Abstract: Zinc carboxylate catalysts for the copolymerization of carbon dioxide and epoxides are prepared by the reaction of zinc oxide with glutaric or adipic acid in an aprotic reaction solvent. Azeotropic distillation may be used to separate the water-solvent phase from the reaction mixture, or the catalyst may be separated from the reaction mixture by filtration and drying, generally without the need for repeated washings to remove active hydrogen atom sources. Examples of aprotic reaction solvents are toluene, dibutyl ether, anisole and ethyl benzoate.
Type:
Grant
Filed:
April 20, 1990
Date of Patent:
June 25, 1991
Assignees:
Air Products and Chemicals, Inc., Arco Chemical Company, Mitsui Petrochemical Industries Ltd.
Inventors:
Stephen A. Motika, Timothy L. Pickering, Andrzej Rokicki, Beatrice K. Stein
Abstract: Crude maleic anhydride produced by catalytic oxidation is distilled and then n-propyl gallate, cuprous chloride and zinc chloride are added thereto.Alternatively, crude maleic anhydride is distilled in the presence of tridecyl phosphite. Further, these procedures can be used in combination. Thermal stability and color stability of the maleic anhydride is improved.
Abstract: Machinable ceramics with 30-60 vol. % of fine crystals of fluorophlogopite, a synthetic mica, evenly dispersed in a vitreous matrix is produced using as principal raw materials kaolin and activated clay, which are natural minerals, other than metal oxides themselves. According to the production process, a mixture of fine particulate raw materials is calcined under first heat treatment conditions in which a maximum temperature is in the range of 1,000.degree.-1,100.degree. C. The raw materials include kaolin and activated clay as principal raw materials, Mg-containing, K-containing and F-containing compounds as auxiliary raw materials and B.sub.2 O.sub.3 as a sintering aid. The resulting calcined mass is ground into fine particles, followed by the formation of a green body of a desired shape. The green body is then sintered into a fired body under second heat treatment conditions in which a maximum temperature is in the range of 1,100.degree.-1,250.degree. C.
Abstract: It is an object of the present invention to provide a tube with precise holes. The side of a tube is drilled at predetermined intervals by a laser beam while the tube is being conveyed in its longitudinal direction in a tubular state. In consequence, manufacture is facilitated, and the precise holes can be drilled.
Abstract: In accordance with the present invention, there are provided 4-methyl-1-pentene polymer compositions comprising 90-10 parts by weight of 4-methyl-1-pentene polymer (A), 90-10 parts by weight of propylene polymer (B) and 70-10 parts by weight of inorganic filler (C), provided that the sum of (A), (B) and (C) total to 100 parts by weight. There are also provided 4-methyl-1-pentene polymer compositions 20-3 parts by weight of .alpha.-olefin copolymer (D) in addition to the above-mentioned components (A), (B) and (C), provided that the sum of (A), (B), (C) and (D) totals to 100 parts by weight.These compositions as illustrated above are capable of vacuum forming, injection blow-forming and the like, and they are excellent in rigidity at high temperatures, toughness at low temperature and impact strength.
Abstract: An epoxy resin comprising an active hydrogen compound having at least three active hydrogen atoms capable of reacting with an epoxy group in its molecule or butadine or isoprene as a main monomer is modified with an oligomer having on average at least 1.5 equivalents of active hydrogen capable of reacting with an epoxy group in its molecule. An epoxy resin modified with a bisphenol and a compound having active hydrogen or acid anhydride groups capable of reacting with an epoxy group is also provided. A toner containing the epoxy resin as a binder is useful in electrostatography.
Abstract: Near-infrared absorbers which contain phthalocyanine derivatives in which the four benzene rings contained in the molecule independently have 1 to 4 substituents are light and thermal resistant and possess high molar extinction coefficients. Such near-infrared absorbers are useful in optical recording media, near-infrared absorption filters, and liquid crystal display devices.
Abstract: A method of treating starch-containing water comprises the step of adding water swellable, cationic polymerizate particles to the starch-containing water. The starch is soluble starch. The water-swellable cationic polymer particles are polymer particles of a crosslinking monomer and either a cationic vinyl monomer or a cationic vinyl monomer and a nonionic vinyl monomer.
Abstract: Disclosed herein are salicylic acid copolymers having a weight average molecular weight of 500-10,000 and obtained (a) by condensing salicylic acid (i) with a benzyl alcohol (ii) and/or benzyl ether (iii) or a benzyl halide (iv) in the presence of an acid catalyst or (b) by reacting a co-condensation resin of (i) and (ii) and/or (iii) with (iv) or (c) by reacting a co-condensation resin of (i) and (ii) and/or (iii) or (iv) with a styrene derivative in the presence of an acid catalyst; multivalent metal salts of the salicylic acid copolymers; color-developing agents comprising the multivalent metal salts; and color-developing sheets suited for pressure-sensitive copying paper and comprising the color-developing agents. Their production processes are also disclosed.
Abstract: The present invention relates to polypropylene resin compositions that exhibit an improved smell over prior art polypropylene resin compositions and comprises a polypropylene resin containing an inorganic filler, at least one phenolic antioxidant, at least one phosphorus antioxidant, and fine powders comprising aggregates of intimately bonded particles comprising zinc oxide, titanium dioxide and water.
Abstract: There are here provided a novel tetraphenylthiophene derivative represented by the general formula ##STR1## wherein AM is a tertiary amino group, each of l, m and n is the integer 0 or 1 and l.gtoreq.m.gtoreq.n are useful as the charge-transporting material in an electrophotographic photoreceptor having an electrically conductive base and a photosensitive layer thereon containing a charge-transporting material and a charge-generating material, which preferably is an azo compound.
Abstract: A process for producing a magnetic hub for an optical disc which is fixed to the spindle of a disc drive by means of a magnetic clamp system, which process comprises positioning and setting an annular metal plate composed of a ferromagnetic substance having burrs on one side thereof produced by punching in a mold and then injecting a resin into the mold.
Type:
Grant
Filed:
March 9, 1990
Date of Patent:
June 4, 1991
Assignee:
Mitsui Petrochemical Industries, Ltd.
Inventors:
Takeshi Minoda, Akira Todo, Toshio Kimura, Masayoshi Kurisu
Abstract: Novel tetrahydro-1,3,5-thiadiazin-4-ones of the following general formula (I) or their salts which are useful as an insecticidal and acaricidal agent. ##STR1## In the formula, each of R.sup.1 and R.sup.2 represents a halogen atom or a C.sub.1 -C.sub.4 alkyl group; R.sup.3 represents a halogen atom, a C.sub.1 -C.sub.4 alkyl group, a C.sub.3 -C.sub.6 cycloalkyl group, a C.sub.1 -C.sub.4 alkoxy group, an acetyl group, a phenoxy group, a halo-substituted phenoxy group, a benzyl group, a benzyloxy group, a phenylcarbonyl group, a C.sub.1 -C.sub.4 haloalkyloxy group, a C.sub.1 -C.sub.4 haloalkyloxymethyl group, a C.sub.2 -C.sub.4 haloalkenyloxy group, a C.sub.1 -C.sub.4 haloalkylthio group, a C.sub.1 -C.sub.4 haloalkylthiomethyl group, a C.sub.2 -C.sub.4 haloalkenylthio group, a C.sub.1 -C.sub.8 haloalkyl group, a C.sub.2 -C.sub.8 haloalkenyl group, a C.sub.1 -C.sub.
Abstract: A nonwoven sheet for agricultural use made of a hydrophobic nonwoven fabric subjected to hydrophilic treatment in which a surfactant is applied to at least part of the surface of the hydrophobic nonwoven fabric, the sheet being characterized in that the hydrophilic treatment creates channels that allow water to pass from the obverse surface of the nonwoven fabric to the underside thereof and in that the percentage of water retention is within the range of 150 to 300 wt %. The provision of the channels enable water to rapidly pass from the obverse surface of the nonwoven sheet to the underside thereof, and the weight of the nonwoven fabric is not increased by water retention because of the percentage of water retention being small.
Abstract: The present invention relates to resin useful in preparing plastic lenses having a high refractive index comprising reacting an aliphatic polyisocyanate compounds having at least one sulfur atom with one or more of active hydrogen compounds selected from the group consisting of a polyol, a polythiol having sulfur atoms only in a mercapto groups, and a polythiol having at least one sulfur atom other than in the mercapto groups; lenses containing the above-mentioned resin; and a method for the preparation thereof characterized by adding an internal release agent to the mixture of the above-mentioned raw materials in casting lenses from the resin; and lenses obtained by this method.
Abstract: An injection-molding polyethylene composition consisting essentially of ultrahigh-molecular-weight polyethylene having a molecular weight of at least about 1,650,000 and low-molecular-weight to high-molecular-weight polyethylene having a molecular weight of, for example, about 1500 to about 360,000. This composition is produced by a multistep polymerization process comprising a step of producing the ultrahigh-molecular-weight polyethylene and a step of producing the low-molecular-weight or high-molecular-weight polyethylene.
Abstract: An optical fiber of heat resistance, low-temperature resistance, flexural resistance, water absorption resistance, chemical resistance, etc., is provided by comprising a composition in which a core component comprises a polycarbonate or a silica type glass, a clad component comprises a graft-modified poly (4-methyl-1-pentene).
Abstract: Supply equipment for providing a stable supply of feed gas of an organic metal compound at a constant concentration comprises a cylindrical vessel with an organic metal compound housed, an inlet tube of carrier gas for vaporizing said organic metal compound, an outlet tube for letting out the carrier gas substantially saturated with the vaporized organic metal compound, a room provided in the lower part of the vessel which is connected to said carrier gas inlet tube, a packed bed of an organic metal compound formed above said room, and a partition with a plurarity of pores partitioning said room and said packed bed.
Abstract: This invention relates to a mounting substrate onto which components such as an IC chip are to be mounted, its production method, and a printed wiring board having a connector function suitable for a fine pitch and its connection method. Metal nodules are formed on conductors of connection portions by electrodeposition, or the like. Connection is made by fixing connection portions by an adhesive. Good conduction can be secured through the metal nodules and good insulation can be held between adjacent conductors.
Abstract: Phenol is produced in a recycle manner by (a) reacting benzene with propylene to synthesize cumene, (b) oxidizing the cumene of step (a) into cumene hydroperoxide, (c) acid cleaving cumene hydroperoxide into phenol and acetone, (d) hydrogenating the acetone of step (c) into isopropanol, (e) dehydrating the isopropanol of step (d) into propylene, and (f) recycling the propylene of step (e) to step (a). It is also possible to take propylene from step (e). The acetone by-product produced upon preparation of phenol is converted into propylene which is useful by itself for any other uses or recycled to the phenol producing process.