Abstract: Aromatic amines of the formula (I)
Ar—[NR6R7]n (I)
are prepared by reacting a haloaromatic of the formula (II)
Ar—Hal (II)
with an amine of the formula (III)
R6R7NH (III)
in the presence of a palladaphosphacyclobutane and a base and in the presence or absence of an ionic halide in a solvent at temperatures of from 20 to 200° C.
Type:
Grant
Filed:
September 8, 2000
Date of Patent:
March 5, 2002
Assignee:
Clariant GmbH
Inventors:
Holger Geissler, Steffen Haber, Stefan Scherer, Andreas Meudt, Frank Vollmueller
Abstract: The present invention relates to dispersion powders comprising
a) at least one base polymer from the group consisting of the vinyl ester, vinyl ester comonomer, vinyl ester/ethylene, (meth)acrylate and styrene/acrylate polymers,
b) from 1 to 25% by weight, based on the base polymer, of at least one protective colloid,
c) from 1 to 25% by weight, based on the base polymer, of at least one partially acetalized, water-soluble polyvinyl alcohol,
d) from 0 to 20% by weight, based on the total polymer weight, of anticaking agent and
e) if required, further additives,
the use of these, and process for their preparation.
Type:
Grant
Filed:
January 12, 2000
Date of Patent:
February 26, 2002
Assignee:
Clariant GmbH
Inventors:
Ludwig Schmitz, Michael Schottler, Robert Fuss
Abstract: The present invention relates to a process for the preparation of an isochroman-3-one of the formula (I)
by reaction of a 1,2-bishalomethylbenzene of the formula (II)
in which X is chlorine, bromine or iodine, with carbon monoxide and a compound of the formula (III)
R5R6R7C—OH (III)
at a CO pressure of 0.1 to 50 MPa and a temperature of 20 to 200° C.
Abstract: The present invention relates to a process for separating hydrogen chloride from a mixture comprising an N-(C1-C18)-alkyl-2-pyrrolidone and hydrogen chloride by distilling the mixture comprising an N-(C1-C18)-alkyl-2-pyrrolidone and hydrogen chloride at from 100 to 220° C. and from 50 to 850 hPa in the presence of water by means of a distillation column, condensing the water as water-hydrogen chloride azeotrope at the top by cooling, returning the water-hydrogen chloride azeotrope to the distillation column, separating off gaseous hydrogen chloride at the top and taking off the N-(C1-C18)-alkyl-2-pyrrolidone from the bottom.
Abstract: The invention relates to a flame retardant combination for thermoplastic polymers comprising, as component A, a salt of 1-hydroxydihydrophosphole oxides of formula (Ia) or formula (Ib) and/or 1-hydroxyphospholane oxides of formula (II),
and, as component B, a synthetic inorganic compound and/or a mineral product.
Type:
Grant
Filed:
January 29, 2000
Date of Patent:
February 5, 2002
Assignee:
Clariant GmbH
Inventors:
Elke Schlosser, Bernd Nass, Wolfgang Wanzke
Abstract: The invention provides hair-treatment compositions which comprise at least one quaternary ammonium compound and a pearly luster concentrate comprising a lusterizing component and nonionic, amphoteric and/or zwitterionic surfactants and water. In a preferred embodiment, the pearly luster concentrates comprise titanium dioxide.
Abstract: Aqueous or aqueous-alcoholic body cleansing compositions comprising sorbitol esters obtained by transesterification of optionally oxalkylated sorbitol with fatty acid methyl esters or fatty acid triglycerides and optional oxalkylation of the reaction products obtained by transesterification with fatty acid methyl esters. The sorbitol esters serve as solubilizing agents of active ingredients, as stabilizer, and as care and refatting components.
Type:
Application
Filed:
March 5, 2001
Publication date:
January 24, 2002
Applicant:
Clariant GmbH
Inventors:
Torsten Henning, Vera Mulitze-Kleinheyer
Abstract: A process for preparing diketopyrrolopyrrole pigments comprises conducting the elementary steps of pigment synthesis (reaction and hydrolysis) in a miniaturized continuous reactor.
Abstract: Body-cleansing compositions are claimed which comprise oligoesters obtained by condensation of one or more dicarboxylic acids or esters thereof and one or more polyhydric alcohols.
Type:
Application
Filed:
January 26, 2001
Publication date:
January 17, 2002
Applicant:
Clariant GmbH
Inventors:
Matthias Loffler, Vera Mulitze-Kleinheyer
Abstract: The present invention relates to homopolymer and copolymer waxes which have been prepared by polymerization using metallocene compounds in the presence of hydrogen and have a melt viscosity of less then 100 mPas, measured at 170° C. As a result of their high thermal stabillty, these waxes display neither discoloration nor crosslinking reactions and are vary well suited for use in toners, for plastics processing, for masterbatches, for printing inks, surface coatings and melt adhesives.
Abstract: Polyvinyl ester dispersions which can be employed as binders in building materials, preferably in the form of redispersible plastics powders, are obtained by polymerization of at least one vinyl ester and optionally other monomers which can be copolymerized with vinyl ester, by use of water-soluble cationic azo initiator.
Abstract: The invention relates to a process for preparing dialkylphosphinic acids and/or alkali metal salts thereof by reacting olefins with alkylphosphonous and/or hypophosphorous acid and/or alkali metal salts thereof, which comprises carrying out the reaction in the presence of a azo free-radical initiator. The invention also relates to the use of the products prepared by the abovementioned process for preparing flame retardants.
Abstract: The invention provides a process for the preparation of ether carboxylic acids or alkali metal or ammonium salts thereof with low residual alcohol content, which comprises firstly converting a mono- or polyhydric alcohol into the corresponding alkoxide using a substoichiometric amount between 5 and 95 mol % of a basic compound, and then reacting the alkoxide with alkylene oxides, and, if necessary after distilling off the residual alcohol which remains, alkylating the highly alkaline reaction mixture, which comprises more than 5 mol % of alkoxylated alkoxides, directly with a chloroacetic acid derivative, and, if necessary, converting the alkylated product into the free ether carboxylic acid by acidification with mineral acid.
Type:
Grant
Filed:
June 19, 2000
Date of Patent:
December 4, 2001
Assignee:
Clariant GmbH
Inventors:
Peter Klug, Rainer Kupfer, Ignaz Wimmer, Rüdiger Winter
Abstract: The present invention relates to a wax mixture comprising
a) 10-80% by weight of partial esters of polyols with carboxylic acids or carboxylic acid mixtures having a chain length of C16-C36;
b) 0-30% by weight of partial esters of polyols with polybasic carboxylic acids having a chain length of C4-C36; and
c) 20-90% by weight of alkaline earth metal soaps of the abovementioned carboxylic acids or carboxylic acid mixtures, with the proviso that 1,2-ethanediol and 1,3-butanediol are excluded. The wax mixtures are highly suitable for the preparation of solvent pastes as a single component or in combination with synthetic, natural or semi-synthetic wax-like products, as lubricants or release agents in plastic or metal processing, and for the preparation of microfine wax powders.
Type:
Grant
Filed:
December 17, 1999
Date of Patent:
November 13, 2001
Assignee:
Clariant GmbH
Inventors:
Franz-Leo Heinrichs, Monika Drechsler, Werner Kapfer, Andree Henze