Patents Examined by In Suk Bullock
  • Patent number: 9399604
    Abstract: A process for making an alkylate is presented. The process includes mixing an isoparaffin stream with an olefin stream in an alkylation reactor. The alkylation reactor includes a catalyst for performing the reaction. The catalyst is an ionic liquid that is a quaternary chloroaluminate based ionic liquid, and the reaction is performed at or near ambient temperatures.
    Type: Grant
    Filed: March 12, 2013
    Date of Patent: July 26, 2016
    Assignee: UOP LLC
    Inventors: Susie C. Martins, Douglas A. Nafis, Alakananda Bhattacharyya
  • Patent number: 9399603
    Abstract: A process is presented for increasing the conversion efficiency of oxygenates to olefins. The conversion of oxygenates recycles unconverted oxygenates and oxygenate by-products to a second reactor unit. The present of oxygenate by-products decreases the efficiency of the methanol to olefins reaction, and passing recycled oxygenates to a second reactor unit maintains the methanol to olefins conversion efficiency while converting the by-products in a secondary zone.
    Type: Grant
    Filed: November 25, 2013
    Date of Patent: July 26, 2016
    Assignee: UOP LLC
    Inventors: John J. Senetar, Daniel A. Kauff, Andrea G. Bozzano
  • Patent number: 9399746
    Abstract: Poly alpha olefins (PAOs) are characterized by very low viscosity and excellent Noack volatility. A preferred process for synthesizing said PAOs involves first oligomerizing low molecular weight linear alpha olefins in the presence of a single site catalyst at high temperatures without adding hydrogen and then subsequently oligomerizing at least a portion of the product from the first step in the presence of an oligomerization catalyst.
    Type: Grant
    Filed: September 12, 2012
    Date of Patent: July 26, 2016
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Craig J. Emett, Mark P. Hagemeister, Bruce A. Harrington, Phillip T. Matsunaga, Pramod J. Nandapurkar, Charles J. Ruff, Kevin B. Stavens
  • Patent number: 9394212
    Abstract: In a process for the cooligomerization of olefins, an olefin starting material comprising olefins having n carbon atoms and olefins having 2n carbon atoms is reacted over an olefin oligomerization catalyst to give a reaction product. The process is carried out under such conditions that the conversion of olefins having 2n carbon atoms is less than 10%. Both the cooligomer having 3n carbon atoms and the olefin having 2n carbon atoms which has been separated off from the reaction product have a high hydroformylatability.
    Type: Grant
    Filed: June 14, 2011
    Date of Patent: July 19, 2016
    Assignee: BASF SE
    Inventors: Wolfgang Rohde, Qiang Miao, Stefan Bitterlich, Gauthier Luc Maurice Averlant, Hans-Guenter Wagner, Beatrice Röβler-Feigel
  • Patent number: 9394215
    Abstract: Processes for making CX to CY olefins are provided. The processes include reacting a feedstock comprising C5 and C6 olefins under dimerization or oligomerization conditions to provide a dimerization or oligomerization product. The product is separated into a stream comprising unreacted C5 and C6 paraffins, a stream comprising C10 to CX-1 olefins, and a stream comprising CX to CY olefins, wherein X is at least 14 and Y is greater than X and less than or equal to 36.
    Type: Grant
    Filed: July 19, 2011
    Date of Patent: July 19, 2016
    Assignee: UOP LLC
    Inventors: Debarshi Majumder, Stephen Wayne Sohn, Bryan K. Glover, Andrea G. Bozzano
  • Patent number: 9388345
    Abstract: Embodiments of the invention include apparatus and systems for hydrocarbon synthesis and methods regarding the same. In an embodiment, the invention includes a process for creating a hydrocarbon product stream comprising reacting a reaction mixture in the presence of a catalyst inside of a reaction vessel to form a product mixture, the reaction mixture comprising a carbon source and water. The temperature inside the reaction vessel can be between 450 degrees Celsius and 600 degrees Celsius and the pressure inside the reaction vessel can be above supercritical pressure for water. In an embodiment, the invention includes an extrusion reactor system for creating a hydrocarbon product stream. The temperature inside the extrusion reactor housing between 450 degrees Celsius and 600 degrees Celsius. Pressure inside the reaction vessel can be above supercritical pressure for water. Other embodiments are also included herein.
    Type: Grant
    Filed: July 3, 2013
    Date of Patent: July 12, 2016
    Assignee: SarTec Corporation
    Inventors: Clayton V. McNeff, Larry C. McNeff, Daniel Thomas Nowlan, Bingwen Yan, Peter G. Greuel
  • Patent number: 9388344
    Abstract: A method comprising providing a carbohydrate feed; contacting at least a portion of the carbohydrate feed directly with hydrogen in the presence of a hydrogenolysis catalyst to produce a first reaction product comprising a stable hydroxyl intermediate; contacting at least a portion of the first reaction product comprising the stably hydroxyl intermediates with a dehydrogenation catalyst to form a second reaction product; and contacting at least a portion of the second reaction product with a condensation catalyst comprising a base functionality to form a fuel blend.
    Type: Grant
    Filed: May 12, 2011
    Date of Patent: July 12, 2016
    Assignee: Shell Oil Company
    Inventors: Juben Nemchand Chheda, Lorna Beatriz Ortiz-Soto, Joseph Broun Powell
  • Patent number: 9387475
    Abstract: An assembly comprising at least one microfluidic device and a mounting piece, this microfluidic device comprising at least one material layer and at least one first fluidic port, which first fluidic port it situated at least partially in an end surface of the material layer and which mounting piece comprises at least one fluidic component, wherein the mounting piece is coupled to the microfluidic device by means of first coupling means provided for this purpose such that the fluidic component is connected to the first fluidic port. The invention also relates to such a mounting piece.
    Type: Grant
    Filed: August 31, 2007
    Date of Patent: July 12, 2016
    Assignee: Micronit Microfluidics B.V.
    Inventors: Ronny Van't Oever, Marko Theodoor Blom
  • Patent number: 9388346
    Abstract: The present invention relates to methods of removing heteroaromatic sulfides from hydrocarbons (e.g. petroleum products such as gasoline and fuel oils), using polyoxometalate catalysts such as H5PV2Mo10O40 or solvates thereof.
    Type: Grant
    Filed: October 31, 2011
    Date of Patent: July 12, 2016
    Assignee: YEDA RESEARCH AND DEVELOPMENT CO. LTD.
    Inventors: Ronny Neumann, Alexander Khenkin
  • Patent number: 9388092
    Abstract: The present invention relates to a process for producing aromatic hydrocarbons comprising contacting a feedstream comprising an oxygenate with a catalyst composition comprising a medium pore-size aluminosilicate zeolite further comprising gallium and one or more elements selected from Group 12 of the Periodic Table. The process of the present invention is preferably performed in absence of any feed diluents.
    Type: Grant
    Filed: December 17, 2012
    Date of Patent: July 12, 2016
    Assignee: SAUDI BASIC INDUSTRIES CORPORATION
    Inventor: Kartick Chandra Mondal
  • Patent number: 9382181
    Abstract: A process for removing a cyclododecanone-rich target fraction (A) from a dehydrogenation mixture (O) comprising low boilers (LB), cyclododecanone (CDON), medium boilers (MB), cyclododecanol (CDOL) and high boilers (HB) is provided. According to the process, substantially pure CDON is obtained via a distillative sequence of two side draw columns connected in series, wherein the sidestream of the primary side draw column is fed into the secondary side draw column. From the top of each of the two side draw columns, a CDON-rich fraction is drawn off, and these are combined to form a target fraction, which is essentially pure CDON.
    Type: Grant
    Filed: December 13, 2013
    Date of Patent: July 5, 2016
    Assignee: EVONIK DEGUSSA GmbH
    Inventors: Luca Cameretti, Daniel Demicoli, Ralf Meier
  • Patent number: 9382172
    Abstract: In a process for producing cyclohexylbenzene, benzene is contacted with hydrogen in the presence of a hydroalkylation catalyst under hydroalkylation conditions effective to form a first effluent stream comprising cyclohexylbenzene, cyclohexane, and benzene. At least a portion of the cyclohexane from the first effluent stream is then contacted with hydrogen in the presence of a dehydrogenation catalyst under dehydrogenation conditions effective to convert at least some of the cyclohexane into benzene contained in a second effluent stream. At least some of the hydrogen is supplied to the process so as to contact the dehydrogenation zone (e.g., the dehydrogenation catalyst) before contacting the hydroalkylation catalyst.
    Type: Grant
    Filed: December 5, 2012
    Date of Patent: July 5, 2016
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Christopher L. Becker, James R. Lattner, Keith H. Kuechler, Hari Nair
  • Patent number: 9381495
    Abstract: A process is described for making renewable isobutene and renewable isoprene, comprising converting a mixed acid feed including acetic acid and propionic acid to a product mixture including isobutene and at least one or both of 2-methyl-1-butene and 2-methyl-2-butene in the presence of a catalyst, separating isobutene from the product mixture and dehydrogenating either or both of the 2-methyl-1-butene and 2-methyl-2-butene in the remainder to provide isoprene.
    Type: Grant
    Filed: April 10, 2015
    Date of Patent: July 5, 2016
    Inventors: Junming Sun, Changjun Liu, Yong Wang, Kevin Martin, Padmesh Venkitasubramanian
  • Patent number: 9382491
    Abstract: Embodiments of the invention include apparatus and systems for hydrocarbon synthesis and methods regarding the same. In an embodiment, the invention includes a method for creating a hydrocarbon product stream comprising reacting a reaction mixture in the presence of a catalyst inside of a reaction vessel to form a product mixture, the reaction mixture comprising a carbon source and water. The temperature inside the reaction vessel can be between 450 degrees Celsius and 600 degrees Celsius and the pressure inside the reaction vessel can be above supercritical pressure for water. In an embodiment, the invention includes an extrusion reactor system for creating a hydrocarbon product stream. The temperature inside the extrusion reactor housing between 450 degrees Celsius and 600 degrees Celsius. Pressure inside the reaction vessel can be above supercritical pressure for water. Other embodiments are also included herein.
    Type: Grant
    Filed: January 2, 2014
    Date of Patent: July 5, 2016
    Assignee: SarTec Corporation
    Inventors: Clayton V. McNeff, Larry C. McNeff, Daniel Thomas Nowlan, Bingwen Yan, Peter G. Greuel
  • Patent number: 9382171
    Abstract: A process is described for producing a catalyst composition comprising an iridium component dispersed on a support. In the process, silica- o group to form an organic iridium complex on the support. The treated support is then heated in an oxidizing atmosphere at a temperature of about 325° C. to about 475° C. to partially decompose the organic metal complex on the support. The treated support is then heated in a reducing atmosphere at a temperature of about 350° C. to about 500° C. to convert the partially decomposed organic iridium complex into the desired iridium component.
    Type: Grant
    Filed: July 21, 2014
    Date of Patent: July 5, 2016
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Stuart L. Soled, Sabato Miseo, Joseph E. Baumgartner, Christine E. Kliewer, Jane C. Cheng
  • Patent number: 9382483
    Abstract: The invention relates to a process for producing hydrocarbon components, comprising: providing a feedstock comprising tall oil and terpene-based compounds; subjecting the feedstock and a hydrogen gas feed to a hydroprocessing treatment in the presence of a hydroprocessing catalyst to produce hydrocarbon components including n-paraffins, and subjecting the hydrocarbon components including n-paraffins to isomerisation in the presence of a dewaxing catalyst to form a mixture of hydrocarbon components. The invention also relates to an apparatus for implementing the process. The invention further relates to a use of the hydrocarbon components produced by the process as a fuel or as an additive in fuel compositions. The invention also relates to a use of a NiW catalyst on a support selected from Al2O3, zeolite, zeolite-Al2O3, and Al2O3—SiO2 for producing fuel or an additive for fuel compositions from a feedstock comprising tall oil and terpene-based compounds.
    Type: Grant
    Filed: May 23, 2011
    Date of Patent: July 5, 2016
    Assignee: UPM-KYMMENE CORPORATION
    Inventors: Pekka Knuuttila, Jaakko Nousiainen, Arto Rissanen
  • Patent number: 9375693
    Abstract: The invention relates to a method for performing chemical processes, where raw materials are heated, wherein a melt pool is produced in a tank or reactor using low-melting metals or metal alloys, wherein the raw materials are metered directly into the melt pool in the lower part of the tank or reactor.
    Type: Grant
    Filed: May 11, 2010
    Date of Patent: June 28, 2016
    Assignees: Hartwig Schleuter
    Inventor: Adam Handerek
  • Patent number: 9371496
    Abstract: A hydroconversion catalyst comprising a Group VIB metal component, a Group VIII metal component and a carrier material is disclosed wherein said catalyst has a total surface area of 240 to 360 m2/g; a total pore volume of 0.5 to 0.9 cc/g; and a pore volume distribution such that greater than 60% of pore volume are in pores present as micropores of diameter between 55 and 115 ?, less than 0.12 cc/g of pore volume are in pores present at pores of diameter greater than 160 ? and less than 10% of pore volume are in pores present as macropores of diameters greater than 250 ?.
    Type: Grant
    Filed: May 20, 2013
    Date of Patent: June 21, 2016
    Assignee: Shell Oil Company
    Inventors: John George Kester, David Andrew Komar, David Edward Sherwood
  • Patent number: 9365788
    Abstract: This invention is directed to a two-step process for the preparation of improved poly alpha olefins wherein the first step involves oligomerizing low molecular weight linear alpha olefins in the presence of a single site catalyst and the second step involves oligomerization of at least a portion of the product from the first step in the presence of an oligomerization catalyst. The dimer product from the first oligomerization is characterized by a tri-substituted vinylene olefin content of at least 25 wt %.
    Type: Grant
    Filed: September 12, 2012
    Date of Patent: June 14, 2016
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Craig J. Emett, Mark P. Hagemeister, Bruce A. Harrington, Chon Y. Lin, Phillip T. Matsunaga, Charles J. Ruff, Kevin B. Stavens
  • Patent number: 9365487
    Abstract: Methods and systems for making dibasic esters and/or dibasic acids using metathesis are generally disclosed. In some embodiments, the methods comprise reacting a terminal olefin ester with an internal olefin ester in the presence of a metathesis catalyst to form a dibasic ester and/or dibasic acid. In some embodiments, the terminal olefin ester or the internal olefin ester are derived from a renewable feedstock, such as a natural oil feedstock. In some such embodiments, the natural oil feedstock, or a transesterified derivative thereof, is metathesized to make the terminal olefin ester or the internal olefin ester.
    Type: Grant
    Filed: October 8, 2013
    Date of Patent: June 14, 2016
    Assignee: Elevance Renewable Sciences, Inc.
    Inventors: Thomas E. Snead, Steven A. Cohen, Demond L. Gildon