Abstract: The invention relates to a liquid mixture of propylene oxide-ethylene oxide derivatives of alcohols corresponding to the following formulaR--O--C.sub.3 H.sub.5 O.sub.1-2 --(C.sub.2 H.sub.4 O).sub.6-8 --Hin which R is a linear alkyl or alkenyl radical which may be methyl-branched in the 2-position, and which has the following chain distribution: C.sub.8 =0 to 5%, C.sub.9-10 =75 to 90%, C.sub.11-12 =5 to 15%, C.sub.13-14 =4 to 10%, C.sub.15-16 =0 to 3%. By virtue of its physical and washing-active properties, the mixing is suitable as a readily biodegradable substitute for alkylphenol ethoxylates.
Type:
Grant
Filed:
June 1, 1989
Date of Patent:
October 23, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Peter Jeschke, Eva Kiewert, Claus Nieendick, Hans Nuesslein, Peter Sandkuehler
Abstract: Foam-depressing additives comprising polyethyleneglycol ethers of formula IR.sup.1 --O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.2 (I)in which R.sup.1 represents a straight-chain or branched alkyl radical with 6 to 13 carbon atoms, R.sup.2 represents an alkyl radical with 1 to 3 carbon atoms and n is a number from 2 to 6, for low-foam, preferably sprayable cleaning agents.
Type:
Grant
Filed:
January 10, 1989
Date of Patent:
October 23, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Karl-Heinz Schmid, Alfred Meffert, Gilbert Schenker, Adolf Asbeck, Juergen Geke
Abstract: A metal treatment solution comprising an effective amount of a soluble or dispersible compound which is a derivative of a polyphenol. Novel derivatives of polyphenol compounds useful in the treatment of the surface of metal articles is provided. Novel surface treatment solutions or dispersions, and methods for using these solutions is provided. Carbohydrate-modified polyphenol compounds are utilized in the present invention. The molecular weight of the polyphenols used in the preparation of derivatives of the present invention are in the range of about 360 to about 30,000 or greater. The resulting derivatives will typically have a molecular weight of up to about 2,000,000 with molecular weights within the range of about 700 to about 70,000 being preferred.
Type:
Grant
Filed:
December 4, 1987
Date of Patent:
October 16, 1990
Assignee:
Henkel Corporation
Inventors:
Andreas Lindert, John R. Pierce, David R. McCormick, William D. Zimmermann
Abstract: Soiled textile articles are washed by the addition of a determined amount of a detergent concentrate containing surfactants to the textile articles to be cleaned while the textiles are dry or only damp. The aqueous washing liquor is formed by the gradual addition of water to the textile articles while they are rotated. At room temperature, the detergent concentrate is to a substantial extent a paste-to dough-like substance, stable in form, and is applied to the textile articles in such an amount that the major portion of the surfactants together with further detergent constituents, if desired, are applied to the textiles or on an article of textile provided with markings for the correct detergent dose, as a dosing aid.
Type:
Grant
Filed:
February 8, 1989
Date of Patent:
October 16, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Hans-Josef Beaujean, Horst Eisenblaetter, Johann F. Fues, Brigitte Giesen, Erich Holz, Ulrich Jahnke, Werner Kuenzel, Alfred Meffert, Karl Schwadtke, Eduard Smulders, Eric Sung, Andreas Syldatk, Hans-Georg Toelken, Ingo Wegener
Abstract: A process and apparatus for the separation and purification of cellulose ethers and other cellulose derivatives in a filter unit at relatively high temperatures and with narrow-mesh filters, employing a pressure vessel having candle filters to which pressure is introduced for separation of the suspension liquid, for the removal of residual liquid from the filter cake formed, and also for washing the filter cake.
Abstract: 3-R.sup.1 -3-oxoprop-1-ene-1,1-diphosphonic acids corresponding to the following general formula ##STR1## in which R.sup.1 is a tertiary substituted alkyl group, an optionally substituted cycloalkyl group, or an optionally substituted aryl or heteroaryl group, andM is hydrogen or the cation of a base;to a process for their production in which 3-R.sup.1 -3-oxo-1-aminopropane-1,1-diphosphonic acids corresponding to the following general formula ##STR2## in which R.sup.1 is as defined above, are reacted with an aqueous or alcoholic alkali metal hydroxide solution; then water followed by an alcohol infinitely miscible with water is added to the reaction mixture, and the pure olefinic diphosphonic acids are obtained by addition of an acid; to the use of the above compounds of formula III as complexing agents and as thresholders; and to compositions containing one or more compounds of formula (III).
Abstract: A process for demulsifying oil/water emulsions using an organic demulsifier which is added in the optimum amount by means of a controlling device for the metered addition, wherein the demulsification reaction is carried out at a temperature of from 60.degree. C. to 90.degree. C. with mixing.
Abstract: An applicator or absorption cover for the head of a wet floor mop includes a textile support with holder insert-pockets sewn on the upper-side at opposite longitudinal ends, and with sponge-cloth or non-woven cloth material with high liquid take-up capacity being arranged as the underside material in the form of several strips in juxtaposed rows, with each of the strips attached over the area on the support, to take up dirt and liquids.
Type:
Grant
Filed:
March 16, 1989
Date of Patent:
October 9, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Franz Kresse, Rainer Osberghaus, Bernfrid Scheller, Roland Schunter, Herta Tuchermann
Abstract: Partial esters of saturated, linear C.sub.22 -C.sub.34 -monocarboxylic acids with polyols containing at least 3 carbon atoms and at least 2 hydroxyl groups are provided. The partial esters contain on average at least 1 free hydroxyl group and are generally obtained as mixtures of partial esters of at least 2 of said C.sub.22 -C.sub.34 -monocaroxylic acids. Particularly contemplated are partial esters based on montanic acids. The partial esters exhibit excellent release effects and transparency properties when used as release agents for plastics based on PVC or PVC copolymers.
Type:
Grant
Filed:
December 9, 1988
Date of Patent:
October 9, 1990
Assignee:
Neynaber Chemie GmbH
Inventors:
Kurt Worschech, Erwin Fleischer, Peter Wedl, Frido Loeffelholz, Ernst-Udo Brand
Abstract: Processes and solutions for phosphating metal surfaces. The solutions are acidic aqueous phosphate solutions containing (a) from 0.1 to 1.5 g/l of zinc ion; (b) from 5 to 50 g/l of phosphate ion; (c) from 0.2 to 4 g/l of manganese ion; (d) at least 0.05 g/l of fluoride ion; (e) less than 0.5 g/l of chloride ion; and (f) a phosphating accelerator. The metal surface phosphated with the solution including galvanized steel, is free of white spots and is suitable for electrocoating.
Abstract: Process for deinking printed waste paper by treatment of the paper pulp in a pulper at alkaline pH values using alkali silicate, oxidative bleaches, higher fatty and/or resinic acids and dispersants and separation of the detached printing ink particles from the fiber suspension by flotation, the fatty and/or resinic acids being used in the form of their alkaline earth metal salts in fine distribution together with dispersants in an oil-in-water dispersion which is liquid at normal temperature.
Type:
Grant
Filed:
February 2, 1988
Date of Patent:
September 25, 1990
Assignee:
Chemische Fabrik Gruenau GmbH
Inventors:
Klaus Lehmann, Andreas Domsch, Hans Hawel
Abstract: Polyfunctional hexasubstituted benzene derivatives wherein at least three of the substituents are saturated carbon chains having from 1 to 21 carbon atoms and functional groups containing hetero functionalities at the ends of the carbon chains and the remainder of the 6 substituents are either saturated carbon chains containing from 1 to 21 carbon atoms or saturated carbon chains containing from 1 to 21 carbon atoms having a functional group including a hetero functional group containing N, O, S, P, or Si at the end of the chains. These derivatives are made by reacting a disubstituted alkyne wherein one or both of the substituents are saturated carbon chains having 1 to 21 carbon atoms to which hetero functional groups are attached with a palladium catalyst and isolating the resulting hexasubstituted benzene derivative.
Type:
Grant
Filed:
May 17, 1989
Date of Patent:
September 25, 1990
Assignee:
Henkel Research Corporation
Inventors:
James M. Renga, Alan G. Olivero, Mark Bosse
Abstract: Glycoside products having a propensity to discolor (i.e., darken) under aqueous alkaline conditions are stabilized against discoloration under such conditions by treatment with from about 0.01 to about 2 weight percent (glycoside product dry weight basis) of a borohydride material such as sodium borohydride, potassium borohydride, lithium borohydride, etc.
Type:
Grant
Filed:
April 3, 1989
Date of Patent:
September 25, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Prasad S. Ravi, Hunter L. Kickle, Patrick M. McCurry, David J. Skogberg
Abstract: An apparatus for scraping solid materials from a conveyor belt comprising an elongate segmented scraper blade formed from a plurality of individual component blades which are aligned adjacent one another in a blade holder and which are supported to engage the conveyor belt under variable linear pressure, each component blade being adjustably attached by a flexible member to provide an elongate segmented scraping edge, the segments of which can independently and automatically flex to provide an elongate scraping edge which conforms to an irregular conveyor surface.
Type:
Grant
Filed:
August 26, 1988
Date of Patent:
September 25, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Roland Hourticolon, Hermann Kloettschen
Abstract: An applicator for the continuous application of a hair dye to the head hair of human beings, comprises a reservoir for hair dye absorbed in a first absorbent material within a tubular element, and teeth of a second absorbent material inserted into the element in a manner not contacting the first absorbent material, whereby for the transfer of the hair dye from the first absorbent material to the teeth not in contact therewith, the reservoir is connected to a rotation mechanism.
Abstract: A dispenser includes a first receptacle enclosing a second receptacle, for storing and providing substantially simultaneous dispensing of free-flowing and pourable substances, respectively. A dosing element is included in the second receptacle for limiting to a predetermined amount or dose the amount of pourable substance dispensed in each dispensing cycle.
Abstract: Silicate- and magnesium-free stabilizer mixtures for stabilizing aqueous peroxide bleaching baths based on organic acids and/or salts thereof comprising:(A) polyhydroxy and/or hydroxycarboxylic acids, and their alkali metal and/or ammonium salts;(B) polyacrylic acids, and their partially neutralized form; and(C) polyamine and/or amine polyphosphonic acids, and their alkali metal and/or ammonium salts;with the proviso that the ratio by weight of components A: B: C is 1 to 6: 0.2 to 1: 0.4 to 4.
Type:
Grant
Filed:
September 7, 1989
Date of Patent:
September 25, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Bernd D. Baehr, Ulrich Rall, Hildegard van Delden, Wolfgang Lillotte
Abstract: Activation of metal surfaces prior to phosphating can be improved by using aqueous dispersions of polymeric titanium(IV) phosphates in which at least 95% by weight of the polymeric particles have a particle diameter of less than 200 nm. This low particle diameter is attained by adding a titanium(IV)-complexing agent before or during an otherwise conventional reaction between a titanium(IV) compound, acid or phosphate, and water. The complexing agent is used in an amount of less than the stoichiometric amount, based on the titanium(IV) content. The best complexing agents are poly(aldehydocarboxylic acids), 1,1-diphosphonic acids, and/or the alkali metal salts of these types of acids.
Type:
Grant
Filed:
April 28, 1989
Date of Patent:
September 18, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Helmut Endres, Peter Christophliemk, Karl-Dieter Brands, Wolf-Achim Roland, Joerg Riesop