Abstract: Disclosed are selected 5-xanthogenato-trihalomethyl-1,2,4-thiadiazole compounds of the formula: ##STR1## wherein R.sub.1 is a CCl.sub.3 or CF.sub.3 group and R.sub.2 is a lower alkyl group having 1 to 4 carbon atoms. These compounds are shown to have post-emergence herbicidal activity.

Abstract: An improved process is described for preparing defluorinated phosphate rock (DPR) granules from fluorine-containing phosphate rock.

Abstract: An improvement in an on-site foam generating apparatus which includes storage tanks for supplying the foam-forming reactants, a mixing chamber, and means for conveying the reactants through the mixing chamber. The improvement comprises means for cleaning the mixing chamber including a solvent storage tank and means for recovering the solvent within the apparatus and recycling the solvent through the chamber.

Abstract: A high conductivity high temperature copper alloy containing mischmetal, phosphorus and magnesium with specific ratios among them. The alloy is free from internal copper oxides and may be annealed at elevated temperatures in hydrogen atmospheres without embrittlement. Strengths on the order of 80 KSI and conductivities on the order of 90% IACS are obtainable in cold worked material.

Abstract: An alloy system is disclosed which is particularly useful for heat exchanger and water tubing applications. This alloy system utilizes additions of zinc, nickel and iron to a copper base. Cobalt and manganese may also be added to the alloy and such elements as arsenic, antimony and phosphorus may be added as parting inhibitors to the system.

Abstract: Graft copolymers of vinyl monomers and unsaturated polyols are described. These copolymers are prepared by the polymerization of an ethylenically unsaturated monomer, or a mixture of such monomers, in a polyol comprising an alkenyl aryl polyol. The alkenyl aryl constituents render the polyols compatible for graft copolymerization with the vinyl monomers. The graft copolymers are shown in polyurethane formulations.

Abstract: A coated, rounded, solid calcium hypochlorite granule is described which is comprised of granular calcium hypochlorite encapsulated with a plurality of layers of an inorganic salt other than calcium hypochlorite. The inorganic salt is admixed with sufficient alkaline material to form a coating which has a pH in dilute aqueous solution at ambient temperature of at least about nine or higher. The inorganic salt is selected from a group consisting of the chloride, chlorate, nitrate, bromide, bromate and sulfate of an alkali metal. The alkaline material is selected from the group consisting of calcium hydroxide, strontium hydroxide, barium hydroxide, magnesium hydroxide and mixtures thereof. The inorganic salt coating comprises from about 4 to about 45 percent by weight of the calcium hypochlorite granule. The coated, rounded, solid granule of this invention is highly stable and resists chemical decomposition and dusting during storage.

Abstract: Described is a mixing apparatus and its use in the hydration of liquid polymers. The apparatus includes two packed mixing columns, each having two reducing couplings attached thereto to form an inlet and an outlet to each column. The outlet of the first mixing column is connected to the inlet of the second mixing column via means of a reducing passageway. The apparatus also has sources of supply for liquid polymer and water connected to the inlet of the first mixing column through metering means and injection check means. The apparatus provides controlled mixing velocity during the hydration with non-shearing agitation and without a chemical buildup.

Abstract: An alloy which exhibits superior resistance to softening at elevated temperatures while maintaining high strength properties is disclosed. This alloy includes from 0.005 to 0.2% by weight for each of niobium and zirconium in a copper base. Magnesium may also be added in amounts ranging up to 0.01% by weight.

Abstract: An improved method is disclosed for the preparation of trialkoxysilanols. The process involves hydrolysis of corresponding trialkoxyhalosilanes with solid bicarbonate in the presence of a critical catalytic amount of water.

Abstract: Particulate gypsum, including phosphogypsum, is used for fire suppression in high fire risk areas such as forests, road sides and areas near railroad lines.

Abstract: A noise reducer for a powder actuated fastening tool comprises a barrel including inner and outer cylindrical walls which are radially spaced to define a gas expansion chamber between them. The chamber is adapted to receive combustion gases through ports or passages in the inner wall, and the gases may be exhausted from the chamber in any appropriate manner, preferably at a location adjacent the front end of the tool. The outer wall of the barrel can thus be made to slidingly fit within the tool receiver, while porting of the expansion chamber can be such as to induce a favorable flow pattern to the combustion gases passing therethrough.

Abstract: Calcium hypochlorite compositions useful as bleaching agents and disinfectants are produced by the reaction of solid granular hydrated lime and a solid granular alkali metal hydroxide with chlorine gas. The process takes place in the absence of a solvent and produces dry, free-blowing Ca(OCl).sub.2 compositions.

Abstract: A process is disclosed for recovering recoverable chlorine from chemical plant waste streams.An aqueous stream containing recoverable chlorine is reacted with an alkali metal hydroxide, such as sodium hydroxide, to form a slurry of solid particles of alkaline earth metal hydroxide, such as calcium hydroxide, suspended in a liquid. The calcium hydroxide is filtered or otherwise separated from the liquid. The liquid is admixed with an organic alcohol to form an organic-aqueous solution. A halogenating agent, such as chlorine, is reacted with the organic-aqueous solution to form a solution of organic hypochlorite in an organic phase and an aqueous phase.The solution of organic hypochlorite is phase separated to form aqueous and organic phases. The aqueous phase containing sodium chloride may be recycled for use as a reactant in a chlor-alkali electrolytic cell.

Abstract: An improved process for precipitating and recovering lime by reacting an aqueous solution of calcium hypochlorite with an alkaline compound is described. The pH of the resulting lime slurry is maintained in the range from about 11 to about 13.0, whereby hemi-basic calcium hypochlorite crystals form in the slurry. When the slurry is filtered or otherwise separated to recover the lime, an improved filtration rate is obtained. In addition, washing of the lime cake to remove impurities such as sodium chloride is easily accomplished because of the ease of separating wash water in the presence of the hemi-basic calcium hypochlorite crystals.

Abstract: A perforated support for helping prevent damage to a non-adherent membrane in a chlorine gas-producing cell configuration having downwardly open, gas-trapping pockets adjacent such a membrane in the upper end of a chlorine-producing anolyte chamber. The cathode chamber can be at a greater pressure than the anode chamber to force the diaphragm against the support.

Abstract: An alloy system is disclosed which is particularly useful for heat exchanger and potable water tubing applications. This alloy system utilizes additions of nickel, tin and manganese in a copper base with the optional addition of aluminum. Such elements as arsenic, antimony and phosphorus may be added as parting inhibitors to this system.

Abstract: A projectile for a centerfire cartridge achieves maximum energy transfer with limited target penetration. A hollow point lead bullet is provided with an aluminum jacket which allows the cartridge containing the projectile to feed reliably in auto-loading pistols and yet does not restrict normal expansion of the bullet upon impact with the target. The jacket extends into the nose recess of the bullet and covers the peripheral portion of the bullet base, whereby the jacket is securely fastened to the bullet and separation subsequent to impact is prevented.A method of fabricating the projectile is also disclosed.

Abstract: A casing suitable for covering a substantially rectangular electrode for a diaphragm-type electrolytic cell comprises a closed end, an open end, and two closed, reinforced sides.The casing is formed of a single flexible material which is folded or sealed to provide a plurality of fingers each having a closed end and then sealed to form two closed sides, such casing preferably having reinforced edges.

Abstract: An electrolytic process is described for purifying an aqueous solution of an alkali metal hydroxide containing an impurity of a soluble heavy metal complex comprised of a heavy metal cation and a plurality of anions.For example, an aqueous solution of sodium hydroxide containing a soluble heavy metal complex, such as mercuric polysulfide, [HgS].sup.+ S.sup.-, is charged to the electrolytic chamber of an electrolytic cell. An electric current is employed to reduce heavy metal cations to a separate phase in elemental form, and simultaneously to oxidize anions to a separate phase in elemental form, and to form a slurry of the separate phases in elemental forms in the aqueous solution.The slurry is removed from the electrolytic chamber and the phases of elemental forms are separated from the purified aqueous solution. The purified alkali metal hydroxide solution is sold commercially or otherwise utilized.