Patents Assigned to Mitsui
  • Patent number: 4649219
    Abstract: Disclosed herein are novel unsaturated cyclic amide-substituted ether compounds having a wide range of utility in crosslinking agents, adhesives, paints, raw materials for hygroscopic resins, etc. These compounds are prepared by reacting cyclic halogen-substituted ether compounds with unsaturated amide compounds in the presence of a strong basic substance in an aprotic polar solvent.
    Type: Grant
    Filed: March 6, 1985
    Date of Patent: March 10, 1987
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Hiroshi Itoh, Atsuhiko Nitta, Tomio Tanaka, Hideo Kamio
  • Patent number: 4643529
    Abstract: Disclosed is a polarizing film containing a base resin and a photodichroic material which is characterized in that (1) the uniaxial orientation coefficient (f) of the principal crystal axis which is a crystal axis parallel to the molecular chain of the base resin, with respect to the reference axis is not less than 0.7 and (2) when a specimen of the polarizing film is cut out so as to have a surface perpendicular to the reference axis and X-rays impinging on the specimen parallel to the reference axis, the product (f.times.R) of the aforesaid uniaxial orientation coefficient (f) and the proportion (R=(I.sub.min /I.sub.max).times.100) of the minimum value (I.sub.min) to the maximum value (I.sub.max) of diffracted X-ray intensity on the resulting Debye-Scherrer ring is not less than 10. This polarizing film has excellent thermal resistance and moisture resistance and gives a high degree of polarization.
    Type: Grant
    Filed: December 20, 1984
    Date of Patent: February 17, 1987
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Sin Hosonuma, Junichi Fujio, Kozo Tanaka, Harue Suzuki, Kenichi Baba
  • Patent number: 4643889
    Abstract: A process for generating an excited molecular oxygen by a procedure which comprises causing a mixture of an alkaline aqueous solution with hydrogen peroxide to wet the surface portion of a layer of a hydrophilic and gas-pervious material, causing a molecular chlorine-containing gas to penetrate said layer from the side opposite said surface thereof, enabling said gas during the penetration thereof through said material to react with said mixed aqueous solution which has wetted said surface portion of said material, and thereby inducing generation of said excited molecular oxygen, O.sub.2 (.sup.1 .DELTA.), through said surface portion of said layer wetted by said mixed aqueous solution.
    Type: Grant
    Filed: March 31, 1986
    Date of Patent: February 17, 1987
    Assignees: Mitsui Grinding Wheel Co., Ltd., Taro Uchiyama
    Inventors: Taro Uchiyama, Kiwamu Takehisa, Isao Ishizaki
  • Patent number: 4642269
    Abstract: A crystalline random propylene copolymer composition comprising (i) a crystalline random propylene copolymer comprising 99 to 85 mole % of propylene and 1 to 15 mole % of an alpha-olefin other than propylene and (ii) a random 1-butene copolymer comprising 1-butene and an alpha-olefin having at least 5 carbon atoms, the weight ratio of the copolymer (i) to the copolymer (ii) being in the range of from 5:95 to 90:10, said random 1-butene copolymer (ii) satisfying the following conditions:(A) it comprises 50 to 99 mole % of the 1-butene component and 1 to 50 mole % of the alpha-olefin,(B) it has an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.5 to 6 dl/g,(C) it has a melting point [Tm], measured by a differential scanning calorimeter, of from 30.degree. to 120.degree. C.,(D) it has a crystallinity, measured by X-ray diffractometry, of from 5 to 60%,(E) the amount [W.sub.
    Type: Grant
    Filed: October 29, 1985
    Date of Patent: February 10, 1987
    Assignee: Mitsui Petrochemical Industries, Ltd
    Inventors: Masaki Kohyama, Takeshi Muranaka, Kunisuke Fukui, Norio Kashiwa
  • Patent number: 4640747
    Abstract: A process for surface-treating copper products, for example, a copper foil to be used for a copper-clad laminate, the resulting surface-treated copper product having a superior bond strength to a base material, resistant to etching solution, acids, etc., is provided, which process comprises electrically depositing a binary alloy consisting of 95 to 20% by weight of zinc and 5 to 80% by weight of nickel, on the surface of a copper product to form a coating layer, followed by laminating the resulting copper product onto a base material under heating and pressure, said binary alloy being converted during the lamination into a ternary alloy of zinc, nickel and copper constituting a boundary layer having a superior bond strength between the copper product and the base material.
    Type: Grant
    Filed: October 23, 1985
    Date of Patent: February 3, 1987
    Assignee: Mitsui Mining and Smelting Co., Ltd.
    Inventors: Kuniki Ueno, Naotomi Takahashi
  • Patent number: 4639355
    Abstract: The present invention provides for the recovery of gallium from aluminum smelting dust. Aluminum smelting dust is leached with mineral acid, such as sulfuric acid, hydrochloric acid, or nitric acid. Gallium is extracted from the obtained leach liquor with an organic solution containing a liquid cation exchange agent. The resulting loaded organic solution is treated with mineral acid in aqueous solution, either after or before scrubbing with a higher concentration of acid in aqueous solution, to strip gallium. Gallium is extracted from this solution with another organic solution containing an ion-pair extracting type extracting agent. Finally, purified gallium is recovered by stripping the latter loaded organic solution with water or dilute acid in aqueous solution.
    Type: Grant
    Filed: July 22, 1985
    Date of Patent: January 27, 1987
    Assignee: Mitsui Aluminium Co., Ltd.
    Inventors: Shingo Matsui, Hidetsugu Ikeda, Akio Era, Sanji Nishimura
  • Patent number: 4639451
    Abstract: This invention relates to pyridazinone derivatives of the general formula: ##STR1## [wherein R.sup.1 stands for a hydrogen atom or a lower alkyl group; R.sup.2 for a hydrogen atom or a lower alkyl group; and A for (i) a ring selected from a benzene ring, a furan ring, a thiophene ring and a pyridine ring (on which ring 1-3 substituents or atoms selected from amino groups, nitro groups, lower alkanoylamino groups, hydroxyl groups, lower alkanoyloxy groups, sulfamoyl groups and halogen atoms may be present), or (ii) a grouping of the formula: ##STR2## (wherein R.sup.3 stands for a hydrogen atom, a lower alkyl group, a phenyl(lower)alkyl, a hydroxyphenyl(lower)alkyl group, a lower alkylmercapto(lower)alkyl group, a benzylmercapto(lower)alkyl group, a guanidino(lower)alkyl group, a nitroguanidino(lower)alkyl group, an indolyl(lower)alkyl group, a carbamoyl(lower)alkyl group or a carboxy(lower)alkyl group, R.sup.4 for a hydrogen atom or a lower alkyl group, R.sup.
    Type: Grant
    Filed: June 3, 1983
    Date of Patent: January 27, 1987
    Assignee: Mitsui Toatsu Kagaku-Kabushiki Kaisha
    Inventors: Tsutomu Katakami, Nobuyuki Fukazawa, Hajime Iizuka, Takashi Nishina, Joji Kamiya, Yasuhito Tanaka, Takuo Nakano
  • Patent number: 4639521
    Abstract: Isoquinoline derivatives represented by the general formula (I): ##STR1## wherein R.sub.1 denotes a hydrogen or halogen atom, or a nitro or acetyl group, and R.sub.2 denotes a hydrogen atom, or a methyl, methoxy, phenyl, 4-pyridyl or 2-pyridyl group, and therapeutically acceptable salts thereof have high cardiotonic activity and low toxicity.
    Type: Grant
    Filed: June 20, 1986
    Date of Patent: January 27, 1987
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Kunio Sannohe, Kengo Otsuka, Toshohiko Ito, Masahiko Maruyama, Takafumi Kitano, Makoto Hirayama
  • Patent number: 4637964
    Abstract: Disclosed herein is a magnetic recording medium, (1) in which a magnetic layer is formed by coating a magnetic paint containing a magnetic powder and a binder as its main components on a non-magnetic base material; (2) which is featured by containing as said binder a polymer having an alkenyl phenol as one of the components of the polymer; and (3) which has markedly improved effects in the dispersibility of the magnetic powder in said medium and in the abrasion resistance and flexibility of the magnetic layer.
    Type: Grant
    Filed: July 12, 1985
    Date of Patent: January 20, 1987
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yoshiro Shimuzu, Yoshio Tada
  • Patent number: 4632969
    Abstract: Disclosed herein are a resin for high-refractivity lenses, formed by copolymerizing at least one unifunctional monomer selected from the group of compounds represented by the following general formula (I); ##STR1## wherein X means a oxygen or sulfur atom, Y denotes a chlorine or bromine atom, R is a hydrogen atom or a methyl group, m is 0 or 1 and n stands for an integer of 1-5 with at least one bifunctional monomer selected from the group of compounds represented by the following general formula (II); ##STR2## wherein Z is a hydrogen, chlorine or bromine atom, R means a hydrogen atom or a methyl group and p stands for an integer 1-4 as well as high-refractivity lenses made of such a resin.
    Type: Grant
    Filed: March 2, 1984
    Date of Patent: December 30, 1986
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Katsuyoshi Sasagawa, Masao Imai, Kimio Kanno
  • Patent number: 4632976
    Abstract: A process is provided herein wherein a solid polymer slurry diluted with a specific diluent is continuously discharged under controlled conditions from a high pressure zone to a low pressure zone substantially maintained at atmospheric pressure and the slurry is then separated into said diluent and dried polymer, the improvement wherein the discharged amount of the solid polymer slurry is strictly controlled by varying the heat in the second zone and simultaneously adding a diluent which is gaseous under normal temperature and pressure so that by the control of these two perimeters a continuous slurry discharge can be maintained at predetermined levels.
    Type: Grant
    Filed: April 16, 1985
    Date of Patent: December 30, 1986
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Tadashi Asanuma, Tatuo Ohoka, Nobutaka Uchikawa
  • Patent number: 4632987
    Abstract: A process for the preparation of triarylmethane compounds which comprises reacting a benzene or naphthalene compound with a formylating agent for such compounds in the presence of an acid catalyst to form an aromatic aldehyde compound; adding water to the reaction mixture and thereby hydrolyzing the acid catalyst without isolating the aromatic aldehyde compound from the reaction mixture; and uninterruptedly condensing the aromatic aldehyde compound with an aromatic compound in the resulting mixture.
    Type: Grant
    Filed: December 2, 1983
    Date of Patent: December 30, 1986
    Assignee: Mitsui Toatsu Chemicals Incorporated
    Inventors: Michihiro Tsujimoto, Hiroyuki Akahori, Kiyoharu Hasegawa, Makoto Asano
  • Patent number: 4632959
    Abstract: A modified polyolefin composition comprising(A) 50 to 99 parts by weight of a modified polyolefin having an intrinsic viscosity [.eta.] of 0.5 to 10 dl/g and a degree of crystallization of at least 20% selected from the group consisting of polyolefins modified with styrene-type hydrocarbons, polyolefins modified with unsaturated epoxy compounds, polyolefins modified with unsaturated silane compounds, halogenated polyolefins and hydroxyl group-containing polyolefins, and(B) 1 to 50 parts by weight of a thermoplastic polymer selected from the group consisting of(B-1) thermoplastic polymers having a flexural modulus of less than 1000 kg/cm.sup.2, a glass transition temperature (Tg) of not higher than 0.degree. C. and a weight average molecular weight (Mw) of at least 400,000, and(B-2) polar non-olefinic thermoplastic polymers or ethylenic polymers having a flexural modulus of at least 1000 kg/cm.sup.2 and an adhesion strength, with respect to the modified polyolefin (A), of not more than 200 g/cm.
    Type: Grant
    Filed: September 19, 1984
    Date of Patent: December 30, 1986
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventor: Riichiro Nagano
  • Patent number: 4631172
    Abstract: Alloys for galvanic anode of this invention include those which contain zinc of 1.0 to 10%, magnesium of 0.1 to 6%, indium of 0.01 to 0.04%, tin of 0.005 to 0.15%, silicon of 0.09 to 1.0%, and calcium or barium or both of 0.005 to 0.45%, the balance being aluminum, and those which contain zinc of 1.0 to 10%, indium of 0.01 to 0.05%, magnesium of 0.05 to 6%, silicon of 0.07 to 1.0%, and calcium or barium or both of 0.01 to 0.5%, the balance being aluminum. The above mentioned alloys of this invention exhibit an exceedingly large output of electric current as compared with conventional alloys, hold the dissolving surfaces uniformly and are exceedingly useful for anticorrosion of large-sized steel structures.
    Type: Grant
    Filed: May 1, 1985
    Date of Patent: December 23, 1986
    Assignees: Nadagawa Corrosion Protecting Co., Ltd., Mitsui Mining & Smelting Co.
    Inventors: Ikuo Yamamoto, Takehito Umino, Yoshio Shinoda, Hisao Yoshino
  • Patent number: 4630969
    Abstract: Inclined plane protection boards are provided in a manner to cover an inclined plane of an artificial island whereby the inclined plane may be protected from ice force of growing or drifting ice bodies or wind and wave force.
    Type: Grant
    Filed: March 23, 1984
    Date of Patent: December 23, 1986
    Assignee: Mitsui Engineering & Shipbuilding Co., Ltd.
    Inventors: Masanao Oshima, Nobuyoshi Yashima
  • Patent number: 4628091
    Abstract: A process for producing dianthraquinone-N,N'-dihydrazine or its chlorination product, which comprises condensing 1-aminoanthraquinone at an elevated temperature in the presence of 1,3-dimethyl-2-imidazolidinone using an oxidizing agent and an alkaline condensing agent, and subjecting the resulting condensation product to a treatment known per se.
    Type: Grant
    Filed: June 13, 1984
    Date of Patent: December 9, 1986
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Kimitoshi Kato, Hiroshi Aiga, Tamio Mikoda, Tunehiro Sakai
  • Patent number: 4626263
    Abstract: Disclosed is a high-performance electret comprising 60 to 99% by weight of a non-polar polymer, 0.5 to 39.5% by weight of a polar polymer and 0.5 to 20% by weight of at least one component selected from the group consisting of (A) a non-polar polymer modified with an unsaturated carboxylic acid or a derivative thereof, (B) a non-polar polymer modified with an unsaturated epoxy monomer and (C) a non-polar polymer modified with a silane monomer having an olefinically unsaturated bond.In this electret, a high charge density can be maintained stably over a long period, and this electret can be easily formed into a film. An air filter prepared from this electret is very excellent in the dust collecting efficiency.
    Type: Grant
    Filed: April 23, 1985
    Date of Patent: December 2, 1986
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Naofumi Inoue, Satoshi Matsuura
  • Patent number: 4626565
    Abstract: Disclosed herein is a preparation process for polypropylene-base resin compositions, which process comprises heating at a temperature of 170.degree.-280.degree. C. a mixture containing a crystalline ethylenepropylene block copolymer having a specific composition, an ethylene-propylene copolymer rubber having a specific composition and viscosity, an inorganic filler having a specific particle size, and an organic peroxide, all in specified amounts. The thus-obtained polypropylene-base resin compositions are suitable for use in the production of large moldings such as automobile bumpers, fenders and body sidemembers because of their excellent low-temperature impact resistance, high molding fluidity, good paintability and high stiffness as well as their low preparation cost.
    Type: Grant
    Filed: March 29, 1985
    Date of Patent: December 2, 1986
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Yoichi Kawai, Masaru Abe, Katsumi Sekiguchi, Akio Yoshihara, Shigeru Hayashi
  • Patent number: 4625062
    Abstract: 4-Alkoxyanilines are obtained industrially advantageously by catalytically hydrogenating a nitrobenzene in the presence of a noble metal catalyst in a mixed solvent containing a lower aliphatic alcohol, sulfuric acid, and water or a lower aliphatic carboxylic acid or both to induce hydrogenation and a Bamberger-type rearrangement reaction. The mixed solvent contains at least 10 moles, preferably 30 to 60 moles, of the lower aliphatic alcohol per mole of the nitrobenzene, 1 to 10 moles, preferably 2 to 7 moles, of sulfuric acid per mole of the nitrobenzene, and 2 to 30% by weight, preferably 3 to 10% by weight, of water, the lower aliphatic carboxylic acid or both.
    Type: Grant
    Filed: November 27, 1984
    Date of Patent: November 25, 1986
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Teruyuki Nagata, Akihiro Tamaki, Hiroki Ohnishi, Hideki Mizuta
  • Patent number: 4623610
    Abstract: A positive image-forming material consisting of a methylpentene homopolymer or a methylpentene copolymer containing 50 mole percent or more of methylpentene units which has an intrinsic viscosity of not less than 0.2 dl/g as measured in decalin at 135.degree. C. and being soluble in not more than 100 times by weight of cyclohexene at 25.degree. C.
    Type: Grant
    Filed: February 26, 1982
    Date of Patent: November 18, 1986
    Assignees: Tokyo Shibaura Denki Kabushiki Kaisha, Mitsui Petrochemical Industries, Ltd.
    Inventors: Hiromi Yoshida, Masataka Miyamura, Katsumi Funakoshi, Riichiro Nagano