Patents Assigned to Union Carbide Corporation
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Patent number: 4857218Abstract: Lubricant compositions having good dilution viscosity characteristics and high viscosity/pressure coefficients can be produced using a connected branch copolymer having a core segment, non-crosslinked branched polymer segments connected to the core segment and a group of linear polymer segments connected to the branched polymer segments and bearing terminal groups capable of effecting hydrogen bonding. These connected branch copolymers are used in aqueous lubricant compositions, which may include a co-solvent such as ethylene or diethylene glycol.Type: GrantFiled: August 22, 1985Date of Patent: August 15, 1989Assignee: Union Carbide CorporationInventors: Debra J. Meschke, Kenneth L. Hoy
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Patent number: 4857232Abstract: A cable conductor shield composition comprising (i) ethylene-vinyl acetate copolymer wherein the vinyl acetate is present in an amount of about 8 to about 14 parts by weight and (ii) the following components in about the following parts by weight, all based on 100 parts by weight of copolymer:______________________________________ Components Parts by Weight ______________________________________ polyethylene having a density 29 to 36 of about 0.90 to about 0.95 carbon black having a surface 19 to 25 area of about 650 to about 1200 square meters per gram an antioxidant at least 0.1 a processing aid at least 0.1 an organic peroxide curing agent at least 0.Type: GrantFiled: March 23, 1988Date of Patent: August 15, 1989Assignee: Union Carbide CorporationInventor: Norman M. Burns, Jr.
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Patent number: 4857150Abstract: A process for the recovery of silicone oil and chlorobenzenes from a mixture containing silicone oil, chlorobenzenes, and polychlorinated biphenyls comprising:(a) introducing the mixture into a distillation zone at a temperature and a pressure which will cause the chlorobenzenes to flash overhead and the mixture of silicone oil and polychlorinated biphenyls to pass to the bottom of the zone; and(b) removing the bottoms from step (a), cooling same, and passing the bottoms through at least one bed of activated carbon, which is an adsorbent for polychlorinated biphenyls.Type: GrantFiled: June 22, 1988Date of Patent: August 15, 1989Assignee: Union Carbide CorporationInventors: Steven E. Rival, William D. Prince
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Patent number: 4857579Abstract: Described herein are curable molding compositions comprising a mixture of:I. from about 25 to about 90 weight percent of a thermosetting resin containing:(a) from about 5 to about 95 weight percent of a polyester resin derived from the reaction of a poly(acrylate) and a vinyl monomer, said poly(acrylate) and vinyl monomer essentially free from functional groups reactive with the polyol or the polyisocyanate of (b);(b) from about 95 to about 5 weight percent of a polyurethane derived from the reaction of a saturated polyol and a polyisocyanate, said polyol and polyisocyanate free from unsaturated groups capable of copolymerizing with the poly(acrylate) or vinyl monomer of (a); andII. from about 75 to about 10 weight percent of one or more fibers with a melting point or a glass transition temperature above about 130.degree. C.; wherein (b) constitutes less than 40 weight percent of (I) and (II).Type: GrantFiled: November 25, 1987Date of Patent: August 15, 1989Assignee: Union Carbide CorporationInventor: Linda A. Domeier
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Patent number: 4857600Abstract: A process for grafting an anhydride of an unsaturated aliphatic diacid onto a polyolefin comprising:(a) passing molten polyolefin through at least two injection zones connected in series;(b) injecting, under grafting conditions, a portion of a solution comprising the anhydride, an organic peroxide catalyst, and an inert organic solvent into the molten polyolefin as it passes through each injection zone, and mixing same in each injection zone until the portion is at least partially grafted onto the polyolefin; and(c) passing the grafted polyolefin, in the molten state, into a devolatilization zone, and mixing same in said zone, under devolatilization conditions, until the grafted polyolefin is essentially devolatilized.Type: GrantFiled: May 23, 1988Date of Patent: August 15, 1989Assignee: Union Carbide CorporationInventors: Laurence H. Gross, Thorne M. Bartlett
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Patent number: 4856285Abstract: This invention pertains to a method and apparatus for cooling and freezing of organic-comprised articles which makes use of liquid cryogen and of chilled gases from a mechanical refrigeration system to provide an economical process for reducing the temperature of the article. The article is contacted with a liquid cryogen and subsequently contacted with circulating cold gases in the mechanical refrigeration system. The improvement relates to the method and apparatus for producing the cold gases which are used in the mechanical refrigeration system; the method comprises using the cryogen vapors generated upon contact of the articles with the liquid cryogen as an indirect heat exchange fluid for removing heat from heat exchange fluids used in the mechanical refrigeration system. This indirect heat transfer using cryogen vapors supplements cooling of the mechanical refrigeration system cold gases by the mechanical refrigeration system chiller.Type: GrantFiled: September 20, 1988Date of Patent: August 15, 1989Assignee: Union Carbide CorporationInventors: Arun Acharya, Michael A. Marchese, Jeffert J. Nowobilski
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Patent number: 4857692Abstract: A spray mode gas metal arc welding process employing a shielding gas mixture consisting essentially of (A) 3 to 8 volume percent carbon dioxide, (B) 30 to 40 volume percent argon and (C) the balance helium.Type: GrantFiled: August 17, 1988Date of Patent: August 15, 1989Assignee: Union Carbide CorporationInventors: Nils E. Larson, David B. Leturno, Lawrence W. Cherne
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Patent number: 4857583Abstract: An improved process is provided for the preparation of siloxane-oxyalkylene block copolymer surfactant compositions which utilized a hydrosilation reaction with high boiling point polar polyols as the reaction solvent. The reaction solvent need not be removed from the block copolymer, particularly when the block copolymer is used as a surfactant for polyurethane foam formulations. Dipropylene glycol is the preferred polar solvent and when used in the preparation of the surfactants need not be removed when the surfactants are employed in the preparation of urethane foams.Type: GrantFiled: July 2, 1987Date of Patent: August 15, 1989Assignee: Union Carbide CorporationInventors: Paul E. Austin, David D. Farris, James D. Reedy, Charles Blevins, Philbert E. Ramdatt
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Patent number: 4857250Abstract: Method of and apparatus for making a shaped crosslinked extruded polymeric product by extruding compacted, melted polymer, e.g., polyethylene, into a mixer formed on or fitted to the discharge end of an extruder, injecting proportionate amounts of a mixture of compounding ingredients including olefinically unsaturated hydrolyzable silane, free-radical generator and, preferably, a silanol condensation catalyst into the compacted, melted polymer. The polymer and compounding ingredients are blended in the mixer until the silane is grafted to said polymer, and the resulting grafted polymer mixed with the silanol condensation catalyst is extruded thruugh a die to form the product of the required final shape. The resulting product is subjected to the action of H.sub.2 O until the grafted polymer is crosslinked.Type: GrantFiled: April 13, 1984Date of Patent: August 15, 1989Assignee: Union Carbide CorporationInventors: George M. Gale, Aldo A. Sorio
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Patent number: 4855379Abstract: Novel siloxane-polyether polymers are provided containing cyclic siloxanes which are useful in silicone surfactants for foam polyurethane foam applications. The novel polymers are prepared by reacting a polyhydridosiloxane polymer with a cyclic polysiloxane containing a vinyl group and with an allyl started polyoxyalkylene polymer in the presence of a platinum catalyst. The resulting polymeric products are highly potent and impart flat breathability profiles to foams when used as surfactants in their preparation.Type: GrantFiled: March 8, 1988Date of Patent: August 8, 1989Assignee: Union Carbide CorporationInventors: Richard A. Budnik, Gerald J. Murphy
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Patent number: 4855070Abstract: A water-glycol energy transmitting fluid having a viscosity of from about 10 to about 200 centistokes at 40.degree. C. comprising:(a) from about 30 to about 40 percent by weight, based upon the total weight of the fluid, of water,(b) diethylene glycol,(c) from about 0.8 to about 5.0 percent by weight, based upon the total weight of fluid, of an aliphatic carboxylic acid having 9 to 12 carbon atoms,(d) a water-soluble polymeric viscosity control agent,(e) A corrosion inhibiting amount of at lease one corrosion inhibitor, and(f) a metal deactivator.Type: GrantFiled: September 16, 1988Date of Patent: August 8, 1989Assignee: Union Carbide CorporationInventor: Walter E. F. Lewis
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Patent number: 4855403Abstract: Capped connected branch copolymers are provided comprising a core segment, branched polymer segments attached to the core segment, linear polymer segments attached to the terminals of the branched polymer segments, and cap segments, which comprise residues of an alkylene oxide containing at least 4 carbon atoms and which are attached to the free terminals of the linear polymer segments. These capped copolymers are less water-soluble than the uncapped connected branched copolymers from which they are derived, and are useful in carbonless copying systems as carriers for the color precursor microcapsules. The microcapsules can be applied to the carbonless copying sheet by dispersing the microcapsules in the capped copolymer, heating the copolymer above its transition temperature and spreading the melted copolymer over the sheet. After cooling, the copolymer forms a coherent layer on the sheet.Type: GrantFiled: August 22, 1985Date of Patent: August 8, 1989Assignee: Union Carbide CorporationInventors: Debra J. Meschke, Kenneth L. Hoy
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Patent number: 4855329Abstract: A polysiloxane-polyoxyalkylene composition of the nominal formula: ##STR1## wherein R is an alkyl group having 1 to 3 carbon atoms and R.degree., R', R" and R'" are individually monovalent polyoxyalkylene polyethers attached to the silicon atom through a difunctional link; and,the polyoxyalkylene of R' is a poly(oxyethylene-oxypropylene) ether which contains 20% to 60% oxyethylene by weight and has an average molecular weight of from about 3,000 to about 5,500;the polyoxyalkylene of R" is a poly(oxyethylene-oxypropylene) ether which contains 20% to 60% oxyethylene by weight and has an average molecular weight of from about 800 to about 2,900; andthe polyoxyalkylene of R'" is a polyoxypropylene polyether having an average molecular weight from about 130 to about 1200;R.degree.Type: GrantFiled: November 17, 1988Date of Patent: August 8, 1989Assignee: Union Carbide CorporationInventors: Charles H. Blevins, II, William B. Herdle, Gerald J. Murphy
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Patent number: 4855370Abstract: A method for reducing sheeting during polymerization of alpha-olefins in a low pressure fluidized bed reactor utilizing titanium or vanadium based compounds as catalysts together with alkyl aluminum cocatalysts wherein water is introduced water into said reactor in an amount sufficient to maintain the electrostatic levels at the site of possible sheet formation at levels which avoid sheeting without substantially altering the effectiveness of said catalysts.Type: GrantFiled: October 1, 1986Date of Patent: August 8, 1989Assignee: Union Carbide CorporationInventors: John R. Chirillo, Kellam C. Kimbrough, II, Peder E. McHattie
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Patent number: 4853356Abstract: A process for the trimerization of an olefin selected from the group consisting of ethylene, propylene, 1-butene, and mixtures thereof comprising passing the olefin in contact with a catalyst comprising the reaction product of (i) a chromium compound, which will provide active catalytic species under trimerization conditions; (ii) a hydrocarbyl aluminum hydrolyzed with about 0.8 to about 1.1 moles of water per mole of aluminum compound; and (iii) a donor liquid selected from the group consisting of hydrocarbyl isonitriles, amines, and ethers wherein the aluminum to chromium mole ratio is in the range of up to about 200 to one and the ligand to chromium mole ratio is in the range of up to about 100 to one.Type: GrantFiled: August 22, 1988Date of Patent: August 1, 1989Assignee: Union Carbide CorporationInventor: John R. Briggs
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Patent number: 4852358Abstract: The present invention comprises a method and apparatus to be used in the cryogenic fast freezing of organic comprised articles such a biologicals and foodstuffs. The method enables control of the time-temperature profile of an article as it progresses through the freezing process, and thus provides the highest quality frozen article. The method requires at least two applications of liquid cryogen to the surface of the article during the freezing process, wherein the applications of liquid cryogen are spaced in time in a manner which essentially prevents thermal cracking and embrittlement of portions of the article, while simultaneously ensuring that a frozen crust which operates as a barrier to water conduction or transmission out of the article remains on the articles throughout the freezing process. In addition, the method and apparatus provide an improved efficiency of operation in terms of utilization of the cryogenic medium within the freezing process.Type: GrantFiled: July 16, 1988Date of Patent: August 1, 1989Assignee: Union Carbide CorporationInventors: Arun Acharya, Jeffert J. Nowobilski
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Patent number: 4851499Abstract: A process for reducing the odor of isotactic polypropylene containing an odor producing unsubstituted or substituted benzoic acid ester by admixing molten isotactic polypropylene with a compound capable of undergoing transesterification with the odor producing ester, said transesterification compound being (i) a partially esterified glycerol; (ii) an expoxide; (iii) a monofunctional or polyfunctional alcohol; (iv) an aliphatic acid ester; or (v) mixtures thereof wherein the transesterification compound is of such functionality and/or of sufficient molecular weight to yield an ester of a molecular weight of at least about 300 upon undergoing ester interchange with said odor causing benzoic acid ester.Type: GrantFiled: September 29, 1987Date of Patent: July 25, 1989Assignee: Union Carbide CorporationInventor: Mahmoud R. Rifi
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Patent number: 4848094Abstract: The present invention relates to a method and apparatus for the generation of essentially spherical frozen droplets of a liquid biological or organic-comprising composition. The liquid composition if fed under positive pressure through a nozzle in a manner which provides a continuous stream of the liquid composition exiting the nozzle; the continuous stream travels through a gas or vapor for a distance sufficient to cause the continuous stream to break apart, forming droplets ranging in size from about 0.6 mm to about 5 mm; the liquid composition droplets are then contacted with a cryogenic liquid capable of freezing the droplets into a solid phase; the frozen droplets are concentrated into a portion of the contacting cryogenic liquid from which they are subsequently separated.Type: GrantFiled: April 29, 1988Date of Patent: July 18, 1989Assignee: Union Carbide CorporationInventors: Robert B. Davis, Donald L. DeVack
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Patent number: 4849263Abstract: This invention relates to a method of pretreatment of inorganics, such as fibers, with members of a class of N-silyl substituted 1-sila-2-azacyclopentane compounds and to a process for making composite materials therefrom. In a preferred embodiment of the instant invention, the pretreatment of fiberglass with 1,1-dimethoxy-2-(trimethoxysilyl)-1-sila-2-azacyclo-pentane is disclosed.Type: GrantFiled: June 30, 1987Date of Patent: July 18, 1989Assignee: Union Carbide CorporationInventors: Enrico J. Pepe, Pedro M. Tarin
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Patent number: 4849559Abstract: A process is provided for the preparation of the dimer, dichloro-[2,2]paracyclophane, which is useful as the starting material for the deposition of conformal parylene coatings employed, for example, in the electronics industry for the protection of various sensitive electronic components.The process avoids the normally low yields of chlorinated dimer formed by the chlorination of 2,2-paracyclophane and instead utilizes the Hofmann elimination of 2(3)-chloro-p-methylbenzyltrimethylammonium hydroxide by conducting the elimination reaction under carefully controlled conditions of reaction temperature and profile, reaction feed configuration, water concentration in the reactor and the use of a cosolvent, certain reaction promoters, or a combination thereof.Type: GrantFiled: May 15, 1987Date of Patent: July 18, 1989Assignee: Union Carbide CorporationInventors: Chinsoo Lee, David R. Bassett