Abstract: Pigment preparations comprising an organic pigment and a phenol-modified natural resin derivative having a weight-average molecular weight (Mw) of from 400 to 10,000 g/mol which is obtainable by reacting a mixture of reactants containing
a) from 50 to 95% by weight of natural resin or natural resin acids,
b) from 0.5 to 30% by weight of monocyclic or polycyclic phenols,
c) from 0.01 to 15% by weight of aldehydes or aldehyde acetals,
d) from 0.001 to 2% by weight of metal compounds from groups Ia and IIa of the Periodic Table, and
e) from 4.489 to 30% by weight of &agr;,&bgr;-ethylenically unsaturated carboxylic acids or their anhydrides
and has an acid number in the range from 160 to 300 mg of KOH per g of resin, preferably from 200 to 260 mg of KOH per g of resin, are used advantageously in offset printing.
Type:
Grant
Filed:
August 17, 1999
Date of Patent:
September 18, 2001
Assignee:
Clariant GmbH
Inventors:
Hans Joachim Metz, Joachim Weide, Thomas Wallach
Abstract: The present invention relates to water-soluble, organosilylated cellulose ethers in which the organosilyl groups are attached hydrolysis-stably to the cellulose ethers and the remaining substituents on the silicon atoms of the organosilyl groups are likewise stable to hydrolysis. The cellulose ethers of the invention exhibit a strongly thickening action in aqueous solution, even at very low degrees of silylation, and are suitable as thickeners, for example, in paints, adhesives, and cosmetics. They are further suitable as protective colloids in the preparation of polymer dispersions.
Abstract: The invention relates to a process for preparing 4-(4′-carboxyphenyl)pyridine, which comprises oxidizing a 4-phenyl-N-acyldihydropyridine of the formula (II) 1
Type:
Application
Filed:
February 15, 2001
Publication date:
September 13, 2001
Applicant:
Clariant GmbH
Inventors:
Andreas Meudt, Stefan Scherer, Peter Koch, Gerhard Demmer, Frank Vollmuller
Abstract: In the process according to the invention, the cellulose ether to be depolymerized is depolymerized in the form of an acid slurry in an apparatus which consists of an acid-resistant material and is provided with an inlet and outlet, where the inlet and outlet are separated from one another by a filter element, at a temperature above the flocculation temperature of the depolymerized cellulose ether in the space between the inlet and the filter element, subsequently neutralized and then separated from the filtrate by releasing the filtrate, which, in contrast to the cellulose ether, is not retained by the filter element. If necessary, this can be followed by purification and drying of the cellulose ether.
Abstract: The novel two-stage process described here makes it possible to obtain substituted benzyl compounds and toluene derivatives in a simple manner and in high yields by means of Suzuki-type coupling reactions of an aromatic with an organoboron compound, followed by a reduction. The process is particularly useful for preparing ortho-substituted benzyl compounds and toluene derivatives. The process can be applied to both intermolecular and intramolecular coupling reactions. Catalysts used for the coupling reaction are palladium compounds and/or nickel compounds. An advantageous aspect is that only very small amounts of catalyst are required.
Type:
Application
Filed:
February 22, 2001
Publication date:
September 6, 2001
Applicant:
Clariant GmbH
Inventors:
Steffen Haber, Stefan Scherer, Heinz Georg Kautz, Andreas Meudt, Frank Vollmuller
Abstract: Oral and dental care compositions comprising sorbitol esters obtained by transesterification of optionally oxalkylated sorbitol with fatty acid methyl esters or fatty acid triglycerides and optionally oxalkylation of the reaction products obtained by transesterification with fatty acid methyl esters.
Abstract: The present invention relates to fuel/water emulsions essentially comprising 60 to 80% by weight of a fuel, 0.5 to 5% by weight of one or more water-soluble and gasoline-insoluble emulsifiers of the formulae
A) R—O—(CH2CH2O)x—H
where R is alkyl or alkenyl having in each case 8 to 18 carbon atoms or C9-C14-alkylphenyl and x is a number from 8 to 30, or
B) HO—(C2H4O)x—(C3H6O)y—(C2H4O)z—H,
in which the proportion of the ethylene oxide units is between 40 and 80% by weight of the molecular mass, or
where x is a number between 8 and 30, and 1 to 10% by weight of a water-soluble and gasoline-insoluble poly(alkylene glycol) as stabilizer, also water and, if appropriate, other additives to 100% by weight. The emulsions according to the invention can be used for operating internal combustion engines.
Type:
Grant
Filed:
January 15, 1998
Date of Patent:
August 28, 2001
Assignee:
Clariant GmbH
Inventors:
Guido Dessauer, Ute Horn, Helmut Berenbold, Gerhard Crass
Abstract: The invention relates to mixtures comprising
A) from 10 to 90% by weight of at least one copolymer comprising structural units derived from ethylene and structural units derived from olefinically unsaturated, hydroxyl-containing compounds, and
B) from 90 to 10% by weight of at least one copolymer comprising structural units derived from ethylene and structural units derived from vinyl esters, olefinically unsaturated ethers and/or acrylates.
Type:
Grant
Filed:
May 26, 1999
Date of Patent:
August 28, 2001
Assignee:
Clariant GmbH
Inventors:
Matthias Krull, Werner Reimann, Markus Kupetz
Abstract: The present invention relates to the use of an absorption liquid for purifying a gas by removal of gaseous, acidic impurities. The gas to be purified can be any gas, such as synthesis gas or natural gas, which contains gaseous, acidic impurities such as CO2, H2S, SO2, CS2, HCN, COS or mercaptans. The absorption liquid comprises:
A) from 0.01 to 4% by weight of at least one compound of the formula
B) from 0.001 to 8.0% by weight of water, and
C) at least one polyalkylene glycol alkyl ether of the formula
R1—O—(R2—O)x—R3
to 100% by weight,
where
R1 is C1-C4-alkyl,
R2 is ethylene or 2-methylethylene,
R3 is hydrogen or C1-C4-alkyl,
R4 is hydrogen or C1-C4-alkyl,
R5 is C1-C4-alkylene and
X is an integer from 1 to 10. The amine may be N-methyldiethanolamine and the ether may be polyethylene glycol dimethyl ether.
Type:
Grant
Filed:
November 23, 1999
Date of Patent:
August 21, 2001
Assignee:
Clariant GmbH
Inventors:
Achim Stankowiak, Horst Streitberger, Michael Wyschofsky
Abstract: The present invention relates to copolymers consisting of
(a) 1-99% by weight of structural units of the formula (1)
where R1 is hydrogen or methyl, R4 is C1-C22-alkylene, R5 is C1-C22-alkyl or hydrogen, and X is ammonium, lithium, sodium, potassium, an amine or a mixture of these substances, and
(b) 99-1% by weight of structural units of the formula (2)
where R1 is hydrogen or methyl, R2 and R3, independently of one another, are hydrogen, or C2-C22-alkyl,
wherein component b) is not hydrolysed and the copolymers have been prepared by a solution precipitation polymerization in a nonaqueous solvent or a water-miscible, organic solvent having a low water content which is a precipitant for the copolymer. The invention furthermore relates to a process for cementing subterranean wells using a cement slurry comprising the following components:
a) water of various salinity
cement
a novel copolymer in a concentration of 0.01-5% bwoc, preferably from 0.05 to 0.
Abstract: The present invention relates to a process for the preparation of phosphinic acid esters, which comprises
a) reacting elemental yellow phosphorus with alkylating agents in the presence of a base to give a mixture which comprises, as principal constituents, the (metal) salts of alkylphosphonous, phosphorous and hypophosphorous acids,
b) esterifying the principal constituents of the mixture from a) to give an ester mixture,
c) isolating the ester of the alkylphosphonous acid from the ester mixture,
d) adding the resultant ester of the alkylphosphonous acid onto an olefin containing a functional group.
The invention likewise relates to the use of the phosphinic acid esters prepared by this process, inter alia as flame retardants and precursors for further syntheses.
Type:
Grant
Filed:
May 24, 2000
Date of Patent:
August 21, 2001
Assignee:
Clariant GmbH
Inventors:
Sebastian Hörold, Norbert Weferling, Heinz-Peter Breuer, Martin Sicken
Abstract: The invention relates to a synthetic magnesium silicate having a layered crystalline structure, to a process for its preparation and to its use.
Type:
Grant
Filed:
June 30, 1998
Date of Patent:
August 14, 2001
Assignee:
Clariant GmbH
Inventors:
Harald Bauer, Günther Schimmel, Volker Thewes
Abstract: Dispersion powders with a reduced tendency to autoignition are obtained by adding antioxidants to dispersions before spray drying or to dispersion powders after spray drying.
Abstract: The invention relates to storage-stable bleach activator granules consisting essentially of a bleach activator and an acid-modified phyllosilicate, prepared by mixing a dry bleach activator with a dry, acid-modified phyllosilicate, compressing this mixture to give relatively large agglomerates and comminuting these agglomerates to the desired particle size.
Abstract: The invention relates to a granular alkali metal phyllosilicate compound which comprises a crystalline alkali metal phyllosilicate, a colorant and an additive. The invention also relates to a process for its preparation, and to detergents and cleaners which comprise such a granular alkali metal phyllosilicate compound.
Type:
Application
Filed:
December 15, 2000
Publication date:
July 26, 2001
Applicant:
Clariant GmbH
Inventors:
Harald Bauer, Josef Holz, Gunther Schimmel
Abstract: The invention relates to a process for the preparation of 4-(4′-chlorobiphenyl-4-yl)-4-keto-2-methylenebutyric acid of the formula (I)
by Friedel-Crafts acylation of 4-chlorbiphenly with itaconic anhydride, which comprises carrying out the Friedel-Crafts acylation in aromatic solvents at a temperature from −20 to +80° C.
Type:
Grant
Filed:
August 3, 1999
Date of Patent:
July 24, 2001
Assignee:
Clariant GmbH
Inventors:
Andreas Meudt, Wilfried Pressler, Antje Noerenberg, Steffen Haber, Michael Erbes, Robert Cosmo
Abstract: The invention relates to a pigment preparation comprising an organic pigment and 0.2 to 20% by weight, based on the total weight of the pigment preparation, of an ammonium polyphosphate or of an organophosphorus compound.
Type:
Application
Filed:
December 8, 2000
Publication date:
July 12, 2001
Applicant:
Clariant GmbH
Inventors:
Rudiger Jung, Klaus Saitmacher, Arpad Acs