Abstract: The invention relates to a process for purifying synthesis gas, comprising at least one stage for separating the crude synthesis gas to be treated into at least two effluents, namely a first part and a complementary part, in which the said first part is subjected to a carbon monoxide conversion stage with steam and the said complementary part is subjected to a COS and HCN catalytic hydrolysis stage, the two gas flows, namely the first part and complementary part, are then each treated separately in two stages intended to remove acid gases such as CO2 and H2S, by washing with aqueous solutions of specific amines, before a recombination stage of the two treated effluents.
Type:
Grant
Filed:
December 16, 2014
Date of Patent:
November 6, 2018
Assignees:
AVRIL, AXENS, IFP ENERGIES NOUVELLES, BIONEXT, THYSSENKRUPP INDUSTRIAL SOLUTIONS AG, TOTAL RAFFINAGE CHIMIE, COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
Inventors:
David Chiche, Anne Claire Pierron, Norbert Ullrich
Abstract: The present invention describes a process for the production of high octane number gasoline by isomerization of a light naphtha cut, comprising two separation steps located downstream of the reaction step which can be used to improve the energy efficiency of said process.
Type:
Grant
Filed:
April 20, 2015
Date of Patent:
October 30, 2018
Assignee:
AXENS
Inventors:
Jerome Pigourier, Isabelle Prevost, Laurent Watripont, Pierre-Yves Martin
Abstract: The present invention describes a catalytic reactor operating as a moving bed to manage interruptions in the circulation of catalyst while at the same time avoiding mechanical damage to the contact means containing the catalyst. The invention also concerns a refining or petrochemicals process using the reactor in accordance with the invention.
Abstract: The present invention relates to the field of extraction of sulphur-containing compounds such as mercaptans, COS, H2S or CS2 from a hydrocarbon cut. This selective extraction is carried out by bringing the hydrocarbon cut in the liquid phase into contact with an alkaline solution, for example caustic soda. The process in accordance with the invention is an improved process for the regeneration of alkaline solution which can be used to reduce the quantity of alkaline solution necessary in the regeneration section.
Type:
Application
Filed:
February 28, 2018
Publication date:
September 6, 2018
Applicant:
AXENS
Inventors:
Jean-Michel BESNAULT, Mai Phuong DO, Sebastien FERRERO
Abstract: The present invention generally relates to a process for making a metal oxide composition for use in removing contaminants from streams. A process of the present disclosure comprises contacting a metal salt with an aqueous solvent to form a metal salt mixture and reacting the metal salt mixture and a metal powder without the addition of heat. The present invention also relates to a process for making a coated metal oxide substrate.
Abstract: In the hydrocracking process in accordance with the invention, which comprises a hydrocracking section, a high pressure hot separator and a fractionation section, upstream of the fractionation section, a stripper or reboiler column type separation column is added which treats at least a portion of the heavy effluent obtained from the high pressure hot separator. All or a portion of the bottom fraction from said column, which is rich in polynuclear aromatic compounds, is purged. At least a portion of the bottom fraction obtained from the fractionation section, which is constituted by unconverted products, is recycled to the reaction section.
Abstract: The invention concerns a process for the oligomerization of ethylene into alpha-olefins, comprising a step for the oligomerization of ethylene, a step for deactivation of the catalyst, a and step for separation of the products, the reactor being provided with a cooling loop (100, 101, 102) by means of which at least a portion of the reaction effluent is moved through at least two switchable heat exchangers, said heat exchangers being cleaned alternately by means of an integrated cleaning device.
Type:
Application
Filed:
December 21, 2017
Publication date:
June 28, 2018
Applicants:
AXENS, IFP Energies Nouvelles
Inventors:
Catherine BOUTROT, Nicolas JANOT, Xavier LIEGE, Etienne NIDERKORN, Jerome PIGOURIER, Daniel Jean VINEL, Frederic FAVRE, Lionel MAGNA
Abstract: An installation for the hydrotreatment and hydroconversion of hydrocarbon-containing feedstocks, with a common fractionation section, for the production of at least one of the following products: naphtha (light and/or heavy), diesel, kerosene, distillate and residue: comprising at least: at least one hydroconversion reactor, a hot high-pressure separator drum B-1, a cold high-pressure separator drum B-2, at least one hydrotreatment reactor, a cold high-pressure separator drum B-20, a common fractionation section separating a top fraction, an intermediate fraction and a heavy fraction, An integrated hydroconversion and hydrotreatment process implementing said installation.
Abstract: A method for treatment of a gas having 10 to 0.5% by volume of at least one of COS and CS2, and 30 ppm to 5% by volume of unsaturated hydrocarbons: a) hydrogenation of organic compounds unsaturated with respect to paraffins by contacting the gas with a hydrogenation catalyst in the presence of hydrogen at 100 to 400° C., to provide an effluent that is low in unsaturated hydrocarbon compounds, the hydrogenation catalyst having at least one metal that is palladium, platinum, nickel, or cobalt deposited on a porous substrate. b) catalytic hydrolysis-hydrogenation in the presence of water of COS and/or CS2 present in the effluent of a) to provide an H2S-rich effluent by bringing the effluent from a) into contact with a hydrolysis-hydrogenation catalyst.
Type:
Application
Filed:
April 4, 2016
Publication date:
April 26, 2018
Applicant:
AXENS
Inventors:
Eric ROISIN, Nicolas LAMBERT, Yann LOONIS
Abstract: The present invention describes a device for controlling cooling of a heat transfer solid supplying or withdrawing heat to or from a unit carrying out globally endothermic or exothermic reactions respectively. The exchange bundle of said device is in a triangular pattern.
Abstract: A method for recovering heat available at low temperature in a process and its use in order to reduce the energy consumption of the said process, and application of this method to an aromatics complex in which the low-temperature heat is recovered at the head of distillation columns in the form of low-pressure steam and is reused to reboil other distillation columns in which the operating pressure has possibly been lowered.
Abstract: A process for producing jet fuel comprising the following steps: A.1) separating at least a portion of the C9 to C15 fraction from the product of a hydrocarbon synthesis process; A.2) converting at least a part of the separated C9 to C15 fraction to aromatic hydrocarbons; A.3) obtaining a jet fuel comprising the, optionally further treated, converted separated C9 to C15 fraction of step A.2); B.1) separating at least a portion of the C16+ fraction from the product of a hydrocarbon synthesis process; B.2) reducing the average number of carbon atoms of at least a portion of the separated C16+ fraction; B.3) optionally, separating the C9 to C15 fraction of at least a portion from the product obtained from step B.2); and B.4) adding at least a portion of the C9 to C15 fraction separated in step B.3), if present; or at least a portion of the product of step B.2).
Abstract: Process for deep conversion of heavy hydrocarbon feed, which includes: a) ebullated bed hydroconverting the feed in at least one three-phase reactor containing at least one supported hydroconversion catalyst; b) atmospheric fractionating effluent from a) producing gasoline fraction, gas oil cut, and atmospheric residue; c) vacuum fractionation of at least a portion of the atmospheric residue to obtain a vacuum gas oil fraction and an unconverted vacuum residue fraction; d) deasphalting at least a portion of the unconverted vacuum residue fraction with an organic solvent obtaining a hydrocarbon cut depleted in asphaltenes, termed deasphalted oil, and residual asphalt; and e) liquid/liquid extraction on the hydrocarbon cut depleted in asphaltenes extracting aromatics by a polar solvent producing an extract enriched in aromatics and resins and a raffinate depleted in aromatics and resins, at least a portion of the extract sent to the inlet of the hydroconversion as an aromatic diluent.
Abstract: The invention concerns a process and a facility for reducing the concentration of heavy polycyclic aromatic compounds (HPNA) in the recycle loop of hydrocracking units, which comprises a fractionation column. In accordance with this process, a portion of the stream present at the level of at least one plate located between the plate for supplying hydrocracked effluent and the plate for withdrawing the distillate fraction which is the heaviest is withdrawn from the fractionation column and at least a portion of said withdrawn stream is recycled to the column directly or after optional liquid separation, and optionally a portion of said withdrawn stream is recycled to the hydrocracking step directly or after optional gas separation.
Abstract: The invention concerns a process and a facility for reducing the concentration of heavy polycyclic aromatic compounds (HPNA) in the recycle loop of hydrocracking units, which comprises a fractionation column. In accordance with this process, a portion of the stream present at the level of at least one plate (I) which is the supply plate or a plate located between the supply plate and said residue evacuation point, or if stripping gas is injected, between the supply plate and said stripping gas injection point, is withdrawn from the fractionation column. A portion, preferably all, of said withdrawn stream is recycled to the hydrocracking step directly or after optional separation of the gases. The residue is purged in its entirety. In a preferred embodiment, a portion of the stream present at the level of at least one plate (II) located between the supply plate and the plate for withdrawing the heaviest distillate fraction is also withdrawn from the column.
Abstract: The invention concerns a fluid distribution device (1) comprising: at least one inlet tube (2) comprising openings (7) and having a first and a second end (3, 4); a cap (5) comprising a principal body (6) with a lenticular shape and with a circular section elongated by a skirt (8) extending in the direction of the second end (4) towards the first end (3) of the inlet tube (2), said cap (5) having an outer surface and an inner surface, the cap being integral with the second end (4) of the tube via the inner surface and the principal body (6) being provided with a plurality of holes (10); and in which the cap (5) comprises at least one deflection means (14) disposed on its outer surface and configured to direct or maintain the gas towards or at the periphery of said cap (5).
Type:
Grant
Filed:
June 10, 2014
Date of Patent:
December 5, 2017
Assignee:
AXENS
Inventors:
Jean Francois Le Coz, Daniel Ferre, Cyril Collado
Abstract: The invention concerns a process and a facility for reducing the concentration of heavy polycyclic aromatic compounds (HPNA) in the recycle loop of hydrocracking units, which comprises a fractionation column. In accordance with this process, a stream is withdrawn from the fractionation column at the level of at least one plate located between the supply plate and the plate for withdrawing the heaviest distillate fraction; the stream is stripped in an external stripping step by a stripping gas, in the presence of a portion of the residue. The separated gaseous effluent is recycled to the column, advantageously as a stripping gas, and the liquid fraction is recycled to the hydrocracking step; a residue is purged in the stripping step.
Abstract: The present invention concerns a device for limiting the entrainment of solid particles placed inside a three-phase fluidized reactor, said device being constituted by an assembly of flat or truncated cone-shaped plates ranked vertically in one or more rows, and the maximum section of the device being in the range 1 to 10 times the section of the outlet pipework for the effluents. It also concerns a three-phase process employing said device.
Abstract: A process for the intense conversion of a heavy hydrocarbon feed, comprising a) ebullated bed hydroconversion of the feed; b) separating at least a portion of hydroconverted liquid effluent obtained from a); c)i) either hydrotreatment of at least a portion of the gas oil fraction and of the vacuum gas oil fraction obtained from b), ii) or hydrocracking at least a portion of gas oil fraction and vacuum gas oil fraction obtained from b); d) fractionation of at least a portion of the effluent obtained from c)i) or c)ii); e) recycling at least a portion of unconverted vacuum gas oil fraction obtained from the fractionation d) to said first hydroconversion a); f) hydrocracking at least a portion of gas oil fraction obtained from fractionation d); g) recycling all or a portion of effluent obtained from f) to the fractionation d).
Abstract: A process for the isomerization of a feed of hydrocarbon compounds containing C5 and/or C hydrocarbon compounds, comprising: a) supplying an isomerization unit with at least one liquid fraction of the feed of hydrocarbon compounds and isomerizing the feed in the presence of a chlorinated catalyst; b) supplying a stabilization unit containing at least one stabilization column with the effluent obtained from the isomerization unit and separating the effluent; c) providing an absorption unit having one absorption column; d) extracting a liquid flow enriched in chlorinated compounds from the absorption unit which is recycled to the isomerization unit; and e) extracting the liquid flow containing at least one isomerate from the stabilization unit.
Type:
Grant
Filed:
October 19, 2015
Date of Patent:
August 29, 2017
Assignee:
AXENS
Inventors:
Jerome Pigourier, Isabelle Prevost, Laurent Watripont, Pierre-Yves Martin