Patents Assigned to Mitsui
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Patent number: 5043393Abstract: According to the present invention, there is provided an improvement of a process for producing fluorine-containing copolymers comprising copolymerizing(a) a chlorinated fluoroolefin,(b) vinyl ether, and(c) an organosilicon compound having an olefinically unsaturated bond and a hydrolyzable bond,the improvement resides in that a chlorine trapping agent is allowed to exist in the system during the copolymerization reaction and/or the purification of the resulting copolymer, and the fluorine-containing copolymers are free from coloration.Further, according to the present invention, a fluorine-containing copolymer composition containing a specific curing catalyst is also provided and said composition is excellent in adhesion to substrates or base materials.Type: GrantFiled: December 1, 1989Date of Patent: August 27, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Shiro Honma, Takashi Izumi, Hajime Inagaki, Sakae Murakami
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Patent number: 5041520Abstract: Disclosed is a process for preparing a polyimide by reacting certain reactants. The reactants include an aromatic diamine which is 3,3'-diaminobenzophenone and/or bis(3-aminophenyl)sulfone, a tetrocarboxylic dianhydride and a dicarboxylic anhydride. A thermally stable polyimide can be obtained which displays excellent processability.Type: GrantFiled: June 26, 1989Date of Patent: August 20, 1991Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Masahiro Ohta, Saburo Kawashima, Katsuaki Iiyama, Shoji Tamai, Hideaki Oikawa, Akihiro Yamaguchi
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Patent number: 5041464Abstract: A process for preparing polymer emulsion particles having pores therein, an outside diameter D of 0.1 to 5.0[ , an inside diameter d of 0.05 to 4.0.mu. , and a ratio (d/D) of 0.1 to 0.9 in dry condition, comprising the steps of forming core-shell emulsion particles from specific monomers by two-emulsion polymerizations, and swelling the core of the particles with water by hydrolyzing the vinyl acetate part of polymer (A), thereby inducing the hydroxyl groups therein, e.g., using an acidic material or a basic material at 50.degree. to 100.degree. C. The particles when use as a pigment in coating compositions provide excellent converage rate, brightness, gloss and water resistance.Type: GrantFiled: December 26, 1989Date of Patent: August 20, 1991Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Futoshi Hoshino, Takeshi Yanagihara, Makoto Nakano
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Patent number: 5041656Abstract: A catalyst useful in the practice of a process, in which (meth)acrylamide is prepared through the hydration reaction between (meth)acrylonitrile and water in a suspended liquid-phase bed of a Raney copper catalyst, has been obtained by leaching a Raney copper alloy in the presence of the Raney copper catalyst which has been deteriorated. The above useful catalyst has higher performances, compared with a catalyst obtained by conventionally leaching the Raney copper alloy alone, has satisfactory handling properties in settling and filtering, and can significantly reduced the amount of catalyst to be discarded.Type: GrantFiled: August 10, 1990Date of Patent: August 20, 1991Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Shiro Asano, Mareo Tokunaga, Yoshihiko Kambara
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Patent number: 5041341Abstract: In accordance with the present invention, there are provided information recording media having a substrate and thereon a recording layer and a metallic layer, wherein the metallic layer is composed of an aluminum alloy containing (i) titanium and (ii) at least one metal selected from among chromium, niobium and magnesium. The information recording media thus provided are excellent in corrosion resistance and small in dependence of the recording power on linear velocity.Type: GrantFiled: May 23, 1990Date of Patent: August 20, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kiyotaka Shindo, Koichi Igarashi, Kunihiko Mizumoto, Hidehiko Hashimoto
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Patent number: 5041329Abstract: Disclosed are vulcanized rubber articles of foamed type and non-foamed type which are prepared by vulcanizing a vulcanizable and foamable (or a vulcanizable) molded product made of a chlorinated ethylene/.alpha.-olefin copolymer rubber, chlorinated polyethylene or chlorosulfonated polyethylene, said vulcanizable and foamable (or vulcanizable) molded product having been surface-treated with a coating solution containing at least one compound selected from alkylammonium halide, alkylphosphonium halide, amine having an acid dissociation constant (pKa) of not less than 10 and amine salt having an acid dissociation constant (pKa) of not less than 10. Also disclosed are processes for the preparation of the vulcanized rubber articles of foamed type and non-foamed type.Type: GrantFiled: December 4, 1990Date of Patent: August 20, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Tetsuo Tojo, Yoshiharu Kikuchi, Keiji Okada
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Patent number: 5041587Abstract: A process for preparing an organic silicon compound is here disclosed which comprises the step of reacting a halogenated hydrocarbon selected from the group consisting ##STR1## wherein each of X.sup.1 to X.sup.16 is selected from the group consisting of hydrogen, an alkyl group, alkenyl group, phenyl group, naphthyl group, alkoxy group, acyl group, alkylamino group and dialkylamino group having 1 to 20 carbon atoms which are unsubstituted or substituted and a halogen atom; and each of at least one of X.sup.1 to X.sup.4, at least one of X.sup.8 to X.sup.10 and at least one of X.sup.11 to X.sup.16 is a halogen atom,with a silane selected from the group consisting of SiH.sub.4, Si.sub.2 H.sub.6 and Si.sub.3 H.sub.8.Type: GrantFiled: February 12, 1990Date of Patent: August 20, 1991Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Masayoshi Itoh, Kenji Iwata, Noriyuki Yanagawa, Tetsura Utsumi, Mineo Kobayashi, Ryo Takeuchi, Tomohiro Abe
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Patent number: 5041529Abstract: The invention relates to a process for the preparation of a bioabsorbable polyester comprising reacting said polyester under reduced pressure in the reaction system while maintaining said polyester in the molten state during the second half of the polymerization reaction or after completion of the reaction and obtaining said polyester which contain almost no residue of unreacted monomers and volatile ingredients of low molecular weight.Type: GrantFiled: October 27, 1989Date of Patent: August 20, 1991Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Hosei Shinoda, Masami Ohtaguro
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Patent number: 5041660Abstract: Disclosed is a novel .alpha.-chloroketone derivative as a synthesis intermediate of N-cyano-N'-methyl-N"-(2-((5-methyl-1H-imidazol-4-yl)methylthio)ethyl)guani dine (general name: Cimetidine) which shows an action of controlling the secretion of gastric acid and is valuable as a medicine for remedy of a gastric ulcer. This .alpha.-chloroketone derivative is prepared by reacting disulfide derivative with sulfuryl chloride and reacting the reaction product with methylvinyl ketone or by reacting a mercapto derivative with 3-chloro-3-buten-2-one.Type: GrantFiled: October 24, 1990Date of Patent: August 20, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Keiichi Yokoyama, Yoshio Noguchi, Noriaki Kihara
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Patent number: 5041338Abstract: The present invention relates to a polypropylene composition useful as an adhesive comprising a modified polypropylene resin graft-modified with from about 0.01 wt. % to about 2 wt. % of a radical-polymerizable unsaturated compound and a crystalline propylene/ethylene block copolymer containing from about 10 wt. % to about 50 wt. % of a propylene/ethylene random copolymer having an ethylene content of from about 20 wt. % to about 90 wt. %. The resin composition is particularly suitable for bonding a polypropylene resin layer and an ethylene/vinyl alcohol copolymer layer, and a polypropylene resin layer and a polyamide resin layer.Type: GrantFiled: November 28, 1989Date of Patent: August 20, 1991Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Keigo Suehiro, Takashi Miyazaki, Katsuyuki Nitta, Sachio Yokote, Yoichi Kawai
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Patent number: 5039780Abstract: A copolyester having an intrinsic viscosity, measured in o-chlorophenol at 25.degree. C., of 0.3 to 1.5 dl/g and being derived from dicarboxylic acid units composed of 95 to 60 mole % of isophthalic acid units and 5 to 40 mole % of 2,6-naphthalenedicarboxylic acid units and dihydroxy compound units composed of 95 to 70 mole % of ethylene glycol units and 5 to 30 mole % of 1,3-bis(2-hydroxyethoxy)benzene units; a gas barrier imparting agent composed of the copolyester; a polyester composition composed of (A) a polyethylene terephthlate and (B) the copolyester; and a film, a preform and a container composed of the polyester composition. Also provided are a polyester laminated structure, a stretched laminated structure, a preform and a laminated blow-molded article each composed of (C) a polyalkylene terephthalate layer and (D) a copolyester layer composed of the copolyester or the polyester composition.Type: GrantFiled: November 7, 1989Date of Patent: August 13, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Mikio Hashimoto, Norio Kaneshige
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Patent number: 5039730Abstract: In accordance with the present invention, there are provided fiber reinforced heat-resistant polyolefin compositions comprising 5-85% by weight of polyphenylene sulfide (A), 15-95% by weight of modified polyolefin (B) having a melting point of above 200.degree. C., which has been graft-modified, either partly or wholly, with 0.01-10% by weight of unsaturated carboxylic acid or its derivative, 10-60 parts by weight, based on 100 parts by weight of (A)+(B), of reinforcing fiber (C) and, if necessary, 5-30 parts by weight, based on 100 parts by weight of (A)+(B), of oxazoline-modified polystyrene (D). The compositions thus provided are excellent in heat resistance, water resistance, moisture resistance and solderability, and that excellent in mechanical strength.Type: GrantFiled: October 27, 1988Date of Patent: August 13, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Akira Yokoyama
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Patent number: 5039757Abstract: This invention provides cationic acrylamide polymers which are highly effective as paper strength agents, drainage agents and suspension flocculants, and which do not show much temporal deterioration; it also provides a method of manufacturing said polymers wherein the manufacturing equipment is compact and can be installed on site, and the cationicity of the polymers can be modified in a short time.This invention comprises a method of manufacturing cationic acrylamide polymers by reaction, with a hypohalogenite, of a (meth)acrylamide homopolymer, a copolymer of (meth)acrylamide and acrylonitrile, a copolymer of (meth)acrylamide and N,N-dimethylacrylamide, in a high temperature range of 50.degree.-110.degree. C. for a short time; the polymers manufactured by said process; and paper strength agents, drainage agents and flocculants having these polymers as their principal constituent.Type: GrantFiled: December 21, 1989Date of Patent: August 13, 1991Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Toshihiko Takaki, Kenji Tsuboi, Hiroshi Itoh, Atsuhiko Nitta
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Patent number: 5037977Abstract: This invention concerns a method for the production of dimeric alkaloids, characterized by reacting of catharanthine with vindoline in the presence of Fe.sup.3+ and (1) removing or inactivating the Fe.sup.3+ and allowing the reaction product to react with a reducing agent or (2) allowing presence of oxygen and a dicarboxylic acid or a derivative thereof in the reaction system and allowing the reaction product to react with a hydride source.In accordance with this invention, such dimeric alkaloid as vinblastine, leurosidin, and 3',4'-anhydrovinblastine which are useful as antineoplastic drugs can be produced in high yields.Type: GrantFiled: August 8, 1989Date of Patent: August 6, 1991Assignee: Mitsui Petrochemical Industries Ltd.Inventors: Hiroaki Tan, Naoya Sakamoto, Eiichiro Hata, Takeshi Ishitoku, Noriaki Kihara
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Patent number: 5036646Abstract: The present invention relates to a container for an integrated circuit wafer comprising a tray-shaped member having a recess and a complimentary sheet member sized to attach to and cover said recess, at least one of said members being made from a material selected from the group consisting of a single layer of a high nitrile resin, and a laminated layer of a high nitrile resin, a polyvinylidene chloride resin, an ethylene vinyl alcohol copolymer or a polyvinyl alcohol resin, and a method for storing the wafer.Type: GrantFiled: May 10, 1989Date of Patent: August 6, 1991Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Masayuki Makihara, Toshirou Ryuno, Mitsunobu Fujita, Osamu Narimatsu, Toshiyuki Konishi
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Patent number: 5037715Abstract: A resin for toner of electrophotography comprises a urethane-modified polyester resin (D) having a glass transition temperature ranging from 40.degree. to 75.degree. C., which is obtained by reacting a resin mixture composed of a polyester resin (A) having a number-averaging molecular weight of 1,000 to 15,000 and a hydroxyl value of 10 to 100 and a polyester resin (B) having a number-average molecular weight ranging from 1,000 to 5,000 and a sum of acid value and hydroxyl value of less than 10, in a weight ratio of (A)/(B) ranging from 20:80 to 60:40, with 0.3 to 0.99 molar equivalent of an isocyanate compound (C) per one molar equivalent of hydroxyl group of the polyester resin (A).The resin for toner is excellent in grindability and storage stability and it provides toners for electrophotography having good anti-blocking properties and good fixing properties whereby good images free of fogging can be obtained.Type: GrantFiled: June 11, 1990Date of Patent: August 6, 1991Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Kazuo Hagiwara, Akira Misawa, Kazuo Hisamatsu, Masaaki Shin
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Patent number: 5037899Abstract: A modified epoxy resin provided with improved flexibility and curing properties is prepared by subjecting a bisphenol type epoxy resin (a) to steps (i) and (ii):(i) the step wherein the epoxy group is reacted with a primary amine (b), and(ii) the step wherein secondary hydroxyl group is at least partly esterified by a reaction with a lactone.Type: GrantFiled: October 31, 1990Date of Patent: August 6, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Hideo Nakamura, Masaru Wakizaka, Michio Hashimoto, Yohzoh Yamamoto
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Patent number: 5036758Abstract: An emboss roll according to the present invention is capable of assuredly performing an embossing work without any risk of shaving a surface of nonwoven fabrics and forming pin holes when used to emboss nonwoven fabrics for the purpose of prevention of filament shavings to be adhered to products. This emboss roll having an outer surface thereof provided with embossing projections wherein all of the top end corners thereof are cut so as to be a surface. As a result of cutting the top end corners of the embossing projections, nonwoven fabrics can be protected from being cut by the corner portions or forming pin holes during the embossing work.Type: GrantFiled: February 6, 1989Date of Patent: August 6, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yoshinori Kobayashi, Naoyuki Tamura
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Patent number: 5037692Abstract: A multilayer structure which provides high strength under low distortion or elongation conditions without impairing the draining properties of conventional structures or the ease with which they can be transported or be made to conform to the earth surfaces over which they are laid. The multilayer structure of the invention comprises knitted or woven fabric layers and non-woven fabric layers multilaid together; the knitted or woven fabric layers consist of synthetic resin multifilaments oriented at least in one direction and having a tensile elastic modulus of 20 GPa or more, preferably 50 GPa or more, and a tensile strength of 1.2 GPa or more, preferably 1.5 GPa or more, while the non-woven fabric layers consist of long or short synthetic resin fibers arranged at random.Type: GrantFiled: April 19, 1989Date of Patent: August 6, 1991Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yoshitomo Miyazaki, Jun Nishimura, Takashi Katoh
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Patent number: 5037587Abstract: In the preparation of a film by melt-extrusion process of thermoplastic polyimide, static charge is applied to a molten film, primary cooling is carried out by adhering the film to a cooling roller having a surface temperature in the range of from the glass transition temperature of said polyimide -50.degree. C. to the glass transition temperature -15.degree. C., the film is successively cooled to 60.degree. C. and less without bringing the film into contact with rollers, and is taken up under tension to give a polyimide film.Type: GrantFiled: July 6, 1990Date of Patent: August 6, 1991Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Masumi Saruwatari, Yasuhiko Ohta, Yasuhiro Fujii, Yasuko Honji, Shoichi Tsuji, Shinobu Moriya