein the salt containing water of crystallization should not undergo any phase transformation between 1.degree. C. and 45.degree. C. In addition, the mixture may contain up to 15% of detergent constituents, such as surfactant and sequestering agent. The average particle size of the individual component is from 0.1 to 0.6 mm, less than 1% by weight being larger than 1.6 mm in size.
    Type: Grant
    Filed: March 15, 1989
    Date of Patent: July 3, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz-Manfred Wilsberg, Rolf Puchta, Jochen Jacobs
  • Patent number: 4936999
    Abstract: Disclosed is a process for recovery of amino acids from aqueous mixtures. In particular, it relates to a treatment of said amino acid containing aqueous mixture prior to extraction of the amino acid with a water immiscible organic solution containing a water insoluble extractant for said amino acid. The overall process of the invention which includes the pretreatment and extraction, also includes optional methods of recovering said extracted amino acid from the water immiscible organic solution. Accordingly, the invention also relates to a process for recovery of the amino acid by stripping of the amino acid from the organic solution and precipitation of the amino acid.
    Type: Grant
    Filed: July 1, 1988
    Date of Patent: June 26, 1990
    Assignee: Henkel Corporation
    Inventors: Phillip L. Mattison, Ronald P. Wirth, Michael J. Virnig, LeRoy Krbechek
  • Patent number: 4936551
    Abstract: Fatty acid polyoxyalkyl ester sulfonates obtained by reaction of C.sub.11 -C.sub.22 monounsaturated monocarboxylic acid polyoxyalkyl esters corresponding to the following general formulaC.sub.m H.sub.2m-1 --CO--(O--C.sub.n H.sub.2n).sub.x --OR (I)in whichR is a C.sub.1 -C.sub.22 alkyl radical or a C.sub.3 -C.sub.22 alkenyl radical,m has a value of 10, 15, 17, 19 or 21,n has a value of 2 or 3 andx has a value of 1 to 20,with sulfur trioxide and subsequent reaction of the sulfonated fatty acid polyoxyalkyl ester obtained with aqueous alkali metal salts. The sulfonates have high surface activity and favorable performance properties as surfactants.
    Type: Grant
    Filed: June 15, 1988
    Date of Patent: June 26, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ansgar Behler, Robert Piorr, Michael Schaefer
  • Patent number: 4937011
    Abstract: Alkaline dishwashing machine detergent compositions containing an active chlorine composition and a foam inhibiting amount of a ketone containing at least 25 carbon atoms. A process for their preparation wherein the ketone is introduced into the composition as a dispersion in a liquid.
    Type: Grant
    Filed: January 11, 1989
    Date of Patent: June 26, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Karl-Heinz Schmid, Adolf Asbeck, Christoph Breucker, Bernhard Gutsche, Alfred Meffert, Horst Rutzen
  • Patent number: 4935159
    Abstract: Long-chain hydroxyalkyl ether amines corresponding to the general formulaR.sup.1 --CHOH--CH.sub.2 --(O--CH.sub.2 --CH.sub.2 --).sub.X NR.sup.2 R.sup.3are suitable as wetting agents for textile products of all kinds and are distinguished by particularly low-foaming behavior. In the formula, R.sup.1 is a linear C.sub.6 -C.sub.22 alkyl group, R.sup.2 and R.sup.3 independently of one another represent a linear or branched C.sub.1 -C.sub.6 alkyl radical, and x is a number of 3 to 20.
    Type: Grant
    Filed: October 31, 1988
    Date of Patent: June 19, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Gilbert Schenker, Andreas Syldatk, Robert Piorr
  • Patent number: 4935556
    Abstract: Process for the production of a new copper (II) chromite spinel catalyst using colloidal silica gel and to its use for the direct fixed-bed hydrogenation of fatty acids to fatty alcohols of corresponding chain length.
    Type: Grant
    Filed: May 24, 1989
    Date of Patent: June 19, 1990
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Joachim Pohl, Franz-Josef Carduck, Gerd Goebel