Abstract: A Group IIA metal-Group IIIA metal-silicon substantially homogeneous liquid alkoxide is prepared from a reaction mixture of a Group IIA metal, a Group IIIA metal, a silicon tetraalkoxide, and a liquid defined by the formula ROR' where R is an alkyl group and R' is hydrogen or an alkyl group. The alkoxide can then be hydrolyzed, azeotropically distilled, dried, milled, and calcined to produce a ceramic powder. Advantageously, the ceramic powder can be compacted and sintered at relatively low temperatures which enable it to be used in electrical applications where high sintering temperatures would be deleterious.

Abstract: A process for purifying tertiary organophosphites by removing secondary organophosphites therefrom.

Abstract: The present invention is directed to a method for crosslinking reactive polyolefins using a rhodium catalyzed hydrosilation reaction and novel siloxanes as crosslinkers.Also disclosed are novel siloxane compounds which are useful in the crosslinking of polyolefins and polyolefin compositions which have been crosslinked through use of the claimed process and siloxane crosslinkers.

Abstract: A process is described for recovering polyester-grade ethylene glycol from crude ethylene glycol containing at least one component which has a normal boiling point below that of ethylene glycol, and which can form a UV absorber in the presence of ethylene glycol which comprises supplying to an ethylene glycol distillation system, preferably comprising a fractional distillation zone having an upper portion, a lower portion and an intermediate portion a crude ethylene glycol stream at a determined pH of less than about 7.

Abstract: Method for replacing a coolant containing PCB in electrical induction apparatus having a tank containing the PCB-containing coolant, an electrical winding and porous solid cellulosic electrical insulation immersed in, and impregnated with, the PBC-containing coolant with a substantially PCB-free permanent coolant to convert said electrical apparatus into one in which the rate of elution of PCB into the PCB-free coolant is below the maximum allowable rate of elution into the coolant of an electrical apparatus rated as non-PCB comprising steps of: (a) draining the PCB-containing coolant from said tank; (b) filling the tank with an interim dielectric cooling liquid; (c) electrically operating the apparatus; (d) thereafter draining the interim dielectric cooling liquid containing the eluted PCB from the tank; (e) repeating the cycle of steps (b), (c) and (d) a sufficient number of times until the PCB elution rate does not exceed the rate of 50 ppm PCB based on the weight of the permanent coolant after 90 days of

Abstract: The present invention is directed to an improved process for producing ultra high purity polycrystalline silicon which process provides for increased production capacity and electrical power efficiency. The process comprises recycling the exhaust gases of the silane pyrolysis reactor after the gases have been preferably first cooled and filtered utilizing a pocket-type reaction zone enclosure having a particular effective radius thereby effectively decreasing the amount of silicon powder formation. Preferably, the rate of recycle flow is sufficient to entrain silicon powder in the reactor and remove the powder from the reactor with the exiting exhaust gases.

Abstract: Process for the improvement of the quality of polyalkylene polyamines prepared by the reaction of (i) ammonia and/or an alkyleneamine compound having at least two amino groups and an alkanolamine compound having at least one amino group in the presence of a catalytically effective amount of a metal acid phosphate and at a temperature and pressure sufficient to form the polyalkylene polyamine.

Abstract: A method for producing a composite hollow fiber membrane by coating a porous hollow fiber substrate with a dilute solution of a membrane-forming composition containing a membrane-forming material and a solvent therefor by contacting the porous hollow fiber substrate with the composition, partially evaporating some of the solvent from the coated porous hollow fiber substrate, contacting the partially dried coating porous hollow fiber substrate with a coagulant and recovering the composite hollow fiber membrane. Also included are the composite hollow fiber membranes so produced and their use as permeable membranes for separating at least one fluid from at least one other fluid in a fluid mixture.

Abstract: The invention relates to a coated article comprising a substrate coated with a tungsten carbide-cobalt layer having a strain-to-fracture greater than 4.3.times.10.sup.-3 inch per inch and a Vickers hardness of greater than about 875 HV.sub.0.3.

Abstract: Composites of flexible graphite particles and an amorphous carbon phase useful for applications such as valve packing end rings.

Abstract: A method and apparatus for reducing the amount of an external fluid which travels through an opening into an enclosed area. Also, a method and apparatus for protecting a surface area or plane from contact with or intermixing with an external fluid. The method, in general, comprises causing a fluid to flow, in laminar form, in proximity to or directly across an opening, a surface or an area plane to be protected. The depth or thickness of the flowing laminar fluid layer at its source of origin is at least about 0.05 times the distance across the opening, surface area or plane to be protected, in the principal direction of flow of the fluid at its source of origin. The width of fluid flow at its source of origin and transverse the direction of fluid flow is at least about as great as the maximum width of the opening, surface or area plane to be protected, transverse the direction of fluid flow. The Force Number of the fluid must range between about 0.

Abstract: An oligomerization or cooligomerization process comprising passing ethylene or a mixture of ethylene and propylene in contact with a catalyst, in the liquid phase.

Abstract: This invention relates to an improved process for application of a metal-comprising coating to a metal-comprising surface without using a flux. The metal-comprising surface must be wettable by or become wettable upon contact with a bath of the metal-comprising coating. Application of the coating is carried out in an environment which is inert at least with respect to the coating material during the time period of its application to the metal-comprising surface, and preferably inert with respect to both the coating material and the metal-comprising surface. The inert environment temperature is sufficiently low that no damage is done to the metal-comprising surface and no damage is done to other materials adjacent to the metal-comprising surface.

Abstract: A coating composition applied to a substrate by thermal spray process, characterized by improved wear, thermal shock resistance and chemical resistance at elevated temperatures, the coating composition containing greater than about 60 volume percent refractory oxide with the balance comprising a cobalt and/or nickel and/or iron base metal matrix containing chromium, aluminum and tantalum.

Abstract: Process and apparatus to produce argon at high recovery with nitrogen at higher than conventional pressure comprising three columns wherein first column bottoms are passed into the second column, second column bottoms drive a third column top condenser, and argon-containing fluid is passed for separation into the third column from the second column at a point intermediate the points where first column bottoms enter and second column bottoms exit the second column.

Abstract: Novel vicinal dioxyalkylene organometalates comprising a cation having a hydrocarbyl-containing substituent are disclosed. The vicinal dioxyalkylene organometalates can be reacted with water to yield alkylene glycols.

Abstract: A gas supply system comprising an atmospheric vaporizer and a powered heat exchanger in series each having a rated capacity at least equal to the design gas usage rate.

Abstract: The present invention is directed to composite membranes having a separation layer comprised of at least one poly(tetramethyl) bisphenol A phthalate resulting in enhanced separation and permeating characteristics. Processes for making these composite membranes and the methods of using them for gas separations are also disclosed.

Abstract: Novel substituted organosilicon carboxylates characterized by the following formula: ##STR1## wherein M is a monovalent cation: Z represents a moiety hydrolyzable to silanol; R.sup.

Abstract: Disclosed are surface-active polycarbodiimides containing a hydrophilic portion and a hydrophobic portion joined through the reaction of a carbodiimide group with a reactive functional group. The surface-active polycarbodiimides may be linear or branched, monodisperse or polydisperse, but preferably are of the branched, monodisperse type. The surface-active polycarbodiimides are useful as surfactants, and are particularly useful as emulsifiers in cross-linkable, carboxyl-containing resin systems, such as aqueous latexes.