Abstract: This invention relates to the conversion or hydrotreatment of petroleum or coal derived liquids in a novel ebullated-bed reactor system. The novel processing scheme results in a much simpler and less costly (investment and annual operating) ebullated-bed reaction system through the elimination of the high pressure, high temperature separator, hydrogen purification plant, and recycle gas compressor as well as a smaller hydrogen make-up compressor all resulting in substantial operational and construction efficiency.
Abstract: Process for hydrogenation of aromatic compounds in a feedstock comprising hydrocarbons having at least five carbon atoms, comprising: a) contacting feedstock, a hydrogen gas, and a nickel or platinum hydrogenation catalyst at 100 to 400° C., 0.5 to 8 MPa, and a feedstock flow rate 0.5 to 5 h?1, as to produce a partially-hydrogenated hydrocarbon feedstock and gas; and b) contacting the partially-hydrogenated feedstock, and a nickel or platinum hydrogenation catalyst at 100 and 400° C., a pressure of between 0.5 and 8 MPa, with a flow rate of the partially-hydrogenated feedstock between 0.3 and 8 h?1, a ratio between the volume of hydrogen and the volume of the partially-hydrogenated feedstock between 0.3 and 3 Nm3/m3, and a ratio between the superficial mass flow rate of the partially-hydrogenated feedstock and the superficial mass flow rate of gas (Ul/Ug) at the inlet of the reactor between 50 and 500.
Type:
Grant
Filed:
April 10, 2014
Date of Patent:
August 15, 2017
Assignee:
AXENS
Inventors:
Jean-Christophe Candelon, Fabienne Le Peltier, Annick Pucci
Abstract: A process for purifying a hydrocarbon feed, using a first adsorption unit with first and second adsorption columns respectively filled with first and second adsorbent solids by simultaneously: a) treating the liquid phase hydrocarbon feed in the first adsorption column by contact with the first adsorbent solid to adsorb at least a portion of impurities present and to produce hydrocarbon effluent which is depleted in impurities; b) treating a secondary liquid hydrocarbon feed constituted either by a fraction of the hydrocarbon feed or by a fraction of the hydrocarbon effluent and depleted in impurities to purify the secondary liquid hydrocarbon feed; c) heating the treated secondary liquid hydrocarbon feed from step b); d) regenerating the second adsorbent solid of the second adsorption column which comprises impurities with the secondary hydrocarbon feed heated in step c) to desorb the impurities to produce an effluent with impurities.
Abstract: The invention concerns an installation and a process which jointly implement compression of the acid gases from the hydroconversion or hydrotreatment unit and that of the gaseous effluents from the catalytic cracking unit.
Type:
Application
Filed:
December 22, 2016
Publication date:
June 29, 2017
Applicant:
AXENS
Inventors:
Odile LAJEUNESSE, Nicolas LAMBERT, Jacinthe FRECON, Jerome PIGOURIER
Abstract: The invention concerns a facility and a process for hydrotreatment or hydroconversion, in which the fractionation section comprises a stripper which operates on the overhead fraction obtained from a low pressure separator drum.
Type:
Application
Filed:
December 22, 2016
Publication date:
June 29, 2017
Applicant:
AXENS
Inventors:
Lajeunesse ODILE, Pierre-Yves ALSPEKTOR, Paris PACKEU, Nicolas PUPAT
Abstract: The invention relates to a process for oligomerising light olefins in which the effluent from the oligomerisation section is passed to a prefractionator that leads to at least one head fraction containing a mixture of liquefied petroleum gas and light gasoline and a bottom fraction containing a mixture of heavy gasoline and middle distillate, the said head fraction being passed to a debutaniser that leads to at least one liquefied petroleum gas cut and a light gasoline cut, the said bottom fraction and at least part of the said light gasoline cut being passed to a separator enabling at least a gaseous fraction, a gasoline fraction and a gasoil fraction to be obtained.
Abstract: The present invention describes a control system for units for the production of 1-butene by the oligomerization of ethylene in the presence of a homogeneous catalyst, in the liquid phase and at the bubble point, which uses a multivariable predictive controller and provides the units with better stability.
Abstract: The invention concerns a process for the production of middle distillates, comprising at least one step for the catalytic oligomerization of a feed comprising olefins containing 3 to 9 carbon atoms, in which the reaction section comprises at least two reactors which are positioned in series and which can be permutated, each containing at least one oligomerization catalyst for the oligomerization reactions, said catalysts being identical or different, and in which the reactor which is the furthest downstream in the direction of movement of said feed comprising olefins contains the catalyst with a period of service which is shorter than the period of service of the catalysts present in the other reactors and is operated at an average temperature (WABTn) which is lower than the average temperature (WABTn?1) of the reactor directly preceding it, the difference between said average temperatures being at least 10° C. (WABTn?1?WABTn?10° C.).
Abstract: The present invention relates to a process for desulfurizing a cracked naphtha containing organic sulfur compounds comprising the following steps: a) feeding the cracked naphtha to a distillation column comprising a bottom reboiler; b) fractionating said cracked naphtha into a light naphtha fraction and a heavy naphtha fraction which is removed as bottoms from the distillation column; c) feeding the heavy naphtha fraction and hydrogen to a hydrodesulfurization unit containing a hydrodesulfurization catalyst to produce a desulfurized heavy naphtha effluent. The process further comprises a step of providing heat to the distillation column by an intermediate reboiler powered with a heat source having a temperature lower than that one of the bottom reboiler.
Abstract: The present invention describes a process for the isomerization of a light naphtha with a view to forming high octane number gasolines, said process using a deisopentanizer and a deisohexanizer which are thermally integrated in a manner such as to reduce the consumption of the high temperature utilities employed in the process.
Abstract: The present invention describes a process for the production of high octane number gasoline by isomerization of a light naphtha cut, comprising two separation steps located downstream of the reaction step which can be used to improve the energy efficiency of said process.
Type:
Application
Filed:
April 20, 2015
Publication date:
February 16, 2017
Applicant:
AXENS
Inventors:
Jerome PIGOURIER, Isabelle PREVOST, Laurent WATRIPONT, Pierre-Yves MARTIN
Abstract: The invention provides a process for the preparation of xanthohumol, wherein a xanthohumol-containing extract is mixed with water, a transition metal salt solution is added to the obtained mixture, and then the obtained xanthohumol precipitate is collected and dried to obtain xanthohumol of the purity higher than 90%.
Abstract: The present invention describes a catalytic reactor operating as a moving bed to manage interruptions in the circulation of catalyst while at the same time avoiding mechanical damage to the contact means containing the catalyst. The invention also concerns a refining or petrochemicals process using the reactor in accordance with the invention.
Abstract: The invention relates to a process for purifying synthesis gas, comprising at least one stage for separating the crude synthesis gas to be treated into at least two effluents, namely a first part and a complementary part, in which the said first part is subjected to a carbon monoxide conversion stage with steam and the said complementary part is subjected to a COS and HCN catalytic hydrolysis stage, the two gas flows, namely the first part and complementary part, are then each treated separately in two stages intended to remove acid gases such as CO2 and H2S, by washing with aqueous solutions of specific amines, before a recombination stage of the two treated effluents.
Type:
Application
Filed:
December 16, 2014
Publication date:
December 22, 2016
Applicants:
AVRIL, AXENS, IFP ENERGIES NOUVELLES, BIONEXT, THYSSENKRUPP INDUSTRIAL SOLUTIONS AG, TOTAL RAFFINAGE CHIMIE, COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
Inventors:
David CHICHE, Anne Claire PIERRON, Norbert ULLRICH
Abstract: The present invention is a device (14) for sampling a solid from a sealed enclosure (12). The device comprises a body (18) carrying a sampling head (16) with a solid collection recess (28), a collected solid transfer recess (28?) and an angular-displacement shutter means (30) for the recesses controlled by the control means (48). The device also comprises means (78, 80) for limiting the angular clearance of the shutter means for no-load displacement (c) of the means.
Type:
Grant
Filed:
June 9, 2014
Date of Patent:
October 11, 2016
Assignee:
AXENS
Inventors:
Michel Munier, Jean Paul Gouzard, Rémi Girod
Abstract: The present invention concerns an integrated process for the production of liquid hydrocarbons starting from a feed containing at least one fraction of biomass and optionally at least one fraction of another feed, said process comprising at least one pre-treatment step, a gasification step, a step for conditioning synthesis gas, a water scrubbing step, a step for eliminating acid gases, a final purification step, and a catalytic Fischer-Tropsch synthesis reaction step.
Type:
Grant
Filed:
October 30, 2013
Date of Patent:
August 23, 2016
Assignees:
IFP ENERGIES NOUVELLES, AXENS, BIONEXT, COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, AVRIL, THYSSENKRUPP INDUSTRIAL SOLUTIONS AG, TOTAL RAFFINAGE CHIMIE
Inventors:
Guillaume Boissonnet, Michael Hecquet, Priscilla Avenier, Laurent Bournay, David Chiche, Jean-Philippe Heraud, Anne Claire Lucquin, Norbert Ullrich, Stéphane Fedou, Julien Rousseau, Raphael Lemaire, Jean-Christophe Viguie
Abstract: A process for the intense conversion of a heavy hydrocarbon feed, comprising a) ebullated bed hydroconversion of the feed; b) separating at least a portion of hydroconverted liquid effluent obtained from a); c)i) either hydrotreatment of at least a portion of the gas oil fraction and of the vacuum gas oil fraction obtained from b), ii) or hydrocracking at least a portion of gas oil fraction and vacuum gas oil fraction obtained from b); d) fractionation of at least a portion of the effluent obtained from c)i) or c)ii); e) recycling at least a portion of unconverted vacuum gas oil fraction obtained from the fractionation d) to said first hydroconversion a); f) hydrocracking at least a portion of gas oil fraction obtained from fractionation d); g) recycling all or a portion of effluent obtained from f) to the fractionation d).
Abstract: The invention concerns a process for the intense conversion of a heavy hydrocarbon feed, comprising the following steps: a) a first step for ebullated bed hydroconversion; b) a step for separating at least a portion of the hydroconverted liquid effluent obtained from step a); c) a step for hydrocracking at least a portion of the vacuum gas oil fraction obtained from step b); d) a step for fractionating at least a portion of the effluent obtained from step c); e) a step for recycling at least a portion of the unconverted vacuum gas oil fraction obtained from step d) to said first hydroconversion step a).
Abstract: A process for the isomerization of a feed of hydrocarbon compounds containing C5 and/or C6 hydrocarbon compounds, in which process: a) an isomerization unit (1) is supplied with at least one liquid fraction of the feed of hydrocarbon compounds and the isomerization is carried out in the presence of a chlorinated catalyst; b) a stabilization unit (20) containing at least one stabilization column (2) is supplied with the effluent obtained from the isomerization unit (1) and a separation is carried out in the stabilization unit (20); c) an absorption unit (7) contains at least one absorption column (3); d) a liquid flow enriched in chlorinated compounds is extracted from the absorption unit (7) and returned to the isomerization unit (1); e) the liquid flow containing at least one isomerate of the feed of hydrocarbon compounds is extracted from the stabilization unit (20).
Type:
Application
Filed:
October 19, 2015
Publication date:
April 21, 2016
Applicant:
AXENS
Inventors:
Jerome PIGOURIER, Isabelle PREVOST, Laurent WATRIPONT, Pierre-Yves MARTIN
Abstract: A reactor allowing continuous regeneration of catalyst grains having a chamber with an oxychlorination zone superposed on a calcination zone equipped with a pipe for introducing calcination gas and at least one pipe for injecting oxychlorination gas emptying into the inner space. Each gas passage has a gas evacuation device that is permeable to gas and impermeable to catalyst grains.