Abstract: Provided is a seamless polishing pad comprising a seamless polishing layer having a substantially uniform depth of penetration into a porous subpad. In one embodiment, the polishing pad comprises a polishing layer produced by applying to the subpad a hardenable fluid. In another embodiment, the subpad is coated with a barrier before coating with the hardenable fluid. In each embodiment, the depth of penetration of the polishing layer and/or barrier is substantially uniform. Also provided is a method of producing a seamless polishing pad comprising a seamless polishing layer having a substantially uniform depth of penetration into a porous subpad.
Type:
Grant
Filed:
June 9, 2003
Date of Patent:
December 10, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Abstract: A chemical mechanical polishing composition is provided, comprising, as initial components: water, an abrasive; a diquaternary substance according to formula (I); a derivative of guanidine according to formula (II); and, optionally, a quaternary ammonium salt. Also, provided is a method for chemical mechanical polishing of a substrate, comprising: providing a substrate, wherein the substrate comprises silicon dioxide; providing the chemical mechanical polishing composition of the present invention; providing a chemical mechanical polishing pad; creating dynamic contact at an interface between the chemical mechanical polishing pad and the substrate; and dispensing the chemical mechanical polishing composition onto the chemical mechanical polishing pad at or near the interface between the chemical mechanical polishing pad and the substrate; wherein the chemical mechanical polishing composition has a pH of 2 to 6.
Type:
Grant
Filed:
September 20, 2010
Date of Patent:
October 29, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Zhendong Liu, Yi Guo, Kancharla-Arun Kumar Reddy, Guangyun Zhang
Abstract: A method for chemical mechanical polishing of a semiconductor wafer containing a nonferrous metal is provided, comprising: providing a chemical mechanical polishing composition comprising 1 to 25 wt % of an oxidizer; 0.01 to 15 wt % of an inhibitor for the nonferrous metal; 0.005 to 5 wt % of a copolymer of poly(ethylene glycol) methyl ether(meth)acrylate and 1-vinylimidazole; and water; wherein the chemical mechanical polishing composition has an acidic pH; providing a chemical mechanical polishing pad; providing a semiconductor wafer containing the nonferrous metal; creating dynamic contact between the chemical mechanical polishing pad and the semiconductor wafer; and, dispensing the polishing solution at or near the interface between the chemical mechanical polishing pad and the semiconductor wafer.
Type:
Grant
Filed:
April 1, 2013
Date of Patent:
October 22, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Tirthankar Ghosh, Terence M. Thomas, Hongyu Wang, Scott A. Ibbitson
Abstract: A chemical mechanical polishing composition and method is provided, wherein the low-k dielectric material removal rate remains stable following the polishing of a 110th polished wafer in a plurality of wafers to be polished.
Type:
Grant
Filed:
October 9, 2012
Date of Patent:
October 1, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Abstract: A method of manufacturing polishing layers for use in chemical mechanical polishing pads is provided, wherein a plurality of polishing layers are derived from a cake, wherein the formation of density defects in the cake and the surface roughness of the polishing layers formed are minimized.
Type:
Application
Filed:
March 22, 2012
Publication date:
September 26, 2013
Applicant:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Brian T. Cantrell, Kathleen McHugh, James T. Murnane, George H. McClain, Durron A. Hutt, Robert A. Brady, Christopher A. Young, Jeffrey Borcherdt Miller
Abstract: A method of manufacturing polishing layers having a window for use in chemical mechanical polishing pads is provided, wherein a plurality of polishing layers having an integral window are derived from a cake, wherein the formation of density defects in the cake and the surface roughness of the polishing layers formed are minimized.
Type:
Application
Filed:
March 22, 2012
Publication date:
September 26, 2013
Applicant:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Brian T. Cantrell, Kathleen McHugh, James T. Murnane, George H. McClain, Durron A. Hutt, Robert A. Brady, Christopher A. Young, Jeffrey Borcherdt Miller
Abstract: A chemical mechanical polishing composition useful for chemical mechanical polishing of a patterned semiconductor wafer containing a nonferrous metal. The chemical mechanical polishing composition comprises an inhibitor for the nonferrous metal; a copolymer of poly(ethylene glycol)methyl ether (meth)acrylate and 1-vinylimidazole; and water.
Type:
Grant
Filed:
August 4, 2008
Date of Patent:
September 24, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Tirthankar Ghosh, Terence M. Thomas, Hongyu Wang, Scott A. Ibbitson
Abstract: A method of making shape memory chemical mechanical polishing pads is provided, wherein the shape memory chemical mechanical polishing pads comprise a polishing layer in a densified state. Also provided is a method for using the shape memory chemical mechanical polishing pads to polish substrates.
Type:
Grant
Filed:
June 12, 2012
Date of Patent:
September 17, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Ravichandra V Palaparthi, Richard D Hreha, Benjamin John Vining
Abstract: A method for chemical mechanical polishing of a semiconductor wafer containing a nonferrous metal is provided, comprising: providing a chemical mechanical polishing composition comprising 1 to 25 wt % of an oxidizer; 0.01 to 15 wt % of an inhibitor for the nonferrous metal; 0.005 to 5 wt % of a copolymer of poly(ethylene glycol) methyl ether(meth)acrylate and 1-vinylimidazole; and water; wherein the chemical mechanical polishing composition has an acidic pH; providing a chemical mechanical polishing pad; providing a semiconductor wafer containing the nonferrous metal; creating dynamic contact between the chemical mechanical polishing pad and the semiconductor wafer; and, dispensing the polishing solution at or near the interface between the chemical mechanical polishing pad and the semiconductor wafer.
Type:
Application
Filed:
April 1, 2013
Publication date:
August 22, 2013
Applicant:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventor:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Abstract: A chemical mechanical polishing pad comprising an acrylate polyurethane polishing layer, wherein the polishing layer exhibits a tensile modulus of 65 to 500 MPa; an elongation to break of 50 to 250%; a storage modulus, G?, of 25 to 200 MPa; a Shore D hardness of 25 to 75; and a wet cut rate of 1 to 10 ?m/min.
Type:
Grant
Filed:
September 29, 2011
Date of Patent:
August 20, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Abstract: A chemical mechanical polishing slurry composition is provided, having, as initial components: water; an abrasive, wherein the abrasive is colloidal silica abrasive; a halogenated quaternary ammonium compound according to formula (I); optionally, a diquaternary substance according to formula (II); and, optionally, a pH adjusting agent selected from phosphoric acid, nitric acid, sulfuric acid, hydrochloric acid, ammonium hydroxide and potassium hydroxide; wherein the chemical mechanical polishing slurry composition has a pH of 2 to <7. Also, provided are methods for making the chemical mechanical polishing slurry composition and for using the chemical mechanical polishing composition to polish a substrate.
Type:
Grant
Filed:
September 22, 2010
Date of Patent:
August 20, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Zhendong Liu, Yi Guo, Kancharla-Arun Kumar Reddy, Guangyun Zhang
Abstract: A method for chemical mechanical polishing of a substrate is provided, comprising: providing a substrate, wherein the substrate comprises polysilicon and at least one of silicon oxide and silicon nitride; providing a chemical mechanical polishing composition, comprising, as initial components: water; an abrasive; and an alkyl aryl polyether sulfonate compound, wherein the alkyl aryl polyether sulfonate compound has a hydrophobic portion having an alkyl group bound to an aryl ring and a nonionic acyclic hydrophilic portion having 4 to 100 carbon atoms; providing a chemical mechanical polishing pad with a polishing surface; moving the polishing surface relative to the substrate; dispensing the chemical mechanical polishing composition onto the polishing surface; and, abrading at least a portion of the substrate to polish the substrate; wherein at least some of the polysilicon is removed from the substrate; and, wherein at least some of the at least one of silicon oxide and silicon nitride is removed from the su
Type:
Grant
Filed:
March 16, 2010
Date of Patent:
July 30, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Yi Guo, Zhendong Liu, Kancharla-Arun Kumar Reddy, Guangyun Zhang
Abstract: A method for chemical mechanical polishing of a substrate is provided, comprising: providing a substrate, wherein the substrate comprises polysilicon, silicon oxide and silicon nitride; providing a chemical mechanical polishing composition, comprising, as initial components: water; an abrasive; an alkyl aryl polyether sulfonate compound, wherein the alkyl aryl polyether sulfonate compound has a hydrophobic portion having an alkyl group bound to an aryl ring and a nonionic acyclic hydrophilic portion having 4 to 100 carbon atoms; and a substance according to formula I wherein each of R1, R2, R3, R4, R5, R6 and R7 is a bridging group having a formula ā(CH2)nā, wherein n is an integer selected from 1 to 10; providing a chemical mechanical polishing pad with a polishing surface; moving the polishing surface relative to the substrate; dispensing the chemical mechanical polishing composition onto the polishing surface; and, abrading at least a portion of the substrate to polish the substrate; wherein at least s
Type:
Grant
Filed:
March 16, 2010
Date of Patent:
July 23, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Yi Guo, Zhendong Liu, Kancharla-Arun Kumar Reddy, Guangyun Zhang
Abstract: A method for chemical mechanical polishing of a substrate is provided, comprising: providing a substrate, wherein the substrate comprises polysilicon and at least one of silicon oxide and silicon nitride; providing a chemical mechanical polishing composition, comprising, as initial components: water; an abrasive; and an acyclic organosulfonic acid compound, wherein the acyclic organosulfonic acid compound has an acyclic hydrophobic portion having 6 to 30 carbon atoms and a nonionic acyclic hydrophilic portion having 10 to 300 carbon atoms; providing a chemical mechanical polishing pad with a polishing surface; moving the polishing surface relative to the substrate; dispensing the chemical mechanical polishing composition onto the polishing surface; and, abrading at least a portion of the substrate to polish the substrate; wherein at least some of the polysilicon is removed from the substrate; and, wherein at least some of the at least one of silicon oxide and silicon nitride is removed from the substrate.
Type:
Grant
Filed:
March 16, 2010
Date of Patent:
July 23, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc
Inventors:
Yi Guo, Zhendong Liu, Kancharla-Arun Kumar Reddy, Guangyun Zhang
Abstract: A method of manufacturing polishing layers for use in chemical mechanical polishing pads is provided, wherein the formation of density defects in the polishing layers is minimized.
Type:
Grant
Filed:
August 16, 2011
Date of Patent:
May 21, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Kathleen McHugh, James T. Murnane, George Harry McClain, Durron Andre Hutt, Robert A Brady, Christopher Alan Young, Jeffrey Borcherdt Miller
Abstract: A chemical mechanical polishing composition, comprising, as initial components: water; 0.1 to 20 wt % abrasive having an average particle size of 5 to 50 nm; and, 0.001 to 1 wt % of an adamantyl substance according to formula (II): wherein A is selected from N and P; wherein each R8 is independently selected from hydrogen, a saturated or unsaturated C1-15 alkyl group, C6-15 aryl group, C6-15 aralkyl group, C6-15 alkaryl group; and, wherein the anion in formula (II) can be any anion that balances the positive charge on the cation in formula (II).
Type:
Grant
Filed:
June 12, 2012
Date of Patent:
May 21, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Yi Guo, Zhendong Liu, Kancharla-Arun Kumar Reddy, Guangyun Zhang
Abstract: A chemical mechanical polishing composition useful for chemical mechanical polishing a semiconductor wafer containing an interconnect metal is provided, comprising, as initial components: water; an azole inhibitor; an alkali metal organic surfactant; a hydrotrope; a phosphorus containing agent; optionally, a non-saccharide water soluble polymer; optionally, a water soluble acid compound of formula I, wherein R is selected from a hydrogen and a C1-5 alkyl group, and wherein x is 1 or 2; optionally, a complexing agent; optionally, an oxidizer; optionally, an organic solvent; and, optionally, an abrasive.
Type:
Grant
Filed:
March 3, 2011
Date of Patent:
May 14, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Hamed Lakrout, Jinjie Shi, Joseph Letizia, Xu Li, Thomas H. Kalantar, Francis Kelley, J. Keith Harris, Christopher J. Tucker
Abstract: A process for chemical mechanical polishing of a substrate having a polysilicon overburden deposited over silicon dioxide is provided using multiple dilutions of a chemical mechanical polishing composition concentrate to polish the substrate, wherein a first dilution of the concentrate used to polish the substrate is tuned to exhibit a first polysilicon removal rate and a first polysilicon to silicon dioxide removal rate selectivity; and wherein a second dilution of the concentrate used to polish the substrate is tuned to exhibit a second polysilicon removal rate and a second polysilicon to silicon dioxide removal rate selectivity.
Type:
Grant
Filed:
October 27, 2011
Date of Patent:
May 14, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Abstract: A process for chemical mechanical polishing of a substrate having a polysilicon overburden deposited over silicon nitride is provided using multiple dilutions of a chemical mechanical polishing composition concentrate to polish the substrate, wherein a first dilution of the concentrate used to polish the substrate is tuned to exhibit a first polysilicon removal rate and a first polysilicon to silicon nitride removal rate selectivity; and wherein a second dilution of the concentrate used to polish the substrate is tuned to exhibit a second polysilicon removal rate and a second polysilicon to silicon nitride removal rate selectivity.
Type:
Grant
Filed:
October 27, 2011
Date of Patent:
May 7, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Abstract: A chemical mechanical polishing composition useful for chemical mechanical polishing a semiconductor wafer containing an interconnect metal is provided, comprising, as initial components: water; an azole inhibitor; an alkali metal organic surfactant; a hydrotrope; a phosphorus containing agent; a water soluble cellulose; optionally, a non-saccharide water soluble polymer; optionally, a water soluble acid compound of formula I, wherein R is selected from a hydrogen and a C1-5 alkyl group, and wherein x is 1 or 2; optionally, a complexing agent; optionally, an oxidizer; optionally, an organic solvent; and, optionally, an abrasive.
Type:
Grant
Filed:
March 3, 2011
Date of Patent:
May 7, 2013
Assignee:
Rohm and Haas Electronic Materials CMP Holdings, Inc.
Inventors:
Hamed Lakrout, Jinjie Shi, Joseph Letizia, Xu Li, Thomas H. Kalantar, Francis Kelley, J. Keith Harris, Christopher J. Tucker