Abstract: A process for the direct esterification of o-phosphoric acid with aliphatic fatty alcohols and/or adducts thereof with alkylene oxides and alkylphenol alkoxylates, in the presence of a substoichiometric quantity of a basic, inorganic or organic compound and a water-entraining agent.
Abstract: A new method of forming agglomerates of fine powdered solids comprises dispersing the powder in a chemically inert carrier liquid that also contains a dissolved binder precursor polymer with cyclic dicarboxylic acid anhydride groups on the polymer chain. The dispersion is shaped and then brought into contact with a second carrier liquid that contains polyamines. The polyamines react with the anhydride groups on the other polymer to form an insoluble binder polymer that hardens the shaped dispersion. The hardened shape can then be separated from the liquids and/or further reacted if desired to produce amide bonds in the final agglomerates. The method is useful for forming mechanically and thermally stable agglomerates of such materials as activated carbon, metals dispersed on catalyst carriers, etc.
Type:
Grant
Filed:
December 5, 1988
Date of Patent:
April 24, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Wolfgang Ritter, Hans-Peter Handwerk, Franz-Josef Carduck
Abstract: A detergent composition containing by weight (a) from 5 to 35% of an anionic or nonionic surfactant, (b) from 10 to 40% of finely crystalline zeolite, (c) from 4 to 20% of alkali metal silicate or carbonate and from 0.1 to 5% of (d) aminoalkanephosphonate or (d2) copolymer of (meth)acrylic acid and maleic acid and (e) from 5 to 80% of other detergent constituents is considerably improved in regard to its incrustation-inhibiting properties if it additionally contains (f) from 0.05 to 1% (based on the free acid) of 1-hydroxyethane-1,1-diphosphonic acid in the form of its alkali metal salt. The weight ratio of (d1) to (f) is from 3:1 to 1:6 and of (d2) to (f) is from 40:1 to 2:1.
Type:
Grant
Filed:
July 7, 1989
Date of Patent:
April 24, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Guenther Vogt, Hans Andree, Gertrud Nienhaus
Abstract: Fiber lubricants comprising a lubricating emulsion and a high molecular weight acrylamidoalkane sulfonic acid polymer are provided. The lubricants, especially those banded on low-friction silicone lubricating emulsions, are characterized by excellent low wet friction properties, particularly on cotton fibers.
Abstract: Cosmetic emulsions of the oil-in-water type which are pourable at 20.degree. C. contain as an oil component dialkyl ethers corresponding to the formula R.sup.1 --O--R.sup.2, in which R.sup.1 and R.sup.2 independently of one another represent a linear or single-branch C.sub.6-22 alkyl. Even a content of only 0.5 to 5% by weight of dialkyl ethers can considerably reduce the viscosity of the emulsions. Preferred emulsions contain from 1 to 30% by weight of discontinuous lipophilic phase and from 70 to 99% by weight of continuous aqueous phase.
Type:
Grant
Filed:
January 5, 1989
Date of Patent:
April 24, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Horst Hoeffkes, Fritz Lange, Achim Ansmann
Abstract: Alkyl glycosides in admixture with bactericidally active alcohols or carboxylic acids in, e.g. aqueous treatment solutions, for potentiating the microbicidal effect thereof.
Type:
Grant
Filed:
July 9, 1987
Date of Patent:
April 24, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Rudolf Lehmann, Klaus Hachmann, Manfred Biermann, Harald Schnegelberger
Abstract: Undesirable greenish tinges that normally result when coloring anodized aluminum by AC electrolysis in solutions of silver salts can be avoided by adding to the electrolytes an appropriate amount of p-toluenesulfonic acid and/or its salts. The coloring solution may also contain (i) sulfuric acid, (ii) alkali metal, ammonium and/or alkaline earth metal salts of sulfuric acid and/or (iii) alkali metal, ammonium and/or alkaline earth metal acetates.
Type:
Grant
Filed:
July 19, 1989
Date of Patent:
April 17, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Dieter Brodalla, Loert de Riese-Meyer, Juergen Lindener
Abstract: A moisture-hardening flocking adhesive composition for application to elastomers. The adhesive contains an isocyanate terminated polyurethane prepolymer, an aromatic dinitroso compound and an essentially hydroxyl-free epoxy resin having an epoxide value of from about 0.45 to about 0.75. The composition is essentially free of highly volatile organic solvents. The composition is characterized as having improved storage stability and provides excellent adhesion between elastomeric substrates and flocking fibers, even after exposure to water.
Abstract: A dispensing storage container comprising a somewhat spherical housing forming a storage compartment for a supply of laundry treatment liquid and having an inlet/outlet portion, which may also be a removable cover portion. The inlet/outlet portion comprises a recessed groove, preferably annular, surrounded by elevated surface areas of the housing, and having inlet/outlet openings recessed at the base of the groove.
Type:
Grant
Filed:
June 7, 1988
Date of Patent:
April 10, 1990
Assignee:
Henkel Kommanditgesellshaft auf Aktien
Inventors:
Herbert Buecheler, Peter Kittscher, Paul-Otto Weltgen
Abstract: A process and circuitry for the electrolytic coloring of an anodized article of aluminum or aluminum alloy in a coloring bath containing at least one metal salt for coloring the article. The process comprises applying to the coloring bath a controllable, asymmetrical and substantially sinusoidal a.c. voltage of substantially constant frequency. The sinusoidal a.c. voltage is obtained from a voltage source supplying a symmetrical sinusoidal a.c. voltage and at least one of the two current paths is divided into two parallel main lines and fed to electrical components whereby the amplitude level of the positive half wave and the amplitude level of the negative half wave and the ratio of the amplitude level of the positive half wave to the amplitude level of the negative half wave of the a.c.
Type:
Grant
Filed:
June 5, 1989
Date of Patent:
April 10, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Dieter Brodalla, Werner Huppertz, Georg Wagner, James W. Costello, Karl-Heinz Munk
Abstract: A process for improving the bonding of hotmelt materials which post crosslink in the presence of moisture, to water vapor impermeable substrates by applying an activator material, which release bound water at the hotmelt application temperature, to at least one of the water vapor impermeable substrates.
Type:
Grant
Filed:
July 20, 1988
Date of Patent:
April 3, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Heinz-Guenther Schulte, Guenter Tauber, Wolfgang Pille-Wolf
Abstract: Thermoplastic polyamide mixtures of polyamides based on dimerized fatty acids in which at least one polyamide contains as an incorporated unit (a) a C.sub.2 -C.sub.10 aliphatic diamine capable of diamide formation, which is N-substituted with C.sub.10 -C.sub.25 -alkyl, and (b) a C.sub.2 -C.sub.40 -diamine capable of diamide formation comprising a diprimary amine, a heterocyclic amine, or a diomine containing one or two secondary amino groups and which is N-C.sub.1 -C.sub.8 -alkyl-substituted on at least one side.
Type:
Grant
Filed:
October 31, 1988
Date of Patent:
April 3, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Roberto Leoni, Werner Gruber, Juergen Wichelhaus
Abstract: A detergent compact for dishwashing machines based on alkali metal metasilicates, pentalkali metal tripolyphosphates, active chlorine compound, and surfactant. The compact comprises a cold water-soluble tablet (1) or melt (2) of the metasilicates, tripolyphosphates and surfactant, and a warm water-soluble melt (1) or tablet (2) of the metasilicates, tripolyphosphates and active chlorine compound. The tablet (1) and melt (1) or melt (2) and tablet (2) are combined into a compact having varying solubility at varying water temperatures.
Type:
Grant
Filed:
January 24, 1989
Date of Patent:
April 3, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Hans Kruse, Jochen Jacobs, Theodor Altenschoepfer, Peter Jeschke
Abstract: Fabric softeners for the treatment of fabrics after washing contain as active constituents a combination of one or more sulfonic acids or phosphonic acids and amines or quaternary ammonium compounds thereof bearing a long alkyl or alkenyl radical. This combination of active constituents is readily and inexpensively obtainable and provides the treated fabrics with a soft, full feel.
Abstract: An improvement in the process of extraction of amino acids from aqueous solutions in which the amino acids are extracted with quaternary ammonium extractants. A pretreatment of the amino acid containing aqueous solution with a tertiary amine prior to extraction of the amino acids with the quaternary ammonium extractant, removes some impurities or poisons present therein, leaving the amino acids in the aqueous solution for subsequent extraction with a water insoluble quaternary ammonium extractant. After extraction with the quaternary extractant, the organic phase is stripped of amino acid and the stripped organic is subjected to an acidic scrub before returning to the quaternary extraction stage.
Type:
Grant
Filed:
August 4, 1988
Date of Patent:
March 27, 1990
Assignee:
Henkel Research Corporation
Inventors:
Thomas J. Stierman, Phillip L. Mattison
Abstract: Thermoplastic polyamide resins with improved low-temperature flexibility and improved bonding properties consisting essentially of polycondensates of the following components:(a) 10 to 50 mol-% of a dimer fatty acid or mixture of such acids,(b) 5 to 45 mol-% of polyoxyalkylene urea diamine,(c) 0 to 25 mol-% of an aliphatic C.sub.6 -C.sub.22 dicarboxylic acid or mixture of such acids,(d) 0 to 45 mol-% of an aliphatic, aromatic or cyclic C.sub.2 -C.sub.40 diamine or a mixture of such diamines selected from the group comprising diprimary diamines, diamines containing secondary amino groups and alkyl substituents with no more than 8 carbon atoms at the nitrogen atom, and heterocyclic diamines capable of double amide formation.Preferred resins are base-terminated resins having amine values of up to 50 and acid-terminated resins having acid values of up to 20 and a molecular weight within the range from 5000 to 20,000 and preferably from 8000 to 15,000.
Type:
Grant
Filed:
July 20, 1988
Date of Patent:
March 27, 1990
Assignee:
Henkel Kommanditgeselschaft auf Aktien
Inventors:
Roberto Leoni, Werner Gruber, Angela Rossini
Abstract: A two-layer cavity floor construction comprising a base layer of profile element panels with a plurality of passage-forming spacer elements and a surface layer which combine to provide a minimal overall height with particularly good noise and footstep insulation. The base layer is formed from a noise-insulating material preferably based on polyurethane bound in a polyurethane foam.
Type:
Grant
Filed:
July 8, 1988
Date of Patent:
March 27, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Dieter Leukel, Andreas Bettgens, Horst Mueller, Horst Tamm
Abstract: A storage stable adhesive for PVC plastics, particularly post-chlorinated PVC plastics, containing a basic mixture of 5 to 30% by weight post-chlorinated PVC and 95 to 70% by weight of an organic solvent, a stabilizer combination of effective quantities of organotin compounds and alkali metal carbonates from the group consisting of ammonium, lithium, sodium and potassium carbonates and also standard additives, such as impact modifiers, antioxidants and UV stabilizers can be included in the basic mixture. The composition has improved stability when stored in tin plated steel containers.
Abstract: Moisture-hardening joint sealing compositions based on polyurethane prepolymers, swellable polymer powders, plasticizers and other auxiliaries have increased stability in storage when they contain C.sub.8 -C.sub.20 olefins as stabilizers.
Type:
Grant
Filed:
August 10, 1988
Date of Patent:
March 20, 1990
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Tore Podola, Wolfgang Ernst, Winfried Emmerling