Patents Assigned to Linde AG
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Patent number: 10647639Abstract: The invention relates to a method for producing butadiene from n-butenes having the steps: A) providing an n-butene-comprising feed gas stream a; B) feeding the n-butene-comprising feed gas stream a and an oxygen-comprising gas into at least one oxidative dehydrogenation zone and oxidatively dehydrogenating n-butenes to butadiene, wherein a product gas stream b comprising butadiene, unreacted n-butenes, steam, oxygen, low-boiling hydrocarbons, high-boiling minor components, optionally carbon oxides and optionally inert gases is obtained; Ca) cooling the product gas stream b by contacting it with a refrigerant and condensing at least a part of the high-boiling minor components; Cb) compressing the remaining product gas stream b in at least one compression step, wherein at least one aqueous condensate stream c1 and a gas stream c2 comprising butadiene, n-butenes, steam, oxygen, low-boiling hydrocarbons, optionally carbon oxides and optionally inert gases is obtained; Da) separating off non-condensable and loType: GrantFiled: January 30, 2017Date of Patent: May 12, 2020Assignees: BASF SE, Linde AGInventors: Jan Pablo Josch, Ragavendra Prasad Balegedde Ramachandran, Ulrike Wenning, Anton Wellenhofer, Christine Toegel, Hendrik Reyneke, Heinz Boelt
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Publication number: 20190277564Abstract: The invention provides a cryogenic pump reservoir (100), for a cryogenic liquid to be fed to a pump (208), with an interior reservoir space (103) extending between a reservoir bottom (101) and a reservoir top (102) and comprising a liquid feeding region (104), which is positioned at a first distance from the reservoir bottom (101) in the direction of the reservoir top (102), and a liquid removing region (105), which is positioned at a second distance from the reservoir bottom (101) in the direction of the reservoir top (102), the second distance being greater than the first distance. It is provided that in the liquid feeding region (104) there is formed a liquid feeding opening (106), that the interior reservoir space (103) is at least partially divided in the liquid feeding region (104) by means of a dividing wall (106), which is arranged in such a way that one of its surfaces (107) is aligned in the direction of the liquid feeding opening (106.Type: ApplicationFiled: October 25, 2017Publication date: September 12, 2019Applicant: Linde AGInventors: Michael Baus, Felix Flegiel, Daniela Lauchner, Christian Matten
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Patent number: 10384990Abstract: The invention relates to a process for preparing 1,3-butadiene from n-butenes, comprising the steps of: A) providing an input gas stream a comprising butanes, 1-butene, 2-butene and isobutene, with or without 1,3-butadiene, from a fluid catalytic cracking plant; B) removing isobutene from the input gas stream a, giving a stream b comprising butanes, 1-butene and 2-butene, with or without 1,3-butadiene; C) feeding the stream b comprising butanes, 1-butene and 2-butene and optionally an, oxygenous gas and optionally water vapor into at least one dehydrogenating zone and dehydrogenating 1-butene and 2-butene to 1,3-butadiene, giving a product gas stream c comprising 1,3-butadiene, butanes, 2-butene and water vapor, with or without oxygen, with low-boiling hydrocarbons, with high-boiling secondary components, with or without carbon oxides and with or without inert gases; D) cooling and compressing the product gas stream c, giving at least one aqueous condensate stream d1 and a gas stream d2 comprising 1,3-butaType: GrantFiled: November 9, 2015Date of Patent: August 20, 2019Assignees: BASF SE, Linde AGInventors: Jan Ungelenk, Philipp Grüne, Christian Walsdorff, Jan Pablo Josch, Michael Bender
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Patent number: 10370310Abstract: The invention relates to a method for producing butadiene from n-butenes having the steps: A) providing a feed gas stream a comprising n-butenes; B) feeding the feed gas stream a comprising the n-butenes and an oxygen-comprising gas into at least one oxidative dehydrogenation zone and oxidatively dehydrogenating n-butenes to butadiene, wherein a product gas stream b comprising butadiene, unreacted n-butenes, steam, oxygen, low-boiling hydrocarbons, high-boiling minor components, possibly carbon oxides and possibly inert gases is obtained; Ca) cooling the product gas stream b by contacting it with a refrigerant and condensing at least a part of the high-boiling minor components; Cb) compressing the remaining product gas stream b in at least one compression stage, wherein at least one aqueous condensate stream c1 and a gas stream c2 comprising butadiene, n-butenes, steam, oxygen, low-boiling hydrocarbons, possibly carbon oxides and possibly inert gases are obtained; Da) separating off non-condensable and low-bType: GrantFiled: January 11, 2017Date of Patent: August 6, 2019Assignees: BASF SE (ISENBRUCK BÖSL HÖRSCHLER LLP), Linde AGInventors: Jan Pablo Josch, Georgios Karanikoulis, Oliver Hammen, Claudia Mossbacher, Ulrike Wenning, Anton Wellenhofer, Christine Toegel, Hendrik Reyneke
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Patent number: 10358399Abstract: A process for preparing butadiene from n-butenes, comprising the steps of: A) providing an input gas stream comprising n-butenes; B) feeding the input gas stream comprising n-butenes and a gas containing at least oxygen into at least one oxidative dehydrogenation zone and oxidatively dehydrogenating n-butenes to butadiene, giving a product gas stream; Ca) cooling the product gas stream by contacting with a circulating cooling medium in at least one cooling zone; Cb) compressing the cooled product gas stream in at least one compression stage, giving at least one aqueous condensate stream c1 and one gas stream c2; D) removing uncondensable and low-boiling gas constituents comprising oxygen and low-boiling hydrocarbons as gas stream d2 from the gas stream c2 by absorbing the C4 hydrocarbons in an absorbent, giving an absorbent stream laden with C4 hydrocarbons and the gas stream d2, and then desorbing the C4 hydrocarbons from the laden absorbent stream, giving a C4 product gas stream d1; E) separating the C4Type: GrantFiled: November 2, 2015Date of Patent: July 23, 2019Assignees: BASF SE, Linde AGInventors: Philipp Grüne, Stephan Deublein, Christian Walsdorff, Jan Pablo Josch, Rainer Rahm, Hendrik Reyneke, Anton Wellenhofer, Ulrike Wenning, Christine Toegel, Heinz Boelt
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Patent number: 10351422Abstract: The invention relates to a method of carrying out heat-consuming processes, wherein the total energy required averaged over a year for the heat-consuming process originates from at least two different energy sources, where one of the energy sources is an electric energy source whose power varies in the range from 0 to 100% of the total power required, and three different energy modes can individually provide the total power required for the heat-consuming process: (i) exclusively electric energy, (ii) a mixture of electric energy and at least one further nonelectric energy source or (iii) exclusively nonelectric energy, where the changeover time in which the change from one energy mode to another energy mode is completed is not more than 30 minutes.Type: GrantFiled: December 12, 2013Date of Patent: July 16, 2019Assignees: BASF SE, Linde AGInventors: Otto Machhammer, Wolfgang Alois Hormuth, Christian Schneider, Andreas Bode, Volker Goeke, Hans-Juergen Maass, Matthias Kern, Dirk Klingler, Rene Koenig, Philipp Brueggemann, Jens Bernnat, Grigorios Kolios
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Patent number: 10308569Abstract: The invention relates to a process for preparing butadiene from n-butenes, comprising the steps of: A) providing an input gas stream a comprising n-butenes, B) feeding the input gas stream a comprising n-butenes and a gas containing at least oxygen into at least one oxidative dehydrogenation zone and oxidatively dehydrogenating n-butenes to butadiene, giving a product gas stream b comprising butadiene, unconverted n-butenes, water vapor, oxygen, low-boiling hydrocarbons and high-boiling secondary components, with or without carbon oxides and with or without inert gases; Ca) cooling the product gas stream b by contacting with a cooling medium in at least one cooling zone, the cooling medium being at least partly recycled and having an aqueous phase and an organic phase, Cb) compressing the cooled product gas stream b which may have been depleted of high-boiling secondary components in at least one compression stage, giving at least one aqueous condensate stream c1 and one gas stream c2 comprising butadiene, nType: GrantFiled: September 14, 2015Date of Patent: June 4, 2019Assignees: BASF SE, Linde AGInventors: Jan Pablo Josch, Philipp Grüne, Regina Benfer, Maximilian Vicari, Andre Biegner, Gergor Bloch, Heinz Boelt, Hendrik Reyneke, Christine Toegel, Ulrike Wenning
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Patent number: 10233078Abstract: The invention relates to a process for utilizing a hydrocarbon-comprising and/or carbon dioxide-comprising coproduct gas, accompanying gas and/or biogas, wherein hydrocarbon-comprising and/or carbon dioxide-comprising coproduct gas, accompanying gas and/or biogas is introduced into a reaction space and the multicomponent mixture comprised in the coproduct gas, accompanying gas and/or biogas is converted in a high-temperature zone at temperatures of more than 1000° C. and in the presence of a carrier into a product gas mixture which comprises more than 95% by volume of CO, CO2, H2, H2O, CH4 and N2 and optionally into a carbon-comprising solid which is deposited to an extent of at least 75% by weight, based on the total mass of the carbon-comprising solid, on the carrier where the flow velocity of the gas mixture of coproduct gas, accompanying gas and/or biogas in the reaction zone is less than 20 m/s.Type: GrantFiled: December 13, 2013Date of Patent: March 19, 2019Assignees: BASF SE, Linde AG, ThyssenKrupp Industrial Solutions AGInventors: Christian Schneider, Andreas Bode, Dirk Klingler, Otto Machhammer, Philipp Brueggemann, Matthias Kern, Wolfgang Alois Hormuth, Marcus Guzmann, Rene Koenig, Jens Bernnat, Grigorios Kolios, Volker Goeke, Hans-Juergen Maass, Karsten Bueker
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Publication number: 20190016650Abstract: The invention relates to a method for producing butadiene from n-butenes having the steps: A) providing a feed gas stream a comprising n-butenes; B) feeding the feed gas stream a comprising the n-butenes and an oxygen-comprising gas into at least one oxidative dehydrogenation zone and oxidatively dehydrogenating n-butenes to butadiene, wherein a product gas stream b comprising butadiene, unreacted n-butenes, steam, oxygen, low-boiling hydrocarbons, high-boiling minor components, possibly carbon oxides and possibly inert gases is obtained; Ca) cooling the product gas stream b by contacting it with a refrigerant and condensing at least a part of the high-boiling minor components; Cb) compressing the remaining product gas stream b in at least one compression stage, wherein at least one aqueous condensate stream c1 and a gas stream c2 comprising butadiene, n-butenes, steam, oxygen, low-boiling hydrocarbons, possibly carbon oxides and possibly inert gases are obtained; Da) separating off non-condensable and low-bType: ApplicationFiled: January 11, 2017Publication date: January 17, 2019Applicants: BASF SE, Linde AGInventors: Jan Pablo JOSCH, Georgios KARANIKOULIS, Oliver HAMMEN, Claudia MOSSBACHER, Ulrike WENNING, Anton WELLENHOFER, Christine TOEGEL, Hendrik REYNEKE
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Publication number: 20180282246Abstract: The invention relates to a process for preparing 1,3-butadiene from n-butenes, comprising the steps of: A) providing an input gas stream a comprising butanes, 1-butene, 2-butene and isobutene, with or without 1,3-butadiene, from a fluid catalytic cracking plant; B) removing isobutene from the input gas stream a, giving a stream b comprising butanes, 1-butene and 2-butene, with or without 1,3-butadiene; C) feeding the stream b comprising butanes, 1-butene and 2-butene and optionally an, oxygenous gas and optionally water vapor into at least one dehydrogenating zone and dehydrogenating 1-butene and 2-butene to 1,3-butadiene, giving a product gas stream c comprising 1,3-butadiene, butanes, 2-butene and water vapor, with or without oxygen, with low-boiling hydrocarbons, with high-boiling secondary components, with or without carbon oxides and with or without inert gases; D) cooling and compressing the product gas stream c, giving at least one aqueous condensate stream d1 and a gas stream d2 comprising 1,3-butaType: ApplicationFiled: November 9, 2015Publication date: October 4, 2018Applicants: BASF SE, Linde AGInventors: Jan UNGELENK, Philipp GRÜNE, Christian WALSDORFF, Jan Pablo JOSCH, Michael BENDER
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Patent number: 9957208Abstract: The invention relates to a process for preparing butadiene from n-butenes, comprising the steps of: A) providing an input gas stream a comprising n-butenes, B) feeding the input gas stream a comprising n-butenes and a gas containing at least oxygen into at least one oxidative dehydrogenation zone and oxidatively dehydrogenating n-butenes to butadiene, giving a product gas stream b comprising butadiene, unconverted n-butenes, water vapor, oxygen, low-boiling hydrocarbons and high-boiling secondary components, with or without carbon oxides and with or without inert gases; Ca) cooling the product gas stream b by contacting with a cooling medium in at least one cooling zone, the cooling medium being at least partly recycled and having an aqueous phase and an organic phase of an organic solvent, wherein the organic solvent is selected from the group consisting of toluene, o-, m- and p-xylene, mesitylene, mono-, di- and triethylbenzene, mono-, di- and triisopropylbenzene and mixtures thereof, and the mass ratio ofType: GrantFiled: August 11, 2015Date of Patent: May 1, 2018Assignees: BASF SE, Linde AGInventors: Philipp Grüne, Oliver Hammen, Rainer Eckrich, Jan Pablo Josch, Christian Walsdorff, Andre Biegner, Gregor Bloch, Heinz Boelt, Hendrik Reyneke, Christine Toegel, Ulrike Wenning
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Publication number: 20180104435Abstract: A clinical oxygen supply device (100) adapted to supply supplemental oxygen to a patient, comprising an oxygen inlet section (110) with a first coupling unit (111) adapted to be releasably coupled to a standardized oxygen wall outlet (1), an oxygen outlet section (120) with a second coupling unit (121) adapted to be releasably coupled to an oxygen dispensing device (2) attached to a patient (3), and an oxygen flow control section (130) with a regulation unit (132) adapted to regulate an oxygen flow between the oxygen inlet section (110) and the oxygen outlet section (120) on the basis of a control signal is provided.Type: ApplicationFiled: April 1, 2016Publication date: April 19, 2018Applicant: Linde AGInventors: Sabine Häussermann, Peter Forsberg
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Publication number: 20160167033Abstract: A catalyst composition including: (a) a chromium compound; (b) a ligand of the general structure (A) R1R2P—N(R3)—P(R4)—NR5R6 or (B) R1R2P—N(R3)—P(XR7)R8 or R1R2P—N(R3)—P(XR7)2, with X=O or S, wherein R1, R2, R3, R4, R5, R6, R7 and R8 are independently C1-C10-alkyl, C6-C20-aryl, C3-C10-cycloalkyl, aralkyl, alkylaryl, or trialkylsilyl, or any cyclic derivatives of (A) and (B), wherein at least one of the P or N atoms of the PNPN-unit or PNP-unit is a member of the ring system, the ring system being formed from one or more constituent compounds of structures (A) or (B) by substitution; and (c) an activator or co-catalyst; and a process for tri- and/or tetramerization.Type: ApplicationFiled: July 28, 2014Publication date: June 16, 2016Applicants: Saudi Basic Industries Corporation, Linde AGInventors: ANINA WOEHL, ANDREAS MEISWINKLE, HEINZ BOELT, BERND H. MUELLER, WOLFGANG MUELLER, NORMEN PEULECKE, UWE ROSENTHAL, MARCO HARFF, MOHAMMED H. AL-HAZMI, ABDULLAH AL-QAHTANI
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Publication number: 20160068390Abstract: The invention relates to a process for utilizing a hydrocarbon-comprising and/or carbon dioxide-comprising coproduct gas, accompanying gas and/or biogas, wherein hydrocarbon-comprising and/or carbon dioxide-comprising coproduct gas, accompanying gas and/or biogas is introduced into a reaction space and the multicomponent mixture comprised in the coproduct gas, accompanying gas and/or biogas is converted in a high-temperature zone at temperatures of more than 1000° C. and in the presence of a carrier into a product gas mixture which comprises more than 95% by volume of CO, CO2, H2, H2O, CH4 and N2 and optionally into a carbon-comprising solid which is deposited to an extent of at least 75% by weight, based on the total mass of the carbon-comprising solid, on the carrier where the flow velocity of the gas mixture of coproduct gas, accompanying gas and/or biogas in the reaction zone is less than 20 m/s.Type: ApplicationFiled: December 13, 2013Publication date: March 10, 2016Applicants: BASF SE, Linde AG, ThyssenKrupp Industrial Solutions AGInventors: Christian SCHNEIDER, Andreas BODE, Dirk KLINGLER, Otto MACHHAMMER, Philipp BRUEGGEMANN, Matthias KERN, Wolfgang Alois HORMUTH, Marcus GUZMANN, Rene KOENIG, Jens BERNNAT, Grigorios KOLIOS, Volker GOEKE, Hans-Juergen MAASS, Karsten BUEKER
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Patent number: 9018431Abstract: The present invention relates to a catalyst composition for oligomerization of ethylene, comprising a chromium compound; a ligand of the general structure R1R2P—N(R3)—P(R4)—N(R5)—H, wherein R1, R2, R3, R4 and R5 are independently selected from halogen, amino, trimethylsilyl, C1-C10-alkyl, aryl and substituted aryl; a modifier containing organic or inorganic halide; and an activator or co-catalyst; and a process for oligomerization utilizing that catalyst.Type: GrantFiled: March 24, 2010Date of Patent: April 28, 2015Assignees: Saudi Basic Industries Corporation, Linde AGInventors: Anina Wöhl, Uwe Rosenthal, Bernd H. Müller, Normen Peulecke, Stephan Peitz, Wolfgang Müller, Heinz Bölt, Andreas Meiswinkel, Bhaskar Reddy Aluri, Mohammed Al-Hazmi, Mohammed Al-Masned, Khalid Al-Eidan, Fuad Mosa
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Patent number: 9011808Abstract: A process for removing impurities, in particular oxides of sulphur (SOx) and/or oxides of nitrogen (NOx) from oxygen-containing gas streams by scrubbing with at least one washing agent is described. In order to achieve effective gas purification in an economical manner even in the case of so-called large “oxyfuel” furnaces which operate with oxygen as fuel gas, it is proposed to convert the impurities at an elevated pressure of at least 2 bar with at least one basic constituent of the washing agent into salts and to wash out said impurities as dissolved salts.Type: GrantFiled: November 26, 2009Date of Patent: April 21, 2015Assignee: Linde AGInventors: Nicole Schodel, Hans Jorg Zander, Florian Winkler, Roland Ritter, Torsten Stoffregen
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Patent number: 9012577Abstract: The present invention relates to a method for preparing linear alpha-olefins by oligomerizing of ethylene in the presence of a first organic solvent and a homogenous catalyst in a reactor, characterized in that the reactor overhead is cooled by means of a refrigerant.Type: GrantFiled: June 13, 2006Date of Patent: April 21, 2015Assignees: Saudi Basic Industries Corporation, Linde AGInventors: Peter Fritz, Heinz Bölt, Karl-Heinz Hoffman, Markus Köhler, Hans-Jörg Zander, Fuad Mosa, Talal Ali
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Patent number: 9004910Abstract: Method for combustion of a fuel uses an existing air burner (1), including a first supply opening (5) for fuel and a second supply opening (7) for air, which supply openings (5,7) open out into a combustion zone (3). The method is characterised in that a gaseous fuel with an LHV (Lower Heating Value) of less than 7.5 MJ/Nm3 is supplied through the second supply opening (7), in that an oxidant including at least 85 percent by weight oxygen is also supplied to the combustion zone (3) through a supply device for oxidant, and in that the gaseous fuel is caused to be combusted with the oxidant in the combustion zone (3).Type: GrantFiled: February 3, 2011Date of Patent: April 14, 2015Assignee: Linde AGInventors: Tomas Ekman, Anders Lugnet, Ola Ritzén
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Patent number: 8899884Abstract: The present application relates to a metering device and a dense phase conveying system for the steady, continuous, dosed supply of a bulk material in powder form made of light, polydisperse particles to a consumer arranged downstream. Furthermore, the present application relates to a method for the continuous, dosed supply of the bulk material in powder form using the dense phase conveying system, which comprises the metering device according to the invention.Type: GrantFiled: October 8, 2010Date of Patent: December 2, 2014Assignee: Linde AGInventors: Horst Kretschmer, Jörg Kleeberg, Dietmar Rüger, Olaf Schulze, Christian Eichhorn
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Patent number: 8834608Abstract: The invention relates to a process for separating off solid particles, in particular coke particles, from a water phase by means of gravity in a plant for generating hydrocarbons by cracking a hydrocarbonaceous feed, and also to a device for carrying out the process. In contrast to the prior art, the water phase is taken off predominantly from a point above the column bottom B via the outlet A. The first gravity separator 2 which is constructed as a multistage settling tank 2 is situated not beneath, but next to, the scrubbing water column 1. The bottom phase of the scrubbing water column 1 already acts as a part of the first gravity separator 2. Thus, via the outlet 5 in the column bottom B, a heavy water phase which is loaded with coke particles is already taken off and passed into the second gravity separator 3. This heavy water phase is further treated, together with the heavy water phase which is loaded with coke particles from the recesses 6 of the multistage settling tank 2.Type: GrantFiled: January 15, 2010Date of Patent: September 16, 2014Assignee: Linde AGInventors: Michael Baus, Gerhard Alzner