Abstract: A biaxially oriented laminate film including a core layer including a blend of crystalline polylactic acid polymer and a minority amount of polyolefin with a compatibilizing resin which is biaxially oriented such that a matte or opaque appearance is obtained. The laminate film may further have additional layers such as a heat sealable layer disposed on one side of the core layer including an amorphous polylactic acid resin and/or a polylactic acid resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.
Abstract: A biaxially oriented laminate film including a core layer including a blend of crystalline polylactic acid polymer and a minority amount of polyolefin with a compatibilizing resin which is biaxially oriented such that a matte or opaque appearance is obtained. The laminate film may further have additional layers such as a heat sealable layer disposed on one side of the core layer including an amorphous polylactic acid resin and/or a polylactic acid resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.
Abstract: A laminate film including a first core polylactic acid layer, a coating receiving-layer of polylactic acid, and coated on one side of the coating receiving-layer with PVOH, EVOH, a blend of crosslinked EVOH/PVOH, vinyl alcohol-vinylamine (PVAm) copolymer, anionic carboxylated styrene-butadiene copolymer (SBR) emulsion, or blends thereof. This coating may be applied after the machine-direction orientation step and dried and oriented in a transverse direction orientation oven if in-line coating is desired; or applied to the film in an off-line coating method and dried in an air flotation oven. The dried coating layer can be metallized. This laminate film exhibits excellent gas and moisture barrier properties, appearance, and metal adhesion. It may also optionally include a heat sealable or winding improving layer on the side opposite the coating receiving-layer of the core layer.
Abstract: Embodiments herein relate to a polyolefin-containing film comprising a solidified form of a melt, the melt comprising at least 1 weight percent shredded recycled crosslinked vinyl-alcohol polymer coated polyolefin material and an amount of a compatibilizing agent and/or an un-crosslinking agent configured to un-crosslink the crosslinked vinyl-alcohol in the melt, the polyolefin-containing film having an average dimple count of less than about 50 dimples/4 in2, and method of manufacturing the same.
Abstract: Described are methods for producing a sequentially biaxially oriented thermoplastic film having balanced machine direction (MD) and transverse direction (TD) heat shrinkage properties. The methods can include extruding a film, orienting the extruded film in a machine direction, quenching the film, heating the film in an transverse orientation oven and transversely orienting the film, and allowing the film to relax in the machine direction at a machine direction tension lower than a machine direction tension of the film in the transverse orientation oven.
Type:
Application
Filed:
December 31, 2013
Publication date:
July 3, 2014
Applicant:
TORAY PLASTICS (AMERICA), INC.
Inventors:
Douglas J. BOWER, Robert Thomas ERVOLINO
Abstract: The novel method can produce a grooved profile metalized polymeric film capable of generating a rainbow iridescent effect without mechanically embossing the film. The method calls for applying a thin uniform thickness coating layer of thermally deformable polymer composition on a thermally stable base layer. Process operating conditions are controlled to heat the composite coating layer surface effectively such that light diffraction-scale grooves of about 5,000-10,000 grooves/cm develop in the coating layer. The grooves are created by shocking the coating layer surface with a sudden burst of heat supplied by film metalization after coating layer application.
Abstract: A two-layer mono-axially oriented film includes a first layer of an opaque beta-nucleated microvoided propylene-based polymer; and a second layer containing a dark pigment that is adapted for use in a thermal printer in which the thermal print-head contacts the exposed surface of the first layer. The dark pigment of the second layer pigment has a color contrasting with the color of the first layer and can contain a carbon black. The first layer includes microvoids and may be made transparent upon the application of heat by collapsing the voids of the first layer or upon the application of ultra-sonic energy.
Abstract: A method reclaims metalized polymer film or mixtures containing metal and/or metal alloys into a metal-containing, polymeric film. The resulting film structure has better oxygen and moisture barrier properties when metalized than plain metalized polymer films. The polymer to be reclaimed, originates in sheet form, and is densified, as by shredding, pelletizing and/or re-extruding into fine particulate form such as chips or pellets. The reclaimed polymeric film can be used, in a range of concentrations, to produce biaxially oriented polyester film for metalizing.
Type:
Application
Filed:
January 31, 2014
Publication date:
May 29, 2014
Applicant:
Toray Plastics (America) Inc.
Inventors:
Douglas James Bower, Larissa Marie Peguero
Abstract: A laminate film including a first core polylactic acid layer, a coating receiving-layer of polylactic acid, and coated on one side of the coating receiving-layer with PVOH, EVOH, a blend of crosslinked EVOH/PVOH, vinyl alcohol-vinylamine (PVAm) copolymer, anionic carboxylated styrene-butadiene copolymer (SBR) emulsion, or blends thereof. This coating may be applied after the machine-direction orientation step and dried and oriented in a transverse direction orientation oven if in-line coating is desired; or applied to the film in an off-line coating method and dried in an air flotation oven. The dried coating layer can be metallized. This laminate film exhibits excellent gas and moisture barrier properties, appearance, and metal adhesion. It may also optionally include a heat sealable or winding improving layer on the side opposite the coating receiving-layer of the core layer.
Abstract: A carrier film of thermoplastic polyester has releasable metal adhesive properties suitable for a metal transfer in which the polyester film is metalized and the metal layer is subsequently transferred to a permanent adhesive-coated substrate. The metal layer is in direct contact with the polyester carrier film and no intermediate release layer is present. Desired metal adhesion is provided by dispersing an suitable surfactant, and optionally, a hydrocarbon wax, uniformly into the polyester film. Surfactant on the outer surface of the carrier film modifies metal adhesion to the polyester such that the metal can be removed in a metal transfer operation.
Abstract: A bio-based polyester thin film substrate for thermal transfer printing ribbon. The bio-based polyester thermal transfer ribbon substrate film has a radiocarbon content of at least 12 pMC. The film exhibits excellent uniformity, handling, and processability, substantially equivalent to petroleum-based counterparts, while being derived wholly or partly from non-petroleum sources.
Type:
Application
Filed:
December 23, 2013
Publication date:
April 24, 2014
Applicant:
TORAY PLASTICS (AMERICA), INC.
Inventors:
Stefanos L. SAKELLARIDES, Milan William MOSCARITOLO
Abstract: A lidding film including a polyester film including a bio-based polyester, and an extrusion coated heat seal layer including a bio-based polymer. The polyester film may include a biaxially oriented core layer including bio-based polyester and an amorphous copolyester skin layer. The heat seal layer may include a low density polyethylene.
Type:
Application
Filed:
August 31, 2012
Publication date:
March 6, 2014
Applicant:
TORAY PLASTICS (AMERICA), INC.
Inventors:
Roberto SIU, Gordon Vincent SHARPS, Stefanos L. SAKELLARIDES, Keunsuk P. CHANG
Abstract: A multi-layer sheet suitable as sealable or peelable sheet specially used for closing foodstuff containers. This multi-layer sheet comprises a polymeric substrate layer and a seal or a peel-seal layer. The multilayer composite film has at least two main component layers, namely in order, a polymeric substrate layer for mechanical strength and a heat-sealable layer applied by extrusion-coating, comprising a polyester of at least one aromatic dicarboxylic acid and at least one aliphatic dicarboxylic acid and at least one aliphatic diol. The polyester substrate layer comprises a crystallizable polyester base layer and an amorphous polyester sealable skin layer. The heat-sealable layer is slow-crystallizing with a glass transition temperature 50° F. or lower and melting point 250-320° F.
Abstract: A monoaxially oriented film including an ethylene-propylene copolymer elastomer, a non-elastomeric propylene-based random copolymer, and a low density polyethylene, which is oriented at least about 2.5 times in one direction and exhibits excellent linear directional tear properties parallel to the orientation direction, excellent heat seal performance in terms of high heat seal strengths and low seal initiation temperature, and is less than 50 ?m in thickness after orientation. This “thin” film formulation and orientation is suitable for pouch applications requiring an “easy-tear” linear tear feature and excellent hermetic seal properties.
Abstract: A lidding film including a polyester film including a bio-based polyester, and an extrusion coated heat seal layer including a bio-based polymer. The polyester film may include a biaxially oriented core layer including bio-based polyester and an amorphous copolyester skin layer. The heat seal layer may include a low density polyethylene.
Type:
Application
Filed:
May 24, 2013
Publication date:
March 6, 2014
Applicant:
TORAY PLASTICS (AMERICA), INC.
Inventors:
Roberto SIU, Gordon Vincent Sharps, Stefanos L. Sakellarides, Keunsuk P. Chang
Abstract: Biaxially oriented polyester films including polyester polymer, a carbodiimide hydrolysis stabilizer, and a UV absorber are described. The polyester films have a carboxyl end group concentration of 5-20 equivalents per ton, and a haze value of 2% or less. The films exhibit superior transparency and possess stable light transmission characteristics. Methods of making the films and articles produced from the films are also described.
Type:
Grant
Filed:
June 9, 2011
Date of Patent:
February 25, 2014
Assignee:
Toray Plastics (America), Inc.
Inventors:
Carlos Hinton, Nao Yokota, Hirokazu Tajima, Roberto Siu
Abstract: Metallized multi-layer biaxially oriented polylactic acid base polymer (BOPLA) films that exhibits improved barrier properties and metal adhesion. The films include a core layer including crystalline polylactic acid base polymer, a first skin layer consisting essentially of amorphous polylactic acid base polymer, and a metal layer on the first skin layer. The films may include a second skin layer consisting essentially of amorphous polylactic acid base polymer.
Type:
Grant
Filed:
March 25, 2010
Date of Patent:
February 18, 2014
Assignees:
Toray Plastics (America), Inc., Toray Industries, Inc.
Inventors:
Mark S. Lee, Claudio M. Paulino, Takeshi Mizumura, Keunsuk P. Chang, Nao Yokota, Jun'ichi Masuda
Abstract: A method reclaims metalized polymer film or mixtures containing metal and/or metal alloys into a metal-containing, polymeric film. The resulting film structure has better oxygen and moisture barrier properties when metalized than plain metalized polymer films. The polymer to be reclaimed, originates in sheet form, and is densified, as by shredding, pelletizing and/or re-extruding into fine particulate form such as chips or pellets. The reclaimed polymeric film can be used, in a range of concentrations, to produce biaxially oriented polyester film for metalizing.
Type:
Grant
Filed:
May 5, 2011
Date of Patent:
February 4, 2014
Assignee:
Toray Plastics (America), Inc.
Inventors:
Douglas James Bower, Larissa Marie Peguero
Abstract: Film structures containing a biaxially oriented film with an extruded polyolefin layer on each side of the biaxially oriented film are obtained. One polyolefin layer may, for example, be fin sealed to exhibit a peelable heat sealable performance. The other polyolefin layer may exhibit a paper like appearance and may be lap sealable.
Type:
Application
Filed:
March 14, 2013
Publication date:
January 16, 2014
Applicant:
TORAY PLASTICS (AMERICA), INC.
Inventors:
Scott NARKEVICIUS, Gordon Vincent SHARPS, Jon Ian MONTCRIEFF, Roberto SIU, John HOLOVACH, Paige MANUEL
Abstract: The present invention is directed to a multilayer film having, as its main component, a hydroxy acid polymer with improved gas barrier and optional heat sealability. The oriented film of predominately hydroxy acid polymer having controlled shrink can be produced by melting and coextruding a hydroxy acid polymer with a much thinner layer of an amorphous aromatic copolyester to form a multilayer film that is quench cooled, then biaxially stretched at a process temperature above the glass transition and below the cold crystallization temperature of the hydroxy acid polymer. A heat-setting treatment with a controlled relaxation of the film above the hydroxy acid polymer glass transition temperature and below its melt temperature may be used to control shrinkage. The films thus obtained are vacuum metallized on the aromatic copolyester surface to produce environmentally friendly packaging from predominately renewable resources having improved gas barrier properties.