Patents Assigned to Mitsui
  • Patent number: 5708128
    Abstract: Novel thermoset polyimide and composite materials comprising the thermoset polyimides and a fibrous reinforcement are prepared according to this invention. The thermoset polyimides are obtained by heat-treating a linear polyamic acid or a linear polyimide prepared by using 4,4'-bis(3-aminophenoxy)biphenyl and pyromellitic dianhydride as essential monomers or by adding 4,4'-diaminodiphenyl ether or 3,3',4,4'-biphenyltetracarboxylic dianhydride to the essential monomers and by end-capping the molecular chain end with an aromatic dicarboxylic anhydride having a carbon-carbon triple bond. The thermoset polyimides have essential excellent properties of thermoplastic polyimide and additionally has enhanced heat resistance and improved mechanical properties. The thermoset polyimide can be used to provide various kinds of composite materials for aircraft matrices, electric and electronic appliances and others.
    Type: Grant
    Filed: June 24, 1996
    Date of Patent: January 13, 1998
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hideaki Oikawa, Shoji Tamai, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5707729
    Abstract: An adhesive composition and foils coated with the adhesive, wherein the adhesive consisting essentially of: (I) a fist amount of a non-modified epoxy resin and a second amount of a rubber-modified epoxy resin in a total amount of 60-100 parts by weight, wherein the amount of rubber-modified epoxy resin is 0.5 to 20 parts by weight; (II) 5-30 parts by weight of a polyvinyl acetal resin; and optionally contains (III) at least one resin selected rom the group consisting of blocked isocyanate resins, polyester resins, polyester resins, melamine resins and urethane resins. The adhesive coating can optionally contain inorganic fillers, fire retardants, and curing agents.
    Type: Grant
    Filed: September 7, 1995
    Date of Patent: January 13, 1998
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventor: Tetsuro Satoh
  • Patent number: 5708080
    Abstract: A graft-modified ethylene/.alpha.-olefin copolymer composition is prepared by graft copolymerizing an ethylene/.alpha.-olefin copolymer. The ethylene/.alpha.-olefin copolymer composition includes first and second ethylene/.alpha.-olefin copolymers. The copolymers are each prepared in the presence of a polymerization catalyst containing (a) an organoaluminum oxy compound and (b) for the first ethylene/.alpha.-olefin copolymer at least two kinds, and for the second ethylene/.alpha.-olefin copolymer one kind, of compounds of Group IV transition metals of the periodic table containing a ligand having a cyclopentadienyl skeleton. The ethylene/.alpha.-olefin copolymer composition may be blended with a polyolefin by mechanical or solution blending. The copolymer compositions have excellent moldability and heat stability properties and forms films having high transparency and mechanical strength.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: January 13, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshiyuki Tsutsui, Ken Yoshitsugu, Mamoru Takahashi, Akira Todo, Seiji Ohta, Hajime Inagaki
  • Patent number: 5705101
    Abstract: A phthalocyanine near infrared absorber having a broad absorption range in the near infrared region and represented by the following formula (1): ##STR1## wherein each of the groups is defined.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: January 6, 1998
    Assignees: Mitsui Toatsu Chemicals, Inc., Yamamoto Chemicals Inc.
    Inventors: Ryu Oi, Kazuhiro Seino, Keisuke Takuma
  • Patent number: 5705584
    Abstract: The novel propylene homopolymer and copolymer produced by using a catalyst which is represented by the following formula (I): ##STR1## wherein M is a transition metal; R.sup.1 is a hydrocarbon group of 2 to 6 carbon atoms, R.sup.2 is an aryl group of 6 to 16 carbon atoms; X.sup.1 and X.sup.2 are each a halogen atom or the like; and Y is a divalent hydrocarbon group, a divalent silicon-containing group or the like.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: January 6, 1998
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Daisuke Fukuoka, Takashi Tashiro, Koji Kawaai, Takashi Ueda, Yoshihisa Kiso, Akira Mizuno, Masaaki Kawasaki, Masaaki Itoh, Mikio Hashimoto
  • Patent number: 5703181
    Abstract: Disclosed are a catalyst for olefin polymerization comprising (A) a compound of a transition metal in Group IVB of the periodic table which contains a ligand having a cyclopentadienyl skeleton, (B) an organoaluminum compound and any one of (C1) a Br.o slashed.nsted acid; (C2) a material obtained by contacting (c-1) a magnesium compound with (c-2) an electron donor; and (C3) a material obtained by contacting (c-1) a magnesium compound, (c-2) an electron donor and (c-3) an organometallic compound with each other. Also disclosed are processes for polymerizing an olefin in the presence of the above-mentioned catalysts for olefin polymerization. Such catalysts and processes for olefin polymerization as described above are excellent in olefin polymerization activity and economical efficiency.
    Type: Grant
    Filed: January 16, 1996
    Date of Patent: December 30, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Takashi Tashiro, Takashi Ueda
  • Patent number: 5703180
    Abstract: An ethylene/.alpha.-olefin copolymer obtained by copolymerizing ethylene with an .alpha.-olefin of 3 to 20 carbon atoms in the presence of a catalyst for olefin polymerization comprising an organoaluminum oxy-compound (a) and at least two kinds of transition metal compounds (b). This ethylene/.alpha.-olefin copolymer has high melt tension and high flowability.
    Type: Grant
    Filed: March 19, 1996
    Date of Patent: December 30, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshiyuki Tsutsui, Ken Yoshitsugu, Mamoru Takahashi, Akira Todo
  • Patent number: 5702827
    Abstract: Olefin thermoplastic elastomers which comprise a partially crosslinked thermoplastic elastomer comprising a crystalline polyolefin resin (A), a block copolymer (B) which is composed of a polymer block of styrene or its derivative and a specific isoprene polymer block, and an olefin rubber (C), and thermoplastic elastomer laminates, having a substrate formed from a specific olefin thermoplastic elastomer or a crystalline polyolefin resin and a skin layer formed from the above-mentioned olefin thermoplastic elastomer, which are excellent in mechanical strength, heat resistance, heat aging resistance, weathering resistance and scratch resistance have been provided by the present invention.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: December 30, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yuichi Itoh, Kyoko Kobayashi, Akira Uchiyama, Toru Takehara
  • Patent number: 5700859
    Abstract: An aqueous emulsion of fluorocarbon polymer according to the present invention is characterized by that the emulsion comprises a sodium dialkylsulfosuccinic acid of not less than 1.5% by weight relative to the fluorocarbon polymer, and an alkyleneglycol. A method for producing a stabilized aqueous emulsions of fluorocarbon polymer according to the present invention comprises mixing an aqueous emulsion of fluorocarbon polymer obtained by an emulsion polymerization process with a sodium dialkylsulfosuccinic acid dissolved in an alkyleneglycol or an aqueous solution of the alkyleneglycol. A novel aqueous emulsion of fluorocarbon polymer having excellent mechanical stability and thermal stability is obtainable.
    Type: Grant
    Filed: February 15, 1996
    Date of Patent: December 23, 1997
    Assignee: DuPont-Mitsui Fluorochemicals Co., Ltd.
    Inventors: Masatsune Ogura, Shizuo Chiba, Kayoko Ohtera
  • Patent number: 5700749
    Abstract: This invention relates to a process for polymerizing olefins using a catalyst composed of a transition metal catalyst component, an aluminoxane component and an organoaluminum component. In the process of this invention, the catalyst exhibits excellent polymerization activity with the use of a small amount of the aluminoxane xane. The polymerization process gives olefin polymers having a narrow molecular weight distribution and by the copolymerization of two or more olefins, gives olefin copolymers having a narrow molecular weight distribution and a narrow composition distribution.
    Type: Grant
    Filed: March 1, 1995
    Date of Patent: December 23, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshiyuki Tsutsui, Akinori Toyota, Norio Kashiwa
  • Patent number: 5700750
    Abstract: A process for producing an alpha-olefin polymer, which comprises polymerizing an alpha-olefin in the presence of a catalyst formed from (A) a transition metal compound comprising (A-1) a transition metal atom, (A-2) a hetero atom-containing ligand containing a heteroatom selected from oxygen, sulfur, nitrogen and phosphorus capable of forming a bond with the transition metal atom, and (A-3) a ligand having a conjugated .pi. electron through which the ligand can be bonded to the transition metal atom (A-1), and (B) an aluminoxane. The transition metal compound may be pre-treated with (C) an organometallic compound, or (D) a halogen-containing inorganic compound of an element of Group III, IV or V of the periodic table.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: December 23, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshiyuki Tsutsui, Akinori Toyota, Norio Kashiwa
  • Patent number: 5701049
    Abstract: A piezoelectric transformer has a piezoelectric substrate having first and second main faces. The substrate has first and second primary-side regions and a secondary-side region in its longitudinal direction in this order. The first region has a length of a half wavelength of stress distribution at the time of resonance in the longitudinal direction and has either positive or negative stress. The second region has a length of a half wavelength or less of the stress distribution and has either positive or negative stress. First and second electrode are respectively disposed on the first and second main faces in the first primary-side region, and the substrate between the first and second electrodes is polarized in the thicknesswise direction. Third and fourth electrodes are respectively disposed on the first and second main faces in the second primary-side region, and the substrate between the third and fourth electrodes is polarized in the thicknesswise direction.
    Type: Grant
    Filed: December 29, 1995
    Date of Patent: December 23, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Kouichi Kanayama, Nobuhiro Maruko
  • Patent number: 5698639
    Abstract: The invention provides ethylene-propylene-diene rubbers capable of imparting excellent heat resistance, weather resistance and dynamic fatigue resistance to vulcanized rubbers made therefrom. The ethylene-propylene-diene rubbers have sulfur uniformly dispersed therein by mixing a solution of the sulfur with a solution of the ethylene-propylene-diene rubber prior to the addition of vulcanization accelerators or other rubber additives to the rubbers. The vulcanized rubbers are particularly suitable for use as automobile components which require dynamic fatigue resistance such as muffler hangers, belts, rubber vibration insulators, engine mounts, tire treads for pneumatic tires, sidewalls for pneumatic tires and white sidewalls.
    Type: Grant
    Filed: August 21, 1996
    Date of Patent: December 16, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hidenari Nakahama, Takashi Mishima
  • Patent number: 5698751
    Abstract: A branched polyene compound represented by the formula ##STR1## wherein f is an integer of 1-5; R.sup.1 and R.sup.2 represent hydrogen atoms or alkyl groups of 1-5 carbons; R.sup.3 represents a hydrogen atom or an alkyl group of 1-5 carbons or an alkenyl group represented by the formula ##STR2## wherein n is an integer of 1-5; R.sup.4, R.sup.5 and R.sup.6 represent hydrogen atoms or alkyl groups of 1-5 carbons; all of R.sup.1, R.sup.2, R.sup.3 are not simultaneously hydrogen atoms; and all of R.sup.4, R.sup.5 and R.sup.6 are not simultaneously hydrogen atoms.
    Type: Grant
    Filed: July 6, 1995
    Date of Patent: December 16, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Tatsuyoshi Ishida, Masaaki Yasuda, Hitoshi Ohnishi, Noriaki Kihara, Toshihiro Sagane, Toshiyuki Tsutsui
  • Patent number: 5698682
    Abstract: The present invention provides a polarizing film having high heat resistance and a high degree of polarization and excellent optical properties by dyeing a polymer film with a novel azo compound represented by the following formula (1) or (2): ##STR1##
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: December 16, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yoriaki Matsuzaki, Ryu Oi, Rihoko Imai, Keisuke Takuma, Hisato Itoh
  • Patent number: 5698315
    Abstract: A electrically-conductive barium sulfate filler and a method for preparing same are herein disclosed and it comprises a particulate core material composed of barium sulfate provided thereon with a coating film of tin dioxide which may be optionally doped with niobium or tentalum, the bare core material free of coating film having a specific surface area ranging from 0.1 to 150 m.sup.2 /g and the film having a thickness ranging from 2 to 80 nm.
    Type: Grant
    Filed: May 23, 1996
    Date of Patent: December 16, 1997
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Takao Hayashi, Norihiro Sato, Nobuyoshi Kasahara, Katsuhiko Yoshimaru, Kouichi Kawaratani
  • Patent number: 5698634
    Abstract: A process for preparing a block copolymer of an .alpha.-olefin and a vinyl compound is here disclosed which comprises the steps of polymerizing an olefin selected from ethylene and the .alpha.-olefin having 3 or more carbon atoms by the use of a divalent or a trivalent rare earth metal complex, and then polymerizing a vinyl compound, a vinylidene compound or a lactone. According to the process of the present invention, a polar group can be introduced into a polyolefin, whereby the characteristics of the polymer can be effectively improved.
    Type: Grant
    Filed: July 18, 1996
    Date of Patent: December 16, 1997
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Hajime Yasuda, Eiji Ihara
  • Patent number: 5698651
    Abstract: Disclosed is an ethylene copolymer rubber which is a random copolymer rubber of (a) ethylene, (b) an .alpha.-olefin of 3 to 20 carbon atoms, (c) a nonconjugated polyene containing, in one molecule, one carbon-to-carbon double bond polymerizable by a metallocene catalyst among carbon-to-carbon double bonds, and (d) a nonconjugated polyene containing, in one molecule, two carbon-to-carbon double bonds polymerizable by the metallocene catalyst among carbon-to-carbon double bonds. The ethylene copolymer rubber has excellent moldability, high vulcanization rate, good mechanical properties such as high vulcanization strength, excellent low-temperature flexibility and thermal aging resistance. Also disclosed is a process for preparing the ethylene copolymer rubber with high activity, high conversion ratio of .alpha.-olefin and high random copolymerizability.
    Type: Grant
    Filed: June 17, 1996
    Date of Patent: December 16, 1997
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Masaaki Kawasaki, Toshiyuki Tsutsui, Tetsuo Tojo, Takashi Hakuta
  • Patent number: 5696049
    Abstract: The present invention aims at providing a novel NOx-decomposing catalyst and a denitrification method using the same. The feature thereof consists in an NOx-decomposing catalyst, in which vanadium oxide is supported on titanium oxide of anatase type, having a specific surface area of 100 to 250 m.sup.2 /g and micro pores of 15 to 25 .ANG. in pore diameter and 75 to 85 .ANG. in pore diameter respectively in an amount of at least 0.05 cc/g, and a method for the denitrification of a waste gas comprising contacting an NOx-containing waste gas with the above described catalyst in the presence of a reducing gas at a temperature of 100.degree. to 350.degree. C. An NOx-containing waste gas with coexistent catalyst-poisonous materials such as water, SOx, etc. can be treated in an effective manner at a relatively low temperature, e.g. 170.degree. C. or lower, at which no practical treatment can be carried out by the prior art method, without formation of N.sub.2 O as a by-product.
    Type: Grant
    Filed: February 2, 1995
    Date of Patent: December 9, 1997
    Assignee: Mitsui Mining Co., Ltd.
    Inventors: Nobuhide Ikeyama, Yutaka Iwanaga, Yuji Torikai, Masatosi Adachi
  • Patent number: 5695911
    Abstract: Phthalocyanine compounds represented by the below-described formula are suitable for use in the fabrication of color filters. ##STR1## wherein R.sup.1, R.sup.4, R.sup.5, R.sup.8, R.sup.9, R.sup.12, R.sup.13 and R.sup.16 represent a group represented by the below-described formula, H or a halogen atom, R.sup.2, R.sup.3, R.sup.6, R.sup.7, R.sup.10, R.sup.11, R.sup.14 and R.sup.15 represent an alkyl, alkoxyl, alkylthio, alkylamino, dialkylamino or aryloxyl, arylthio group or --COOR.sup.17, R.sup.17 being a particular monovalent group, H or a halogen atom; and Met represents a metal atom. ##STR2## wherein X and Z represent O or S, R.sup.18, R.sup.19 and R.sup.20 represent H or an alkyl group, A, B and D represent a connecting group, n and l is an integer of 0-10, m, q, t, u, r and w are an integer of 0-2, and p is 0 or 1.
    Type: Grant
    Filed: November 17, 1995
    Date of Patent: December 9, 1997
    Assignees: Mitsui Toatsu Chemicals, Incorporated, Yamamoto Chemicals, Incorporated
    Inventors: Hisato Itoh, Akio Karasawa, Kenichi Sugimoto, Takahisa Oguchi, Shin Aihara