Patents Assigned to Mitsui
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Patent number: 4622268Abstract: A five-component copolyester not described in the prior art literature which comprises at least five components, i.e. (a) two aromatic dicarboxylic acid components composed of a major amount of an isophthalic acid component and a minor amount of another dicarboxylic acid component, (b) a diol component composed of an ethylene glycol component and optionally another diol component, (c) an aromatic monohydroxy-monocarboxylic acid component and (d) a polyfunctional compound component having at least three functional groups. The copolyester has excellent melt moldability, mechanical strength, transparency and gas-barrier property in a well balanced combination, and shows improved properties over conventional copolyesters containing a major amount of isophthalic acid as a dicarboxylic acid component.Type: GrantFiled: November 27, 1984Date of Patent: November 11, 1986Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Tadao Yatsu, Takayuki Nakano, Nobuya Hinooka, Tatsuo Kato
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Patent number: 4622360Abstract: Removable water-borne urethane resin coating composition comprising polyurethane resin containing carboxyl groups and/or carboxylate groups and polyvalent metal complex as a cross-linking agent and method for removing the coating formed by using the removable water-borne urethane resin coating composition which comprises treating said coating with a ligand containing alkaline solution and removing the coating.The coating formed by using the composition is superior in water resistance, recoatability, detergent resistance, black heel mark resistance, abrasion resistance and service life.Type: GrantFiled: November 6, 1985Date of Patent: November 11, 1986Assignees: Yuho Chemicals Inc., Mitsui Toatsu Chemical Inc.Inventors: Tadashi Gomi, Kenji Sakata, Ichiro Aoyama, Nobuo Sono
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Patent number: 4622176Abstract: A method of processing radioactive liquid wastes containing radioactive ruthenium by passing said wastes through a column packed with an adsorbent comprising a mixture of activated carbon with zinc and palladium powders is herein disclosed.Type: GrantFiled: December 10, 1984Date of Patent: November 11, 1986Assignees: Japan Atomic Energy Research Institute, Mitsui Mining & Smelting Co.Inventors: Ryozo Motoki, Shoji Motoishi, Mishiroku Izumo, Katsuyuki Onoma, Toshikazu Sato
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Patent number: 4621114Abstract: A propylene resin composition composed of(A) 50 to 70% by weight, based on the total weight of (A), (B) and (C), of a propylene-ethylene block copolymer which has an ethylene content of 15 to 35 mole % and a melt flow rate (MFR) of 10 to 60 g/10 min. and in which the propylene component has an isotacticity index of at least 95%,(B) 25 to 40% by weight, based on the total weight of (A), (B) and (C), of a random copolymer of ethylene with an alpha-olefin having at least 3 carbon atoms which has an ethylene content of 60 to 85 mole %, a melt flow rate of 0.1 to 2 g/10 min. and a crystallinity, determined by the X-ray method, of not more than 10, and(C) 3 to 20% by weight, based on the total weight of (A), (B) and (C), of talc powder having an average particle size of 0.1 to 5 microns.Type: GrantFiled: July 2, 1984Date of Patent: November 4, 1986Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Junichi Watanabe
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Patent number: 4619689Abstract: Novel diphenyl ether hydrazine derivatives, particularly 2-nitro-5 (nucleus-substituted phenoxy) phenylhydrazine derivatives are provided. They are useful as a selective herbicide having a high herbicidal activity and residual efficacy.Type: GrantFiled: October 12, 1984Date of Patent: October 28, 1986Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Takeo Yoshimoto, Akira Hosono, Joh Miki, Yasunobu Funakoshi, Takashi Fujita, Yoshikata Hojo
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Patent number: 4619959Abstract: A process for producing a styrene-base resin having improved moldability and a good hue by continuously adding a specific higher fatty acid amide in a dissolved or molten state, and/or a mixture of a specific higher fatty acid amide and a specific metallic soap in a molten state, to a styrene-base resin in the course of its production by continuous bulk or solution polymerization. The above process is particularly effective for rubber-modified styrene-acrylonitrile resins.Type: GrantFiled: May 24, 1985Date of Patent: October 28, 1986Assignees: Mitsui Toatsu Chemicals, Incorporated, Toyo Engineering CorporationInventors: Tetsuyuki Matsubara, Norifumi Ito, Kazuo Sugazaki, Kouzo Ichikawa, Mune Iwamoto, Toshihiko Ando
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Patent number: 4618386Abstract: Anti-gas permeation property and impact strength of a container such as a bottle which is made of polyethylene terephthalate resin by biaxially orienting blow molding are improved by using a multilayered structure of the polyethylene terephthalate and the other polyester of a dicarboxylic acid component containing a specific amount of isophthalic acid and a glycol component. The container is made preferably by preparing a preform which is a laminate of the polyethylene terephthalate and the other polyester in the molten state under pressure, and by biaxially orienting blow molding the preform.Type: GrantFiled: July 8, 1985Date of Patent: October 21, 1986Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Tadao Yatsu, Nobuya Hinooka
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Patent number: 4618714Abstract: Preparation of 3,3'- or 3,4'-diaminobenzophenone by nitrating a chloronitrobenzophenone mixture obtained by the Friedel-Crafts reaction between 3- or 4-nitrobenzoyl chloride and chlorobenzene, and catalytically reducing and dechlorinating the resulting chlorodinitrobenzophenone mixture in the presence of a reduction catalyst and a dehydrochlorinating agent.Type: GrantFiled: May 2, 1983Date of Patent: October 21, 1986Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Keizaburo Yamaguchi, Kenichi Sugimoto, Yoshimitsu Tanabe, Saburo Kawashima, Akihiro Yamaguchi
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Patent number: 4618298Abstract: A method and apparatus for constructing an enlarged tunnel in a portion of a predetermined region of an existing tunnel. A circumferentially enlarged portion is excavated to define a starting base for a shield machine. The shield machine is positioned in the circumferentially enlarged portion and advanced forward along the existing tunnel in order to enlarge the circumference in the predetermined region of the existing tunnel. A section of a tubular liner lining the existing tunnel is broken and removed therefrom. Thereafter, the resultant enlarged tunnel portion is lined with segments.Type: GrantFiled: March 30, 1984Date of Patent: October 21, 1986Assignee: Mitsui Kensetsu Kabushiki KaishaInventors: Shigeo Takamiya, Kazutoshi Inoue, Kenzo Tsutaya
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Patent number: 4617367Abstract: A methyl methacrylate syrup composition comprises an intimate mixture of 1-99 parts by weight of a first polymer-in-monomer syrup (A) and 99-1 parts by weight of a second polymer-in-monomer syrup which can be either (B.sub.1) or (B.sub.2), wherein the syrups (A), (B.sub.1) and (B.sub.2) are as follows:(A) a polymer-in-monomer syrup obtained by copolymerizing a mixture of methyl methacrylate monomer, one or more monomers having reactivity with glycidyl groups and containing at least one ethylenically-unsaturated bond, and one or more of (meth)acrylates, styrene and styrene derivatives;(B.sub.1) a polymer-in-monomer syrup obtained by copolymerizing a mixture of one or more monomers containing at least one glycidyl group and at least one ethylenically-unsaturated bond, and one or more monomers selected from the group consisting of methyl methacrylate, (meth)acrylates, styrene and styrene derivatives;(B.sub.Type: GrantFiled: November 28, 1984Date of Patent: October 14, 1986Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Katsushi Watanabe, Takafumi Kageyama, Taisaku Kano, Koichi Hirai, Yoshinobu Ichihara
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Patent number: 4617207Abstract: Disclosed herein are thermoplastic resin sheets having a thermal shrinkage within .+-.0.3%, and a process for producing thermoplastic resin sheets by co-extruding a first thermoplastic resin and a second thermoplastic resin which is nonadhesive to the first thermoplastic resin, into a sheet-like structure so that the first thermoplastic resin is covered on both surfaces thereof with the second thermoplastic resin and then peeling off the resulting outer layers of the second thermoplastic resin B to obtain a sheet of the first thermoplastic resin. The thermoplastic resin sheets obtained in accordance with the above production process have an extremely small thermal shrinkage, undergo an extremely low degree of mechanical strain, and exhibits a little optical anisotropy. Because of the small thermal shrinkage, they may be used in liquid crystal displays (LCDs), poultice or sticker.Type: GrantFiled: August 9, 1984Date of Patent: October 14, 1986Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Toru Ueki, Yoshiaki Fukuda, Katsuyuki Usami, Kazuharu Kanasaki
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Patent number: 4615207Abstract: In a metallic mold apparatus, a rotational power for a skewing operation and a rotational power for an indexing operation are applied through a differential gear device to a rotatably supported die. More specifically, the skew power from such an electric motor as a servomotor operative in synchronism with a press operation and the indexing power from an index means operatively coupled to a press are applied to the differential gear device.Type: GrantFiled: September 28, 1984Date of Patent: October 7, 1986Assignee: Mitsui High-Tec, Inc.Inventors: Takamitsu Oboshi, Tomoaki Koga, Eiji Imoto
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Patent number: 4616059Abstract: A graft-modified ultrahigh-molecular-weight polyethylene obtained by grafting (A) an ultrahigh-molecular-weight polyethylene having an inherent viscosity [.eta.], determined at 135.degree. C. in decalin, of at least 5 dl/g with (C) an unsaturated carboxylic acid graft-copolymerizable therewith or its graft-copolymerizable derivative, under melt-kneading condition in the presence of (B) an aliphatic compound having a melting point, determined by the DSC method, of at least 10.degree. C. and a boiling point of at least 130.degree. C., an amount of the component (C) grafted in said graft-modified ultrahigh-molecular-weight polyethylene being 0.01 to 10% by weight, and said graft-modified ultrahigh-molecular-weight polyethylene being substantially free of an insoluble gel product and having a tensile strength of at least 1.0 GPa; and a process for producing the same.Type: GrantFiled: August 28, 1985Date of Patent: October 7, 1986Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Masanori Motooka, Hitoshi Mantoku
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Patent number: 4614826Abstract: Disclosed are a polynuclear polyhydric phenol represented by the following general formula [I]: ##STR1## wherein R.sup.1 and R.sup.2 stand for a hydrogen atom or a lower alkyl group, R.sup.3 stands for a hydrogen atom, an alkyl group, an aryl group or a halogen atom, and n is an integer of from 0 to 10,and a polyepoxy compound consisting of a polyglycidyl ether of this polynuclear polyhydric ether. When this polyepoxy compound is combined with a curing agent, a curable epoxy resin composition excellent in the heat resistance characteristics is provided.Type: GrantFiled: February 27, 1984Date of Patent: September 30, 1986Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Shigeru Katayama, Takayuki Nakano, Nobuyuki Takeda
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Patent number: 4613373Abstract: New tetraarylboron-ammonium complexes having the general formula: ##STR1## wherein R.sub.1 represents a hydrogen or a halogen atom or a lower alkyl group; R.sub.2 represents a halogen atom or a lower alkyl or a lower alkenyl group; and R.sub.3 represents a heterocyclic amine are provided as active ingredient of anti-fouling paint and also of antiseptic, antifungal agent. These compounds exhibit remarkably long-lasting anti-fouling activities against substantially all kinds of aquatic organisms including slimes with acceptably low toxicity against human beings and also exhibit high antimicrobial activities against various fungi, bacteria and yeasts.Type: GrantFiled: January 23, 1985Date of Patent: September 23, 1986Assignees: Hokko Chemical Industry Co., Ltd., Mitsui Engineering & Shipbuilding Co., Ltd., Nippon Paint Co., Ltd.Inventors: Masayuki Umeno, Akitomo Wakabayashi, Kazuo Tomozane, Sumio Wakabayashi, Hitoshi Okamoto, Junji Yokoi
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Patent number: 4612148Abstract: Stretched articles of ultrahigh-molecular-weight polyethylene are prepared by melt-kneading a mixture of ultrahigh-molecular-weight polyethylene with a paraffinic wax having a melting point of 40.degree. to 120.degree. C. and a weight average molecular weight of at least 230 but less than 2000 in a screw extruder while maintaining the temperature of the mixture at 180.degree. to 280.degree. C. The molten mixture is melt-extruded through a die at a temperature of 180.degree. to 300.degree. C. under a draft condition of a draft ratio of less than 2 or in the absence of a draft and the resulting unstretched extrudate is cooled to solidify it. The unstretched solidified extrudate is than subjected to a stretching treatment in a heated liquid medium which is a solvent for the paraffinic wax at a temperature of 60.degree. to 140.degree. C. at a particular stretch ratio.Type: GrantFiled: July 16, 1985Date of Patent: September 16, 1986Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Masanori Motooka, Hitoshi Mantoku, Takao Ohno
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Patent number: 4612252Abstract: An improved laminated structure comprised of two adjoining layers of synthetic resin laminated through a layer of a post-halogenated adhesive olefin resin of an alpha-olefin having 2 to 8 carbon atoms. The post-halogenated adhesive olefin resin has a halogen content of 0.1 to less than 10% by weight based on its own weight and a crystallinity, determined by the X-ray diffraction method, of 5 to 30%, and is obtained by the post-halogenation of an unhalogenated olefin resin having a crystallinity, determined by the X-ray diffraction method, of 10 to 45%.Type: GrantFiled: December 18, 1984Date of Patent: September 16, 1986Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Toshihiro Sagane, Riichiro Nagano
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Patent number: 4612388Abstract: Disclosed herein is a process for producing an N-acyl-substituted or unsubstituted phenylalanine comprising hydrolyzing a 2-substituted-4-substituted or unsubstituted benzylidene-5-oxazolone with alkali, adjusting pH of the reaction solution containing its hydrolysis product with acid at 5-9 and reducing the resultant reaction solution catalytically in the presence of a palladium or platinum reducing catalyst.In accordance with the process of the present invention, time duration required for effecting the reduction can be shortened markedly in comparison with the reduction in an aqueous strong alkaline solution. Moreover, the catalyst recovered after completion of the reduction can be used repeatedly without any additional treatment and without any observed lowering in its activity. Accordingly, the reduction using the recovered catalyst may proceed in practically the same time as in the case of using a fresh catalyst.Type: GrantFiled: April 3, 1985Date of Patent: September 16, 1986Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Ryuichi Mita, Toshio Katoh, Chojiro Higuchi, Akihiro Yamaguchi
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Patent number: 4610859Abstract: A process for producing silicon hydrides represented by the general formula Si.sub.n H.sub.2n+2 wherein n is a positive integer of 1 to 6, which comprises reacting a silicon-containing alloy with an aqueous solution of an acid in the presence of at least one inert organic solvent having a boiling range of from -60.degree. C. to 250.degree. C.Type: GrantFiled: December 27, 1984Date of Patent: September 9, 1986Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Hiroharu Miyagawa, Masayoshi Itoh, Tomohiro Abe, Kenji Iwata, Kyogo Koizumi
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Patent number: RE32261Abstract: Solid copolymers are produced by copolymerizing a mixture of: (A) at least 30% by weight of a monomer having the formula: ##STR1## wherein R.sub.1 is H or CH.sub.3 and R.sub.2 is an alkyl radical containing from 1 to 14 carbon atoms; (B) from 3 to 20% by weight of an ethylenic .alpha.,.beta. unsaturated carboxylic acid or anhydride thereof, or from 3 to 40% by weight of glycidyl acrylate or glycidyl methacrylate; and (C) from 0 to 67% by weight of a monomer copolymerizable with said monomers (A) and (B). Preferably, the mixture is first bulk-polymerized until conversion to the copolymer is from 10 to 80% by weight and the polymerization is completed by suspension-polymerization. Thermosetting solid coating compositions are produced by mixing a major proportion of a solid copolymer so produced with a minor proportion of a cross-linking compound or with an epoxy resin containing at least 2 epoxy radicals in the molecule in presence of a tertiary amine curing accelerator.Type: GrantFiled: March 19, 1979Date of Patent: October 7, 1986Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Kuniomi Hirota, Akio Masumoto, Hiroshi Ozawa, Nobuki Kobayashi, Teruo Honda