Patents Assigned to Hercules
  • Patent number: 4923943
    Abstract: A cross-linked copolymer comprising repeating units derived from a mixture comprising metathesis polymerizable cyclic compounds such as dicyclopentadiene and carboxylic acid esters of which the acid residue and alcohol residue have individually at least one norbornene-moiety, a process for producing the copolymer, a process for producing a molded article from the copolymer and a polymerizable composition therefor.
    Type: Grant
    Filed: March 14, 1988
    Date of Patent: May 8, 1990
    Assignee: Hercules Incorporated
    Inventors: Shigeyoshi Hara, Zen-ichiro Endo
  • Patent number: 4924413
    Abstract: An apparatus and method in which a color graphics display system can run software written for either a color graphics system or a monochrome system, and in which a monochrome graphics system can run software written for either a monochrome system or a color graphics system, in which color image data is separated into monochrome image data and color control information so that a central processing unit can operate upon the image data as if running a monochrome program, yet continue to provide a color visual display by use of color control information which designates the colors to be displayed as part of a control operation.
    Type: Grant
    Filed: May 29, 1987
    Date of Patent: May 8, 1990
    Assignee: Hercules Computer Technology
    Inventor: Sakarin Suwannukul
  • Patent number: 4923703
    Abstract: A container comprising an uniaxially oriented, polyolefin film, which film is prepared by melt blending a mixture of a polyolefin, an inert filler, a processing aid such as calcium stearate, and optionally a stabilizer, maintaining the moisture level in the melt blend below 700 ppm, casting a film, and uniaxially stretching the film at least about 2 times its original casting dimensions in one direction until the film has a sufficient number of elongated, narrow shaped, microporous voids in order to create a CO.sub.2 and O.sub.2 permeance in the range of 5,000 to 10,000,000 cc/100.sup.2 - atm - day. Such a film is used in a controlled atmosphere packaging container as a panel in a window for a controlled flow or flux of CO.sub.2 and O.sub.2 through its wall in an otherwise gas impermeable container.
    Type: Grant
    Filed: May 22, 1989
    Date of Patent: May 8, 1990
    Assignee: Hercules Incorporated
    Inventor: Mitchell K. Antoon, Jr.
  • Patent number: 4920743
    Abstract: A propellant composition and method for limiting the corrosive properties of by-products from initiated crash bag propellant compositions comprising a 1(a) or 2(a) group metal azide salt, an oxidizer in the form of an oxide of a non-toxic transition metal element, and an effective amount of a modifier component of the formulaMe.sub.x (An).sub.owhereinMe is a metal cation selected from iron, copper, cobalt, nickel, and molybdenum;An is an anion group which is chemically compatible with and capable of reacting with the metal of the azide salt to form nitrogen gas and non-toxic by-products less corrosive than the corresponding hydroxide of the azide metal would be; andx and o are individually defined as positive numbers appropriate to indicate the correct chemical formula.
    Type: Grant
    Filed: July 25, 1988
    Date of Patent: May 1, 1990
    Assignee: Hercules Incorporated
    Inventor: Richard V. Cartwright
  • Patent number: 4921882
    Abstract: An electron beam irradiated release film is formed from a melt processible composition including a silicone component crosslinked by the reaction of a hydride-containing silicone and a silicone containing an unsaturated substituent within a polymeric thermoplastic matrix to form a silicone pseudo-interpenetrating polymer network. The crosslinking of the silicone component by reaction of the hydride and unsaturated substituents is inititated during thermoplastic melt-mixing and film forming of the component with the matrix. Coated films are preferably formed by coextrusion of a polymeric thermoplastic film and a crosslinkable mixture of the silicone components and a polymeric thermoplastic. Alternatively, extrusion coating of the mixture onto a preformed film may be used to form the coated films. Preferably, these films have a thickness of from 0.000005 to 0.2 inch. The film is electron beam irradiated with a dose of from about 50 rad to about 50 Mrad.
    Type: Grant
    Filed: June 16, 1988
    Date of Patent: May 1, 1990
    Assignee: Hercules Incorporated
    Inventor: George A. Senich
  • Patent number: 4919724
    Abstract: Stabilized aqueous emulsions of ketene dimer and nonreactive hydrophobe and method for sizing unbleached fibers and undigested wood chips for use in building products are provided.
    Type: Grant
    Filed: January 17, 1989
    Date of Patent: April 24, 1990
    Assignee: Hercules Incorporated
    Inventors: Marco F. Cenisio, Vido J. Vareika
  • Patent number: 4920060
    Abstract: In a chemical analysis system a sample liquid is passed through a non-wetting porous membrane from a reservoir of sample liquid to a flowing stream of diluent which is constantly flowing when the sample liquid penetrates the membrane under positive pressure differential from the sample side of the membrane. The pressure differential is suitably obtained both by means for exerting pressure on the sample liquids as for example on a stream of sample liquid on the entry side of the membrane as well as a reduction in pressure on the exit side of the membrane. The passage of the sample liquid through the non-wetting porous membrane requires a minimum liquid entry pressure differential across the membrane to cause enough penetration to give a sample liquid which provides in an analyzed diluent stream a detectable presence of the sample liquid in an analytical detector receiving and measuring the stream.
    Type: Grant
    Filed: April 8, 1988
    Date of Patent: April 24, 1990
    Assignee: Hercules Incorporated
    Inventors: George B. Parrent, Jr., Harold Hauer
  • Patent number: 4918039
    Abstract: A metathesis polymerization catalyst composition comprising a binuclear catalyst, wherein said binuclear catalyst is a mixture of at least two transition metal components, wherein a first transition metal component is a halide complex of tungsten, an oxyhalide complex of tungsten or a mixture thereof and a second transition metal component is a halide complex of a transition metal selected from the group consisting of high valent transition metals belonging to Groups IV or V of the Periodic Table, from about 1 to about 3 moles of phenolic compound per mole of tungsten component, activated by a metathesis catalyst activator and containing a rate moderator.
    Type: Grant
    Filed: September 21, 1988
    Date of Patent: April 17, 1990
    Assignee: Hercules Incorporated
    Inventor: Andrea E. Martin
  • Patent number: 4918138
    Abstract: A process for producing a colored cross-linked molded article by metathesis polymerizing in a mold a mixture comprising metathesis polymerizable monomers such as dicyclopentadiene and a metathesis polymerizable multi-part composition therefor.
    Type: Grant
    Filed: February 15, 1989
    Date of Patent: April 17, 1990
    Assignee: Hercules Incorporated
    Inventors: Shigeyoshi Hara, Zen-ichiro Endo, Umewaka Nakatani
  • Patent number: 4918146
    Abstract: It has been found that the properties of polycyclic cycloolefins, in particular poly(dicyclopentadiene), can be substantially improved by halogenation of the surface. Both aqueous and gaseous treatments of the polymer have been found to significantly improve the resistance to various acids and solvents. Chlorine, fluorine and bromine, in particular, when incorporated into the surface of the polymer increase chemical resistance, improve retention of properties upon aging, reduce emission of residual monomer, and encourage better adhesion of paint.Among the substances found to provide the desired chemical resistance on the polymer surface were dry chlorine gas, aqueous chlorine, immersion in liquid bromine, aqueous bromine, and fluorine gas. Similar improvement in chemical resistance can be obtained through treatment with pseudohalogen compounds or interhalogen compounds.
    Type: Grant
    Filed: April 20, 1989
    Date of Patent: April 17, 1990
    Assignee: Hercules Incorporated
    Inventor: Albert S. Matlack
  • Patent number: 4910032
    Abstract: A container capable of creating within it preselected CO.sub.2, O.sub.2, and moisture concentrations in the presence of respiring fresh fruit, vegetables, or flowers is constructed of a substantially gas-impermeable material having a gas-permeable panel that is substantially impermeable to moisture in one or more of its walls to provide a controlled flow of CO.sub.2 and O.sub.2 through its walls and a cellophane panel that is substantially impermeable to the flow of CO.sub.2 and O.sub.2 in one or more of its walls to provide a controlled flow of moisture through its walls. The gas-permeable panel is a uniaxially or biaxially oriented film where the size of the area it covers is a function of its permeance, the amount and respiration rate of the contents, and the desired steady-state oxygen concentration. The size of the cellophane panel is a function of its permeance to water vapor and the desired rate of removal of water vapor from the package.
    Type: Grant
    Filed: November 16, 1988
    Date of Patent: March 20, 1990
    Assignee: Hercules Incorporated
    Inventor: Mitchell K. Antoon, Jr.
  • Patent number: 4907609
    Abstract: Filter element and method for increasing the hardness thereof by contacting filter plug material with effective amounts of (a) a water soluble resin (or copolymer) having available chelate bond-forming chemical groups and (b) a water soluble nontoxic salt, the metal cation of the nontoxic salt forming a chelate bond with the chelate bond-forming chemical groups of said water soluble resin.
    Type: Grant
    Filed: August 24, 1988
    Date of Patent: March 13, 1990
    Assignee: Hercules Incorporated
    Inventors: Richmond R. Cohen, Jimmie D. McCarty
  • Patent number: 4904520
    Abstract: Disclosed is a liquid-impermeable, gas-permeable nonwoven material comprising a thermally consolidated blend of (1) 5% to 30% of a first polyolefin pulp, (2) 15% to 90% of a second polyolefin pulp having a melting point at least 20.degree. C. higher than the first polyolefin pulp, and (3) 5% to 55% of a staple fiber. Also disclosed is a wet forming method for making such a nonwoven material without the use of surfactants.
    Type: Grant
    Filed: October 17, 1988
    Date of Patent: February 27, 1990
    Assignee: Hercules Incorporated
    Inventors: David H. Dumas, Elliott Echt
  • Patent number: 4902560
    Abstract: A method of preparing a glass fiber-reinforced, crosslinked polymer structure which comprises saturating an uncoated, unsized woven glass fabric with a polymerizable liquid comprised of dicyclopentadiene and, optionally, one or more other metathesis polymerizable strained ring polycyclic cycloolefins, subjecting said saturated fabric to polymerization conditions, and, thereafter, post-curing the resultant structure at a temperature greater than about 225.degree. C., and a glass fiber-reinforced, crosslinked polymer prepared by that process, are disclosed. Post-curing at temperatures greater than 225.degree. C. enhances the physical properties of the woven fiber-reinforced, crosslinked polymer.
    Type: Grant
    Filed: June 1, 1988
    Date of Patent: February 20, 1990
    Assignee: Hercules Incorporated
    Inventor: Paul A. Silver
  • Patent number: 4902731
    Abstract: A novel organosilicon prepolymer, which is the partial reaction product of (a) a cyclic polysiloxane or a tetrahedral siloxysilane containing at least two hydrosilane groups and (b) a polycyclic polyene having in its rings at least two chemically distinguishable carbon-carbon double bonds, wherein the ratio of carbon-carbon double bonds in the rings of (b) to hydrosilane groups in (a) is greater than 0.5:1 and up to 1.8:1, and at least one of the compounds (a) and (b) has more than two reactive sites, a method for making the organosilicon prepolymer, and a method for preparing an organosilicon polymer therefrom, are disclosed.
    Type: Grant
    Filed: August 16, 1988
    Date of Patent: February 20, 1990
    Assignee: Hercules Incorporated
    Inventor: Raymond T. Leibfried
  • Patent number: 4900779
    Abstract: Novel thermoset and thermoplastic organosilicon polymers, comprised substantially of alternating polycyclic hydrocarbon residues and cyclic polysiloxane or tetrahedral siloxysilane residues linked through carbon-silicon bonds, are disclosed.
    Type: Grant
    Filed: July 30, 1987
    Date of Patent: February 13, 1990
    Assignee: Hercules Incorporated
    Inventor: Raymond T. Leibfried
  • Patent number: 4897305
    Abstract: Metal adhesion to a polyolefin substrate is improved by subjecting the substrate to a plasma treatment with aliphatic hydrocarbon vapors.
    Type: Grant
    Filed: March 12, 1987
    Date of Patent: January 30, 1990
    Assignee: Hercules Incorporated
    Inventor: Floyd F.-L. Ho
  • Patent number: 4897456
    Abstract: Disclosed is a method of reducing the activation rate of an alkyl aluminum activator in the metathesis polymerization of polycyclic cycloolefins. Activation rate is reduced by use of a bidentate Lewis base as the reaction rate moderator.
    Type: Grant
    Filed: January 13, 1989
    Date of Patent: January 30, 1990
    Assignee: Hercules Incorporated
    Inventor: Lawrence L. Nelson
  • Patent number: 4897144
    Abstract: An epoxy-sulfonylazide having the general formula ##STR1## wherein R is lower alkyl and R' is hydrogen or lower alkyl.
    Type: Grant
    Filed: May 2, 1988
    Date of Patent: January 30, 1990
    Assignee: Hercules Incorporated
    Inventor: Anthony B. Clayton
  • Patent number: 4896683
    Abstract: A method for controlling nicotine delivery through a cigarette filter relative to total particulate pass-through concentration, and the corresponding filter utilizing, as a filter modifier component, at least one water-soluble metal salt of a weak acid, the choice and amount of salt within the filter favoring an alkaline pH exceeding about pH 8, the amount of alkalinity being correlated to the desired amount of nicotine pass-through while corresponding nicotine filter retention properties are keyed to the presence and concentration of a water soluble salt of a strong acid within the filter.
    Type: Grant
    Filed: October 17, 1988
    Date of Patent: January 30, 1990
    Assignee: Hercules Incorporated
    Inventors: Richmond R. Cohen, David J. Gibboni