Abstract: Disclosed is a process for recovery of amino acids from aqueous mixtures. In particular, it relates to a treatment of said amino acid containing aqueous mixture prior to extraction of the amino acid with a water immiscible organic solution containing a water insoluble extractant for said amino acid. The overall process of the invention which includes the pretreatment and extraction, also includes optional methods of recovering said extracted amino acid from the water immiscible organic solution. Accordingly, the invention also relates to a process for recovery of the amino acid by stripping of the amino acid from the organic solution and precipitation of the amino acid.
Type:
Grant
Filed:
May 16, 1986
Date of Patent:
December 12, 1989
Assignee:
Henkel Corporation
Inventors:
Phillip L. Mattison, Ronald P. Wirth, Michael J. Virnig, LeRoy Krbechek
Abstract: The invention is a process for the separation of biotechnologically produced valuable materials from a fermenter broth by crossflow microfiltration and/or ultrafiltration, in which at least two modules arranged in series and fitted with porous membranes are used per stage, to produce concentrate and a permeate which contains the valuable material. The pressure of the permeate is controlled so that the absolute pressure on the permeate side is at different absolute pressure in each module.
Abstract: Amino acids can be purpified and/or concentrated by extracting aqueous mixtures such as fermentation broths by contacting an aqueous mixture containing amino acids with an organic solution containing a water insoluble extractant selected from the group consisting of:1. A quaternary ammonium ion having the formula: ##STR1## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are aliphatic, each having from 1 to 22 carbon atoms, and together have a minimum of 25 carbon atoms, and where at least three of the four R groups are at least a C.sub.4.2. A quaternary phosphonium ion having the formula: ##STR2## where R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are as defined above. 3. A tertiary sulfonium ion having the formula: ##STR3## where R.sub.1, R.sub.2 and R.sub.3 each are aliphatic with from 1 to 22 carbon atoms, and together have a minimum of 24 carbons and where at least two of these groups are at least a C.sub.6.4. An organic boride ion having the formula: ##STR4## where R.sub.1, R.sub.2, R.sub.3 and R.sub.
Type:
Grant
Filed:
December 22, 1986
Date of Patent:
December 12, 1989
Assignee:
Henkel Corporation
Inventors:
Francis W. Tuominen, Ronald R. Swanson, Phillip L. Mattison, Kenneth D. MacKay, Bradley W. Glorvigen
Abstract: Process for the production of modified triglycerides which contain epoxide groups, secondary hydroxyl groups and ether groups. The invention particularly relates to the production of reaction products of epoxidized triglycerides, for example epoxidized soy oil, with polyfunctional alcohols, for example glycols. The products so prepared are valuable starting materials, particularly for the production of alkyd resins.
Abstract: Alkyl ether sulfuric acid half-esters are neutralized in the presence of polyhydroxy oligomers such as polyglycerol to provide half-ester salt compositions of high activity and good viscosity characteristics. The products are particularly useful in shampoo formulations.
Abstract: Dispensing storage containers and assemblies of such containers secured over the conventional cup-like cap of a bottle designed to contain a supply of laundry treatment material. The dispensing storage containers have a shell housing, a closed base end, an open filling end and a cover including media transfer holes and means for securing it over the filling end of the container to disperse laundry treatment material from the container into the wash during use. The open filling end has a collar forming an opening sufficiently wide to receive and be secured over the cup-like bottle cap during periods of non-use, and the base end of the container preferably includes a flange means to which the cover can be secured on the assembly.
Abstract: The invention relates to compositions and methods for smoothing textile fibers which compositions are characterized in that they contain as lubricants an aliphatic polyether corresponding to the following general formula:R.sup.1 --X--O--R.sup.2in which R.sup.1 and R.sup.2 are linear and/or branched, saturated and/or saturated, OH-containing or OH-free C.sub.6 -C.sub.24 alkyl radicals of natural and/or synthetic origin and X is a homopolymer or copolymer containing one or more C.sub.2 -C.sub.6 alkylene oxides having a degree of polymerization of 1 to 25, either alone or in admixture with other smoothing agents.The other smoothing agents include paraffins, polyethylenes, fatty acid ethers, silicones or polyalkylene glycols. The compositions may be applied to textile fiber in the form of solutions, emulsions or aqueous dispersions.
Type:
Grant
Filed:
February 23, 1988
Date of Patent:
November 28, 1989
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Rudolf Veitenhansl, Peter Waltenberger, Fritz Lange, Guenter Uphues, Uwe Ploog
Abstract: A rotatable liquid hair treatment medium applicator comprising a container having a distal face surrounding its opening which is at an angle to its verticle axis, a conical applicator head rotatably mounted around the mouth, and an applicator mouth co-rotatably projecting from the applicator head at an angle to the common central axis of the opening and applicator head.
Type:
Grant
Filed:
January 26, 1988
Date of Patent:
November 21, 1989
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Detlef Hollenberg, Hans Schneider, Georg Weihrauch
Abstract: Monomer compositions crosslinkable by photoinitiators and stabilizers and containing liquid polymerizable monomers having one or more ethylenic double bonds, camphor quinone, an aryl sulfinate, thickeners, and, optionally, adhesion promoters and/or accelerators as photoinitiated adhesives hardening in darkness for the bonding of non-transparent surfaces. Bonds having excellent tensile shear strengths are obtained.
Type:
Grant
Filed:
July 27, 1988
Date of Patent:
November 21, 1989
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
ReneA. A. Gonzalez, Heinz-Christian Nicolaisen, Lothar Kammer
Abstract: Liquid cleaning preparations for hard surfaces containing(a) 0.5 to 40% by weight, preferably 5 to 20% by weight, of a surfactant or a surfactant mixture;(b) 0.01 to 1% by weight, preferably 0.05 to 0.5% by weight, of cleaning enhancer;(c) 0 to 6% by weight, preferably 1.0 to 6% by weight, of at least one organic and/or inorganic builder;and up to a total of 100% by wiehgt, based on the total weight, of water, and optionally, one or more of solubilizers (solvents, hydrotropes), preservatives, antimicrobial agents, viscosity regulators, pH regulators, perfumes, and dyes. Component (b) is a mixture of (i) at least one polyacrylamide and (ii) at least one highly polyethoxylated monofunctional or polyfunctional alkanol.
Abstract: 3-R.sup.1 -3-oxoprop-1-ene-1,1-diphosphonic acids corresponding to the following general formula ##STR1## in which R.sup.1 is a tertiary substituted alkyl group, an optionally substituted cycloalkyl group, or an optionally substituted aryl or heteroaryl group, andM is hydrogen or the cation of a base;to a process for their production in which 3-R.sup.1 -3-oxo-1-aminopropane-1,1-diphosphonic acids corresponding to the following general formula ##STR2## in which R.sup.1 is as defined above, are reacted with an aqueous or alcoholic alkali metal hydroxide solution; then water followed by an alcohol infinitely miscible with water is added to the reaction mixture, and the pure olefinic diphosphonic acids are obtained by addition of an acid; to the use of the above compounds of formula III as complexing agents and as thresholders; and to compositions containing one or more compounds of formula (III).
Abstract: Water-soluble polycondensates of dialkanolamides, fatty acid diethylaminopolyglycolates and fatty acid diethyl ammonium alkyl polyglycolates, which are first reacted with maleic anhydride in a molar ratio of 1:0.5 to 1:2, followed by reaction of substantially all the olefinic double bonds in the .alpha.-position to carboxyl groups with sulfites, are excellent plasticizers for hydraulic compositions.
Type:
Grant
Filed:
December 20, 1988
Date of Patent:
November 14, 1989
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Bernd Wahle, Hermann Anzinger, Horst Ziche, Erhard Schinski
Abstract: Silicate- and magnesium-free stabilizer mixtures for stabilizing aqueous peroxide bleaching baths based on organic acids and/or salts thereof comprising:(A) polyhydroxy and/or hydroxycarboxylic acids, and their alkali metal and/or ammonium salts;(B) polyacrylic acids, and their partially neutralized form; and(C) polyamine and/or amine polyphosphonic acids, and their alkali metal and/or ammonium salts;(D) 35% hydrogen peroxide solution with the proviso that the ratio by weight of components A:B:C is 1 to 6:0.2 to 1:0.4 to 4.
Type:
Grant
Filed:
December 22, 1988
Date of Patent:
November 14, 1989
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Bernd D. Baehr, Ulrich Rall, Hildegard van Delden, Wolfgang Lillotte
Abstract: Polythiols prepared by the reaction of hydrogen sulfide or organic dithiols with polyglycidyl substituted amines have been found to be outstanding curing agents for epoxy resins. Epoxy resins cured with these polythiols are characterized by not only improved gel times, but also improved cure rates, better heat resistance and greater resistance to absorption of water.A useful polythiol is the reaction product of N,N,N',N'-tetraglycidyl-m-xylylenediamine with hydrogen sulfide.
Type:
Grant
Filed:
February 17, 1988
Date of Patent:
November 7, 1989
Assignee:
Henkel Corporation
Inventors:
Grannis S. Johnson, Reuben H. Grinstein, Stuart J. Hartman, Raymond P. Dallago
Abstract: A process for the electrolytic coloring of anodized surfaces of aluminum or aluminum alloys using alternating current or direct current superimposed on alternating current, the electrolytic coloring being carried out with an electrolyte which contains cationic organic dyes and, optionally, conducting salts.
Abstract: Textile treatment preparations are obtained by reaction of aliphatic monocarboxylic acids or amide-forming derivatives thereof with hydroxyalkylpolyamines and subsequent neutralization of unreacted amino groups and which contain monosaccharides or polyhydroxy compounds derived therefrom by hydrogenation and also synthetic or natural polymers as dispersion accelerators which may be dispersed particularly rapidly, even in cold water, if the dispersion accelerator is present in the reaction mixture during the actual reaction.
Abstract: A cleaning preparation containing from 2 to 40% by weight ethoxylated fatty alcohol and/or oxoalcohol and from 10 to 90% by weight of a fatty acid ester. In addition, the cleaning preparation may contain water, a monohydric alcohol and liquid hydrocarbons. The cleaning preparation is used for the pretreatment of heavily soiled fabrics before washing.
Abstract: Copolyester plasticizers useful for the formulation of PVC refrigerator gaskets which exhibit improved resistance to migration and marring and improved processing characteristics are provided. The copolyesters are obtained by reacting an acid component consisting of a mixture of a benzene dicarboxylic acid (or anhydride or methyl ester thereof) and an aliphatic C.sub.5-12 saturated dicarboxylic acid (or methyl ester) with an alcohol component consisting of a mixture of neopentyl glycol and ethylene glycol. An aliphatic C.sub.6-13 saturated monofunctional alcohol or aliphatic C.sub.6-13 saturated monocarboxylic acid terminating agent is also included in the reaction.