Abstract: Improved reactors for catalytic, exothermic gas-phase reactions having, viewed in the flow direction of a feed gas, an inlet zone (1), a reaction zone (2) containing at least one catalyst (4), and an outlet zone (3) for the product gas, are described. The reactors are provided in the inlet zone (1) or in the inlet zone (1) and the reaction zone (2) with an insulating liner (6) and/or apparatuses for the transport of cooling media and/or the interior walls of the reactor in the inlet zone (1) or in the inlet zone (1) and the reaction zone (2) consist of inert material. The insulating liner and/or cooling media reduce heat transport from the reaction zone (2) into the inlet zone (1) and thus reduce the risk of preignition of the feed gas mixture used or occurrence of undesirable secondary reactions in the inlet zone (1).

Abstract: With a method for discharging slag from a water bath of a reactor for synthesis gas production, whereby the slag is brought to a lower pressure level by means of a transfer container, a solution is supposed to be created, with which the components connected with transferring the slag out are subject to a low temperature, whereby immediate slag transfer without water exchange is supposed to be made possible, with a minimal required cooling power. This is accomplished in that a cooling water stream is passed to the slag stream in the outlet region of the slag from the water bath of the gas generator or the pressurized container that surrounds it, in a region having a greater cross-section than the cross-section of the entry connector of another system part, such as, for example, the transfer container, in such a manner that temperature stratification in the outlet region is made possible.

Abstract: In the case of a gasification reactor for the production of crude gas, containing CO or H2, by gasification of ash-containing fuel with oxygen-containing gas, at temperatures above the melting temperature of the ash, wherein a reaction chamber formed by a membrane wall through which coolant flows, within a pressure container, subsequently a transition region and a quench chamber are provided, with a slag/water bath following in the direction of gravity, a funnel-shaped slag collection container is provided in the slag/water bath, which container is equipped, in the inflow direction of the slag, with a second funnel-shaped insert as a precipitation cone, the funnel wall of which forms a circumferential ring gap to the slag collection container, and the free border edge of which is positioned above the free border edge of the slag collection container.

Abstract: A process for the recovery of a pure aromatics-containing product is disclosed. This product is obtained by extractive distillation of a gasoline rich in aromatics, in which olefins, diolefins and polyolefins are separated, and this extractive distillation is followed by a hydrogenation of the recovered aromatics-rich, olefin-lean product stream, in which the alkylated aromatics, especially toluene and xylene, are dealkylated and the paraffinic dealkylation products further converted into methane so that a significant portion of hydrogen can be saved by carrying out the hydrogenation subsequent to the extractive distillation, as the aromatics mixture is then free of olefins and no hydrogen is required for an olefin hydrogenation, with extractive distillation and recovery of the extracting solvent taking place in one column. An apparatus for carrying out the process described is also disclosed.

Abstract: The invention relates to a reactor for catalytic reformation of hydrocarbons with steam at elevated pressure, said reactor comprising a reaction space and a fire space, said reaction space comprised of a multitude of vertical tubes arranged in rows and suitable for being filled with a catalyst, and having facilities for feeding hydrocarbons and steam to be reformed to the reaction space, and furthermore comprising facilities for discharge of reformed synthesis gas from the reaction space, and furthermore comprising a multitude of firing facilities in the upper area of the firing space, said firing facilities being able to generate mainly downwardly directed flames that are suitable to heat the aforementioned reaction tubes, with the tube feeding air to the burner being equipped with a facility for adjusting and setting the air flow, and there being a secondary air feeder mounted additionally to this tube and branching-off from it and configured in various layouts and having an independently controllable facil

Abstract: A process for keeping coke oven chambers hot during the stoppage of a waste heat boiler. The coke oven chambers are kept hot after emptying using externally heated burners, in which a flue gas low in pollutants is obtained from the burners. The waste heat boilers which, during normal operation, cool the flue gases can be shut off and overhauled, and a flue gas low in pollutants which can be dissipated directly into the atmosphere is obtained by the burner operation. Also disclosed is an apparatus for keeping coke oven chambers hot, the apparatus has a coke oven chamber bench, a flue gas collection line, a flue gas chimney, a waste heat boiler, a waste gas collection line and a waste gas purification system, wherein the flue gas chimney and the waste heat boiler can be shut off on the flue gas side and on the waste gas side.

Abstract: A gasification reactor for producing crude gas, containing CO or H2, by gasification of ash-containing fuel with oxygen-containing gas, at temperatures above the melting temperature of the ash, has a reaction chamber formed by a membrane wall through which coolant flows, within a pressure container, is provided, with a narrowing transition channel into a gas cooling chamber, and spin-reducing, cooled bulkheads in the transition channel. The, wall that carries the bulkheads makes a transition, below the bulkheads, into a cylinder wall that is reduced in diameter, by way of a step having a corrugated surface. The cylinder wall, which is reduced in diameter, is enclosed by a further cylindrical wall, which is enlarged in diameter, which wall forms a second slag drip edge at its end, in the direction of gravity. The further cylindrical wall is disposed to be adjustable in its vertical position, with reference to the first drip edge.

Abstract: A methane-rich gas from synthesis gas is made in a methane reactor with a row of methanation stages and, at an upstream end of the row of methanation stages, a CO conversion stage. An incoming stream of synthesis gas containing CO and H2 is split into a plurality of partial streams, one of which is fed to the reactor upstream of the CO conversion stage. Each of the other partial syngas streams is fed to the reactor upstream of a respective one of the methanation stages such that methanation takes place in each of the methanation stages and gas exits from the stages and mixes with the partial syngas stream being fed to the next downstream stage. A plurality of partial streams are diverted from a product-gas stream issuing from the furthest downstream stage and are each fed to the reactor upstream of a respective one of the methanation stages.

Abstract: A device for feeding and controlling secondary air from secondary air ducts into flue gas channels of horizontal coke oven chambers is shown. The flue gas channels are located underneath the coke oven chamber floor on which coal carbonization is realized. The flue gas channels serve for combustion of partly burnt coking gases from the coke oven chamber. The partly burnt gases are burnt with secondary air, thus heating the coke cake also from below to ensure even coal carbonization. Secondary air comes from the secondary air ducts connected to atmospheric air and to the flue gas channels. Controlling elements are mounted in the connecting channels between the flue gas channels and secondary air ducts which can precisely control the air flow into the flue gas channels. Thereby, it is possible to achieve a much more regular heating and heat distribution in coke oven chambers. The actual controlling devices in the connecting channels can be formed by turnable pipe sections, wall bricks, or metal flaps.

Abstract: A method for reducing the coking time in the oven area near the door or end wall and for improving coke quality and situation of emissions by compensating for radiation losses through coke oven chamber doors and end walls is described. This compensation is accomplished by varying the height of the coal cake in the environment of the frontal coke oven chamber doors. The variation is achieved both by increasing or decreasing the coal cake over part of the length or over the entire length of the coke oven chamber door. The reduction in the height of the coal cake can be generated by omission of coal or coal compacts, the increase in height can be accomplished by stacking of coal and pressing or adding of coal compacts, with it also being envisaged to omit the pressing cycle so as to obtain a recess with a lower coal cake density which also has less heat radiation.

Abstract: The invention relates to a method for simultaneously producing iron and a crude syngas containing CO and H2 by means of a blast furnace that is charged with iron ore and carbon-containing reducing agents. The amount of carbon-containing reducing agents fed to the blast furnace is greater than the amount of fuel required for producing the iron. Technically pure oxygen is fed into the blast furnace for the blast furnace process and for producing the crude syngas. In addition, CO2 and/or steam are fed to the blast furnace in order to control the ratio between CO and H2 in the crude syngas discharged from the blast furnace as top gas and/or moderate the temperature at which the oxygen is injected.

Abstract: A device for proportioning of secondary combustion air into the secondary air soles of coke oven chamber ovens is shown. The device is formed by a slide gate or a parallelepiped device or by plates moved by means of a thrust bar, the thrust bar being moved longitudinally in parallel to the coke oven chamber wall so that the plates move away from the secondary air apertures and open or close these. The thrust bar is moved by means of a positioning motor, with the power transmission being effected hydraulically or pneumatically. Via suitable measuring parameters, it is thus possible to optimize secondary heating so that heating is provided evenly from all sides, thus achieving an improvement in coke quality.

Abstract: A process for removing, isolating and purifying dicarboxylic acid from fermentation broths, which includes the following steps: 1) removal of the biomass and any solids present from the fermentation broth in two successive stages, 2) removal of the dicarboxylic acid solution from the biomass-free fermentation broth by simulated moving bed (SMB) chromatography, 3) fine purification of the dicarboxylic acid solution, 4) multistage evaporative concentration and crystallization, and 5) separation and drying of the crystals.

Abstract: A mixture of cyclic diesters derived from lactic acid and in cases a mixture of a racemate of dilactide may be produced in several different processes. In some instances, the process can thereby start from the corresponding alpha-hydroxycarboxylic acids, the corresponding cyclic diesters or oligomers of the corresponding alpha-hydroxycarboxylic acids.

Abstract: Improvement in carbonization in a carbonization furnace and simultaneous reduction in NOx emissions is achieved by recirculation of waste gas from a coking oven back to the oven chamber, the downcomers, or the sole channel system.

Abstract: With a method for supplying an entrained-flow gasification reactor with carbonaceous fuel for the production of a gas that contains CO and H2 and flue ash under pressure and at a temperature above the melting point of the ash, wherein the resulting gas is passed to further treatment stages, particularly at least one synthesis stage, the waste gas that is derived from the subsequent treatment stage and still contains hydrocarbons and/or hydrogen is used for pneumatic conveying of the fuel into the entrained-flow gasification reactor.

Abstract: A device for compensating deviations from a coaxial arrangement of components of a regulating organ, said regulating arrangement being comprised of a regulating organ, a crown pipe, and an immersion cup which serve for controlling the gas pressure of a coke oven chamber, with the regulating arrangement being comprised of an immersion cup with a water immersion that seals the gas space of a coke oven chamber versus the gas collecting main and/or plant units downstream, and wherein the height of the water level of the water immersion represents a regulating means to control the gas pressure, and wherein said regulating arrangement is furthermore comprised of an immersion pipe that configures a specially shaped crown pipe at its end submerging into the water of the immersion cup, and that is comprised of a regulating organ to regulate the water level.

Abstract: A method for removing acid gases from a fluid flow using an absorbent including an aqueous solution with at least two different amines. An amine in a proportion of greater than 50 wt. % of the total amine amount in the aqueous solution is the first amine component in the aqueous solution, and a sterically hindered amine in a proportion of less than 50 wt. % is the second amine component in the aqueous solution. The fluid flow is brought into contact with the absorbent at a partial pressure of <200 mbar.

Abstract: A method for producing individual compacts made of coke and suitable for coke oven chambers by dividing a coal cake in a non-mechanical manner, wherein the coal cake is produced by a compression method according to the prior art and the coal cake is divided by non-mechanical, energy-supplying media, and the non-mechanical media supplying shearing energy are, for example, a laser beam, a high-pressure water jet, an abrasive-solid jet, an ultrasonic beam, a compressed-air jet, or a gas jet. By using the method, coal compacts can be produced from coal cakes without forming dust, without wearing out cutting tools, and with high precision.

Abstract: A process for the discharge of slag and ash from a gasification reactor is disclosed. These solids are directed from the gasification reactor into a water bath housed with the gasification reactor in a pressure vessel. There are at least two lock hoppers underneath the water bath which are fed with a stream of water/solids via a pipe and a flow divider element, it being possible to supply the lock hoppers individually and in a controlled manner with a stream of water/solids via shut-off devices. The filling is performed in a manner that encourages the sett-ling process by withdrawing a stream of liquid from the lock hopper being filled, the filling time being controlled so as to prevent the solids settling above the valves and lock hoppers. Also disclosed is an apparatus with at least two lock hoppers underneath the water bath of a gasification reactor, there being, in an advantageous embodiment, a flow divider element and shut-off devices between the water bath and the lock hoppers.