Abstract: The invention is directed to a process for the preparation of high viscosity lubricant base stocks by contacting alphaolefin feedstocks with single-site metallocene catalysts in a mixed flow or continuous stirred tank reactors.
Type:
Grant
Filed:
February 19, 2009
Date of Patent:
June 14, 2016
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Mark Paul Hagemeister, Peijun Jiang, Margaret M. Wu, Norman Yang
Abstract: A process for liquefying a cellulosic material to produce a liquefied product from cellulosic material is provided. Products obtained from such process and use of such products to prepare biofuels is also provided.
Type:
Grant
Filed:
May 12, 2011
Date of Patent:
June 14, 2016
Assignee:
Shell Oil Company
Inventors:
Klaas Lambertus Von Hebel, Jean-Paul Lange
Abstract: In a process for producing cyclohexylbenzene, benzene is contacted with hydrogen under hydroalkylation conditions effective to form a first effluent stream comprising cyclohexylbenzene, cyclohexane, methylcyclopentane, and unreacted benzene. At least a portion of the first effluent stream is contacted with a dehydrogenation catalyst under dehydrogenation conditions to convert at least a portion of the cyclohexane to benzene thereby forming a second effluent stream. The amount of methylcyclopentane in the second effluent stream is different by no more than 65% of the total amount of the portion of the first effluent stream, said amounts being on a weight basis. A methylcyclopentane-containing stream is removed from either the first or the second effluent stream and at least a portion of the second effluent stream containing benzene is recycled to the hydroalkylation step.
Type:
Grant
Filed:
December 2, 2011
Date of Patent:
June 14, 2016
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Keith H. Kuechler, James R. Lattner, Christopher L. Becker, Jihad M. Dakka, Tan-Jen Chen
Abstract: The present invention is a process for transalkylating aromatic hydrocarbon compounds, the process comprising introducing an aromatic hydrocarbon feed stream into a transalkylation zone to yield high-purity benzene as a byproduct while meeting transalkylation objectives. The feed stream contacts a catalyst in the transalkylation zone under conditions adjusted to control benzene purity as well as transalkylation performance.
Type:
Grant
Filed:
September 14, 2011
Date of Patent:
June 14, 2016
Assignee:
UOP LLC
Inventors:
David S. Lafyatis, Edwin P. Boldingh, Eric J. Baker, James A. Johnson, Robert B. Larson
Abstract: Process for hydrotreating a heavy hydrocarbon fraction using a system of switchable fixed bed guard zones each containing at least one catalyst bed including at least one step during which the flow of feed supplied to the first guard zone brought into contact with the feed is partly displaced to the next guard zone downstream, preferably progressively.
Type:
Grant
Filed:
December 20, 2011
Date of Patent:
June 7, 2016
Assignee:
IFP ENERGIES NOUVELLES
Inventors:
Frederic Bazer-Bachi, Mathieu Digne, Jan Verstraete, Nicolas Marchal, Cecile Plain
Abstract: A process and a plant for producing C2-C4 olefins, in particular propylene, from an educt mixture containing steam as well as methanol vapor and/or dimethyl ether vapor.
Type:
Grant
Filed:
June 23, 2006
Date of Patent:
June 7, 2016
Assignee:
Lurgi GmbH
Inventors:
Martin Rothaemel, Uwe Finck, Thomas Renner, Henning Buchold
Abstract: To economically regenerate a catalyst and to produce aromatic hydrocarbon stably for a long time maintaining a high aromatic hydrocarbon yield when the aromatic hydrocarbon is produced upon making a contact reaction between lower hydrocarbon and the catalyst. A method of producing aromatic hydrocarbon and an apparatus for producing aromatic hydrocarbon by repeating a reaction step for obtaining aromatic hydrocarbon upon making a contact reaction between lower hydrocarbon and a catalyst and a regeneration step for regenerating the catalyst used in the reaction step. Off-gas which is gas obtained by removing aromatic hydrocarbon produced in the reaction step from discharge gas passing through the reaction step is used as a regeneration gas in the regeneration step.
Abstract: A coke oven includes an oven chamber, an uptake duct in fluid communication with the oven chamber, the uptake duct being configured to receive exhaust gases from the oven chamber, an uptake damper in fluid communication with the uptake duct, the uptake damper being positioned at any one of multiple positions, the uptake damper configured to control an oven draft, an actuator configured to alter the position of the uptake damper between the positions in response to a position instruction, a sensor configured to detect an operating condition of the coke oven, wherein the sensor includes one of a draft sensor, a temperature sensor configured to detect an uptake duct temperature or a sole flue temperature, and an oxygen sensor, and a controller being configured to provide the position instruction to the actuator in response to the operating condition detected by the sensor.
Type:
Grant
Filed:
August 17, 2012
Date of Patent:
June 7, 2016
Assignee:
SUNCOKE TECHNOLOGY AND DEVELOPMENT LLC
Inventors:
John F. Quanci, Peter U. Chun, Milos J. Kaplarevic, Vince G. Reiling
Abstract: The invention relates to an arrangement for feeding heat-sensitive feedstock to a fixed-bed reactor system comprising means for product recycle and a fixed-bed reactor system comprising a fixed-bed reactor comprising at least one reaction zone having at least one catalyst bed and said reaction zone comprising a cold feed distributor arranged on top of each catalyst bed and a conventional distributor arranged above each cold feed distributor. Also a method is provided for feeding heat-sensitive feedstock to a fixed-bed reactor system wherein said fixed-bed reactor system comprises means for product recycle and a fixed-bed reactor comprising at least one reaction zone having at least one catalyst bed and said reaction zone comprising a cold feed distributor arranged on top of each catalyst bed and a conventional distributor arranged above each cold feed distributor.
Abstract: A device (100) for distilling or thickening fluids, having a chamber (102), an electromagnetic radiation generator (104) and a waveguide (106) connecting the electromagnetic radiation generator (104) with the interior of the chamber (102). The device (100) has a channel (108) located below the end (110) of the waveguide (106), the channel being adapted for transporting the fluid. One end of the channel (108) is the inlet (112) and the other end of the channel (108) is the outlet (114) for the fluid, the channel being shaped so as to prolong the dwell time of the fluid in the chamber (102).
Abstract: The present disclosure provides oxidative coupling of methane (OCM) systems for small scale and world scale production of olefins. An OCM system may comprise an OCM subsystem that generates a product stream comprising C2+ compounds and non-C2+ impurities from methane and an oxidizing agent. At least one separations subsystem downstream of, and fluidically coupled to, the OCM subsystem can be used to separate the non-C2+ impurities from the C2+ compounds. A methanation subsystem downstream and fluidically coupled to the OCM subsystem can be used to react H2 with CO and/or CO2 in the non-C2+ impurities to generate methane, which can be recycled to the OCM subsystem. The OCM system can be integrated in a non-OCM system, such as a natural gas liquids system or an existing ethylene cracker.
Type:
Grant
Filed:
July 1, 2015
Date of Patent:
May 31, 2016
Assignee:
Siluria Technologies, Inc.
Inventors:
Humera A. Rafique, Srinivas Vuddagiri, Guido Radaelli, Erik C. Scher, Jarod McCormick, Joel Cizeron
Abstract: The invention provides a process for comminuting coal or other fuel solids in a shear field, and for optionally coating the solids with catalysts for combustion, liquefaction, and or gasification during the milling process. The process further provides for control of water content in the solids may be controlled before, during and after the milling in order to obtain micronized solids with fine hydration layers. The output fuel solids from the process can burn at low temperatures, avoiding emissions of nitrogen oxides, and they also have improved properties for surfactant-free suspension in either water or oil media, as well as for liquefaction and gasification.
Abstract: The present invention relates to processes for hydromethanating a carbonaceous feedstock to a methane-enriched synthesis gas, where an oxygen-rich gas stream and the carbonaceous feedstock are fed into a fluidized-bed hydromethanation reactor at a specified zone in order to assist in heat management within the hydromethanation reactor.
Type:
Grant
Filed:
October 28, 2011
Date of Patent:
May 31, 2016
Assignee:
GreatPoint Energy, Inc.
Inventors:
Pattabhi K. Raman, Veeraya Jiradilok, Earl T. Robinson, Avinash Sirdeshpande
Abstract: The present invention relates to a process for isomerizing linear alpha-olefins having from 4 to 8 carbon atoms over a heterogeneous catalyst, wherein the catalyst comprises a hydrogenation metal and a selectivity promoter selected from among selenium and tellurium on a support, and also a process for preparing 1-olefins by a metathesis reaction of 2-olefins with ethene, wherein the 2-olefins are prepared by the above mentioned isomerization process.
Type:
Grant
Filed:
April 27, 2012
Date of Patent:
May 24, 2016
Assignee:
BASF SE
Inventors:
Stefan Iselborn, Michael Hesse, Piotr Makarczyk
Abstract: A catalyst return apparatus is disclosed as well as a riser reactor system comprising the conduit apparatus and a riser reactor, the conduit apparatus comprising a catalyst return conduit and at least two flow control devices in series, each flow control device arranged to control the flow of fluid through the conduit, wherein the length of the catalyst return conduit is more than 20 m. A process for reacting a feedstock in a riser reactor system comprising a riser reactor, the catalyst return apparatus and, and a stage vessel, the process comprising: holding a fluid comprising the catalyst in the at least one stage vessel for a residence time of at least 10 seconds.
Type:
Grant
Filed:
April 24, 2014
Date of Patent:
May 17, 2016
Assignee:
Shell Oil Company
Inventors:
Leslie Andrew Chewter, Hubertus Wilhelmus Albertus Dries, Rene Samson, Mao Ye
Abstract: A liquid fuel formed by the mixture of toluene, meta-xylene and n-hexane, in proportions of between 50 and 70% of toluene, between 10 and 20% of meta-xylene and between 20 and 30% of n-hexane.
Abstract: Disclosed is a method for producing a conjugated diene by subjecting a monoolefin having a carbon atom number of 4 or more and an oxygen gas to an oxidative dehydrogenation reaction by using a molybdenum-containing metal oxide catalyst under heat removal with a coolant, wherein an amount of molybdenum adhered onto a cooling heat transfer surface within a reactor is kept at not more than 20 mg/m2, or not only a surface roughness Ra of a cooling heat transfer surface within a reactor is not more than 3 ?m, but a temperature difference between a reaction temperature and a coolant temperature is in the range of from 5 to 220° C.
Abstract: A process for oligomerization of ethylene, comprising subjecting a catalyst composition to a gas phase of ethylene and conducting an oligomerization, wherein the catalyst composition comprises (a) a chromium compound, (b) a metalated ligand, and (c) an activator or cocatalyst; and catalyst composition as well as a metalated ligand.
Type:
Grant
Filed:
February 10, 2014
Date of Patent:
May 17, 2016
Assignees:
SAUDI BASIC INDUSTRIES CORPORATION, LINDE AG
Inventors:
Abdullah Mohammad Al-Qahtani, Mohammed H. Al-Hazmi, Uwe Rosenthal, Bernd H. Müller, Normen Peulecke, Marco Harff, Anina Wöhl, Andreas Meiswinkel, Heinz Bölt, Wolfgang Müller
Abstract: A process for conversion of isobutanol to make propylene includes dehydrating isobutanol to produce butenes. The process includes cracking the butenes to produce propylene.
Type:
Grant
Filed:
May 13, 2015
Date of Patent:
May 10, 2016
Assignee:
Total Research & Technology Feluy
Inventors:
Cindy Adam, Delphine Minoux, Nikolai Nesterenko, Sander Van Donk, Jean-Pierre Dath
Abstract: Disclosed are methods and apparatuses for recovering and reusing energy when processing materials with reactive fluids. More particularly, disclosed are methods and apparatuses for recovering and reusing energy from processes in which materials comprising polymers and/or oligomers are treated with a reactive fluid.
Type:
Grant
Filed:
July 10, 2013
Date of Patent:
May 3, 2016
Assignee:
Renmatix, Inc.
Inventors:
Frederick John Moesler, Michel Adam Simard, Manuk Colakyan, Paul Anthony Neilson