Patents Assigned to Mitsui
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Patent number: 5677398Abstract: Disclosed are an epoxy acrylate resin of the general formula (1) ##STR1## and an acid-modified epoxy acrylate resin obtained by reacting the epoxy acrylate resin with a carboxylic acid or an anhydride thereof, as well as curable resin compositions containing such a resin and the cured products thereof.Type: GrantFiled: April 3, 1996Date of Patent: October 14, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Toshihiro Motoshima, Akio Karasawa, Keisuke Takuma, Akihiro Yamaguchi
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Patent number: 5677409Abstract: Described herein are propylene waxes and a production process thereof. The waxes are each produced by polymerizing propylene in a reaction vessel while using a solid catalyst in the presence or absence of an organoaluminum compound. A hydrogen partial pressure of a gas phase in the reaction vessel, said gas phase being formed of the propylene and hydrogen, is maintained at 10% or higher. The solid catalyst is formed of a transition metal compound or a reaction product between the transition metal compound and an organometallic compound, an aluminoxane and a fine particulate carrier. Also described herein is a heating-roll fixing type toner composition composed essentially of a binder resin or a binder resin composition, a colorant and, as a releasing agent, the wax.Type: GrantFiled: May 8, 1995Date of Patent: October 14, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Norihide Inoue, Masahiro Kouno, Yoshiho Sonobe, Kazumi Mizutani, Tetsunosuke Shiomura, Nobuhiro Hirayama
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Patent number: 5677408Abstract: The novel propylene elastomer according to the invention contains (1) units derived from propylene in amounts of 50 to 95% by mol and units derived from 1-butene in amounts of 5 to 50% by mol, and has (2) triad tacticity (mm fraction), determined by the .sup.13 C-NMR spectrum (hexachlorobutadiene solution, based on tetramethylsilane), of not less than 90%, (3) an intrinsic viscosity (in decalin at 135.degree. C.) of 0.1 to 12 dl/g, (4) a molecular weight distribution (Mw/Mn) of not more than 3 and (5) a randomness parameter B value of 1.0 to 1.5, preferably 1.0 to 1.3. In addition, the elastomer desirably has properties that (6) the elastomer has a melting point Tm of 60.degree. to 140.degree. C., and the melting point Tm and a 1-butene constituent unit content M (% by mol) in the elastomer satisfy the relation -2.6M+130.ltoreq.Tm.ltoreq.-2.3M+155, and (7) a crystallinity C of the elastomer measured by X-ray diffractometry and the 1-butene constituent unit content M (% by mol) satisfy the relation C.ltoreq.Type: GrantFiled: June 5, 1995Date of Patent: October 14, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takashi Ueda, Akira Mizuno, Masaaki Kawasaki, Daisuke Fukuoka, Yoshihisa Kiso, Tatsuya Tanizaki, Mikio Hashimoto, Masahiro Sugi, Toshiyuki Tsutsui
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Patent number: 5677397Abstract: An epoxy resin composition which exhibits a low dielectric constant and a low dielectric dissipation factor as well as an excellent working susceptibility after its curing is provided. The epoxy resin composition contains at least one member selected from a novolak resin (A) prepared by condensing formalin and an alkylphenol compound; and an epoxy resin (B) prepared by glycidylating said novolak resin (A) with an epihalohydrin.Type: GrantFiled: June 13, 1996Date of Patent: October 14, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Hideo Nakamura, Terufumi Suzuki, Kiyomi Yasuda
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Patent number: 5676847Abstract: A method for recovering crystals from a crystal-containing slurry, which comprises supplying the slurry to a rotary filter having a rotating cylindrical filter medium, filtering the supplied slurry in a filtering region to retain the crystals on the filter medium and washing the filter cake formed on the rotating filter medium repeatedly in a plurality of washing regions by spraying a washing liquid onto the cake in each region by supplying any one of washing regions on the aft side in the rotating direction of the filter medium with the spent washing liquid of the washing region adjacent to said one washing region on the fore side in the rotating direction.Type: GrantFiled: May 20, 1994Date of Patent: October 14, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Ryoichi Yamamoto, Toshiyuki Sakata, Hiroshi Suzuki, Etsuro Okamoto
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Patent number: 5674954Abstract: In a novel method of homo- or copolymerization of vinyl chloride, a specified coating agent is applied on the surfaces of the portions which will become into contact with the vinyl chloride monomer during the polymerization process. The coating agent is in a form of an aqueous solution of a modified condensation product of phenol and aldehyde, the pH of the solution being adjusted in a range that the product is dissolved at an ambient temperature upon coating of the solution and separates out of the solution upon being heated on the surfaces. The wall surface of the polymerization tank and the like is then coated with a thin film of the coating agent having a uniform thickness and being strongly adhered to the wall surface, thereby providing an excellent effect of preventing adhesion of the product polymer to the wall surface.Type: GrantFiled: June 6, 1995Date of Patent: October 7, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Seiichi Masuko, Ichisaburo Nakamura, Yoshimatsu Naka, Keiichi Fukuda, Akira Yamamoto, Yasuyuki Hatakeyama
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Patent number: 5674611Abstract: An adhesive for copper foils which comprises 40-70% by weight of an epoxy resin, 20-50% by weight of a polyvinyl acetal resin and 0.1-20% weight of a melamine or urethane resin, all of said resins totalling 100% by weight, with the proviso that 5-80% by weight of said epoxy resin is a rubber-modified epoxy resin; andAn adhesive-applied copper foil having said adhesive attached onto its one face.Type: GrantFiled: May 8, 1995Date of Patent: October 7, 1997Assignee: Mitsui Mining Smelting Co., Ltd.Inventors: Muneo Saida, Muneharu Ohara, Teturoh Satoh
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Patent number: 5674920Abstract: A flexible high-resilience polyurethane foam which has improved impact resilience and compression set, excellent effect on the reduction of transmissibility at 6 Hz and also improved mechanical strengths even under a reduced amount of a catalyst and is prepared by using, as an organic polyisocyanate composition, a mixture having a specified ratio of tolylene diisocyanate to polymethylenepolyphenyl isocyanate having a specific benzenoid composition or by using an isocyanate terminated prepolymer obtained by reacting the mixture with polyoxyalkylene polyol which has specific structure and is used for modification, and by using polyalkylene polyol which satisfies specific conditions in a hydroxyl value, monool content, and head-to-tail coupling selectivity; and a preparation process of the flexible high resilience polyurethane foam.Type: GrantFiled: November 16, 1995Date of Patent: October 7, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Masashi Obata, Seijiro Sakai, Kaoru Ueno
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Patent number: 5674947Abstract: There are herein disclosed a method for preparing a modified resin which comprises thermal/reaction by the use of a norbornenyl group-containing compound typified by norbornenecarboguanamine or its derivative, a method for preparing an epoxy-modified resin which comprises the step of reacting the above-mentioned modified resin and an epoxide, a flame-retarding method, a thermal stabilization method, a compatibilizing method and a surface modification method which comprise utilizing the modified resin, as well as a coating resin composition and an adhesive resin composition containing the modified resin. According to the, preparation methods of the present invention, the deterioration of a material scarcely occurs, and a functional group which is excellent in flame retardancy, thermal stability, compatibility and the like can be introduced to the resins.Type: GrantFiled: August 14, 1995Date of Patent: October 7, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Tetsuya Oishi, Kazuo Sugazaki, Jin Suzuki
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Patent number: 5674919Abstract: Biaxially oriented films from high molecular weight polyethylene are characterized by a gas permeable structure formed from random-arranged microfibrils. The films have coefficients of static friction and kinetic friction of not more than 1.0. The biaxially oriented films are further characterized by service smoothness as well as tensile (tangent) modulus and tensile strength. The films may be used for lamination, filter, or for packaging for moisture absorbers. The biaxially oriented films may be obtained by extracting a hydrocarbon plasticizer from a sheet formed from the high molecular weight polyethylene and a hydrocarbon plasticizer, stretching the resulting sheet to obtain an oriented film having a specific surface area of at least 70 m.sup.2 /g and a fibril structure, and heating the oriented film under a standard length constraint to reduce the oriented film in specific area by at least 20 m.sup.2 /g.Type: GrantFiled: June 5, 1995Date of Patent: October 7, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kazuo Yagi, Hitoshi Mantoku, Akinao Hashimoto, Isaburo Higashi, Yoshinori Akana
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Patent number: 5674945Abstract: Ethylene copolymer compositions comprise: an ethylene/.alpha.-olefin copolymer component comprising at least one ethylene/.alpha.-olefin copolymer having a density within a specific range, a melt flow rate (MFR) within a specific range, an amount of an n-decane-soluble portion within a specific range and a melt tension (MT) that satisfies a specific relation with the MFR; and a (co)polymer component comprising one (co)polymer selected from the group consisting of a low-density polyethylene obtained by high-pressure radical polymerization, a crystalline polyolefin and an olefin elastomer. The ethylene copolymer compositions are excellent in heat stability and moldability, and able to form films of high transparency, high mechanical strength and anti-blocking resistance.Type: GrantFiled: April 26, 1995Date of Patent: October 7, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Mamoru Takahashi, Akira Todo, Seiichi Ikeyama, Toshiyuki Tsutsui, Shinya Matsunaga, Norio Kaneshige
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Patent number: 5674624Abstract: Disclosed is a highly light-transmitting dust protective film composed of at least one member selected from the group consisting of transparent gels of oxides, hydroxides, organic group-containing oxides and organic group-containing hydroxides of polyvalent metals, formed by the sol-gel process.Type: GrantFiled: December 17, 1993Date of Patent: October 7, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Tetsuya Miyazaki, Mayumi Kawasaki, Takao Ohno
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Patent number: 5674914Abstract: A method of reclaiming waste polyvinyl chloride according to the present invention includes the steps of bringing industrial waste containing polyvinyl chloride into contact with a solvent in which polyvinyl chloride can be dissolved, to remove polyvinyl chloride from the industrial waste, removing substances which cannot be dissolved in the solvent from a polyvinyl chloride solution consisting of the solvent and the polyvinyl dissolved therein, and recovering reclaimed polyvinyl chloride as a substance left over when the solvent is removed from the polyvinyl solution. The industrial waste to be reclaimed includes polyvinyl chips obtained from waste electric wires, polyvinyl chloride-impregnated wallpaper and used agricultural polyvinyl chloride sheets. The solvent used in the present invention consists of at least one kind of organic solvent selected from the group composed of methyl ethyl ketone, methyl isobutyl ketone and dioctyl phthalate.Type: GrantFiled: August 31, 1995Date of Patent: October 7, 1997Assignees: Mitsui & Co., Ltd., Masakazu AbeInventors: Masakazu Abe, Kiyoshi Murakami
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Patent number: 5674953Abstract: In a novel method of homo- or copolymerization of vinyl chloride, a specified coating agent is applied on the surfaces of the portions which will become into contact with the vinyl chloride monomer during the polymerization process. The coating agent is in a form of an aqueous solution of a modified condensation product of phenol and aldehyde, the pH of the solution being adjusted in a range that the product is dissolved at an ambient temperature upon coating of the solution and separates out of the solution upon being heated on the surfaces. The wall surface of the polymerization tank and the like is then coated with a thin film of the coating agent having a uniform thickness and being strongly adhered to the wall surface, thereby providing an excellent effect of preventing adhesion of the product polymer to the wall surface.Type: GrantFiled: June 6, 1995Date of Patent: October 7, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Seiichi Masuko, Ichisaburo Nakamura, Keiichi Fukuda, Yasuyuki Hatakeyama, Akihiro Yamaguchi, Keizaburo Yamaguchi
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Patent number: 5672462Abstract: The present invention relates to an optical recording medium having a recording layer, a reflective layer and a protective layer on a substrate, wherein a quinophthalone compound represented by the following formula (1) is contained in the above recording layer. The use of the quinophthalone compound or a mixture of the quinophthalone compound and a photoabsorbing compound having an absorption maximum in a wavelength falling in a range of 550 to 900 nm in the recording layer makes it possible to provide an interchangeable optical recording medium not only capable of recording and reproducing with a laser having a wavelength falling in a range of 480 to 600 nm, but is also capable of recording and reproducing with red lasers having wavelengths of 630 nm and 680 nm and a near infrared laser having a wavelength of 780 nm.Type: GrantFiled: June 10, 1996Date of Patent: September 30, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Keisuke Takuma, Tsutami Misawa, Kenichi Sugimoto, Taizo Nishimoto, Takeshi Tsuda, Hideki Umehara
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Patent number: 5670154Abstract: A tyrosinase inhibiting agent acts specifically on tyrosinase to inhibit it; the effective component of this action being an inhibitor of tyrosinase consisting of tea polyphenols.Type: GrantFiled: December 2, 1994Date of Patent: September 23, 1997Assignee: Mitsui Norin Co., Ltd.Inventors: Yukihiko Hara, Miwa Honda
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Patent number: 5670551Abstract: A crosslinked foamed body obtained by subjecting a rubber compounded product comprising (A) a chlorinated ethylene/.alpha.-olefin copolymer rubber, (B) a triazinethiol as a vulcanization agent, (C) an alkyl ammonium halide as a vulcanization promotor, and (D) a hydrazide-type blowing agent to two step vulcanization and foaming at a vulcanization temperature of 120.degree. to 140.degree. C. for a vulcanization time of 5 to 10 minutes in a first step and at a vulcanization temperature of 125.degree. to 160.degree. C. for a vulcanization time of 5 to 20 minutes in a second step, the second step vulcanization temperature being higher than the first step by at least 5.degree. C., so that the expansion factor will be 3 to 10 times. This crosslinked foamed body can be colored brilliantly, exhibit excellent weatherability, suppleness and shape retention as well as good outer appearance. This product is well usable, for example, as wet suits.Type: GrantFiled: August 11, 1995Date of Patent: September 23, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Muneyuki Matsumoto, Keiji Okada, Yoshihisa Matsuo, Akemi Uchimi
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Patent number: 5668229Abstract: A process for preparing an acrylamide polymer is herein disclosed which comprises the step of initiating polymerization in the presence of an oxidation-reduction system polymerization initiator comprising two or more kinds of oxidizing agents and a reducing agent. According to this process, the polymerization rate can be remarkably increased without bringing about a decrease in the molecular weight of the polymer, and hence, restriction on manufacturing facilities and apparatuses can be relieved and productivity can be remarkably enhanced, which permits a decrease in manufacturing cost.Type: GrantFiled: November 12, 1996Date of Patent: September 16, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Takashi Abe, Hiroshi Itoh, Manabu Tsuruta, Shoko Oyanagi, Kenichi Nakamura
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Patent number: 5667726Abstract: Disclosed is a highly light-transmitting dust protective film composed of at least one member selected from the group consisting of transparent gels of oxides, hydroxides, organic group-containing oxides and organic group-containing hydroxides of polyvalent metals, formed by the sol-gel process.Type: GrantFiled: January 25, 1994Date of Patent: September 16, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Tetsuya Miyazaki, Mayumi Kawasaki, Takao Ohno
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Patent number: 5666834Abstract: An anti-theft mechanism for a vehicle door lock device comprises a latch mechanism having a latch engaging with a striker, an opening means for releasing the engagement of the latch and the striker, and a lock lever connected to a key cylinder of a door and changed between a locked position and an unlocked position, and a relay mechanism having a sill knob lever connected to a sill knob of the door, an anti-theft member arranged to be changed between an anti-theft cancelled position and an anti-theft position, and an actuator for anti-theft operation for changing the anti-theft member. The sill knob lever is arranged to be pushed by the anti-theft member to return to the locked position, if the anti-theft member switches from the anti-theft position to the cancelled position when the sill knob lever is in the unlocked position.Type: GrantFiled: December 14, 1994Date of Patent: September 16, 1997Assignee: Mitsui Kinzoku Kogyo Kabushiki KaishaInventor: Jiro Inoue