Abstract: The present invention provides expanded beads of thermoplastic polyurethane, wherein the thermoplastic polyurethane constituting the expanded beads is an ether-based thermoplastic polyurethane, and a difference (T1?T2) between a melting peak temperature (T1) and a melting peak temperature (T2) is from 0 to 8° C., wherein the melting peak temperature (T1) is a melting peak temperature at the time of first heating in a DSC curve obtained by heating the expanded beads from 20° C. to 260° C. at a heating rate of 10° C./min, the melting peak temperature (T2) is a melting peak temperature at the time of second heating in a DSC curve obtained by cooling from 260° C. to 20° C. at a cooling rate of 10° C./min after the first heating and further heating again from 20° C. to 260° C. at a heating rate of 10° C./min, and the DSC curves are obtained by the heat flux differential scanning calorimetry in conformity with JIS K7121-1987.

Abstract: Polyurethane foams and methods of manufacturing are described herein. The foam can include (a) a polyurethane formed by the reaction of (i) one or more isocyanates selected from the group consisting of diisocyanates, polyisocyanates, and mixtures thereof, and (ii) one or more polyols; and (b) a filler. The amount of filler in the foam can be from 50 to 90% by weight, based on the total weight of the foam. The filler can include a plurality of fibers and/or a particulate filler. The polyurethane foams described herein are made without adding a surfactant to the reaction mixture. The density of the polyurethane foam can be at least 5 lb/ft3.

Abstract: The present invention relates to a process for producing flame-retarded polyurethane foams, in particular flexible polyurethane foams, using halogen-free flame retardants, wherein the resulting flame-retarded polyurethane foams exhibit low emission values coupled with good mechanical properties. The present invention further relates to halogen-free flame retardants.

Abstract: A method of forming a flexible polyurethane foam that passes BS 5852:2006 source V (Crib 5) test. The method includes providing a modified polyisocyanate polyaddition (PIPA) 5 polyol formed by contacting a PIPA polyol dispersion with at least one carboxylic acid having a melting point above zero degree Celsius and present in a carrier solvent. The PIPA polyol dispersion has a polyol liquid phase content of 60 wt. % to 90 wt. % and a solid particle phase content of 10 wt. % to 40 wt. % based on a total weight of the PIPA polyol dispersion. From 10 weight percent (wt. %) to 80 wt. % of the modified PIPA polyol is combined with 90 wt. % to 20 10 wt. % of at least another polyether polyol based on a total weight of a polyol blend of the PIPA polyol and the at least another polyether polyol, where the polyether polyol is formed with propylene oxide and ethylene oxide and has an equivalent weight of 1,000 to 2,000 and a functionality of 3 to 6.

Abstract: The present invention provides a stabilising composition, comprising: a) a first phenolic antioxidant comprising one or more phenolic compounds having the structure of formula (I) wherein R1 is a linear or branched alkyl group having from 12 to 20 carbon atoms; and b) one or more second phenolic antioxidants independently selected from: a mono-hydroxybenzene having lower steric hindrance than the first phenolic antioxidant; a di-hydroxybenzene; and/or a tri-hydroxybenzene.

Abstract: A rigid foam or a composition allowing a rigid foam to be obtained, including a polyester polyol or a polymer including a polyester polyol, the polyester polyol being obtained by a first polycondensation (a) of a C3 to C8 sugar alcohol Z and two identical or different C4 to C36 diacids Y and Y? and a second polycondensation (b) of the product obtained in (a) with two identical or different C2 to C12 diols X and X?.

Abstract: A polyester polyol of formula produced by a first polycondensation (a) of a sugar alcohol Z in C3 to C8 and two diacids Y and Y? which are the same or different in C4 to C36, and a second polycondensation (b) of the product produced in (a) with two diols X and X? which are the same or different in C2 to C12, the polymer including such a polyester polyol. Also, a method for producing the polyester polyols and the use thereof in foams, adhesives, coatings or elastomers of polyurethane or polyisocyanurate.

Abstract: A composition for forming polyurethane foams is provided using epoxidized triglycerides with unopened rings. The composition further includes a polyol, a blowing agent, and a catalyst that catalyzes the reaction of polyols with isocyanates to form polyurethanes. The polyol is a polyoxyalklylene and the epoxidized triglyceride is an epoxidized soybean oil. A method for forming polyurethane foam using the aforementioned composition is also provided.

Abstract: The invention relates to a process used to produce open-cell and extremely fine-cell PUR/PIR rigid foams, said process using a polyol formulation comprising a specific isocyanate-reactive component, a catalyst component having zerewitinoff-active hydrogens and a cell-opener component.

Abstract: Polyol blends are disclosed that include a saccharide-initiated polyether polyol, an aromatic polyester polyol, and a polyalkylene polyamine-initiated polyether polyol. Also disclosed are foam-forming compositions containing such polyol blends, rigid foams made using such polyurethane foam-forming compositions, and methods for producing such foams, including use of such foams as panel insulation.

Abstract: Methods and materials used for production of constructs having a porous open or semi-open celled structure. Constructs may include a porous matrix as a base and a biocompatible conformal coating thereon.

Abstract: The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to open-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a sterically hindered amine catalyst.

Abstract: This invention relates to novel macromers containing dithiocarbonate (or xanthate) groups, novel preformed stabilizers comprising macromers, and novel polymer polyols comprising the novel macromers and/or novel preformed stabilizers. This invention also relates to processes for the preparation of these materials. Other aspects of this invention include foams comprising the novel polymer polyols and a process for preparing foam comprising the novel polymer polyols.

Abstract: The invention relates to a process for production of expanded thermoplastic elastomer, said process comprising the steps of: (e) adding monomers and/or oligomers used for producing the thermoplastic elastomer with or without further starting materials into a first stage of a polymer-processing machine, (f) mixing the monomers and/or oligomers and also the optionally added further starting materials and reacting the monomers and/or oligomers to give a polymer melt in the first stage of the polymer-processing machine, (g) passing the polymer melt into a second stage of a polymer-processing machine and adding a physical blowing agent with or without further starting materials to obtain a polymer melt comprising a blowing agent, (h) molding the polymer melt comprising a blowing agent into an expanded thermoplastic elastomer.

Abstract: The present invention relates to self-foaming hot melt adhesive compositions and methods of making and using the same. Self-foaming hot melt adhesive compositions are formed by admixing a dispersion concentrate including a chemical blowing agent and a compatible carrier (liquid or molten) with a molten base hot melt adhesive composition at a temperature below the decomposition temperature of the chemical blowing agent. The resolidified material is processed through a device that heats the material above the decomposition temperature of the chemical agent and cools it below such temperature before being dispensed. The device preferably includes sensors and a controller configured to prevent the material from accumulating an adverse thermal history during processing.

Abstract: The present invention relates to the use of hydrophilized polyisocyanates for the production of water-diluted coating compositions.

Abstract: The present invention relates to the use of hydrophilized polyisocyanates for the production of water-diluted coating compositions which have a polymeric polyol content of not more than 10%.

Abstract: An attrition-resistant superabsorbent polymer and a preparation method thereof are disclosed herein. In some embodiments, an attrition resistant superabsorbent polymer includes a superabsorbent polymer having a crosslinked surface, water, particles, a multivalent metal salt, an organic acid and a polyhydric alcohol, wherein the particles having a BET specific surface area of 300 to 1500 m2/g and a porosity of 50% or more.

Abstract: A direct and simple method to control cell size in a polyurethane foam is disclosed. Polyurethane foam is made by mixing prepolymer with foam-forming ingredients comprising isocyanate and water which react to give carbon dioxide. The reaction is driven by a catalyst and results in a foam structure with cells of a particular size. Using the addition of a pre-determined amount of mineral oil, the coalescence of neighboring cells of the foam structure may be advantageously controlled to form a cell structure with a desired average cell size.

Abstract: A liquid resin composition may include a base resin (A) in an amount of 100 parts by weight, a chemical foaming agent (B) in an amount of 2 parts by weight or more and 100 parts by weight or less, and water (C) in an amount of 1 part by weight or more and 30 parts by weight or less. The base resin may be a polymer that includes a hydrolyzable group bonded to a silicon atom, at least one reactive silicon group that is capable of being crosslinked by forming a siloxane bond, and a main chain that is constituted by an oxyalkylene-based monomer unit. The chemical foaming agent (B) may include a bicarbonate (B-1) and an acidic compound (B-2) having an acid dissociation constant pKa of 3.0 or less.