Abstract: The invention relates to a process for producing a methane-containing gas from synthesis gas, wherein a synthesis gas containing carbon monoxide and hydrogen is fed for methanation to a reactor system (1) having a catalyst material, wherein the process gas stream leaving the reactor system (1) is divided into a product gas stream and a recycle gas stream, and wherein the recycle gas stream, for compensation of the pressure drop, is transported through an ejector (5) and for cooling is passed together with the synthesis gas into the reactor system (1). According to the invention, the product gas stream is compressed to a pressure which is greater than the pressure of the synthesis gas that is fed to the reactor system (1). Either compressed product gas or industrial gas from an industrial gas pipe system (9) is fed as propellant medium to the ejector (5). The invention also relates to a methane production plant for carrying out the process.

Abstract: The invention is directed to a process for the removal of ammonia from an ammonia-containing gas stream by treating the ammonia in the ammonia-containing gas stream with an acid, during which treatment an aqueous stream comprising an ammonium salt, wherein the aqueous stream comprising the ammonium salt is treated with electrodialysis, whereby the acid is recovered and an aqueous stream comprising an ammonium hydroxide salt is formed.

Abstract: A coke oven of horizontal construction (non-recovery/heat recovery type) includes at least one coking chamber, laterally arranged vertical downcomers as well as bottom flues arranged horizontally and extending underneath the coking chamber for indirect reheating of said coking chamber. One or more gas space dividing walls are arranged in the oven free space which in the intended operation of the coke oven is not destined for being filled with solid matter so that the gas routing is improved and a homogenisation of radiation in the coking chamber is achieved.

Abstract: A device for removing slag from a coal gasification or synthesis gas production process and a slag water bath is enclosed by the reaction vessel The slag is discharged by means of a lock-type transfer vessel arranged located downstream of the slag bath. A vessel includes an upper and a lower cylindrical section, the upper cylindrical section having a diameter larger than that of the lower cylindrical section and both sections are connected by a tapered section which preferably is conical in shape, the angle of the cone being similar to that of the angle of repose of the slag. A process for removing slag from a coal gasification reactor the process including a discharge of slag from the coal gasification reactor to a transfer vessel which precludes formation of slag incrustations in the transfer vessel is also defined.

Abstract: A process for removing silicon compounds from aqueous NaCl brine includes, first, adjusting a weak brine to a pH value of less than 3 with hydrochloric acid. Iron(III) chloride or other trivalent iron ions are added to the acidified weak brine, the obtained weak brine is then continuously fed to a stirred dissolution vessel which contains undissolved salt in addition to brine. Fresh salt is charged batch-wise and intermittently to the dissolution vessel to produce strong brine. The obtained strong brine is fed to a stirred buffer vessel, the pH value in this buffer vessel being maintained at a level ranging from 5 to 8. A strong-brine flow is continuously withdrawn from the buffer vessel and filtered, and the filtrate containing the added iron and silicon is discharged. Also a system for carrying out this process is disclosed.

Abstract: Method of concentrating aqueous alkali and apparatus suitable for this purpose. A very energy-saving method of concentrating aqueous alkali originating, for example, from a chloralkali electrolysis plant and an apparatus suitable for this purpose are described. The method/the apparatus utilizes heat of reaction from the formation of 1,2-dichloroethane and includes multistage concentration of the aqueous alkali, where at least part of the heat required for concentrating the aqueous alkali originates from the plant for preparing 1,2-dichloroethane and at least a further part of the heat required for concentrating the aqueous alkali originates from at least one of the higher stages of the plant for concentrating the aqueous alkali and is used for partial heating of the first stage. The apparatus can be used for retrofitting existing integrated plants made up of a DCE plant and chloralkali electrolysis or in the erection of new plants.

Abstract: A method of starting up an autothermal reactor for the production of synthesis gas by reforming of hydrocarbon-containing feed gases in a reaction chamber in which oxidation reactions and reforming reactions are carried out, by feeding a hydrocarbon containing feed gas, steam and an oxidant.

Abstract: Process for operating a distillation column for the removal of water and lower-boiling components than 1,2-dichloroethane from 1,2-dichloroethane in which at least part of the heat from condensation of the aqueous vapors from the distillation column is used to concentrate caustic soda solution by evaporation; furthermore, at least part of the 1,2-dichloroethane formed when chlorine and ethylene react in a direct chlorination unit is used to heat said distillation column and can subsequently also be used as a heat transfer fluid to concentrate caustic soda solution by evaporation.

Abstract: The invention relates to a method and a system for operating a Fischer-Tropsch synthesis, wherein a feed gas comprising CO and H2 from coal gasification (1) is desulfurized and subsequently fed into a Fischer-Tropsch synthesis as an input gas, wherein hydrocarbons are formed from carbonic oxides and hydrogen by catalytic reactions. The hydrocarbons are separated as liquid products (4), and a gas flow comprising CO and CO2 exiting the Fischer-Tropsch synthesis unit (3) is compressed and fed into a conversion stage, wherein CO and steam are transformed into H2 and CO2. In the method according to the invention, the gas exiting the conversion stage is fed back into the Fischer-Tropsch synthesis unit as a gas rich in H2, together with the desulfurized input gas, after the gas is prepared in that CO2 and/or further components other than H2 are removed.

Abstract: A porously coated, densely sintered ceramic membrane, which can be produced from a green membrane and subsequent sintering. The membrane is coated with ceramic material, which contains noble metals, which can be produced by application and subsequent thermal treatment. The noble metals are contained at a concentration of 2.5 to 5 mass percent.

Abstract: A device for latching of horizontal coke oven chambers which is triggered by an auxiliary frame located on the coke oven chamber door is provided. The auxiliary frame is restrictively movable in vertical direction on the coke oven chamber door. During the outward movement, the auxiliary frame hits upwardly against limit stop cams firmly mounted on the oven door and transmitting the vertical traction force onto the coke oven chamber door. During the upward movement, the auxiliary frame actuates levers which are rotationally movable to an axis arranged orthogonally to the coke oven chamber and which are connected to a translatorily freely movable latch. On actuation of this lever, it pulls the latch from the latch take-up bearings mounted on the coke oven chamber door so that the coke oven chamber door is unlatched and opened. In an embodiment of the present invention, the coke oven chamber door can be arrested the open or closed position with a device suitable for this purpose.

Abstract: A coal-charging larry cart for lifting lids out of charging holes in the roof of a coke oven and for cleaning the charging-hole jambs has a lid lifter with a lift magnet and a jamb cleaner with a cleaning head. Respective travel frames are horizontally movable on rails on the cart in a first horizontal direction, and respective support frames inside the respective travel frames are each movable relative to the respective travel frame in a second horizontal direction transverse to the first direction. Respective carriages horizontally displaceable in the first direction on the support frames carry the support arms for horizontal movement of each of the support arms relative to the respective support frame between an operating position in which the lift magnet or the cleaning head is aligned with a charging hole in the roof of the coke oven and a rest position spaced from the charging hole.

Abstract: A process is disclosed for removing acid gases from a gas stream, in particular from a natural gas stream, synthesis gas stream or the like, wherein the acid gases are absorbed from the gas stream by at least one absorbent. The absorbent used is a mixture of a physical scrubbing agent, a chemical scrubbing agent and water. The absorbent comprises more than 60% by weight of the physical scrubbing medium, wherein the physical scrubbing medium used is a morpholine derivative and a chemical scrubbing agent based on at least one aliphatic amine compound which includes a polyethylene glycol substituted amine.

Abstract: A method of removing acid gases from raw gas is disclosed in which the raw gas is supplied to an absorption column where it is contacted with a physical absorption agent, having a boiling point lower than 100° C. at atmospheric pressure, under elevated operating pressure to load, the physical absorption agent with acid gases and usable gases and then the physical absorption agent loaded with acid gases and usable gases is driven from the absorption column at its sump while drawing off at the head of the absorption column a purified top gas containing up to a few ppm of acid-gas components. Following the absorption, the physical absorption agent undergoes stripping to remove usable gases, and regeneration to remove the acid gases as well as to provide a regenerated physical absorbent which may be used to treat additional raw gas.

Abstract: A device for regulating the chamber pressure of coking chambers of a coke-oven battery using adjustable iris diaphragms or iris nozzles at the ascending pipe elbow openings in the raw gas receiver. The gas stream flowing from the gas chamber of a coking chamber into the raw gas receiver can thus be regulated so that the pressure in the gas chamber of the coking chamber can be controlled. A method is also disclosed for regulating the gas stream which flows out the gas chamber of a coking chamber, wherein the pressure in the coking chamber is regulated by the control, and wherein also the liquid stream is regulated which serves to wash out the coking gases from the raw gas stream of the coking chamber.

Abstract: A device for increasing the interior surface of a compact coke charge in a receiving trough, which device increases the interior surface of a coke cake or coke leaving the coking chamber by mechanically breaking apart or roughening it, resulting in a break-up of the coke structure and the formation of crevice-type cavities in the compacted coke charge so that an increased amount of water can flow into the interior of the coke charge during the subsequent quenching step through these crevices, resulting in a high profitability of the method due to reduced quenching times and lower water consumption. A method for increasing the interior surface of a compact coke charge in a receiving trough, which serves to break up a fresh coke cake or to roughen the coke in order to reduce water consumption during quenching is disclosed.

Abstract: An apparatus (1) and method for drying polymer powders is described. The apparatus has an inlet (2) and an outlet (3) for the polymer powder, heat registers (5) installed in the interior space (4) and lines (7) for a heated gas (6a) for drying the polymer powder. The lines open into the interior space (4) and are connected to heat exchangers (9) for heating gas (6). The heat exchangers (9) are connected to a plant for the preparation of 1,2-dichloroethane (15) and/or for the preparation of vinyl chloride from 1,2-dichloroethane so that thermal energy from the plant can be utilized for heating the gas (6). The method comprises treatment of a polymer powder with a heated gas (6a) in the drying apparatus (1).

Abstract: The invention relates to a process for the biological purification of coking plant wastewater that is loaded with nitrogen compounds, cyanides, phenols and sulphides. The coking plant wastewater, for removal of pollutants that inhibit a nitrification, is fed together with a biomass-containing stream of matter to a detoxification reactor that has a gas-treatment zone and a reaction zone. The feed mixture supplied to the detoxification reactor is exposed in the gas-treatment zone to a gaseous oxidizing agent. A stream of matter enriched with the oxidizing agent is fed to the reaction zone in which cyanides and other pollutants inhibiting the nitrification are biodegraded. A stream of matter is withdrawn from the reaction zone and returned to the detoxification reactor. In addition, a wastewater stream from the detoxification reactor is separated by a membrane filtration into a biomass-containing retentate stream and a purified permeate stream.

Abstract: Coal compacts which are suitable for coking in coke oven chambers are prepared by pressing and compacting coal in a pressing device having a design which shapes the surface of the coal compacts to provide higher surface area. Already compacted coal blocks can be pressed to generate the surface shape. The resulting coal compacts exhibit significantly improved properties during the coking process, resulting in improved gas and heat exchange. A device for compacting coal preferably contains a plate provided with shaping elements on the pressing surface.

Abstract: A process and device is provided for the generation and purification of a crude gas for synthesis gas generation from a solid carbon-containing fuel by a coal gasification reaction. The fuel is mixed with a quenching medium directly after generation to dissipate the internal energy and is then brought into contact with a compound or a sorbent in the mixing chamber or downstream of the mixing chamber such that the acidic or basic or sulphur-containing or halogen-containing constituents contained in the crude gas and originating from the gasification reaction are absorbed. A solids-separating device removes the solid or solidified constituents from the system. The sorbent can be regenerated and returned to the process such that an energy-intensive cooling of the crude gas is not required for its purification and the synthesis gas thus purified can be used in a subsequent process without any further heating.