Abstract: Polymer bound hindered amine light stabilizers are prepared by reacting hindered amine light stabilizers containing reactive hydrazide functionalities with anhydride containing polymers or copolymers. The reactions may be carried out in an inert solvent or in a melt blending step. The polymer bound hindered amine light stabilizers are useful alone or may also be used to stabilize other polymers, copolymers or polymer blends against the deleterious effects of heat and/or light.
Type:
Grant
Filed:
June 21, 1989
Date of Patent:
December 4, 1990
Assignee:
Atochem North America, Inc.
Inventors:
Robert T. Kazmierzak, Ronald E. MacLeay
Abstract: 1,1-Dichloro-1-fluoroethane, 1-chloro-1,1-difluoroethane and hydrogen fluoride are separated from their liquid mixtures, such as liquid mixtures resulting from the hydrofluorination, of 1,1,1-trichloroethane or vinylidene chloride. 1,1-Dichloro-1-fluoroethane and 1-chloro-1,1-difluoroethane are first separated by distillation into their respective mixtures with hydrogen fluoride, which are thereafter subjected to parallel phase separations resulting in two hydrogen fluoride-enriched liquid phases, a 1-chloro-1,1-difluoroethane-enriched liquid phase and a 1,1-dichloro-1-fluoroethane-enriched liquid phase. 1-Chloro-1,1-difluoroethane and 1,1-dichloro-1-fluoroethane are purified from the respective halohydrocarbon-enriched liquid phases by distillation. The hydrogen fluoride-enriched stream generated from the phase separation of the hydrogen fluoride/1,1-dichloro-1-fluoroethane mixture is recycled to the hydrofluorination reaction mixture.
Abstract: Non-toxic organotin catalysts containing at least one direct oxygen-to-tin bond and one direct carbon-to-tin bond are provided for use as esterification catalysts in the production of non-toxic polyester and polyester-containing compositions. Articles made from such polyester and polyester-containing compositions are suitable for use in regulated food, beverage, pharmaceutical, and medical-device applications.
Type:
Grant
Filed:
September 22, 1989
Date of Patent:
November 13, 1990
Assignee:
Atochem North America, Inc.
Inventors:
William A. Larkin, Emily C. Bossert, Edmund M. Gibbons
Abstract: A method for the preparation of alkanesulfonamides in high purity and high yield using solvents selected from C.sub.4 to C.sub.8 cyclic ethers or mixtures thereof is disclosed. The final products have use as synthetic intermediates for the manufacture of useful final products.
Type:
Grant
Filed:
November 30, 1988
Date of Patent:
November 13, 1990
Assignee:
Atochem North America, Inc.
Inventors:
Stanley R. Sandler, James S. Perilli, John F. Kennoy
Abstract: The process for the cyclization of orthobenzoylbenzoic acid into anthraquinone comprising heating orthobenzoylbenzoic acid in the solid phase at a temperature between about 300.degree. C. to 400.degree. C. in the presence of a superactive bleaching earth. The invention also comprises a process for the separation of phthalic acid and any phthalic anhydride impurities from orthobenzoylbenzoic acid prior to its cyclization into anthraquinone through the use of said earth at a temperature from 200.degree. C. to 250.degree. C.
Abstract: Improved printing with polymers is achieved by interposing a liquid layer conforming to rough substrate surfaces and possibly exhibiting different characteristics from an outer surface polymer layer. This is particularly advantageous in printed wiring board (PWB) manufacture requiring solder mask coating. Thus, a two layer composite polymer coating is provided. One inner adhesive photopolymer layer is applied to the PWB in the liquid state, displacing air from PWB surface. The outer layer of the composite therefore can be epoxy, dry film or liquid polymer. Dry film thus carried on a thin plastic sheet may be overlaminated onto a liquid inner layer already on the substrate, without the need for a vacuum laminator to eliminate bubbles or a plasticizing heat step to conform the dry film to the surface.
Abstract: A novel lubrication blend useful per se as a lubricant or as an additive to form a novel lubricant composition. The lubrication blend consists essentially of a mixture of: (1) at least one complex sulfide of antimony, represented by the formula:Sb.sub.x S.sub.ywherein, x is a number in the range from about 1.7 to about 2.3, and y is a number in the range from about 3.6 to about 4.4, (2) at least one antimony oxide, and (3) at least one lamellar crystalline solid lubricant.
Abstract: 1,1-Dichloro-1-fluoroethane and 1-chloro-1,1-difluoroethane are prepared from the liquid phase fluorination of 1,1,1-trichloroethane by HF in the presence of a homogenous catalyst. 1,1-Dichloro-1-fluoroethane or 1-chloro-1,1-difluoroethane are selectively produced substantially free of vinylidene chloride.
Abstract: A distribution head having an inlet for accepting a stream of fluid plastic and an outlet for discharging the stream, two pairs of discrete channels in the distribution head extending from the input to the output for splitting the streams into corresponding discrete substreams, selected ones of the channels being of predetermined different lengths to provide lateral mixing of the stream as it passes through the head. The invention also includes a combination of the distribution head and a connected extrusion tool and the process of making homogeneous plastic articles, particularly pipes.
Abstract: A catalyst composition for the polymerization of propylene comprising a catalytic solid comprising a titanium halide and a magnesium halide and isoprenyl aluminum associated therewith and the process of polymerizing propylene using such catalyst.
Abstract: Oxides having the spinel structure of .gamma.-Fe.sub.2 O.sub.3 /Fe.sub.3 O.sub.4 type, substituted by trivalent and monovalent metals, or doped with non-spinel derivatives thereof, more particularly iron/aluminum/potassium oxides well suited as dehydrogenation catalysts, e.g., for dehydrogenating ethylbenzene into styrene, are prepared by thermally decomposing mixed iron, aluminum and potassium salts, notably the oxalates thereof, in the presence of air, then reducing the product of thermal decomposition at a temperature of less than 400.degree. C., advantageously in the presence of steam and hydrogen, and optionally oxidizing the product of reduction; oxides of .beta.-alumina structure are also produced.
Type:
Grant
Filed:
December 16, 1988
Date of Patent:
October 2, 1990
Assignee:
Atochem
Inventors:
Abel Rousset, Belaid Maachi, Bernard Gilot, Michel Gougeon
Abstract: A device for measuring the speed of a moving object has first and second impact detectors separated by a preselected known distance and disposed in the path of movement of the object. As the object strikes the first and second detectors, the detectors each produce a signal. The signals are separated by a time interval indicative of the distance between the detectors. The elapsed time between the signals is measured by a counter device, and the speed of the object is calculated by a programmable device.
Type:
Grant
Filed:
October 11, 1988
Date of Patent:
September 25, 1990
Assignee:
Atochem North America, Inc.
Inventors:
Mitchell L. Thomspon, Kyung T. Park, Kumar Ogale, William B. Powers
Abstract: An apparatus for the manufacture of sections of thermoplastic resin reinforced with continuous fibers. The apparatus includes coating rovings, having their fibers previously arranged in the form of a sheet by passage through a baffle zone having at least one transverse baffle, in a coating zone fed with a molten thermoplastic, then, to ensure impregnation of each of the fibers of the rovings, the coated rovings are passed into a forced impregnation zone having at least two baffles parallel to the baffle in the baffle zone prior to passing into the channel for shaping the final product.
Abstract: Polyarylalkane oligomer compositions consisting essentially of a mixture of isomers of xylyl-xylene and of higher homologues and a mixture of isomers of bis(dimethylphenyl)xylylene and of higher homologues; the method of making such compositions by first reacting toluene, xylene, or a mixture of toluene and xylene with chlorine in the presence of a radical generator, removing the unreacted toluene, and then subjecting the reaction product to the action of an inorganic halide or inorganic acid in the presence of xylene, and microcapsules containing color-forming material wherein the compositions are used as solvents for the color-forming material.
Abstract: Polyarylalkane oligomer compositions containing essentially of a mixture of isomers of benzylcumene and its higher homologues and a mixture of isomers of bis(isopropylphenyl)phenylmethane; the method of making such compositions by first reacting chlorine with toluene, xylene, or a mixture of toluene and xylene in the presence of a radical generator, removing the unreacted toluene and/or xylene, and then subjecting the reaction product to the action of an inorganic halide or of an inorganic acid in the presence of a benzene-related compound; and microcapsules containing color-forming material wherein the compositions are used as solvents for the color-forming material.
Abstract: This invention relates to novel reactive amino or hydrazino peroxides (hereinafter generally referred to as "AHP's") and derivatives all having a Structure A:(P--R11--X--(--NH--).sub.x --R22--).sub.y --Q].sub.z Ain which the definitions of P, R11, R22, X, Q and x, y and z are given in the Summary of The Invention section, for example, 4,4-di-(t-butylperoxy)pentanohydrazide (I-1), and the use of these novel compounds in curing unsaturated polyester resins, in initiating polymerization of ethylenically unsaturated monomers, for modifying rheology, for crosslinking and curing olefin polymers and elastomers, for producing novel graft and block copolymers, and for producing novel polymers with covalently bound performance additive functions.
Abstract: The subject of the invention is functional chlorofluoro compounds of general formula: ##STR1## in which R.sub.F denotes a perfluoroalkyl radical, n is equal to 0 or 1, X denotes a chlorine or fluorine atom or a trichloromethyl or trifluoromethyl radical, and Y denotes a chlorine atom, an optionally salified or esterified hydroxyl group or an optionally substituted amino group, the arrangement R.sub.F --CCl.sub.2 --(CCl.sub.2 --O).sub.n containing at least 3 carbon atoms.By photochlorination of the esters R.sub.F --CH.sub.2 CH.sub.2 --O--CO--X, the compounds I (n=1) are obtained, which are then rearranged to acid chlorides I (n=0, Y.dbd.Cl) from which the corresponding acids, salts, esters and amides are optionally formed (formula I with n=0 and Y=optionally salified or esterified hydroxyl or optionally substituted amino).
Type:
Grant
Filed:
December 19, 1989
Date of Patent:
September 4, 1990
Assignee:
Societe Atochem
Inventors:
Yves Correia, Gilles Drivon, Jean Lesparre
Abstract: An agricultural machine and method for applying and securing a plastic film onto a seed bed. The machine includes a cutter that severs the plastic film at the end of a row or other area for which covering is desired, while covering the severed ends so as to anchor them to the soil.
Abstract: An electrolytic cell, e.g., for the electrolysis of NaCl to produce chlorine and sodium hydroxide, has an improved operation control system, such system including a plurality of means for monitoring and controlling the flowstreams of inlet starting materials and/or outlet final products, the temperature of the electrolyte, the various reagent concentrations and the cell current, and such plurality of means being operably connected to a computing function which carries out corrective coherence calculations on certain of the parameters of electrolysis and adjusts the operation of the cell in response thereto.
Type:
Grant
Filed:
March 17, 1989
Date of Patent:
August 28, 1990
Assignee:
Atochem
Inventors:
Bernard Bouche-Pillon, Rene Clair, Jean-Pierre Caujolle
Abstract: A process for the preparation of vinyl chloride homopolymer and copolymer pulverulent powders suitable for the preparation of plastisols with improved rheological properties, comprising polymerizing to form a vinyl chloride homopolymer or copolymer latex and drying said latex by atomization, the temperature at which the latex to be subjected to drying by atomization is employed being at least equal to 40.degree. C. and being lower than the degradation temperature of said homopolymer or copolymer, and the resultant vinyl chloride polymer pulverulent powders.