Abstract: Embodiments of the present disclosure pertain to electrodes that include a plurality of vertically aligned carbon nanotubes and germanium associated with the vertically aligned carbon nanotubes. The electrodes may also include a substrate (e.g., copper foil) and a carbon layer (e.g., graphene film). In some embodiments, the carbon layer may be positioned between the substrate and the vertically aligned carbon nanotubes. In some embodiments, the electrodes may be in the form of a graphene-carbon nanotube hybrid material that includes: a graphene film; and vertically aligned carbon nanotubes covalently linked to the graphene film. In some embodiments, the electrodes of the present disclosure serve as cathodes or anodes in an energy storage device. Additional embodiments pertain to energy storage devices that contain the electrodes of the present disclosure. Further embodiments of the present disclosure pertain to methods of making the electrodes and incorporating them into energy storage devices.

Abstract: The present disclosure pertains to methods of capturing CO2 from an environment at pressures above 1 bar by associating the environment with a porous material that has a surface area of at least 2,800 m2/g, and a total pore volume of at least 1.35 cm3/g, where a majority of pores of the porous material have diameters of less than 2 nm. The present disclosure also pertains to methods for the separation of CO2 from natural gas in an environment at partial pressures of either component above 1 bar by associating the environment with a porous material that has a surface area of at least 2,200 m2/g, and a total pore volume of at least 1.00 cm3/g, where a majority of pores of the porous material have diameters of greater than 1 nm and less than 2 nm.

Abstract: A porous memory device, such as a memory or a switch, may provide a top and bottom electrodes with a memory material layer (e.g. SiOx) positioned between the electrodes. The memory material layer may provide a nanoporous structure. In some embodiments, the nanoporous structure may be formed electrochemically, such as from anodic etching. Electroformation of a filament through the memory material layer may occur internally through the layer rather than at an edge at extremely low electro-forming voltages. The porous memory device may also provide multi-bit storage, high on-off ratios, long high-temperature lifetime, excellent cycling endurance, fast switching, and lower power consumption.

Abstract: Bacteria that run the beta oxidation cycle in reverse anabolic direction are provided, along with many novel primers to start the reverse cycle, pathways to make such primers, and a large variety of products produced thereby. Methods for making desired product by using such primers in the reverse pathway are also disclosed.

Abstract: A method and system to induce bone growth by locally delivering bone morphogenetic proteins (BMPs) to the target location for a prolonged period without invasive procedures are disclosed. The new bone growth is induced by delivering cells producing BMPs from transduced viral vectors to the target cite. In various embodiments, the cells are encapsulated in hydrogel microspheres that are non-degradable or degradable by enzymes produced during the bone formation process. Various embodiments may be used to induce spinal fusion or repair critical bone defects.

Abstract: In one aspect, the present disclosure provides tubulysin analogs of the formula (I) wherein R1, R2, R3, R4, X1, X2, X3, and A1 are as defined herein. In another aspect, the present disclosure also provides methods of preparing the compounds disclosed herein. In another aspect, the present disclosure also provides pharmaceutical compositions and methods of use of the compounds disclosed herein.

Abstract: An active cancellation system may be utilized to cancel interference, such as from transmitter leakage or self-interference in a transceiver of an electron paramagnetic resonance (EPR) spectrometer. The active cancellation system may be inserted between the transmitter and receiver. The active cancellation system may receive the output of the transmitter, and generate a cancellation signal with the same amplitude, but phase shifted relative to the self-interference signal. The cancellation system may include an attenuator/amplitude tuner, buffer, VQ generator, and phase shifter.

Abstract: A system for estimating a photoplethysmogram waveform of a target includes an image processor configured to obtain images of the target and a waveform analyzer. The waveform analyzer is configured to determine a weight of a portion of the target. The weight is based on a time variation of a light reflectivity of the portion of the target. The time variation of the light reflectivity of the target is based on the images. The waveform analyzer is further configured to estimate a PPG waveform of the target based on the weight of the portion and the time variation of the light reflectivity of the portion.

Abstract: The controller includes a differentiating engine configured to receive an input signal value (ISV), wherein the ISV corresponds to state information for one selected from a group consisting of a controlled process and a user interface. The differentiating engine is further configured to determine an error between the ISV and an estimated input signal (EIS), estimate a frequency of the IS, select a plurality of pre-determined gains using the frequency, wherein at least one plurality of pre-determined gains is a suction control gain, determine a first estimated derivative of the input signal (EDIS) using the plurality of pre-determined gains and the error, and to output the first EDIS.

Abstract: Embodiments of the present disclosure pertain to methods of making electrically conductive materials by applying nanowires and graphene nanoribbons onto a surface to form a network layer with interconnected graphene nanoribbons and nanowires. In some embodiments, the methods include the following steps: (a) applying graphene nanoribbons onto a surface to form a graphene nanoribbon layer; (b) applying nanowires and graphene nanoribbons onto the graphene nanoribbon layer to form the network layer; and (c) optionally applying graphene nanoribbons onto the formed network layer to form a second graphene nanoribbon layer on the network layer. Additional embodiments of the present disclosure pertain to the formed electrically conductive materials and their use as components of electronic devices, such as energy storage devices. Further embodiments of the present disclosure pertain to electronic devices that contain the electrically conductive materials of the present disclosure.

Abstract: Mechanically flexible and optically transparent thin film solid state supercapacitors are fabricated by assembling nano-engineered carbon electrodes in porous templates. The electrodes have textured graphitic surface films with a morphology of interconnected arrays of complex shapes and porosity. The graphitic films act as both electrode and current collector, and when integrated with solid polymer electrolyte function as thin film supercapacitors. The nanostructured electrode morphology and conformal electrolyte packaging provide enough energy and power density for electronic devices in addition to possessing excellent mechanical flexibility and optical transparency.

Abstract: A lens-free imaging system for generating an image of a scene includes an electromagnetic (EM) radiation sensor; a mask disposed between the EM radiation sensor and the scene; an image processor that obtains signals from the EM radiation sensor while the EM radiation sensor is exposed to the scene; and estimates the image of the scene based on, at least in part, the signals and a transfer function between the scene and the EM radiation sensor.

Abstract: A Magnetic Resonance Imaging (MRI) enhancement agent includes a plurality of particles, each particle including: a metal core; a dielectric shell disposed on the metal core comprising at least one MRI contrast agent; and a metal shell disposed on the exterior surface of the dielectric shell that encapsulates the dielectric shell.

Abstract: In some embodiments, the present disclosure pertains to methods of capturing CO2 from an environment by hydrating a porous material with water molecules to the extent thereby to define a preselected region of a plurality of hydrated pores and yet to the extent to allow the preselected region of a plurality of pores of the porous material to uptake gas molecules; positioning the porous material within a CO2 associated environment; and capturing CO2 by the hydrated porous material. In some embodiments, the pore volume of the hydrated porous material includes between 90% and 20% of the pre-hydrated pore volume to provide unhydrated pore volume within the porous material for enhanced selective uptake of CO2 in the CO2 associated environment. In some embodiments, the step of capturing includes forming CO2-hydrates within the pores of the porous material, where the CO2·n/H2O ratio is n<4.

Abstract: A vessel including a concentrator configured to concentrate electromagnetic (EM) radiation received from an EM radiation source and a complex configured to absorb EM radiation to generate heat. The vessel is configured to receive a cool fluid from the cool fluid source, concentrate the EM radiation using the concentrator, apply the EM radiation to the complex, and transform, using the heat generated by the complex, the cool fluid to the heated fluid. The complex is at least one of consisting of copper nanoparticles, copper oxide nanoparticles, nanoshells, nanorods, carbon moieties, encapsulated nanoshells, encapsulated nanoparticles, and branched nanostructures. Further, the EM radiation is at least one of EM radiation in an ultraviolet region of an electromagnetic spectrum, in a visible region of the electromagnetic spectrum, and in an infrared region of the electromagnetic spectrum.

Abstract: Method of cell culture, comprising adding a redox active compound with a redox potential of between ?0.116 to ?0.253 to a culture capable of forming hydrogen via a hydrogenase so that the redox potential is diverted from hydrogen to form a longer chain acids, e.g., butryic acid.

Abstract: Embodiments of the present disclosure pertain to electrocatalysts that include a surface and a plurality of catalytically active sites associated with the surface. The catalytically active sites include individually dispersed metallic atoms that are associated with heteroatoms. In some embodiments, the surface includes graphene oxide, the heteroatoms include nitrogen, and the metallic atoms include cobalt. Additional embodiments of the present disclosure pertain to methods of mediating an electrocatalytic reaction by exposing a precursor material to an electrocatalyst of the present disclosure. In some embodiments, the electrocatalytic reaction is a hydrogen evolution reaction that results in the formation of molecular hydrogen from the precursor material. Further embodiments of the present disclosure pertain to methods of making the electrocatalysts of the present disclosure by associating a surface with heteroatoms and metallic atoms.

Abstract: A method of wireless local area network communication between a client and an access point includes sending, by the client, a client-originated message to the access point over a bidirectional upload channel; receiving, by the client, a client-acknowledgement message from the access point over the bidirectional upload channel; receiving, by the client, an access point-originated message from the access point over a bidirectional download channel that was generated in response to the client-originated message; and sending, by the client, an access point-acknowledgement message to the access point over the bidirectional download channel. The bidirectional download channel is separate from the bidirectional upload channel.

Abstract: A metal-semiconductor-metal photodetecting device and method of manufacturing a metal-semiconductor-metal photodetecting device that includes a p-type silicon substrate with an oxide layer disposed on the p-type silicon substrate. Schotty junctions are disposed adjacent to the oxide layer on the p-type silicon substrate and a plasmonic grating disposed on the oxide layer. The plasmonic grating provides wavelength range selectability for the photodetecting device.

Abstract: The present disclosure pertains to materials for CO2 adsorption at pressures above 1 bar, where the materials include a porous material with a surface area of at least 2,800 m2/g, and a total pore volume of at least 1.35 cm3/g, where a majority of pores of the porous material have diameters of less than 2 nm as measured from N2 sorption isotherms using the BET (Brunauer-Emmett-Teller) method. The present disclosure also pertains to materials for separation of CO2 from natural gas at partial pressures of either component above 1 bar, where the materials include a porous material with a surface area of at least 2,200 m2/g, and a total pore volume of at least 1.00 cm3/g, where a majority of pores of the porous material have diameters of greater than 1 nm and less than 2 nm as measured from N2 sorption isotherms using the BET method.