Abstract: The invention provides an efficient process for producing alkylated aromatic compounds such as cumene in a compact reactor. The invention also provides a process for producing phenol which includes a step of producing cumene by the above process. The process for producing alkylated aromatic compounds of the invention includes feeding raw materials including an aromatic compound and an alcohol in a gas-liquid downward concurrent flow mode to a fixed-bed reactor packed with a solid acid catalyst thereby to produce an alkylated aromatic compound, wherein the raw materials are fed to the reactor in a stream of a gas, and the reaction gas flow rate defined by the equation below is not less than 0.05 at an entrance of a solid acid catalyst layer: ?g·ug·[?air·?water/(?g·?l)]1/2(kgm?2s?1).
Abstract: Disclosed herein is a fluorescence detection method. The fluorescence detection method includes the steps of: irradiating a measurement object with laser light modulated at a predetermined frequency; receiving fluorescence emitted by the measurement object and outputting two or more pulsed fluorescent signals; setting reference timing in units of period corresponding to the frequency; acquiring a generation time to output of each of the pulsed fluorescent signals based on the reference timing; generating a cumulative fluorescent signal indicating the relationship between a generation frequency of the pulsed fluorescent signal and the generation time; determining, by using a signal corresponding to modulation of the laser light as a reference signal, a phase difference between the reference signal and the cumulative fluorescent signal; and determining, by using the phase difference, a fluorescence relaxation time of the fluorescence emitted by the measurement object.
Abstract: A fluorescence detection device includes a flow cell body including a flow channel through which a measurement object flows, a laser light source unit that irradiates, with a laser beam, the measurement object passing through a measurement point in the flow channel, a light-receiving unit that receives fluorescence emitted from the measurement object irradiated with the laser beam and outputs a light-reception signal, and a processing unit that outputs an output value of fluorescence intensity based on the light-reception signal outputted by the light-receiving unit. The flow cell body has a lens provided on a surface thereof so as to traverse an optical path of the laser beam.
Abstract: There are provided an electrode foil which has both the functions of a supporting base material and a reflective electrode and also has a superior thermal conductivity; and an organic device using the same. The electrode foil comprises a metal foil and a reflective layer provided directly on the metal foil.
Abstract: The present invention relates to a solvent composition for removing radioactive substance, characterized by comprising at least one selected from hydrofluorocarbon, hydrofluoroether, and perfluoroketone as a medium for transporting the radioactive substance, and a method for removing a radioactive substance characterized by using the solvent composition for removing.
Type:
Application
Filed:
November 2, 2012
Publication date:
March 21, 2013
Applicant:
DU PONT-MITSUI FLUOROCHEMICALS CO., LTD.
Inventor:
Du Pont-Mitsui Fluorochemicals Co., Ltd.
Abstract: A chiral tetraaminophosphonium salt represented by formula (1) and a method for producing chiral ?-nitroalcohol comprising reacting an aldehyde or a ketone and a nitroalkane in the presence of the chiral tetraaminophosphonium salt represented by formula (1) and a base, or in the presence of a conjugated base of the chiral tetraaminophosphonium salt represented by formula (1): wherein R1 to R4 are independently a hydrogen atom or a monovalent hydrocarbon group; and, R1 and R2 are different groups or R3 and R4 are different groups.
Type:
Grant
Filed:
September 17, 2008
Date of Patent:
March 19, 2013
Assignees:
Mitsui Chemicals, Inc., National University Corporation Nagoya University
Abstract: Aniline derivatives represented by formula (8): The aniline derivatives can be used as insecticides and/or intermediates in production of insecticides.
Abstract: Polymerization catalysts for organic polythiourethane glass which do not contain organometallic compounds contain a mixture of a tertiary aliphatic amine and a disubstituted phosphoric acid in a molar ratio ranging from 1/1.3 to 1/20. Polymerizable liquid compositions containing three components (A), (B) and (C) are also provided, wherein component (A) contains at least one cycloaliphatic diisocyanate monomer wherein the weight percentage of free isocyanate groups in component (A) ranges from about 20% to about 50% by weight with respect to the total weight of component (A); component (B) contains at least one polythiol having a molecular weight ranging from 50 to 1,200 g/moles and a functionality ranging from 2 to 5, said components (A) and (B) being present in a weight ratio varying from 0.5:1 to 2:1; and component (C) being said polymerization catalyst. A process for the production of organic glass using the polymerizable liquid composition is further provided.
Type:
Application
Filed:
May 20, 2011
Publication date:
March 14, 2013
Applicant:
MITSUI CHEMICALS, INC.
Inventors:
Fiorenzo Renzi, Roberto Forestieri, Andrea Vecchione, Willem Bos
Abstract: The additive for a polymerizable composition according to the present invention contains a compound represented by the general formula (a). In the general formula (a), R represents a saturated hydrocarbon group having 1 to 3 carbon atoms. M represents Sn, Sb, Bi, or Ge. m represents 0 or 1. R and M are not directly bonded when m is 0. n represents an integer of 1 to 3. X represents a monovalent linking group, and a plurality of X may be the same as or different from each other. When two or more linking groups X are bonded with the metal atom M, the linking groups X may combine together to form a ring.
Abstract: Object is to provide a surface-treated copper foil free from chromium in the surface-treatment layer and excellent in peel strength of a circuit and chemical resistance against to degradation of the peel strength after processing into a printed wiring board. To achieve the object, the surface-treated copper foil having a surface-treatment layer on a bonding surface of a copper foil for manufacturing a copper-clad laminate by laminating it to an insulating resin substrate has the surface-treatment layer formed by depositing a metal component having high melting point not lower than 1400° C. by dry process film formation method to the bonding surface of the copper foil after the cleaning treatment and further depositing a carbon component to the surface.
Abstract: It is an object of the present invention to provide a hollow bottle made of polyester, which has excellent heat resistance and is not likely to undergo deformation or change in capacity even if a liquid of high temperature is filled therein. The present invention relates to a hollow bottle formed by blow molding polyester, which has a thickness in the range of 200 to 400 ?m, and satisfies that ?d=d1?d2 is not less than ?7 kg/m3 and more than 7 kg/m3, with d1 [kg/m3] being a density of a part ranging from an outer surface up to 50 ?m inward, and d2 [kg/m3] being a density of a part of the body portion ranging from an inner surface up to 50 ?m inward. The polyester is preferably polyethylene terephthalate, and it is preferable that d1=1370 to 1375 kg/m3, while d2=1373 to 1378 kg/m3.
Abstract: The present invention provides a material that is less likely to cause flex cracking, has high scratch resistance, and is suitable for a protective layer for a thermosensitive material. A thermosensitive recording material according to the present invention includes a base, a thermosensitive recording layer formed on the base, and a protective layer formed on the thermosensitive recording layer, wherein the protective layer is formed from a mixture that contains an emulsion (a) containing particles formed of a hydrophobic polymer (1) and a hydrophilic polymer (2); and a non-crosslinking urea compound (b). Preferably, the hydrophobic polymer (1) contains an acrylonitrile-derived constitutional unit. Preferably, the non-crosslinking urea compound (b) is urea or a urea derivative.
Abstract: The present invention provides a multilayer material which has a layer (A) that contains a silane coupling agent and an ethylene type zinc ionomer, and a layer (B) that contains at least one of an ethylene type magnesium ionomer or an ethylene type sodium ionomer. The multilayer material is suitable for use as an encapsulant for a solar cell or an interlayer for safety (laminated) glass. It is preferable that the multilayer material contains at least two of the layer (A) and at least one of the layer (B) and has a multilayered structure in which the layer (B) is interposed between the two of the layer (A).
Abstract: Ethanol obtained from ordinary biomass resources contains many impurities other than water and these impurities themselves or their decomposition products contaminate ethylene when the ethylene is produced by a dehydration reaction, whereby the activity of metathesis catalyst is adversely affected. A method for producing propylene of the present invention is characterized in that the ethanol obtained from biomass is converted to ethylene by a dehydration reaction, the ethylene is separated from the generated water, the separated ethylene is purified by adsorption in an adsorption tower filled with an adsorbent, and then a metathesis reaction is carried out along with a raw material containing n-butene. With the present invention, propylene having biomass-derived carbon and reduced-environmental burden can be efficiently produced without lowering the catalysis activity.
Abstract: A door latch device in a motor vehicle comprises an engagement portion including a latch which engages with a striker of a vehicle body. The door latch device comprises an inner lever connected to an inside handle, a lock lever connected to a lock knob on a door inside the vehicle, a subsidiary lever connected to the lock lever, a childproof lock lever, a motor and an actuating member driven by the motor to actuate the childproof lock lever. Childproof locking and a double locking can be carried out by the single motor.
Abstract: There are provided an electrode foil which has all the functions of a supporting base material, an electrode and a reflective layer and also has a superior thermal conductivity; and an organic device using the same. The electrode foil comprises a metal foil, wherein the electrode foil has at least one outermost surface which is an ultra-smooth surface having an arithmetic average roughness Ra of 10.0 nm or less as measured in accordance with JIS B 0601-2001.
Abstract: Disclosed herein is a method for measuring FRET by irradiating with laser light a measurement sample. FRET is transfer of energy from a first molecule to a second molecule. The first molecule and the second molecule are included in the measurement sample in which ligands are bound to receptors. The method includes the steps of: irradiating the measurement sample with laser light; measuring fluorescence emitted by the measurement sample; calculating a fluorescence lifetime of the first molecule; calculating a binding ratio; setting a binding condition for the measurement sample; and calculating a dissociation constant. In the dissociation constant calculating step, the dissociation constant is determined by using a least-squares method to fit a function having, as variables, a total concentration of the receptor in the measurement sample and the dissociation constant to the binding ratio calculated in the binding ratio calculating step.
Abstract: Provided are a solid titanium catalyst component for ethylene polymerization which can polymerize ethylene at a high activity and which can provide an ethylene polymer having an excellent particle property, an ethylene polymerization catalyst and an ethylene polymerization method in which the catalyst is used. The solid titanium catalyst component (I) for ethylene polymerization according to the present invention is obtained by bringing a liquid magnesium compound (A) including a magnesium compound, an electron donor (a) having 1 to 5 carbon atoms and an electron donor (b) having 6 to 30 carbon atoms into contact with a liquid titanium compound (C) under the presence of an electron donor (B) and includes titanium, magnesium and a halogen. The ethylene polymerization catalyst of the present invention includes the component (I) and an organic metal compound catalyst component (II).
Abstract: Provided is a carbodiimide-modified, high-density polyolefin-based adhesive with minimal lowering of adhesion power even in a high temperature environment, and a laminate having excellent interlayer adhesion power at high temperatures prepared by using the adhesive. Provided is an adhesive obtained by reaction of a polyolefin (A) having a group reactive with a carbodiimide group and a compound (B) containing a carbodiimide group in the presence of an unmodified polyolefin (C), having a ratio of a peak intensity at 2130 to 2140 cm?1 to a peak intensity at 1470 cm?1 of 50% or less (but not including 0%).