Patents Examined by Harry I. Moatz
  • Patent number: 3975408
    Abstract: Refined dicarboxylic acid anhydrides such as maleic anhydride are provided with improved color stability by a treating agent selected from the group consisting of chlorine and halides or elements in group IVb of the periodic table, the transition elements, vanadium, chromium, manganese, mercury, silicon, phosphorus, bismuth, antimony, lead, cerium and sulfur.
    Type: Grant
    Filed: October 31, 1972
    Date of Patent: August 17, 1976
    Assignee: Monsanto Company
    Inventors: Ronald J. Boyer, Raymond E. Stenseth, Richard J. Sheehan
  • Patent number: 3975407
    Abstract: Maleic anhydride is obtained by oxidizing an unsaturated hydrocarbon having at least 4 carbon atoms in the presence of a catalyst consisting essentially of the oxides of phosphorus and tungsten, with small amounts of a catalyst promoter selected from compounds of alkali metals, alkaline earth metals, copper, zinc, chromium, bismuth and titanium.
    Type: Grant
    Filed: May 14, 1975
    Date of Patent: August 17, 1976
    Assignee: Kuraray Co., Ltd.
    Inventor: Ryuhei Ueeda
  • Patent number: 3975443
    Abstract: Compounds of the general formula I: ##EQU1## in which R.sup.1 - R.sup.4 which may be the same or different represent hydrogen atoms, or C.sub.1.sub.-6 straight or branched chain alkyl, alkenyl or alkynyl group or an alkyl group substituted by a cycloalkyl group, or represents a cycloalkyl, alkoxycarbonyl, aryl, arakyl, acyl (which includes anylsulphonyl) groups in which the alkyl group or the alkyl portion of the aralkyl group may be substituted with one or more hydroxy or esterified hydroxy groups and in which the aryl groups or the aryl portion of the acyl or aralkyl group may be substituted by one or more halogen atoms, alkyl groups, hydroxy groups, alkoxy groups, trifluoromethyl, nitro, amino or dialkylamino groups, and in which R.sup.5 - R.sup.8 which may be the same or different represent hydrogen atoms or alkyl groups except that not all groups may be hydrogen, or R.sup.5 and R.sup.6 or R.sup.7 and R.sup.8 together represent a carbonyl (=O) oxygen and in any of the pairs of groups R.sup.1 /R.sup.2, R.
    Type: Grant
    Filed: October 29, 1974
    Date of Patent: August 17, 1976
    Assignee: Allen & Hanburys Limited
    Inventors: Norman James Harper, George Bryan Austin Veitch
  • Patent number: 3974149
    Abstract: Azomethine pigments of the formula ##SPC1##And metal complexes thereof, wherein A denotes an isocyclic or heterocyclic aromatic radical, R denotes a H atom, an alkyl group containing 1-6 C atoms, or an aryl radical, X.sub.2 and X.sub.4 denote H atoms or halogen atoms, X.sub.1 and X.sub.3 denote H atoms or halogen atoms, alkoxy or alkylmercapto groups containing 1-6 C atoms, cycloalkoxy groups containing 5-6 C atoms, or aralkoxy, aryloxy or arylmercapto groups, it being possible for one of the substituents X.sub.1 -X.sub.4 also to be a nitro group which are useful for pigmenting of high molecular material.
    Type: Grant
    Filed: August 30, 1974
    Date of Patent: August 10, 1976
    Assignee: Ciba-Geigy Corporation
    Inventors: Francois L'Eplattenier, Andre Pugin, Laurent Vuitel
  • Patent number: 3974148
    Abstract: Filaricidal and trypanocidal phenylarsenodithio compounds of the formula ##SPC1##Wherein R.sub.1 is --OH or --CO.NH.sub.2 or the rest ##SPC2##And R.sub.2 is hydrogen or the amino group, as well as salts of these compounds with acids and bases.
    Type: Grant
    Filed: July 11, 1972
    Date of Patent: August 10, 1976
    Inventor: Ernst A. H. Friedheim
  • Patent number: 3974166
    Abstract: A novel process for the preparation of 2,4-dibromo-, 2,6-dibromo- and 2,4,6-tribromopyridines, and the new bromopyridines to be obtained therewith, are disclosed. The novel process comprises treating 2,4-dichloro-, 2,6-dichloro- and 2,4,6-trichloropyridines, in an anhydrous organic medium, with gaseous HBr at temperatures between 80.degree. and 130.degree.C, said process being both simple and economical.
    Type: Grant
    Filed: June 17, 1974
    Date of Patent: August 10, 1976
    Assignee: Ciba-Geigy Corporation
    Inventor: Francis Mutterer
  • Patent number: 3974177
    Abstract: Polyhalo copper phthalocyanines are purified in concentrated sulfuric acid under addition of peroxo compounds including addition compounds of hydrogen peroxide. The products are useful as pigments having very pure green shades and good fastness properties.
    Type: Grant
    Filed: August 15, 1975
    Date of Patent: August 10, 1976
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Friedrich Ische, Ernst Spietschka
  • Patent number: 3974218
    Abstract: Undesired vegetation such as crabgrass, downey brome, giant foxtail, yellow foxtail, barnyard grass, flax and wild oats are combated by pre-emergent application of at least one compound belonging to a class of substituted N-benzyl amides of alkanoic and benzoic acids, particularly in the presence of seeds of such crops as cotton and soybeans.
    Type: Grant
    Filed: July 7, 1972
    Date of Patent: August 10, 1976
    Assignee: Gulf Research & Development Company
    Inventor: Roger P. Cahoy
  • Patent number: 3972893
    Abstract: A method for preparing a cobalt phthalocyanine complex salt is described. More particularly, the invention pertains to a method for the advantageous preparation of a 6-valence cobalt phthalocyanine complex salt composed of a 6-valence cobalt phthalocyanine complex, in which an aliphatic polyamine has been coordinated at the two ligands not occupied by the phthalocyanine ring, and a mineral acid.
    Type: Grant
    Filed: March 12, 1975
    Date of Patent: August 3, 1976
    Assignee: Nippon Chemical Works Co., Ltd.
    Inventor: Toshiki Tanaka
  • Patent number: 3971811
    Abstract: 5-(4-chlorophenyl)-2-furyl phenyl ketone is an effective anthelmintic agent.
    Type: Grant
    Filed: June 16, 1975
    Date of Patent: July 27, 1976
    Assignee: Morton-Norwich Products, Inc.
    Inventor: Stanford S. Pelosi, Jr.
  • Patent number: 3970652
    Abstract: Unwanted vegetation is combated in the presence of grain crops and soybeans by post-emergent application of one or more of the following compounds:2-(m-chlorophenyl)-4H-3,1-benzoxazin-4-one,2-(m-trifluoromethylphenyl)-4H-3,1-benzoxazin-4-one,2-(2-thienyl)-4H-3,1-benzoxazin-4-one,2-(o-trifluoromethylphenyl)-4H-3,1-benzoxazin-4-one,2-(p-trifluoromethylphenyl)-4H-3,1-benzoxazin-4-one,2-(4-methyl-1,2,3-thiadizole-5-yl)-benzoxazin-4-one2-(m-bromophenyl)-4H-3,1-benzoxazin-4-one.
    Type: Grant
    Filed: June 2, 1972
    Date of Patent: July 20, 1976
    Assignee: Gulf Research & Development Company
    Inventor: William C. Doyle, Jr.
  • Patent number: 3970655
    Abstract: Pyridine is prepared by reacting acetaldehyde, ammonia and oxygen at elevated temperatures and in the presence of a condensation catalyst, the oxygen (or air) oxidatively demethylating, in situ, the picolines and/or higher condensation products produced along with pyridine. A second embodiment includes incorporating methanol in the above reaction mixture. A third embodiment includes incorporating isobutyraldehyde in the above reaction mixture. These processes obviate the need for formaldehyde as a reactant.
    Type: Grant
    Filed: July 29, 1974
    Date of Patent: July 20, 1976
    Assignee: Celanese Corporation
    Inventor: Anthony B. Baylis
  • Patent number: 3969371
    Abstract: A process for converting .gamma.-butyrolactone to tetrahydrofuran by treating the lactone with hydrogen in the presence of a cobalt-copper chromite catalyst at elevated pressures and temperatures.
    Type: Grant
    Filed: July 15, 1974
    Date of Patent: July 13, 1976
    Assignee: Deutsche Texaco Aktiengesellschaft
    Inventors: Georg Michalczyk, Karl-Heinz Gluzek
  • Patent number: 3969373
    Abstract: Compounds of the formula ##SPC1##Wherein R.sub.1 is lower alkyl or phenyl lower alkyl; R.sub.2 is phenyl or substituted phenyl; and R.sub.3 is substituted or unsubstituted phenyl, naphthyl or indolyl;Are fluorogenic reagents which react with primary amino groups to form fluorophors. The above compounds are useful for fluorescent labeling of materials of biological importance.
    Type: Grant
    Filed: June 26, 1975
    Date of Patent: July 13, 1976
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Roy Cleeland, Jr., Emanuel Grunberg, Willy Leimgruber, Manfred Weigele
  • Patent number: 3968127
    Abstract: A process for producing citraconic anhydride from isoprene which comprises contacting the isoprene feed and oxygen-containing gas in vapor phase in a pretreatment zone at a temperature between 150.degree. and 430.degree.C with a solid base composition, said base composition comprising an alkali or alkaline earth metal, and then contacting the effluent from the pretreatment zone at a temperature between 180.degree. and 500.degree.C with a hydrocarbon oxidation catalyst effective for catalyzing the reaction of isoprene with oxygen to obtain citraconic anhydride.
    Type: Grant
    Filed: April 24, 1975
    Date of Patent: July 6, 1976
    Assignee: Chevron Research Company
    Inventor: Jonas P. Harrison
  • Patent number: 3966771
    Abstract: Certain 5-(4-chlorophenyl)-2-furyl ketones of the formula: ##SPC1##Wherein R is cyclopropyl or 2-furyl are effective anthelmintic agents.
    Type: Grant
    Filed: June 16, 1975
    Date of Patent: June 29, 1976
    Assignee: Morton-Norwich Products, Inc.
    Inventor: Stanford S. Pelosi, Jr.
  • Patent number: 3965123
    Abstract: A process for recovery of good color stability maleic anhydride which comprisesA. removing maleic anhydride from a gaseous mixture containing maleic anhydride by absorption into an organic absorbent,B. distilling maleic anhydride overhead from the resulting absorbent in a first distillation column,C. condensing maleic anhydride out of the resulting overhead thereby obtaining condensed liquid maleic anhydride,D. passing at least a portion of the condensed maleic anhydride to the upper part of a second distillation column, andE. distilling material more volatile than maleic anhydride out of the condensed liquid maleic anhydride in a second distillation column, thereby obtaining stripped maleic anhydride which is withdrawn from the lower part of the second distillation column.Preferably the stripped maleic anhydride is distilled in a third distillation column and purified maleic anhydride is withdrawn as an overhead product.
    Type: Grant
    Filed: June 10, 1974
    Date of Patent: June 22, 1976
    Assignee: Chevron Research Company
    Inventor: Frederick C. Franklin
  • Patent number: 3965127
    Abstract: The present invention relates to new cyclic organophosphorus esters having the following structures: ##EQU1## where R is aryl or chloroalkyl of 2 to 10 carbon atoms,R' is aryloxy or chloroalkyloxy of 2 to 10 carbon atoms,R" is hydrogen, alkyl, alkenyl, furanyl or aryl of 1 to 15 carbon atoms and substituted aryl forms where the substituent is fluorine, chlorine, bromine, cyano, hydroxyl, alkyloxy, alkylthio or mixtures of such substituents, andY is O or S.The organophosphorus compounds have biological activity and are also useful as fire retardants, and as lead scavengers in gasoline.
    Type: Grant
    Filed: June 2, 1975
    Date of Patent: June 22, 1976
    Assignee: Monsanto Company
    Inventor: Gail H. Birum
  • Patent number: 3963726
    Abstract: Quaternary ammonium salts of chloromethylated silanes or siloxanes which contain at least one[Cl.sup.-R.sub.3 "N.sup.+CH.sub.2 --Ar--(R).sub.n ]radical directly linked to a silicon atom wherein Ar is an arylene radical, wherein R.sub.3 "N taken collectively is a tertiary amine radical and wherein the compounds are useful in conventional silicon applications such as anti-static agents, wetting agents, lubricants, hydraulic fluids, coating resins, elastomers and cationic surfactants.
    Type: Grant
    Filed: November 9, 1971
    Date of Patent: June 15, 1976
    Assignee: Union Carbide Corporation
    Inventors: Enrico James Pepe, Bernard Kanner
  • Patent number: 3963744
    Abstract: Phthalocyanine dyestuffs containing the tris(trimethylsilyloxy)silylalkylamino group, ##EQU1## where R.sup.1 is H or lower alkyl are produced and are found to be compatible with cured silicone polymers.
    Type: Grant
    Filed: August 8, 1975
    Date of Patent: June 15, 1976
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Carl Mayn Smith, George V. D. Tiers