Patents Assigned to Cassella Aktiengesellschaft
  • Patent number: 4714766
    Abstract: The process for the preparation of 2-chlorobenzoxazoles of the formula ##STR1## wherein R.sup.1 and R.sup.2, independently of one another, are hydrogen or halogen comprising reacting a benzoxazolinone of the formula ##STR2## with a molar excess of phosphorus pentachloride.
    Type: Grant
    Filed: July 14, 1986
    Date of Patent: December 22, 1987
    Assignee: Cassella Aktiengesellschaft
    Inventors: Johannes Becherer, Reinhardt Handte, Hans J. Nestler, Ulrich Kussmaul
  • Patent number: 4695656
    Abstract: 2,4-Dinitrophenyl ethers are prepared by reacting a 2,4-dinitrochlorobenzene or 2,4-dinitrobromobenzene with an alkali metal alcoholate in a non-polar, inert solvent, at a temperature from -25.degree. C. to 50.degree. C.
    Type: Grant
    Filed: March 31, 1986
    Date of Patent: September 22, 1987
    Assignee: Cassella Aktiengesellschaft
    Inventors: Kuno Reh, Friedrich Schophoff
  • Patent number: 4686303
    Abstract: A process for preparation of diaryl sulphides by reaction of an aromatic diazonium salt in an alkaline medium with arenethiol is catalyzed by a non-metallic solid, such as charcoal, silica gel or aluminium oxide, having a specific surface of greater than or equal to 0.02 m.sup.2 /cm.sup.3.
    Type: Grant
    Filed: June 26, 1986
    Date of Patent: August 11, 1987
    Assignee: Cassella Aktiengesellschaft
    Inventors: Wolfgang Bauer, Manfred Langer, Winfried Sperling
  • Patent number: 4681891
    Abstract: 1,4-dihydropyridines of the formula I ##STR1## wherein R.sup.1 denotes optionally substituted phenyl, pyridyl or thienyl, R.sup.2 denotes optionally substituted oxadiazolyl, thiadiazolyl or thiazolyl and R.sup.3 denotes hydrogen or --COOH, their preparation by a modified Hantzsch synthesis and their use as a calcium-agonist in pharmacy.
    Type: Grant
    Filed: November 12, 1985
    Date of Patent: July 21, 1987
    Assignee: Cassella Aktiengesellschaft
    Inventors: Karl Schonafinger, Helmut Bohn, Piero Martorana, Rolf-Eberhard Nitz
  • Patent number: 4678476
    Abstract: Synthetic fiber materials are effectively colored by dyeing or printing with a dyestuff mixture containing at least two separate dyestuffs (I) and (II) in a weight ratio of (I):(II) of from (20 to 99):(80 to 1) wherein:(I) is at least one dyestuff of the formula ##STR1## and (II) is at least one dyestuff of the formula ##STR2## in which X and Y are the same or different and each is independently chloro and bromo:R.sup.1 and R.sup.
    Type: Grant
    Filed: September 26, 1986
    Date of Patent: July 7, 1987
    Assignee: Cassella Aktiengesellschaft
    Inventors: Horst Tappe, Hubert Kruse, Reinhard Kuhn, Albert Bode, Margareta Boos
  • Patent number: 4677209
    Abstract: 2-Mercaptobenzoxazoles of the formula ##STR1## wherein R is hydrogen or halogen and M is hydrogen or a metal atom, are prepared by reacting an ortho-aminophenol or metal salts thereof, with an alkali metal trithiocarbonate in aqueous solution.
    Type: Grant
    Filed: March 27, 1986
    Date of Patent: June 30, 1987
    Assignee: Cassella Aktiengesellschaft
    Inventors: Ulrich Kussmaul, Manfred Langer, Kuno Reh, Johannes Becherer, Herbert Wille, Rolf Muller
  • Patent number: 4666902
    Abstract: Tetrahydropyridazinones of the formula I ##STR1## wherein R denotes an optionally substituted carbocyclic or heterocyclic radical, R.sup.1 denotes hydrogen; alkyl; aralkyl, which is optionally substituted in the aryl part; or acyl, and R.sup.2 denotes hydrogen; alkyl, which can optionally be substituted; or optionally substituted phenyl; and their acid addition compounds, if these can be prepared.The tetrahydropyridazinone derivatives of the formula I according to the invention and their physiologically acceptable salts exhibit useful pharmacological actions.
    Type: Grant
    Filed: June 8, 1984
    Date of Patent: May 19, 1987
    Assignee: Cassella Aktiengesellschaft
    Inventors: Gerhard Zoller, Rudi Beyerle, Melitta Just, Piero Martorana, Helmut Bohn, Rolf-Eberhard Nitz
  • Patent number: 4620853
    Abstract: Dyestuff mixtures which contain dyestuffs (A) of the formula ##STR1## and dyestuff (B) of the formula ##STR2## in an (A):(B) weight ratio of (80 to 60):(20 to 40) useful for dyeing and printing hydrophobic fiber materials.
    Type: Grant
    Filed: December 9, 1985
    Date of Patent: November 4, 1986
    Assignee: Cassella Aktiengesellschaft
    Inventors: Horst Tappe, Klaus Hofmann, Manfred Hahnke, Albert Bode
  • Patent number: 4610984
    Abstract: This invention relates to certain 4-acyl-piperazine-1-acetamides. These compounds are useful as memory and learning enhancers and for the treatment and prevention of cerebral insufficiency.
    Type: Grant
    Filed: April 18, 1984
    Date of Patent: September 9, 1986
    Assignee: Cassella Aktiengesellschaft
    Inventors: Karl Schonafinger, Rudi Beyerle, Ursula Schindler, Piero Martorana, Rolf-Eberhard Nitz
  • Patent number: 4598079
    Abstract: Aryl-substituted piperazinones and their physiologically-acceptable acid-addition salts have a useful nootropic action. They are administered enterally or parenterally in conventional dosage forms.
    Type: Grant
    Filed: May 15, 1984
    Date of Patent: July 1, 1986
    Assignee: Cassella Aktiengesellschaft
    Inventors: Rudi Beyerle, Heinz Bender, Ursula Schindler, Rolf-Eberhard Nitz, Piero A. Martorana
  • Patent number: 4588413
    Abstract: Improvements in the fastness properties of substrates dyed with reactive dyestuffs are achieved by a dyeing after-treatment with an agent which is the reaction product polyethyleneimine and a bifunctional alkylating agent.
    Type: Grant
    Filed: July 19, 1984
    Date of Patent: May 13, 1986
    Assignee: Cassella Aktiengesellschaft
    Inventors: Karl-Heinz Keil, Fritz Engelhardt, Ulrich Greiner, Klaus Sternberger, Manfred Pelster
  • Patent number: 4585845
    Abstract: Crosslinked copolymers wherein crosslinking is effected with crosslinking bridge members of the formula ##STR1## wherein R.sup.1 and R.sup.2 independently of one another are each hydrogen or alkyl with 1 to 4 carbon atoms and m represents a number from 0 to 6 are prepared by copolymerization of monomers with vinylphosphonic acid (ester)-anhydrides and the new crosslinked polymers according to the invention are suitable for the preparation of acid-soluble coatings and encapsulation materials.
    Type: Grant
    Filed: April 9, 1984
    Date of Patent: April 29, 1986
    Assignee: Cassella Aktiengesellschaft
    Inventors: Friedrich Engelhardt, Klaus Kuhlein, Juliane Balzer, Walter Dursch, Hans-Jerg Kleiner
  • Patent number: 4582509
    Abstract: The mixture of monoazo dyestuffs containing at least different individual dyestuffs of the formula ##STR1## wherein R.sup.1 is alkyl of 1 to 6 carbon atoms, cyclopentyl, cyclohexyl, fluoro, chloro, bromo, alkoxy of 1 to 4 carbon atoms or trifluoromethyl,R.sup.2 is alkyl of 1 to 3 carbon atoms andR.sup.3 and R.sup.4, independently of each other, are alkyl of 1 to 4 carbon atoms,is highly suitable for dyeing and printing hydrophobic materials.
    Type: Grant
    Filed: February 4, 1985
    Date of Patent: April 15, 1986
    Assignee: Cassella Aktiengesellschaft
    Inventors: Ulrich Buhler, Manfred Hahnke, Albert Bode, Kurt Roth, Margarete Boos
  • Patent number: 4576973
    Abstract: The crosslinked, porous copolymer in the form of beads and containing 50 to 99.9% by weight of recurring units of a heterocyclic 5-membered ring compound which contains a polymerizable olefinic group and which has at least one protonizable nitrogen atom in the ring, 0.1 to 50% by weight of units of a crosslinking agent, 0 to 25% by weight of units of a polymerizable organoboron or organosilicon compound and, relative to 100% by weight of the sum of the abovementioned units, 5 to 350% by weight of units of an N-vinylamide of the general formula I CH.sub.2 .dbd.CH--N(R.sup.1)--C(R.sup.2).dbd.O wherein R.sup.1 denotes hydrogen, methyl or ethyl and R.sup.2 denotes hydrogen or C.sub.1 -C.sub.3 -alkyl, or several such N-vinylamides and 0 to 40% by weight of units of another polymerizable compound or several such compounds, is prepared by inverted suspension polymerization and is used, for example, as a sorbent for acid substances from solutions thereof, preferably aqueous solutions.
    Type: Grant
    Filed: June 22, 1984
    Date of Patent: March 18, 1986
    Assignee: Cassella Aktiengesellschaft
    Inventors: Karl-Heinz Keil, Fritz Engelhardt, Ulrich Greiner, Klaus Kuhlein, Reinhold Keller, Merten Schlingmann, Gerhard Hess
  • Patent number: 4571246
    Abstract: An improved process for production of discharge resist prints on textile material which contain hydrophobic fibers wherein at least one disperse dyestuff dischargeable to white discharge-resistant disperse dyestuff is applied, in the form of a dye liquor or printing paste, to the textile material and a discharge resist printing paste is printed on the material in the desired pattern, and the material is subsequently subjected to heat treatment at 100.degree. to 230.degree. C., wherein the improvement comprises the discharge resist printing paste containing, as the discharging agent, at least one salt of hydrogen sulphide, polysulphanes, compounds have a thiolate group of the formula --S.sup..crclbar. or a tautomerizable thio-group of the formula .dbd.S, and mixtures thereof.
    Type: Grant
    Filed: September 17, 1984
    Date of Patent: February 18, 1986
    Assignee: Cassella Aktiengesellschaft
    Inventors: Ulrich Buhler, Theo Stahl, Konrad Mix, Kurt Roth
  • Patent number: 4567252
    Abstract: Azo dyestuff of the formula ##STR1## wherein X is secondary amino or tertiary amino moiety, useful for dyeing and printing hydrophobic fiber materials to produce a deep orange color having excellent fastness properties and also useful for coloring organic solvents, mineral oil products, waxes, plastics and surface coatings.
    Type: Grant
    Filed: May 6, 1983
    Date of Patent: January 28, 1986
    Assignee: Cassella Aktiengesellschaft
    Inventors: Ulrich Buhler, Horst Tappe, Albert Bode, Manfred Hahnke, Kurt Roth
  • Patent number: 4564682
    Abstract: A compound of the formula ##STR1## is reacted with a phenol of the formula ##STR2## in the presence of an acid to produce a heterocyclic phenyl ether of the formula ##STR3## wherein each R is independently selected from halogen, trifluoromethyl, nitro, cyano, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms or alkylthio having 1 to 4 carbon atoms;A is oxygen, sulfur or N-alkyl having 1 to 4 carbon atoms; andn is a number from 0 to 3.
    Type: Grant
    Filed: February 27, 1984
    Date of Patent: January 14, 1986
    Assignee: Cassella Aktiengesellschaft
    Inventors: Ulrich Kussmaul, Johannes Becherer, Reinhard Handte, Rolf Muller
  • Patent number: 4558058
    Abstract: 1,4-dihydropyridines of the formula I ##STR1## in which R denotes, for example, --CO.sub.2 R.sup.3 or cyano, R.sup.1 denotes, for example, an optionally substituted phenyl, pyridyl or thienyl, R.sup.2 denotes the radical of a 5-membered, optionally substituted, ring having at least one double bond and at least 2 heteroatoms or heteroatom groups from the series comprising O, N, NH and S, and R.sup.3 denotes, for example, alkyl or alkoxyalkyl, and their acid addition salts, have valuable pharmacological properties.
    Type: Grant
    Filed: December 9, 1983
    Date of Patent: December 10, 1985
    Assignee: Cassella Aktiengesellschaft
    Inventors: Karl Schonafinger, Helmut Bohn, Melitta Just, Piero Martorana
  • Patent number: 4552905
    Abstract: The crosslinked copolymer containing 75 to 99.9% by weight of recurring units of a pyridyl, quinolyl, isoquinolyl or pyrazinyl compound containing a polymerizable olefinic group, 0.1 to 25% by weight of units of a crosslinking agent and 0 to 25% by a weight of units of a polymerizable organosilicon and/or organoboron compound and, based on 100% by weight of the sum of the abovementioned units, 5 to 350% by weight of units of an N-vinyl-amide, is prepared by bead polymerization and used as a sorbent for acid substances from their aqueous solutions.
    Type: Grant
    Filed: June 22, 1984
    Date of Patent: November 12, 1985
    Assignee: Cassella Aktiengesellschaft
    Inventors: Karl-Heinz Keil, Ulrich Greiner, Fritz Engelhardt, Klaus Kuhlein, Reinhold Keller, Merten Schlingmann
  • Patent number: 4552953
    Abstract: Monoazo dyestuffs, free of carboxylic acid moieties or sulphonic acid moieties, of the formula ##STR1## wherein A and A' independently of one another are linear or branched alkylene having 2 to 6 carbon atoms;R is hydrogen, alkyl having 1 to 4 carbon atoms, cycloalkyl having 5 or 6 carbon atoms, alkenyl having 3 to 5 carbon atoms, phenyl, benzyl, phenethyl, alkylcarbonyl having 1 to 4 atoms or benzoyl;m is a number from 1 to 5 and n is a number from 0 to 1.
    Type: Grant
    Filed: December 16, 1982
    Date of Patent: November 12, 1985
    Assignee: Cassella Aktiengesellschaft
    Inventors: Ulrich Buhler, Klaus Kuhlein, Horst Tappe, Maria Kallay, Uwe Kosubek, Rudolf Lowenfeld