Patents Assigned to Mitsui
  • Patent number: 4675373
    Abstract: A substantially linear polyhydroxy polyether, which (1) is composed substantially of aromatic units and aliphatic units, the proportion of the aromatic units being 50 to 98 mole % based on the total amount of the aromatic units and the aliphatic units, (2) has an intrinsic viscosity, measured at 25.degree. C. in o-chlorophenol, of from 0.3 to 2 dl/g, and (3) has a glass transition, temperature of from 30.degree. to 120.degree. C. Two processes for preparing the polyhydroxy polyether are proposed. The polyhydroxy polyether is useful in applications which require gas-barrier property.
    Type: Grant
    Filed: April 16, 1986
    Date of Patent: June 23, 1987
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Tadao Yatsu, Etsuji Ishimaru, Kimiyoshi Miura
  • Patent number: 4675444
    Abstract: A process for producing an aminophenol, which comprises(A) a step of reacting a dihydric phenol with an aminating reagent in the liquid state under heat in the presence of water and a water-soluble catalyst,(B) a step of removing the unreacted aminating reagent from the reaction mixture, and then precipitating the crude aminophenol from the reaction mixture from which the aminating reagent has been removed, thereby to obtain a crystallization mixture containing the crude aminophenol,(C) a step of separating the crystallization mixture into crystals of the crude aminophenol and the reaction mother liquor containing the catalyst,(D) a step of circulating part or the whole of the reaction mother liquor to the aminating step, and(E) a step of washing the crude aminophenol crystals with a washing liquor to obtain the washed crude aminophenol crystals and the washing mother liquor, and thereafter separating the aminophenol from the washed crude aminophenol crystals and purifying it.
    Type: Grant
    Filed: November 25, 1985
    Date of Patent: June 23, 1987
    Assignees: Mitsui Petrochemical Ind., Ltd., Honshu Chemical Ind. Co., Ltd.
    Inventors: Fujihisa Matsunaga, Eiji Kato, Tsuyoshi Kimura, Yoichiro Isota
  • Patent number: 4675439
    Abstract: A process for preparing an N-acylphenylalanine represented by the formula (II): ##STR1## wherein R.sub.3 and R.sub.4 mean individually a hydrogen atom or an alkyl, alkoxy, phenoxy, hydroxy or methylenedioxy group, and R denotes a methyl or phenyl group, which comprises catalytically reducing an N-acyl-.beta.-phenylserine represented by the formula (I): ##STR2## wherein R.sub.1 and R.sub.2 mean individually a hydrogen atom or an alkyl, alkoxy, phenoxy, benzyloxy or methylenedioxy group, and R has the same meaning as defined in the formula (II), in the presence of a reducing catalyst or both reducing catalyst and acid, in a solvent.
    Type: Grant
    Filed: November 4, 1985
    Date of Patent: June 23, 1987
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Ryuichi Mita, Toshio Katoh, Chojiro Higuchi, Akihiro Yamaguchi
  • Patent number: 4673530
    Abstract: A process for producing a natural antioxidant from tea leaves comprising treating said tea leaves with a solvent selected from the group consisting of hot water (preferably 80.degree. C.-100.degree. C.), a 40-75% aqueous solution of methanol, a 40-75% aqueous solution of ethanol and a 30-80% aqueous solution of acetone to obtain an extract-containing solution; washing the extract-containing solution with chloroform to obtain a washed extract; combining the washed extract with an organic solvent to transfer said washed extract into said organic solvent; removing the organic solvent; and drying the resulting extract. The invention also provides the natural antioxidant produced by the aforesaid process.
    Type: Grant
    Filed: May 22, 1984
    Date of Patent: June 16, 1987
    Assignee: Mitsui Norin Co., Ltd.
    Inventor: Yukihiko Hara
  • Patent number: 4673719
    Abstract: In a process for producing olefin polymers or copolymers which comprises polymerizing olefins or copolymerizing olefins with each other or with dienes in the presence of [A] a solid titanium catalyst component containing magnesium, titanium and halogen as essential ingredients and [B] an organometallic compound of a metal selected from the group consisting of metals of Groups I to III of the periodic table; the improvement wherein said catalyst component [A] is obtained by contacting (i) a magnesium compound in the liquid state with (ii) a titanium compound in the liquid state to form a solid product or first preparing a liquid mixture of the magnesium compound (i) and the titanium compound (ii) and then forming a solid product therefrom, said reaction of forming the solid product being carried out in the presence of at least one electron donor (iii) selected from the group consisting of aliphatic carboxylic acids with 1 to 6 carbon atoms, aryloxy group-containing alcohols, alkylene glycol diethers, aluminum
    Type: Grant
    Filed: December 20, 1983
    Date of Patent: June 16, 1987
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Mamoru Kioka, Norio Kashiwa
  • Patent number: 4671890
    Abstract: A composition of aminobenzylamine is provided which is mainly composed of m-aminobenzylamine and p-aminobenzylamine in either the presence or absence of a small quantity of o-aminobenzylamine, is liquid at room temperature, and is an excellent cold-setting type curing agent useful for thermosetting resin compositions.
    Type: Grant
    Filed: June 17, 1985
    Date of Patent: June 9, 1987
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Keizaburo Yamaguchi, Kenichi Sugimoto, Yoshimitsu Tanabe, Midori Yamazaki, Akihiro Yamaguchi
  • Patent number: 4670349
    Abstract: An adhesive resin composition comprising(A) 100 parts by weight of a polymer having a crystallinity, determined by X-ray diffractometry, of not more than 40% selected from the group consisting of an ethylene/vinyl acetate copolymer and ethylene/alpha-olefin random copolymers,(B) 1 to 50 parts by weight of modified polyethylene having a melt flow rate of 0.01 to 50 g/10 minutes and containing 0.01 to 10% by weight of an unsaturated carboxylic acid or its derivative grafted thereto, and(C) 1 to 125 parts by weight of a hydrogenated aromatic petroleum resin in which at least 70% of the romatic ring is hydrogenated;provided that the total amount of the modified polyethylene (B) and the hydrogenated aromatic petroleum resin (C) is not more than 150 parts by weight.
    Type: Grant
    Filed: December 17, 1985
    Date of Patent: June 2, 1987
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Mikio Nakagawa, Koichiro Sato, Kuniaki Kanemoto, Akito Nishimura
  • Patent number: 4670508
    Abstract: A thermoplastic resin composition comprising a melt mixed product of (A) 70% to 98% by weight of at least one thermoplastic resin selected from the group consisting of polyamides, polyacetals, polyesters, and polycarbonates and (B) 30% to 2% by weight of ultra-high molecular weight polyolefin powder having an intrinsic viscosity [.eta.] of 10 dl/g or more, measured in decalin at 135.degree. C., and having an average particle size of 80 .mu.m or less and having a particle size distribution such that substantially all of the powder particles pass through a sieve having a sieve number of 100 and at least 20% by weight of the total powder particles pass through a sieve having a sieve number of 350.This thermoplastic resin composition has excellent abrasion resistance, excellent impact resistance, and a high critical PV value.
    Type: Grant
    Filed: January 2, 1985
    Date of Patent: June 2, 1987
    Assignee: Mitsui Petrochemical Industries Ltd.
    Inventors: Akio Ohdaira, Michiharu Suga, Akifumi Kato, Toshio Kobayashi, Akira Yokoyama
  • Patent number: 4670590
    Abstract: Acrylamide crystals are prepared from an aqueous solution of acrylamide by causing the aqueous solution and a coolant to flow inside each electrolytically-polished cooling tube of a double-walled or shell-and-tube heat exchanger and outside the cooling tube, respectively, instead of relying upon vacuum crystallization.
    Type: Grant
    Filed: April 11, 1986
    Date of Patent: June 2, 1987
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Yoshihiko Kambara, Shiro Asano, Wataru Isozaki, Syoji Kitado, Masao Yamaguchi
  • Patent number: 4670226
    Abstract: A reactor of the moving bed type wherein a granular material is packed and held by a louver structure and moved downward and brought into contact with a gas passing through the louver, is improved so as to avoid both accumulation of dust on the louver part at the gas inlet side and excessive rising of the pressure loss.
    Type: Grant
    Filed: April 8, 1985
    Date of Patent: June 2, 1987
    Assignees: Mitsui Mining Company, Limited, Mitsui Miike Engineering Corp.
    Inventors: Kuninori Furuyama, Yoshiro Ito
  • Patent number: 4668793
    Abstract: A process for producing 1,3-dimethyl-2-imidazolidinone with a high yield which comprises reacting N,N'-dimethylethylene diamine and/or its hydrochloride with phosgene in the presence of a substantial amount of water and a dehydrochlorinating agent. Particularly, higher yield is attained by carrying out the reaction in water medium while controlling a pH to the range of 3.0 to 10.0 by adding a dehydrochlorinating agent.
    Type: Grant
    Filed: November 1, 1985
    Date of Patent: May 26, 1987
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Teruyuki Nagata, Nobuyuki Kajimoto, Masaru Wada, Hitoshi Nakayama, Tadao Yamada
  • Patent number: 4668283
    Abstract: Magnetic powder protected from subsequent oxidation and deterioration can be obtained by effecting contact of starting magnetic powder, which is formed of an intermetallic compound containing a rare-earth metal and an iron-group metal as principal components thereof, with a phosphorus compound containing at least one active proton having a pKa of 4 or smaller and exposure of the starting magnetic powder to an oxygen-containing atmosphere in an arbitrary order or simultaneously. Production of a plastic magnet with the magnetic powder of this invention allows to avoid danger and deterioration in magnetic characteristics of the resulting product due to oxidation of the magnetic powder even if exposed to elevated temperatures during its production or use.
    Type: Grant
    Filed: June 20, 1985
    Date of Patent: May 26, 1987
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Tadatoshi Honda, Takeshi Tsuda
  • Patent number: 4668137
    Abstract: This invention is characterized by that the high-frequency motor is adapted to provide the tapered surface engagements in both engaging parts between a draw bar set in a rotary shaft of the motor and a slit hook engaged with the draw bar, and between this hook and a holder for the hook, and to reverse mutually the inclined directions of these tapered surfaces so as to obtain a large clamp force.
    Type: Grant
    Filed: November 15, 1984
    Date of Patent: May 26, 1987
    Assignee: Mitsui Seiki Kogyo Co., Ltd.
    Inventor: Koichi Iwakura
  • Patent number: 4668753
    Abstract: A film-forming propylene copolymer composed of a major amount of propylene and a minor amount of ethylene, characterized by having(A) an ethylene content (Ec) of from 0.1 mole % to 2.0 mole % based on the total amount of propylene and ethylene, and(B) an isotactic value (Iso) in the range represented by the following formula (1) or (2),(i) when 0.1.ltoreq.Ec.ltoreq.0.3,Iso.gtoreq.-5Ec30 96.3 (%) (1),and(ii) when 0.3<Ec.ltoreq.2.0,Iso.gtoreq.-0.67Ec30 95.0 (%) (2)wherein Ec0 represents the numerical value of Ec (mole %);a film of the copolymer; and a process for producing the film.
    Type: Grant
    Filed: August 25, 1986
    Date of Patent: May 26, 1987
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Norio Kashiwa, Mamoru Kioka, Masaki Kohyama, Masanobu Ishiyama
  • Patent number: 4668752
    Abstract: Ethylene/C.sub.4 -C.sub.20 alpha-olefin copolymers are disclosed which have new characteristics in regard to composition distribution, degree of branching, randomness and crystallinity by DSC melting points. These copolymers have excellent transparency, impact strength, tear strength, blocking resistance, environmental stress cracking resistance, heat resistance and low-temperature heat sealability in a well-balanced combination when they have a density of at least 0.90. When their density is less than 0.90, these copolymers have particularly excellent transparency, impact strength and low-temperature heat sealability, and by incorporating them in various thermoplastic resins, they serve as an excellent modifier for improved impact strength and low-temperature heat sealability.
    Type: Grant
    Filed: October 22, 1984
    Date of Patent: May 26, 1987
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Kenichi Tominari, Hiroshi Inoue, Masayuki Sakai
  • Patent number: 4667048
    Abstract: A process for disproportionating silanes, which comprises contacting a silane having at least one Si--H bond represented by the general formulaR.sub.l H.sub.m SiX.sub.4-(l+m)wherein R represents an alkyl or aryl group, X represents a halogen atom or an alkoxy group, l is 0, 1 or 2, and m is 1, 2 or 3 and l+m is 1, 2 or 3, and when l is 2, R's may be identical or different, and when l+m is 1 or 2, X's may be identical or different, with a reaction product of a strong acid-type cation exchange resin with an amine and disproportionating the silane.
    Type: Grant
    Filed: June 9, 1986
    Date of Patent: May 19, 1987
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Kaoru Inoue, Hiroharu Miyagawa, Masayoshi Itoh, Tomohiro Abe, Kyogo Koizumi, Noriyuki Yanagawa
  • Patent number: 4665176
    Abstract: A process for the preparation of 5,6,7,8-tetrahydrofolic acid which comprises dissolving and/or suspending folic acid or dihydrofolic acid in an aqueous solution containing an inorganic base, and bringing the resulting solution or suspension into contact with hydrogen in the presence of a noble metal catalyst while maintaining its pH at 5-9, thereby catalytically hydrogenating the folic acid of dihydrofolic acid into 4,5,6,7-tetrahydrofolic acid.
    Type: Grant
    Filed: October 10, 1985
    Date of Patent: May 12, 1987
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Yutaka Hirai, Masaaki Torisu, Eri Nagayoshi
  • Patent number: 4663294
    Abstract: This invention relates to DNA consisting of a DNA base sequence coding for the signal amino acid sequence:______________________________________ Met Phe Ala Lys Arg Phe Lys Thr Ser Leu Leu Pro Leu Phe Ala Gly Phe Leu Leu Leu Phe Tyr Leu Val Leu Ala Gly Pro Ala Ala Ala Ser Ala Glu Thr Ala Asn Lys Ser Asn Glu, ______________________________________and to DNA containing such a DNA base sequence. The DNA base sequence coding for said amino acid sequence includes, for example, ______________________________________ ATG TTT GCA AAA CGA TTC AAA ACC TCT TTA CTG CCG TTA TTC GCT GGA TTT TTA TTG CTG TTT TAT TTG GTT CTG GCA GGA CCG GCG GCT GCG AGT GCT GAA ACG GCG AAC AAA TCG AAT GAG. ______________________________________The desired products in cells can be secreted out of cells by the use of a vector containing DNA consisting of the DNA base sequence coding for said signal amino acid sequence.
    Type: Grant
    Filed: January 6, 1984
    Date of Patent: May 5, 1987
    Assignees: Kunio Yamane, The Calpis Food Industry Co., Ltd., Mitsui Toatsu Chemicals, Inc.
    Inventors: Kunio Yamane, Kazutaka Ohmura, Akira Nakayama, Yasutoshi Takeichi
  • Patent number: 4663369
    Abstract: A glass-fiber reinforced polypropylene composition having superior adhesion of glass fibers therein, stiffness, high-impact properties and molding properties is provided, which composition comprises a graft polypropylene resin obtained by graft-polymerizing a radically polymerizable unsaturated compound onto a crystalline polypropylene resin with an organic peroxide catalyst in a hydrocarbon solvent or a blend of the graft polypropylene with a crystalline polypropylene resin, glass fibers treated with an organic silane or titanium compound, Ca stearate and an alkaline earth metal compound, the respective quantities of the above components being specified.
    Type: Grant
    Filed: June 3, 1986
    Date of Patent: May 5, 1987
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yoichi Kawai, Masaru Abe, Masami Maki, Koutarou Suzuki, Minoru Hoshino
  • Patent number: 4662787
    Abstract: A device for locking the vertical position of a leg relative to an off-shore work platform having a vertical rack with angular teeth and a lock body with mating angular teeth. The lock body is positioned between a pair of upper and lower wedge members adapted to slidably engage a horizontal face on one side and an inclined face on the other side. The inclined faces of the upper and lower blocks are in opposed directions parallel to the pressure faces of the teeth of the rack and block body. The wedge blocks are adapted to be displaced horizontally in coordination so that when moved simultaneously, a horizontal displacement of the lock body occurs, and when one is moved without the other, an angular displacement of the lock body parallel to the pressure surface of the meshing teeth of the rack is obtained.
    Type: Grant
    Filed: May 6, 1985
    Date of Patent: May 5, 1987
    Assignee: Mitsui Ocean Development & Engineering Co., Ltd.
    Inventor: Masamitsu Tatsuguchi