Patents Assigned to Toray Plastics (America) Inc.
  • Patent number: 9669600
    Abstract: A physically crosslinked, closed cell continuous multilayer foam structure comprising at least one polypropylene/polyethylene coextruded foam layer is obtained. The multilayer foam structure is obtained by coextruding a multilayer structure comprising at least one foam composition layer, irradiating the coextruded structure with ionizing radiation, and continuously foaming the irradiated structure.
    Type: Grant
    Filed: December 30, 2014
    Date of Patent: June 6, 2017
    Assignee: TORAY PLASTICS (AMERICA), INC.
    Inventors: Jesse Baldwin, Kaitlyn M. Bock, Pawel Sieradzki
  • Patent number: 9669591
    Abstract: A monoaxially oriented film including an ethylene-propylene copolymer elastomer, a non-elastomeric propylene-based random copolymer, and a low density polyethylene, which is oriented at least about 2.5 times in one direction and exhibits excellent linear directional tear properties parallel to the orientation direction, excellent heat seal performance in terms of high heat seal strengths and low seal initiation temperature, and is less than 50 ?m in thickness after orientation. This “thin” film formulation and orientation is suitable for pouch applications requiring an “easy-tear” linear tear feature and excellent hermetic seal properties.
    Type: Grant
    Filed: November 11, 2013
    Date of Patent: June 6, 2017
    Assignee: TORAY PLASTICS (AMERICA), INC.
    Inventors: Harold Egon Koehn, Matthew H. Brown
  • Patent number: 9669607
    Abstract: A laminate film comprising a core layer comprising of a high crystalline propylene homopolymer blended with an amount of hydrocarbon resin; crystalline polyethylene wax; and a fluoropolymer and/or a metal oxide nanoparticle which exhibits excellent transparency and moisture vapor barrier properties. The laminate film could further have additional layers such as a second polyolefin resin-containing layer, or a heat-sealable polyolefin-containing layer, or combinations thereof.
    Type: Grant
    Filed: March 28, 2016
    Date of Patent: June 6, 2017
    Assignee: TORAY PLASTICS (AMERICA), INC.
    Inventors: Shichen Dou, Keunsuk P. Chang
  • Patent number: 9663958
    Abstract: A physically crosslinked, closed cell continuous foam structure derived from recycled metallized polyolefin material; polypropylene, polyethylene, or combinations thereof, a crosslinking agent, and a chemical blowing agent is obtained. The foam structure is obtained by extruding a structure comprising a foam composition, irradiating the extruded structure with ionizing radiation, and continuously foaming the irradiated structure.
    Type: Grant
    Filed: December 31, 2013
    Date of Patent: May 30, 2017
    Assignee: TORAY PLASTICS (AMERICA), INC.
    Inventors: Jesse Baldwin, Gary Hostman Clark, Pawel Sieradzki
  • Patent number: 9656447
    Abstract: A multi-layer sheet suitable as sealable or peelable sheet specially used for closing foodstuff containers. This multi-layer sheet comprises a polymeric substrate layer and a seal or a peel-seal layer. The multilayer composite film has at least two main component layers, namely in order, a polymeric substrate layer for mechanical strength and a heat-sealable layer applied by extrusion-coating, comprising a polyester of at least one aromatic dicarboxylic acid and at least one aliphatic dicarboxylic acid and at least one aliphatic diol. The polyester substrate layer comprises a crystallizable polyester base layer and an amorphous polyester sealable skin layer. The heat-sealable layer is slow-crystallizing with a glass transition temperature 50° F. or lower and melting point 250-320° F.
    Type: Grant
    Filed: August 31, 2012
    Date of Patent: May 23, 2017
    Assignee: TORAY PLASTICS (AMERICA), INC.
    Inventor: Stefanos L Sakellarides
  • Patent number: 9637605
    Abstract: A biaxially oriented laminate film including a core layer including a blend of crystalline polylactic acid polymer and a metal salt phosphorus-containing compound nucleating agent which is biaxially oriented at low transverse direction orientation temperatures to impart a degree of cavitation around the metal salt phosphorus-containing metal such that a white opaque cavitated appearance and a lower film density and improved mechanical properties are obtained. The laminate film could further have additional layers such as a heat sealable layer disposed on one side of said core layer including an amorphous polylactic acid resin and/or a polylactic acid resin-containing layer disposed on the side of the core layer opposite the heat sealable layer, a metal layer, or combinations thereof.
    Type: Grant
    Filed: November 9, 2012
    Date of Patent: May 2, 2017
    Assignee: TORAY PLASTICS (AMERICA), INC.
    Inventors: Nao Yokota, Mark S. Lee, Claudio M. Paulino
  • Patent number: 9630385
    Abstract: A carrier film of thermoplastic polyester has releasable metal adhesive properties suitable for a metal transfer in which the polyester film is metalized and the metal layer is subsequently transferred to a permanent adhesive-coated substrate. The metal layer is in direct contact with the polyester carrier film and no intermediate release layer is present. Desired metal adhesion is provided by dispersing a suitable surfactant, and optionally, a hydrocarbon wax, uniformly into the polyester film. Surfactant on the outer surface of the carrier film modifies metal adhesion to the polyester such that the metal can be removed in a metal transfer operation.
    Type: Grant
    Filed: June 28, 2013
    Date of Patent: April 25, 2017
    Assignee: Toray Plastics (America), Inc.
    Inventor: Jan Moritz
  • Patent number: 9630383
    Abstract: A laminate film comprising a core layer comprising of a high crystalline propylene homopolymer blended with an amount of hydrocarbon resin; crystalline polyethylene wax; and a fluoropolymer and/or a metal oxide nanoparticle which exhibits excellent transparency and moisture vapor barrier properties. The laminate film could further have additional layers such as a second polyolefin resin-containing layer, or a heat-sealable polyolefin-containing layer, or combinations thereof.
    Type: Grant
    Filed: May 20, 2014
    Date of Patent: April 25, 2017
    Assignee: TORAY PLASTICS (AMERICA), INC.
    Inventors: Shichen Dou, Keunsuk P. Chang
  • Patent number: 9624020
    Abstract: A composite barrier film has a base layer of polyester or polyolefin with a barrier layer modified polyvinyl amine (mPVA). The mPVA is polyvinyl alcohol/polyvinyl amine copolymer crosslinked with citric acid and an optional additional crosslinking agent such as epichlorohydrin. The barrier layer can be applied by deposition of a reactive aqueous solution onto the base layer, heating and drying to remove water and crosslink the reactants. Excellent barrier properties of the film are obtained by applying and crosslinking the barrier layer during the transverse stretching steps of a biaxial oriented polymer film continuous fabrication process. Superior barrier properties are achieved with transverse stretching by a factor of about 3-4 for polyester and 4-10 for polyolefin.
    Type: Grant
    Filed: October 31, 2014
    Date of Patent: April 18, 2017
    Assignee: TORAY PLASTICS (AMERICA), INC.
    Inventors: Tracy A. Paolilli, Joshua Cloutier, John J. Fitch
  • Patent number: 9617059
    Abstract: A composite barrier film has a base layer of polyester with a barrier layer modified polyvinyl amine (mPVA). The mPVA is polyvinyl alcohol/polyvinyl amine copolymer crosslinked with citric acid and an optional additional crosslinking agent such as epichlorohydrin. The barrier layer can be applied by deposition of a reactive aqueous solution onto the base layer, heating and drying to remove water and crosslink the reactants. Excellent barrier properties of the film are obtained by applying and crosslinking the barrier layer during the transverse stretching steps of a biaxial oriented polymer film continuous fabrication process. Superior barrier properties are achieved with transverse stretching by a factor of about 3-4.
    Type: Grant
    Filed: November 15, 2016
    Date of Patent: April 11, 2017
    Assignee: Toray Plastics (America), Inc.
    Inventors: Tracy A. Paolilli, Joshua Cloutier, John J. Fitch
  • Publication number: 20170057727
    Abstract: A composite barrier film has a base layer of polyester with a barrier layer modified polyvinyl amine (mPVA). The mPVA is polyvinyl alcohol/polyvinyl amine copolymer crosslinked with citric acid and an optional additional crosslinking agent such as epichlorohydrin. The barrier layer can be applied by deposition of a reactive aqueous solution onto the base layer, heating and drying to remove water and crosslink the reactants. Excellent barrier properties of the film are obtained by applying and crosslinking the barrier layer during the transverse stretching steps of a biaxial oriented polymer film continuous fabrication process. Superior barrier properties are achieved with transverse stretching by a factor of about 3-4.
    Type: Application
    Filed: November 15, 2016
    Publication date: March 2, 2017
    Applicant: TORAY PLASTICS (AMERICA), INC.
    Inventors: Tracy A. Paolilli, Joshua Cloutier, John J. Fitch
  • Patent number: 9573348
    Abstract: A multi-layer film structure suitable as a sealable sheet used for closing foodstuff containers with a peelable seal. This multi-layer film comprises a polyester substrate layer and a heat-sealable layer. The heat-sealable layer is applied by coextrusion and contains an epoxy-containing thermoplastic polymer composition comprising residues of epoxy-containing monomers selected from glycidyl methacrylate, glycidyl acrylate, allyl glycidyl ether, 3,4-epoxy-1-butene, and a mixture of any two or more of such monomers.
    Type: Grant
    Filed: November 5, 2012
    Date of Patent: February 21, 2017
    Assignee: TORAY PLASTICS (AMERICA), INC.
    Inventor: Stefanos L. Sakellarides
  • Patent number: 9561886
    Abstract: Multi-layer films suitable as sealable or peelable sheet that can be used for closing foodstuff containers are described. These multi-layer films includes a polymeric substrate layer and a seal or a peel-seal layer. The multilayer composite film preferably includes four component layers, namely in order, a polymeric base layer for mechanical strength, a thin organic barrier layer, an ethylene polymer-based adhesive layer, and a heat seal layer including an ethylene copolymer, such as ethylene vinyl acetate copolymer. The film is useful as a peelable heat sealable lid for containers of diverse polymer compositions storing various products such as foodstuffs and pharmaceuticals.
    Type: Grant
    Filed: September 13, 2012
    Date of Patent: February 7, 2017
    Assignee: TORAY PLASTICS (AMERICA), INC.
    Inventors: Tracy A. Paolilli, John J. Fitch, Roberto Siu
  • Patent number: 9561676
    Abstract: A bio-based polyester thin film substrate for thermal transfer printing ribbon. The bio-based polyester thermal transfer ribbon substrate film has a radiocarbon content of at least 12 pMC. The film exhibits excellent uniformity, handling, and processability, substantially equivalent to petroleum-based counterparts, while being derived wholly or partly from non-petroleum sources.
    Type: Grant
    Filed: December 23, 2013
    Date of Patent: February 7, 2017
    Assignee: TORAY PLASTICS (AMERICA), INC.
    Inventors: Stefanos L. Sakellarides, Milan William Moscaritolo
  • Publication number: 20170015821
    Abstract: Described are transparent oriented polypropylene films with improved barrier properties and methods of making these films. The films and methods include a core layer comprising polypropylene, hydrocarbon resin, and polyethylene wax to improve moisture vapor barrier properties, an optional barrier layer comprising polar polymers to improve oxygen barrier properties, and optional skin layers to improve heat sealing, winding, printing, and/or adhesion.
    Type: Application
    Filed: July 13, 2015
    Publication date: January 19, 2017
    Applicant: TORAY PLASTICS (AMERICA), INC.
    Inventors: Shichen DOU, Tracy A. PAOLILLI, Keunsuk P. CHANG
  • Patent number: 9539605
    Abstract: Methods and apparatuses for masking the edges of a substrate when performing direct or reverse gravure coating using a kiss-coat configuration, particularly useful for in-line coating of biaxially oriented polymeric films. The methods and apparatuses include a masking plate configured to prevent the edge of a portion of a substrate from contacting a gravure roll, the masking plate includes a top portion having a Rockwell B hardness equal to or greater than 80, and a thickness of between 0.03125 inches and 0.375 inches. This masking plate prevents build-up of coating on the edges of the substrate which otherwise can cause film orientation production instabilities such as film breaks, sticking to tenter clips, and/or edge trim recycling incompatibilities. The masking plate provides a masking method that is effective and durable, minimizing production downtime and maintenance.
    Type: Grant
    Filed: February 28, 2012
    Date of Patent: January 10, 2017
    Assignee: TORAY PLASTICS (AMERICA), INC.
    Inventors: Jeffrey S. L'Heureux, Joshua R. Cloutier, Will E. Nunn
  • Patent number: 9492962
    Abstract: Described are metallized biaxially oriented polylactic acid (BOPLA) films with a novel formulation that exhibits a softer feel and quieter sound, without jeopardizing film making stability. It has been found that when these films are metallized, moisture barrier properties are surprisingly improved compared to conventional metallized BOPLA films. Specifically, the moisture barrier of the films may be 2.0 g/m2/day or less at 38° C. and 90% relative humidity. The films can be used, for example, in packaging applications. The films have characteristics that are beneficial to converting processes, are economical, and maintain bio-compostability similar to typical BOPLA films.
    Type: Grant
    Filed: March 31, 2011
    Date of Patent: November 15, 2016
    Assignee: TORAY PLASTICS (AMERICA), INC.
    Inventors: Shichen Dou, Mark S. Lee, Claudio M. Paulino, Nao Yokota, Keunsuk P. Chang
  • Publication number: 20160264747
    Abstract: Described is a mono-axially oriented polyolefin film including a core or base layer containing a plurality of voids formed by a cavitating agent, wherein the film is oriented at least 4 times in the machine direction, and exhibits excellent tear resistance in the transverse direction.
    Type: Application
    Filed: February 26, 2016
    Publication date: September 15, 2016
    Applicant: TORAY PLASTICS (AMERICA), INC.
    Inventors: Matthew H. BROWN, Harold Egon KOEHN, Claudio M. PAULINO
  • Publication number: 20160244616
    Abstract: This invention relates to an optically clear film of predominantly thermoplastic polyester base layer and a carbodiimide-crosslinked, polyester and polymethylmethacrylate blend primer layer. The base layer preferably has a particle-free core layer and outer layers containing nonpolyester, organic and/or inorganic particles. The primer layer is preferably applied to the base layer from solution that is organic solvent-free. The primer layer and base layer composite can be laminated with a protective layer of primarily acrylic polymer to form a solar control film. Functional additives, such as UV light blockers, can be present in various layers of the solar control film. Polymethylmethacrylate in the primer, especially in combination with crosslinking by the carbodiimide, provides the acrylic coated polyester base solar control film with notably reduced iridescence. Adhesion between the acrylic layer applied from organic solvent solutions and the polyester layers is durable in moist and warm service conditions.
    Type: Application
    Filed: April 16, 2016
    Publication date: August 25, 2016
    Applicant: Toray Plastics (America), Inc.
    Inventor: Tracy Paolilli
  • Patent number: 9399318
    Abstract: A monoaxially oriented film including a metallized layer; a gas barrier layer; and a propylene-based random copolymer and at least about 3 wt % of a low density polyethylene which is oriented at least about 2.5 times in one direction and exhibits excellent linear directional tear properties parallel to the orientation direction and excellent heat seal performance in terms of high heat seal strengths and low seal initiation temperature. This film formulation and orientation is suitable for pouch applications requiring high gas and moisture barrier, an “easy-tear” linear tear feature, and excellent hermetic seal properties.
    Type: Grant
    Filed: September 12, 2014
    Date of Patent: July 26, 2016
    Assignee: Toray Plastics (America), Inc.
    Inventors: Tracy A. Paolilli, Scott Narkevicius, Harold Egon Koehn, Matthew H. Brown