Abstract: The invention provides for the use of copolymers containing structural units derived from the compounds of the formulae 1 and 2
in which
R1 is H or C1-C4 alkyl,
R2 is a branched or unbranched C1-C6 alkylene radical, and
Y is an alkali metal or ammonium to prevent misting in water-based cooling lubricants.
Abstract: Water-soluble or water-swellable polymers, preferably having a particle size no greater than 10 &mgr;m, which, in addition to from 0.01 to 5% by weight of crosslinking structures originating from monomers having at least two olefinic double bonds, comprise, in random distribution, from 1 to 50% by weight of the repeat structural unit (1) and from 49.99 to 98.
Abstract: Pigment preparations comprise
a) at least one diketopyrrolopyrrole pigment, and
b) at least one perylene pigment dispersant of the formula (I)
and have advantageous rheological and coloristic properties.
Abstract: C.I. Pigment Yellow 191 is obtained in new crystal polymorphs (beta, gamma, delta and epsilon phases) if the known alpha phase or another inventive phase of this pigment is treated with certain solvents and reprecipitated.
Type:
Application
Filed:
July 2, 2001
Publication date:
June 20, 2002
Applicant:
Clariant GmbH
Inventors:
Martin U. Schmidt, Arpad Acs, Rudiger Jung, Franz Schui
Abstract: The present invention relates to the use of a CuPc composition consisting essentially of CuPc, e.g., C.I. Pigment Blue 15:3, and a hydroxymethylphthalimido CuPc, as a colorant in electrophotographic toners and developers, powders and powder coating materials, electret materials, inkjet inks, and color filters, wherein the phthalocyanines have a particle morphology with an average length-to-width ratio of more than 2.5:1.
Type:
Grant
Filed:
November 16, 2001
Date of Patent:
June 18, 2002
Assignee:
Clariant GmbH
Inventors:
Hans-Tobias Macholdt, Ruediger Baur, Eduard Michel, Josef Geisenberger, Heidemarie Menzel, Andreas Harz
Abstract: The present invention relates to mixtures comprising from 70 to 99.5% by weight of a compound of the formula (R)4P+X− (1) and from 30 to 0.5% by weight of a compound of the formula (R)3P═O (2), where R is in each case a radical
and X− is an inorganic or organic anion or the equivalent of a multiply charged inorganic or organic anion, also to a process for preparing the mixtures by reacting a phosphorus pentahalide with pyrrolidine or piperidine in the molar ratio 1:6 to 1:50 in the presence of an inert solvent initially at −20 to 80° C., subsequently continuing the reaction at 90 to 180° C., treating the resulting reaction product at 0 to 80° C. with aqueous alkali at a pH of 7 to 15, and separating aqueous and organic phase from one another, and to the use of the mixtures as catalyst and cocatalyst for phase-transfer reactions, nucleophilic substitution reactions or halogen-fluorine exchange reactions.
Type:
Grant
Filed:
July 17, 2000
Date of Patent:
June 18, 2002
Assignee:
Clariant GmbH
Inventors:
Berthold Schiemenz, Thomas Wessel, Ralf Pfirmann, Andreas Beck, Walter Hahn
Abstract: The present invention relates to a polypropylene wax having a melt viscosity of from 50 to 100,000 mPas at 170° C., a DSC heat of fusion less than 80 J/g, a DSC melting point of greater than 130° C. and a molecular weight distribution Mw/Mn of less than or equal to 3.
Abstract: The invention relates to a crystalline alkali metal phyllosilicate of the formula
aMI2O.bEO2.cX2O5.dZO3.SiO2.eH2O,
in which MI is an alkali metal, E is an element of the fourth main group, X is an element of the fifth main group and Z is an element of the sixth main group of the Periodic Table of the Elements and the following also applies:
0.25≦a≦6.25
2.5·10−4≦b≦5.63
0≦c≦2.81
0≦d≦5.63
0≦e≦15.3.
The invention also relates to a process for the preparation of this crystalline alkali metal phyllosilicate and also to detergents and cleaners which comprise the crystalline alkali metal phyllosilicate according to the invention.
Type:
Grant
Filed:
September 11, 2000
Date of Patent:
June 18, 2002
Assignee:
Clariant GmbH
Inventors:
Harald Bauer, Josef Holz, Günther Schimmel
Abstract: The present invention provides water-soluble acid dyes of the formula (I)
in which
R1, R2 and R3 independently of one another are A—X—COOM, A—X—SO3M, OR4 or NR5R6,
A is NR7or S,
X is a straight-chain or branched (C1-C16)-alkylene radical, a straight-chain or branched, hydroxyl-, carboxyl- or amino-substituted (C1-C16)-alkylene radical, an arylene radical or a hydroxyl-, carboxyl- or sulfo-substituted arylene radical;
R4, R5, and R6 independently of one another are hydrogen or (C1-C4)-alkyl or are (C1-C4)-alkyl substituted by one or more hydroxyl, 2-hydroxyethoxy, (C1-C4)-alkoxy or amino groups,
R7 is hydrogen, methyl or ethyl;
M is a monovalent cation or one equivalent of a polyvalent cation, and which are suitable for printing natural and synthetic fiber materials for recording liquids, especially for the inkjet process, and for pulp-dyeing paper.
Type:
Grant
Filed:
March 13, 2000
Date of Patent:
June 18, 2002
Assignee:
Clariant GmbH
Inventors:
Wolfgang Bauer, Josef Geisenberger, Heidemarie Menzel, Reinhard Pedrazzi
Abstract: The invention relates to fine emulsions comprising at least one W/O emulsifier and at least one hydrophilic component, and to a process for their preparation. The fine emulsions are obtainable by converting a W/O preemulsion comprising at least one W/O emulsifier into an O/W fine emulsion by adding at least one hydrophilic component and, where appropriate, changing the temperature. Suitable W/O emulsifiers are preferably sorbitol esters. The fine emulsions are preferably spray emulsions for cosmetic and pharmaceutical applications.
Type:
Application
Filed:
July 20, 2001
Publication date:
June 13, 2002
Applicant:
Clariant GmbH
Inventors:
Dennis Miller, Torsten Henning, Wiebke Johannpeter, Eva-Maria Wiener
Abstract: The invention relates to six new crystal polymorphs, &agr; (alpha), &bgr; (beta), &ggr; (gamma), &dgr; (delta), &zgr; (zeta), and &eegr; (eta), of the disazo colorant of the formula I, 1
Type:
Application
Filed:
September 13, 2001
Publication date:
May 30, 2002
Applicant:
Clariant GmbH
Inventors:
Ruediger Jung, Hans-Joachim Metz, Joachim Weber, Martin U. Schmidt, Olaf Schupp, Andreas Wacker
Abstract: The invention relates to copolymers comprising a) 5-95% by weight of structural units which are derived from compounds of the formula 1
b) from 1 to 95% by weight of structural units which are derived from compounds of the formula 2
and
c1) from 1 to 95% by weight of structural units which are derived from compounds of the formula 3
or, alternatively, to c1),
c2) from 1 to 95% by weight of structural units which are derived from compounds of the formula 4
n which X is a cation. The copolymers according to the invention are suitable as a fluid loss additive for water-based drilling muds and for cement slurries in deep wells, for completion and clearing-out liquids and for water shut-off in production probes.
Type:
Grant
Filed:
June 8, 2000
Date of Patent:
May 28, 2002
Assignee:
Clariant GmbH
Inventors:
Reinhard J. Oswald, Roman Morschhäuser, Karl Heinz Heier, Aranka Tardi, Juergen Tonhauser, Christoph Kayser, Dan Patterson
Abstract: The present invention relates to terpene ethers of the general formula (I)
in which the substituents have the meanings defined in the description, to a process for their preparation and to their use.
The novel terpene ethers are suitable as traction fluids, as fragrances, as solvents and as reactive intermediates.
Type:
Grant
Filed:
March 19, 1999
Date of Patent:
May 28, 2002
Assignee:
Clariant GmbH
Inventors:
Adalbert Wagner, Frank Ebmeyer, Georg Stuhlmüller, Maximilian Simon, Herbert Vojacek
Abstract: Detergents and cleaners which comprise fatty acid alkyl ester alkoxylates of the formula
R1—COO(AO)n—R2
with narrow homolog distribution, where R1 is a straight-chain or branched alkyl or alkenyl group having from 5 to 22, preferably from 8 to 18, carbon atoms, R2 is C1-C6-alkyl or C2-C6-alkenyl, preferably methyl, AO is a C2-C4-alkylene oxide unit, and n is a number from 1 to 20, preferably from 3 to 12, in particular from 4 to 10, and these fatty acid alkyl ester alkoxylates contain less than 14% by weight of compounds with a content of no more than (a−3) —AO groups and less than 16% by weight of compounds with a content of not below (a+3) —AO groups, where A is the number of —AO groups with the maximum frequency.
Abstract: Aqueous liquids comprising a surfactant and an acetal. It has now surprisingly been found that readily biodegradable acetals are outstandingly suitable as solubility promoters in microemulsions and liquid-crystalline phases. On the basis of homogeneous single-phase liquids consisting of acetal and surfactant, it is also possible to prepare formulations without the addition of cosurfactants.
Type:
Application
Filed:
August 30, 2001
Publication date:
May 23, 2002
Applicant:
Clariant GmbH
Inventors:
Dennis Miller, Franz Xaver Scherl, Werner Skrypzak, Eva-Maria Wiener
Abstract: What is claimed are copolymers consisting essentially of from 1 to 90% by weight of the repetitive structural unit of the formula (1)
in which R1 is hydrogen or methyl, Z is a C1-C4-alkylene group and X is hydrogen, an alkali metal or ammonium, from 10 to 99% by weight of a repetitive structural unit which is derived from olefinically unsaturated comonomers containing at least one oxygen, nitrogen, sulfur or phosphorus atom and from 0 to 20% by weight of crosslinking structures originating from monomers having at least two olefinic double bonds.
These copolymers are suitable for use as drift control agents for crop protection compositions.
Abstract: Biaryls, e,g,. biphenyls, phenylpyridines, phenylfurans, phenylpyrroles, phenylthiophenes, bipyridines, pyridylfurans or pyridylpyrroles are prepared in high yields by coupling aromatics with an aromatic boric acid or boric ester in the presence of a palladaphosphacyclobutane catalyst.
Type:
Grant
Filed:
July 13, 2000
Date of Patent:
May 21, 2002
Assignee:
Clariant GmbH
Inventors:
Holger Geissler, Steffen Haber, Andreas Meudt, Frank Vollmueller, Stefan Scherer
Abstract: The present invention relates to aqueous dispersions preparable by polymerization of an olefinically unsaturated, water-insoluble compound in the presence of a water-soluble allyl or vinyl ether of the formula 1
in which
b is 0 or 1
n is 0 or 1
k is an integer from 1 to 20,
X is O or N[(A—O)m—R]
A is C2-C4-alkylene
m is an integer from 5 to 900, and
R is H or C1-C4-alkyl,
and in which A is not exclusively C3- or C4-alkylene, by mixing the olefinically unsaturated water-insoluble compound with the water-soluble allyl and vinyl ether in water, and triggering the polymerization by a free-radical initiator.
Type:
Grant
Filed:
July 13, 2000
Date of Patent:
May 21, 2002
Assignee:
Clariant GmbH
Inventors:
Klaus Pöllmann, Hendrik Ahrens, Achim Stankowiak