Abstract: A dispersant or dispersant mixture that is useful in fuel and lubricant compositions, and that is characterized by its derivation from a long chain dicarboxylic acid material and an amino alcohol, is stabilized against oxidation by sulfurization by reaction with sulfur or with a sulfur compound selected from the group consisting of carbon disulfide, sulfides of phosphorus including P.sub.2 S.sub.5 and P.sub.4 S.sub.3, and phosphosulfurized olefins. More particularly, the dispersant so treated will usually comprise a mono or bis-oxazoline prepared by reaction of a hydrocarbyl-substituted C.sub.4 -C.sub.10 dicarboxylic acid or anhydride or ester thereof, having at least 50 carbon atoms in the hydrocarbyl group, with a 2,2-disubstituted 2-amino-1-alkanol that has from two to three hydroxy groups and that contains from 4 to 8 total carbon atoms.
Abstract: Antioxidant additives for lubricating oil are prepared by combining water, an acidic molybdenum compound, a basic nitrogen compound complex and a sulfur source to form a sulfur- and molybdenum-containing composition.
Abstract: Antioxidant additives for lubricating oil are prepared by combining an acidic molybdenum compound and certain basic nitrogen compounds to form a molybdenum-containing compositions.
Abstract: Novel polyureas of the formula: ##STR1## wherein n is 9 to 18, m is 2 to 10, X and Y are each either ethyl, methyl or a hydrogen atom and R=aromatic, aliphatic or cycloaliphatic, are described herein. These polyureas are particularly useful as thickening agents for lubricating oils to make greases. The polyureas may be prepared by reacting the aminated products of propoxylated fatty alcohols with organic polyisocyanates. The reaction is a simple process requiring no heat. Very low levels of the resulting polyureas are required to thicken oils of lubricating viscosity into greases which have good high temperature stability.
Abstract: Lubricant compositions containing oleaginous materials and, in an amount sufficient to impart oxidation stability and corrosion resistance thereto, an adduct of a benzotriazole compound and an alkyl vinyl ether or a vinyl ester of a carboxylic acid in combination with an alkyl dimercapto thiadiazole.
Abstract: A synthetic metal working lubricant characterized by an absence of mineral oil but which is water immiscible and dispersible in water to form oil-in-water emulsions in which said lubricant is in the discontinuous phase is prepared using polybutenes, also referred to as polyisobutylenes, having an average molecular weight within the range of approximately 320-610 constituting a principal ingredient in combination with polyethylene glycol mono- and/or diesters of higher carboxylic acids or mixtures of such acids containing 8 to 22 carbon atoms in an acyclic or branched carbon chain and/or higher fatty acids containing 8-22 carbon atoms together with optional corrosion inhibiting agents which are effective in inhibiting corrosion of ferrous and non-ferrous metals to which the lubricant is applied for the purpose of working such metals.
Abstract: Antioxidant additives for lubricating oil are prepared by combining a polar promoter, an acidic molybdenum compound and certain basic nitrogen compound to form a molybdenum-containing compositions.
Abstract: Antioxidant additives for lubricating oil are prepared by combining ammonium tetrathiomolybdate and a basic nitrogen compound complex to form a sulfur-and molybdenum-containing composition.
Abstract: Metal working operations, especially drawing, are facilitated by applying to the metal a composition which provides lubricity thereto, which melts between about 30.degree. and about 150.degree. C., and which contains a minor amount of a phosphorus-containing composition which may be prepared by the reaction of an alkoxylated alkyl phenol with a phosphorus trihalide, or, in combination with water, with a triaryl phosphite. The former reaction also produces, as a by-product, the corresponding halide. The phosphorus-containing compositions are especially useful in combination with a chlorinated wax. The preferred lubricant bases for the metal working lubricants comprise esters or polymers of epoxides or episulfides.
Abstract: A diesel crankcase lubricant composition comprising a lubricating oil base and the reaction product of a hydrocarbyl succinic anhydride in which the hydrocarbyl radical has from 12 to 30 carbon atoms and 5-amino-triazole is provided.
Abstract: Phosphosulfurized hydrocarbyl oxazoline reacted with nitrogen-containing compounds and certain olefins are novel compounds effective for reducing friction and wear when added to a lubricant.
Type:
Grant
Filed:
November 20, 1979
Date of Patent:
March 10, 1981
Assignee:
Mobil Oil Corporation
Inventors:
Andrew G. Horodysky, Robert M. Gemmill, Jr.
Abstract: A viscous composition capable of substantially retaining its viscosity within a temperature range of from 5.degree.-30.degree. C. comprising as its components diisopropyl adipate, a mixture of cetyl and stearyl octanoates, glyceryl tribehenate, silicone oil and a surfactant is described.
Abstract: The friction performance of a lubricating oil composition that has been compounded to serve as a functional fluid that is particularly useful in mechanical and hydraulic units containing wet clutches, for example an automotive automatic transmission, is greatly improved by the incorporation of a combination of a friction modifier of the type comprising a straight chain alkenyl or alkyl C.sub.4 to C.sub.10 dicarboxylic acid or the reaction product of an aldehyde/tris hydroxymethyl aminomethane adduct and a long chain dicarboxylic acid anhydride such as an alpha-olefin succinic anhydride; with an overbased detergent salt such as an alkali metal salt or alkaline earth metal salt of a hydrocarbyl sulfonic acid, an alkyl phenol or a sulfurized alkyl phenol, in certain proportions.
Abstract: Metal salts of phosphosulfurized hydrocarbyl oxazoline phosphorodithioic acids are novel compounds effective for reducing friction and wear when added to a lubricant.
Type:
Grant
Filed:
November 20, 1979
Date of Patent:
March 3, 1981
Assignee:
Mobil Oil Corporation
Inventors:
Andrew G. Horodysky, Robert M. Gemmill, Jr.
Abstract: Lubricant compositions are provided containing antiwear improving amounts of a bis-oxazoline having an alkyl group containing from about 4 to about 24 carbon atoms.
Abstract: Reaction products of selected inorganic thiocyanates and alkyl or aryl phosphorus halides provide additive compounds which impart excellent antiwear and load-carrying protection to lubricant base stocks in which they are incorporated.
Abstract: A quaternary ammonium salt of a diester represented by the formula: ##STR1## in which R.sup.i, R.sup.ii, R.sup.iii and R.sup.iv represent hydrogen, alkyl or alkenyl radicals at least one of which is a hydrocarbyl radical having from 50-200 carbon atoms, R is a divalent radical having from 2-10 carbon, or carbon and oxygen atoms, R.sup.v is hydrogen or a hydrocarbyl radical, z has a value from 0-4 and X is an anion is provided, as well as a method of preparation and a hydrocarbon lubricating oil composition containing same.
Abstract: Metalworking fluids containing diethanol disulfide in effective amounts to provide extreme pressure and anti-wear properties are disclosed. A preferred metalworking fluid is an aqueous solution of diethanol disulfide and water-soluble polyoxyalkylene glycols. Concentrates and use solutions are disclosed.
Abstract: Synthetic fibers are treated for the purpose of lubrication with a compound of the formula: ##STR1## wherein R.sub.1 is hydrogen or phenyl, R.sub.2 is an alkylene group having 1 to 3 carbon atoms, R.sub.3 is an alkylene group having 2 to 4 carbon atoms or a mixed alkylene group thereof, R.sub.4 is hydrogen, an acyl having 1 to 18 carbon atoms or alkyl group having 1 to 18 carbon atoms, p is a number of from 2 to 5 and n is a number of from 1 to 50.
Abstract: A hydrocarbon composition having a major portion of a hydrocarbon preferably a lubricating oil such as mineral oil and at least a friction-reducing amount usually 0.01 to 10 weight percent of an amine or amine derivative of a hydrocarbon-soluble polymerized fatty acid e.g. a dimeramine derived from a dicarboxylic acid containing at least 12 carbon atoms such as 9(10)-carboxy stearic acid has improved antifriction and fuel economy properties.