Abstract: Plant for producing at least partially desulfurized biogas, comprising a biomass digester and/or post-digester, the digester and/or post-digester comprising: a chamber comprising the biomass and the gas space, and a means for introducing an oxidizing gas, characterized in that the portion of the inner wall of the chamber situated at the level of the gas space exhibits expansions and/or hollows.
Type:
Application
Filed:
December 10, 2020
Publication date:
June 17, 2021
Applicant:
L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
Inventors:
Aude BERTRANDIAS, David FRIMAT, Antonio TRUEBA, Jacopo SEIWERT, Jeremy OLLIER, Solene VALENTIN
Abstract: A method for improving the capacity of an existing air separation unit employing a lost air turbine is provided in which the capacity is increased by operating the existing air separation unit as previously operated, with the exception of collecting the lost air from the lost air turbine, and instead of venting said lost air to the atmosphere, the lost air is compressed in a supplemental air compressor and returned to the air separation unit at a location downstream a front-end purification unit and upstream a booster. This setup advantageously allows for increased production without having to adjust the sizing of the front-end purification unit or main air compressor.
Type:
Grant
Filed:
November 16, 2018
Date of Patent:
June 8, 2021
Assignee:
L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Abstract: A method for reducing process disturbances during pressurization of an adsorber in an air separation unit is provided, in which the air separation unit includes a front end purification unit and an air buffer tank. In one embodiment, the method can include the steps of: pressurizing a first adsorber while a second adsorber operates in an adsorption cycle, wherein the step of pressurizing the first adsorber further includes the steps of withdrawing a pressurized air stream from the air buffer tank and introducing the pressurized air stream to the first adsorber until the first adsorber is at a target pressure, wherein the air buffer tank is in fluid communication with the booster air compressor, wherein the method further includes the step of continually sending a first portion of air flow from the booster air compressor to the air buffer tank and continually sending a second portion of air flow from the booster air compressor to a system of columns within a cold box for rectification therein.
Type:
Grant
Filed:
December 21, 2018
Date of Patent:
June 8, 2021
Assignee:
L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Abstract: Moulded insulation bodies, processes for the production thereof and use thereof consisting essentially of ceramic material comprising SiO2 fibers and Al2O3 fibers which has been produced using Al2O3 sol as a binder and kilned at a temperature of above 800° C. for insulation of the ends of cracking tubes of a tubular reactor for performing a steam reforming process for generating synthesis gas which project out of the reactor heating space.
Type:
Grant
Filed:
July 3, 2017
Date of Patent:
June 1, 2021
Assignee:
L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Abstract: Heat exchanger with plates comprising a first series of passages for conducting at least one frigorigenic fluid and a second series of passages for conducting at least one calorigenic fluid, each passage being defined between two successive plates and extending parallel to a longitudinal axis, at least one mixing device arranged in at least one passage of the first series, said mixing device being configured to receive a liquid phase and a gaseous phase of the frigorigenic fluid and to distribute a mixture of said phases into said at least one passage.
Type:
Grant
Filed:
June 27, 2017
Date of Patent:
June 1, 2021
Assignee:
L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Inventors:
Ludovic Granados, Philippe Grigoletto, Natacha Haik-Beraud, Sophie Lazzarini, Jean-Marc Peyron, Eduard Rosa
Abstract: In a helium purification process, a stream containing at least 10% of helium, at least 10% of nitrogen in addition to hydrogen and methane is separated to form a helium-enriched stream containing hydrogen, a first stream enriched in nitrogen and in methane and a second stream enriched in nitrogen and in methane, the helium-enriched stream is treated to produce a helium-rich product and a residual gas containing water, the residual gas is treated by adsorption (TSA) to remove the water and the regeneration gas from the adsorption is sent to a combustion unit (O).
Type:
Grant
Filed:
June 5, 2020
Date of Patent:
June 1, 2021
Assignee:
L'Air Liquide Société Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
Abstract: A method for producing power and argon is provided by providing a residual gas stream, purifying the residual gas stream in a front-end purification unit to remove carbon dioxide, thereby forming a purified residual gas stream, and introducing the purified residual gas stream to a cold box, wherein the purified residual gas stream is cooled and expanded within the cold box to produce power and then fed to a distillation column system for separation therein, thereby forming an argon-enriched stream and optionally a nitrogen-enriched stream and/or an oxygen-enriched stream, wherein the residual gas stream is sourced from a retentate stream of a cold membrane having oxygen, nitrogen, carbon dioxide, and argon.
Type:
Application
Filed:
November 27, 2019
Publication date:
May 27, 2021
Applicant:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Alain GUILLARD, Michael A. TURNEY, Abigail BONIFACIO
Abstract: A method for producing liquid nitrogen using a residual gas stream derived from a flue gas of a power plant is provided. The residual gas stream is purified in a front-end purification unit to remove freezable components and then the purified stream is compressed. Following compression, the stream can be divided into a first portion and a second portion, wherein the first portion is cooled and sent to a distillation column, wherein oxygen and argon are separated, thereby leaving an essentially pure gaseous nitrogen stream. The gaseous nitrogen stream can then be liquefied using refrigeration provided by expanding the second portion of the purified stream. In a preferred embodiment, the second portion is expanded in two turbines, and the gaseous nitrogen is compressed in a cold nitrogen booster, which is powered by one of the two turbines. In an additional embodiment, after warming, the expanded second portion of the purified stream can be used to regenerate the front-end purification unit.
Type:
Application
Filed:
November 27, 2019
Publication date:
May 27, 2021
Applicant:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: Process for the combined production of a mixture of hydrogen and nitrogen, and of carbon monoxide by cryogenic distillation and cryogenic scrubbing, wherein a methane-rich liquid is introduced at a first intermediate level of a scrubbing column as first scrubbing liquid and at least one nitrogen-rich liquid is introduced at a level higher than the first level of the scrubbing column as second scrubbing liquid and a mixture of hydrogen and nitrogen is drawn off as overhead gas from the scrubbing column.
Type:
Grant
Filed:
May 24, 2017
Date of Patent:
May 25, 2021
Assignee:
L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: Plant and process for the generation of hydrogen from a hydrocarbonaceous feed gas and steam by means of catalytic steam reformation, wherein the heat of the synthesis gas and the flue gas is utilized for generating export steam from boiler feed water and process steam from the condensate separated from the synthesis gas, and wherein the gases expelled from the boiler feed water during its degasification and the vapors obtained during the depressurization of the elutriation waters of the steam boilers for the generation of export and process steam are used for preheating the fuel gas for operation of the burners of the steam reformer.
Type:
Grant
Filed:
April 12, 2017
Date of Patent:
May 25, 2021
Assignee:
L'Air Liquide, Societe Anonyme Pour l'Etude et l'Exploitation des Procedes Georges Claude
Inventors:
Jean-Philippe Tadiello, Taekyu Kang, Thomas Wenz
Abstract: A valve for a pressurized fluid, including a body housing a fluid circuit including an upstream end configured to be placed in communication with a reserve of pressurized fluid and a downstream end configured to be placed in communication with a user apparatus, the circuit including a control valve controlling the flow rate in the circuit, the control valve being operated by a mobile actuating member to command the opening or the closing thereof, the valve including a first wireless remote communications electronic member using electromagnetic data waves, wherein the first electronic communication member is secured to a support component mounted to move on the body of the valve between at least a first position and a second position with respect to the body.
Type:
Grant
Filed:
June 20, 2017
Date of Patent:
May 18, 2021
Assignee:
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Abstract: Disclosed are methods of using Group 4 transition metal azatrane precursors to deposit Group 4 transition metal-containing films on one or more substrates via vapor deposition processes.
Type:
Grant
Filed:
April 10, 2017
Date of Patent:
May 18, 2021
Assignee:
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Abstract: An air separation unit using cryogenic distillation comprises a first column, a second column thermally linked to the first column, a first argon column, a second argon column, means for sending cooled, compressed and purified air to at least the first column, means for sending at least one fluid enriched in nitrogen from the first column to the second column and at least one fluid enriched in oxygen from the first column to the second column, means for sending a gas enriched in argon from the second column to a first end of the first argon column, means for sending gas from a second end of the first argon column to a first end of the second argon column, means for removing argon rich fluid from a second end of the second argon column, a pump, means for removing argon enriched liquid from the first end of the second argon column and sending it to the second end of the first argon column via the pump, the first end of the first argon column being raised above the ground by a first supporting structure, the pum
Type:
Application
Filed:
January 26, 2018
Publication date:
May 13, 2021
Applicant:
L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
Abstract: Disclosed in the present invention are a pressure equalizing system for air separation purification, and a control method. The system comprises: a first air main pipe; a pressurizing gas pipeline, which is connected to the first air main pipe and used for receiving a pressurizing gas and delivering same to the first air main pipe; and a control valve, located on the pressurizing gas pipeline, and having a degree of opening regulated by the flow regulator, thereby regulating an air intake amount of the pressurizing gas pipeline.
Type:
Application
Filed:
October 28, 2020
Publication date:
May 13, 2021
Applicant:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: The present invention discloses a cryogenic rectification process-based method for producing an air product, and an air separation system. By adding an air product outlet line and a liquid air booster pump to an existing cryogenic rectification process apparatus, the existing rectification apparatus is used to prepare oxygen-enriched liquid air by pressurizing, cooling and liquefying feed air; and moreover, a high-pressure or ultra-high-pressure air product can be prepared according to customer requirements by adjusting the ratio of the feed air to the oxygen-enriched liquid air, and pressurizing the mixture to a target pressure by the liquid air booster pump before being vaporized via heat exchange with a gas or liquid product produced by rectification through a heat exchange apparatus.
Type:
Application
Filed:
December 28, 2017
Publication date:
May 13, 2021
Applicant:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: A cylinder of pressurized fluid, including a valve assembly housing a fluid circuit including at least one shut-off valve, the cylinder being equipped with a bonnet for protecting the valve assembly including a rigid structure delimiting a protective volume around the valve assembly, including a pressure indicating device including at least one piston sensitive to the pressure in the cylinder and mobile relative to the body of the valve assembly according to the level of pressure in the cylinder between at least a retracted first position and a deployed second position, the pressure indicating device including at least one mobile information support configured to collaborate mechanically with the piston, the information support being able to move between at least two distinct positions or states to symbolize respectively at least two levels of pressure according to the position of the piston.
Type:
Grant
Filed:
September 22, 2016
Date of Patent:
May 11, 2021
Assignee:
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Abstract: A method of distributing an electrically insulating liquefied gas mixture to high-voltage electrical equipment from a storage means containing an insulating gas mixture, including: heating the insulating gas mixture to a temperature such that the contents of the storage means are a homogeneous fluid; and withdrawing the insulating mixture resulting from step a) to fill high-voltage electrical equipment by raising the temperature of the mixture resulting from step a), wherein, during step b), a set value for regulation is applied at variable pressure, calculated in real time based on weighing the storage means, when the change in the set value of pressure is less than 0.2 bar per 1 kg/m3 of change in density, and then a set value for regulation is applied at constant temperature until the storage means is emptied of its content.
Type:
Grant
Filed:
July 7, 2017
Date of Patent:
May 11, 2021
Assignee:
L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
Abstract: A station and method for refilling a tank or tanks with pressurized gas in which liquefied gas is vaporized in a vaporizer. One portion of the vaporized gas is compressed to produce a compressed gas. Another portion of the vaporized gas is not compressed but instead is fed to a heat exchanger where it is used to cool the compressed gas. The thus-warmed gas is reinjected into a filling line that feeds the liquefied gas to the vaporizer.
Type:
Application
Filed:
April 16, 2018
Publication date:
May 6, 2021
Applicant:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
Abstract: In a method for separating air by cryogenic distillation, cooled air purified to remove water is sent to a first column operating at a first pressure, where it is separated into a nitrogen-enriched gas as an oxygen-enriched liquid; a gas enriched in argon relative to the air is withdrawn from the second column; at least a portion of the oxygen-enriched liquid is vaporized by heat exchange with the argon-enriched gas; and the vaporized, oxygen-enriched liquid is sent to an intermediate level of the second column.
Type:
Application
Filed:
October 21, 2020
Publication date:
April 29, 2021
Applicant:
L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude