Abstract: Described herein are methods and processes of manufacturing irradiation crosslinked polypropylene foam. In some embodiments, this includes extrusion of all material components, including a liquid crosslinking agent, to manufacture extruded structures for production of irradiation crosslinked polypropylene foam.

Abstract: A composite barrier film has a base layer of polyester or polyolefin with a barrier layer modified polyvinyl amine (mPVA). The mPVA is polyvinyl alcohol/polyvinyl amine copolymer crosslinked with citric acid and an optional additional crosslinking agent such as epichlorohydrin. The barrier layer can be applied by deposition of a reactive aqueous solution onto the base layer, heating and drying to remove water and crosslink the reactants. Excellent barrier properties of the film are obtained by applying and crosslinking the barrier layer during the transverse stretching steps of a biaxial oriented polymer film continuous fabrication process. Superior barrier properties are achieved with transverse stretching by a factor of about 3-4 for polyester and 4-10 for polyolefin.

Abstract: A physically crosslinked, closed cell continuous foam structure derived from recycled metallized polyolefin material; polypropylene, polyethylene, or combinations thereof, a crosslinking agent, and a chemical blowing agent is obtained. The foam structure is obtained by extruding a structure comprising a foam composition, irradiating the extruded structure with ionizing radiation, and continuously foaming the irradiated structure.

Abstract: A method of incorporating a UV light absorber into a polyester during the esterification or the condensation process by selecting the UV absorber from a class that is substantially not reactive with the polyester raw materials, is stable in the conditions of polycondensation or polymerization, and does not suffer loss through volatilization, resulting in an incorporation yield of 70% or higher, preferably 90% or higher. One embodiment comprises selecting the appropriate compound from the class of triazines and incorporating is as a solid powder in the beginning of the esterification. Another embodiment comprises selecting the appropriate compound from the class of triazines and incorporating it in the form of slurry during the time interval between esterification and condensation. Other embodiments include novel resins and films made by the UV absorber containing polyester resin made by the methods disclosed herein.

Abstract: A biaxially oriented polypropylene (BOPP) film with a novel coating layer which has an O2TR value in cc/m2/day in a range from 100 to 2000, and a MOSH value of 0.6 mg/kg or less is disclosed. This coating layer comprises a blend of additives that are approved for coatings for direct contact with food. In one embodiment, the coating layer comprises a poly-vinyl amine and a styrene butadiene resin emulsion.

Abstract: A laminate film including a first core polylactic acid layer, a coating receiving-layer of polylactic acid, and coated on one side of the coating receiving-layer with PVOH, EVOH, a blend of crosslinked EVOH/PVOH, vinyl alcohol-vinylamine (PVAm) copolymer, anionic carboxylated styrene-butadiene copolymer (SBR) emulsion, or blends thereof. This coating may be applied after the machine-direction orientation step and dried and oriented in a transverse direction orientation oven if in-line coating is desired; or applied to the film in an off-line coating method and dried in an air flotation oven. The dried coating layer can be metallized. This laminate film exhibits excellent gas and moisture barrier properties, appearance, and metal adhesion. It may also optionally include a heat sealable or winding improving layer on the side opposite the coating receiving-layer of the core layer.

Abstract: A carrier film of thermoplastic polyester has releasable metal adhesive properties suitable for a metal transfer in which the polyester film is metalized and the metal layer is subsequently transferred to a permanent adhesive-coated substrate. The metal layer is in direct contact with the polyester carrier film and no intermediate release layer is present. Desired metal adhesion is provided by dispersing an suitable surfactant, and optionally, a hydrocarbon wax, uniformly into the polyester film. Surfactant on the outer surface of the carrier film modifies metal adhesion to the polyester such that the metal can be removed in a metal transfer operation.

Abstract: A moisture vapor and oxygen transmission resistant flexible film has a polymeric base layer and a barrier layer of discrete particles of a first organic polymer dispersed throughout a matrix of a second organic polymer. Preferably, the first and second polymers are water insoluble and water soluble, respectively. The barrier layer is formed by depositing onto the base layer a coating composition of finely divided insoluble organic polymer particles suspended in an aqueous solution of the water soluble organic polymer, a crosslinking agent and surfactant. The coating composition is heated to crosslink the barrier layer polymers and evaporate solvent to provide a barrier film suitable for packaging applications. Optionally, the film can be metalized to increase barrier properties.

Abstract: A two-layer mono-axially oriented film includes a first layer of an opaque beta-nucleated microvoided propylene-based polymer; and a second layer containing a dark pigment that is adapted for use in a thermal printer in which the thermal print-head contacts the exposed surface of the first layer. The dark pigment of the second layer pigment has a color contrasting with the color of the first layer and can contain a carbon black. The first layer includes microvoids and may be made transparent upon the application of heat by collapsing the voids of the first layer or upon the application of ultra-sonic energy.

Abstract: A multi-layer biaxially oriented polypropylene (BOPP) film with a novel formulation which exhibits matte appearance is disclosed. This improved formulation comprises a blend of high density polyethylene (HDPE), medium density polyethylene (MDPE), low density polyethylene (LDPE) or linear low density polyethylene (LLDPE) with polypropylene (PP) used in the core layer to achieve a matte appearance low gloss PP-based film that still exhibits typical properties of BOPP films with significantly lower haze than conventional matte films. The multi-layer BOPP film has additional layers such as a second polyolefin resin-containing layer, a metal layer, or combinations thereof.

Abstract: A monoaxially oriented film including a propylene-based random copolymer and at least about 3 wt % of a low density polyethylene which is oriented at least about 2.5 times in one direction and exhibits excellent linear directional tear properties parallel to the orientation direction and excellent heat seal performance in terms of high heat seal strengths and low seal initiation temperature. This film formulation and orientation is suitable for pouch applications requiring an “easy-tear” linear tear feature and excellent hermetic seal properties.

Abstract: A monoaxially oriented film including a metallized layer; a gas barrier layer; and a propylene-based random copolymer and at least about 3 wt % of a low density polyethylene which is oriented at least about 2.5 times in one direction and exhibits excellent linear directional tear properties parallel to the orientation direction and excellent heat seal performance in terms of high heat seal strengths and low seal initiation temperature. This film formulation and orientation is suitable for pouch applications requiring high gas and moisture barrier, an “easy-tear” linear tear feature, and excellent hermetic seal properties.

Abstract: A method is presented for making releasable transfer film suitable to provide a metalized embossed composite onto a paper substrate without a release layer between the composite and a polymeric carrier layer. The transfer film includes a polymeric base layer, an embossing material layer and a metal layer. The transfer film is bonded to the paper substrate with an adhesive layer allowing the polymeric barrier layer to peel away from and to expose the metal-backed, embossing material layer. The substrate covered with the metalized embossed composite can be used to impart holographic style images to packaging, printed media products such as magazines.

Abstract: A biaxially oriented laminate film including a core layer including a blend of crystalline polylactic acid polymer and an inorganic antiblock particle which is biaxially oriented at low transverse direction orientation temperatures to impart a degree of cavitation around the particles such that a matte or opaque appearance is obtained. The laminate film may further have additional layers such as a heat sealable layer disposed on one side of the core layer including an amorphous polylactic acid resin and/or a polylactic acid resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.

Abstract: A biaxially oriented laminate film including a core layer including a blend of crystalline polylactic acid polymer and an inorganic antiblock particle which is biaxially oriented at low transverse direction orientation temperatures to impart a degree of cavitation around the particles such that a matte or opaque appearance is obtained. The laminate film may further have additional layers such as a heat sealable layer disposed on one side of the core layer including an amorphous polylactic acid resin and/or a polylactic acid resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.

Abstract: A substrate composite film for thermal transfer printing includes a biaxially oriented base layer including polyester, a first type of lubricant particles, and a second type of lubricant particles. The substrate composite film satisfies the following: (1) a ratio of maximum height SRma and peak count SPc is 1?SRma/SPc?4.5, (2) a center plane average roughness Sra is 15 to 30 nm, (3) coefficient of dynamic friction is <0.60, and (4) 20 and 60 degree gloss is greater than 160 SGU. The 20 degree gloss may be equal in all directions, and the 60 degree gloss may be equal in all directions.

Abstract: A releasable transfer film is suitable to provide a metalized embossed composite onto a paper substrate without a release layer between the composite and a polymeric carrier layer. The transfer film includes a polymeric base layer, an embossing material layer and a metal layer. The transfer film is bonded to the paper substrate with an adhesive layer allowing the polymeric barrier layer to peel away from and to expose the metal-backed, embossing material layer. The substrate covered with the metalized embossed composite can be used to impart holographic style images to packaging, printed media products such as magazines.

Abstract: A monoaxially oriented film including heat sealable layer including an ethylene-propylene impact copolymer and a metallocene-catalyzed propylene-butene elastomer. The heat sealable layer may include a metallocene-catalyzed ethylene-butene elastomer. The film is oriented at least 4 times in the machine direction and exhibits excellent linear directional tear properties in the machine direction and excellent heat seal performance. This film formulation and orientation is suitable for pouch applications requiring an “easy-tear” linear tear feature and excellent hermetic seal properties, particularly for retort pouches.

Abstract: A biaxially oriented multilayer film having (a) a polyolefinic core layer containing (i) a thermoplastic material containing an alpha-olefin/polypropylene-containing copolymer, the thermoplastic material being in an amount of about 10% to 70% by weight of the core layer and (ii) an isotactic polypropylene-containing copolymer in an amount of greater than 0% to about 50% by weight of the core layer and (b) a skin layer containing a styrene-butadiene copolymer or a cyclic olefin copolymer is disclosed.

Abstract: Multi-layer films suitable as sealable or peelable sheet that can be used for closing foodstuff containers are described. These multi-layer films includes a polymeric substrate layer and a seal or a peel-seal layer. The multilayer composite film preferably includes four component layers, namely in order, a polymeric base layer for mechanical strength, a thin organic barrier layer, an ethylene polymer-based adhesive layer, and a heat seal layer including an ethylene copolymer, such as ethylene vinyl acetate copolymer. The film is useful as a peelable heat sealable lid for containers of diverse polymer compositions storing various products such as foodstuffs and pharmaceuticals.