Patents Examined by Harry I. Moatz
-
Patent number: 3936479Abstract: The present invention concerns benzophenone compounds of the formula: ##SPC1##WhereinR.sub.1, r.sub.2, r.sub.3 and R.sub.4 are hydrogen or substituents, e.g. alkyl,X is a mono-, di- or trivalent radical andn is an integer 1, 2 or 3.The compounds are useful as U.V. stabilizers for, for example, plastics materials.Type: GrantFiled: May 4, 1973Date of Patent: February 3, 1976Assignee: Sandoz Ltd., (Sandoz AG)Inventors: Lajos Avar, Kurt Hofer, Martin Preiswerk
-
Patent number: 3935203Abstract: The invention relates to new derivatives of 3-oxo-2,3-dihydro-1,4-benzoxazine corresponding to the general formula ##SPC1##In whichR.sub.1 is selected from the group consisting of the hydrogen atom and a lower alkyl group;R.sub.2, r.sub.3 and R.sub.4 which are identical or different, are selected from the group consisting of the hydrogen atom, a halogen atom, a nitro group, a lower alkyl group, a lower alkoxy group and R.sub.4 may be an allyl group;R.sub.5 is selected from the group consisting of the hydrogen atom and an acyl group, preferably acetyl. These derivatives can be used for therapeutic purposes, more especially as analgesics and anti-oedematous agents.Type: GrantFiled: August 2, 1973Date of Patent: January 27, 1976Assignee: CERPHAInventors: Germaine Thuillier, Jacqueline Laforest
-
Patent number: 3935249Abstract: Viscous polybutenes of number average molecular weight (M.sub.n) in the range of about 300 to about 3,000 have improved reactivity with intramolecular anhydrides of unsaturated aliphatic dicarboxylic acids when reacted in the presence of rather small amounts, i.e., 5 to 200 ppm, of inorganic halogen preferably chlorine and/or bromine containing compounds. Use of such halogen containing compounds in the addition reaction of polybutene with said unsaturated anhydrides can reduce formation of undesired tarry product resulting from polymerization and/or thermal decomposition of the unsaturated anhydrides.Type: GrantFiled: May 10, 1973Date of Patent: January 27, 1976Assignee: Standard Oil CompanyInventors: Imre Puskas, John A. Cengel
-
Patent number: 3935252Abstract: Disclosed herein is a method which provides substantially zero acid number polytetramethylene ether glycol thus making it possible to regard polytetramethylene ether glycol as a fungible commodity. The improvement is achieved by complete removal of a trace impurity, believed to be n-butyl aldehyde, from dry tetrahydrofuran, by contact with molecular sieves of a particular definition, prior to the polymerization of the tetrahydrofuran in the production of polytetramethylene ether glycol.Type: GrantFiled: September 18, 1974Date of Patent: January 27, 1976Assignee: The Quaker Oats CompanyInventor: Hideo Tomomatsu
-
Patent number: 3933861Abstract: Tetrahydrofurans are produced by the codimerization of an alkene oxide with an alkene in the presence of catalytic amounts of a Group VIII noble transition metal compound and an iodide promoter.Type: GrantFiled: January 7, 1974Date of Patent: January 20, 1976Assignee: Chevron Research CompanyInventor: Victor P. Kurkov
-
Patent number: 3933863Abstract: 3-Furyl beta-chalcogenalkyl sulfides having the structure: ##SPC1##Wherein X is a chalcogen selected from the group consisting of oxygen and sulfur; R.sub.2 and R.sub.3 are each selected from the group consisting of methyl and hydrogen, at least one of R.sub.2 or R.sub.3 being methyl; and R.sub.4 and R.sub.5, taken separately, are each methyl, or R.sub.4 and R.sub.Type: GrantFiled: January 21, 1975Date of Patent: January 20, 1976Assignee: International Flavors & Fragrances Inc.Inventors: William J. Evers, Igor A. Pelse, Manfred Hugo Vock
-
Patent number: 3933907Abstract: Amides of phosphorus-containing thioacids are reacted with sulphenyl halides to give phosphorus-containing thioacid amides in which one or more of the nitrogen atoms carries a substituent attached through a sulphur atom. These substituted amides are inhibitors of premature vulcanisation in rubbers. The most effective compounds carry a secondary alkylthio or cycloalkylthio on each nitrogen atom.Type: GrantFiled: January 17, 1974Date of Patent: January 20, 1976Assignee: Imperial Chemical Industries LimitedInventors: Stanley Ashton, Vijay Ratna Sharma, John Anthony Taylor
-
Patent number: 3932180Abstract: Process for direct alpha to X phase conversion of metal-free phthalocyanine. In this process, the alpha polymorph of a metal-free phthalocyanine pigment can be directly converted to the X form by depositing the alpha form of the pigment on a suitable substrate followed by in situ conversion of this deposit by controlled heating. The X form of metal-free phthalocyanine is known to possess good electrophotographic speed, and, thus, can be used either alone or in combination with other photoconductive materials in electrophotography.Type: GrantFiled: June 4, 1973Date of Patent: January 13, 1976Assignee: Xerox CorporationInventors: Clifford H. Griffiths, Michael S. Walker
-
Patent number: 3932454Abstract: A process for the preparation of substantially hexagonal crystals of metal-free alpha phthalocyanine, said crystals ranging in size from about 1 micron to about 75 microns is disclosed. Photoelectrophoretic and manifold processes employing said crystals are also disclosed.Type: GrantFiled: August 7, 1973Date of Patent: January 13, 1976Assignee: Xerox CorporationInventor: Ray H. Luebbe, Jr.
-
Patent number: 3932468Abstract: A process for preparing a substituted or unsubstituted dihydrofuran from a substituted or unsubstituted butadiene monoxide which comprises contacting the butadiene monoxide with a catalyst comprising a hydrogen halide selected from the group consisting of hydrogen iodide or bromide and a homogeneous transition metal compound in an organic solvent under conditions effective to convert the butadiene monoxide to the dihydrofuran and wherein said transition metal compound is effective to accelerate said conversion. Preferably the transition metal is iron, manganese, cobalt, molybdenum, vanadium, copper, or nickel.Type: GrantFiled: February 8, 1974Date of Patent: January 13, 1976Assignee: Chevron Research CompanyInventor: Victor P. Kurkov
-
Patent number: 3932421Abstract: Alkylpyridines such as 2-picoline and 4-picoline are prepared by contacting acetaldehyde and ammonia in a gaseous phase with a phosphate of two metals such as cobalt magnesium phosphate, cobalt aluminum phosphate or lead aluminum phosphate, impregnated with an aqueous solution of phosphoric acid or ammonium phosphate, as a catalyst, at a temperature of 350.degree. to 500.degree.C and a space velocity of 200 to 2,000 Hr.sup.-.sup.1. Silica-alumina and a promoter can be added to the catalyst. The impregnated catalyst has a higher catalytic activity and holds the initial high activity even after a considerable number of regeneration.Type: GrantFiled: July 2, 1971Date of Patent: January 13, 1976Assignee: Koei Chemical Company, Ltd.Inventors: Yoshizo Minato, Shinichi Yasuda
-
Patent number: 3932403Abstract: Amides of phosphorus-containing acids are reacted with sulphenyl halides to give phosphorus-containing acid amides in which one or more of the nitrogen atoms carries the appropriate substitutent attached through a sulphur atom. These substituted amides are inhibitors of premature vulcanisation in rubbers. The most effective compounds are arylamides substituted by secondary alkylthio groups.Type: GrantFiled: July 20, 1973Date of Patent: January 13, 1976Assignee: Imperial Chemical Industries LimitedInventors: Stanley Ashton, Vijay Ratna Sharma, John Anthony Taylor
-
Patent number: 3932469Abstract: The preparation of citraconic anhydride by catalytic vapor phase oxidation of methyl butanols and methyl butenols.Type: GrantFiled: June 3, 1974Date of Patent: January 13, 1976Assignee: Pfizer Inc.Inventors: Rudolph G. Berg, Bryce E. Tate
-
Patent number: 3931190Abstract: A process is provided for the preparation of 2-chloropyridine by the liquid phase hydrogenolysis of 2,6-dichloropyridine in the presence of a selected metal and a strong base.Type: GrantFiled: March 4, 1974Date of Patent: January 6, 1976Assignee: Olin CorporationInventor: Roland R. Kyi
-
Patent number: 3931245Abstract: Furan Sulfur compounds of the formula ##SPC1##Wherein n is 1 and R is methyl, ethyl, propyl, 1-methyl-prop-1-en-1-yl, 2-methyl-prop-1-en-1-yl, furyl or hydrogen; and wherein n is 2 and R is methyl which are useful as flavor additives for foodstuffs and beverages.Type: GrantFiled: July 26, 1974Date of Patent: January 6, 1976Assignee: Firmenich & CieInventors: Max Winter, Fritz Gautschi, Ivon Flament, Max Stoll
-
Patent number: 3931246Abstract: Furan Sulfur compounds of the formula ##SPC1##Wherein when n is 0, R.sub.1 and R.sub.2 are methyl; when n is 1, R.sub.1 and R.sub.2 are methyl or R.sub.1 is hydrogen and R.sub.2 is 5-methylfuryl; and when n is 2, R.sub.1 and R.sub.2 are hydrogen which are useful as flavor additives to foodstuffs and beverages.Type: GrantFiled: July 26, 1974Date of Patent: January 6, 1976Assignee: Firmenich & CieInventors: Max Winter, Fritz Gautschi, Ivon Flament, Max Stoll
-
Patent number: 3931268Abstract: Benzene-ring substituted (2-methylhydrazino)methylbenzene compounds and intermediates therefor are described. The former compounds are useful as cytostatic agents.Type: GrantFiled: May 6, 1970Date of Patent: January 6, 1976Assignee: Hoffmann-La Roche Inc.Inventors: Werner Bollag, Hugo Gutmann, Balthasar Hegedus, Ado Kaiser, Albert Langemann, Marcel Muller, Paul Zeller
-
Patent number: 3931310Abstract: The subject of the invention is a process for the manufacture of water-soluble condensation products of hydroxymethyl-phosphonium compounds and dicyandiamide, characterised in that (a) 1 mol of a tetrakis-(hydroxymethyl)phosphonium compound is condensed with (b) 0.02 to 0.2 mol, preferably 0.05 to 0.15 mol, of an optionally methylolated dicyandiamide at 40.degree. to 120.degree.C, optionally in the presence of formaldehyde or a formaldehyde-donating agent, and an inert organic solvent, and optionally subsequently further condensed at temperature of 100.degree. to 150.degree.C, and if appropriate free hydroxyl groups are at least partially etherified with at least one alkanol with 1 to 4 carbon atoms and if appropriate the salts of the condensation products are converted into the corresponding hydroxides.The condensation products are used for flameproofing organic fibre material, especially textiles.Type: GrantFiled: August 31, 1972Date of Patent: January 6, 1976Assignee: Ciba-Geigy AGInventors: Hermann Nachbur, Arthur Maeder
-
Patent number: 3931238Abstract: Alcohols and ethers are prepared by reacting a substituted hydrocarbon compound containing halogen or alkyl sulfate groups with an alkali metal hydroxide, in aqueous solution, in the presence of a catalytic amount of certain betaines and recovering from the reaction mixture the desired alcohol and/or ether. The reaction mixture can contain alcohols, ethers, and diethers, in varying amounts, depending on reactants and reaction conditions. Typical examples of materials used are: 1,4-dichlorobutane, sodium hydroxide, and tridodecylcarbomethoxymethyl ammonium bromide as the catalyst. The ethers are useful as solvents.Type: GrantFiled: April 17, 1974Date of Patent: January 6, 1976Assignee: Continental Oil CompanyInventor: Charles M. Starks
-
Patent number: 3931250Abstract: New heterocyclic compound useful as odor-modifying agent for manufacturing perfumes, perfumed products, natural or synthetic essential oils, and as flavor-modifying agent for the manufacture of artificial flavors or for flavoring foodstuffs, animal feeds, beverages, pharmaceutical preparations and tobacco products.Process for preparing said heterocyclic compound.Type: GrantFiled: November 1, 1974Date of Patent: January 6, 1976Assignee: Firmenich SAInventor: Alan Francis Thomas