Abstract: The present invention is to provide a bound stopper, which has high mechanical strength, is excellent in durability against fatigue breaking, settling or the like when a heavy load is repeatedly received, and is easy to be produced, in which the bound stopper comprises a polyurethane foam obtained from a polyurethane foam composition containing an isocyanate component and a blowing agent, and the isocyanate component contains a urethane prepolymer having an isocyanate group, the urethane prepolymer being obtained from a polyol component, a polyrotaxane containing a cyclic molecule having an active hydrogen group as a constituent, and an isocyanate.

Abstract: A foamed, opacifying element is prepared to have a light-blocking value (LBV) of at least 4. A method is carried out in a specific order with a unique series of steps including: providing a unique foamable aqueous composition; aerating that foamable aqueous composition to a foam density of at least 0.1-0.5 g/cm3; disposing the foamed aqueous composition onto a surface of a porous substrate; drying the foamed aqueous composition without substantial curing of the binder material therein, to provide a dry foamed composition on the surface, without substantial curing; densifying the dry foamed composition to provide a dry opacifying layer in a foamed, opacifying element; and curing the dry opacifying layer in the foamed, opacifying element.

Abstract: Heat-expandable microspheres and applications thereof, the heat-expandable microspheres including a thermoplastic resin shell and a thermally-vaporizable blowing agent encapsulated therein. The thermoplastic resin is produced by polymerizing a polymerizable component containing (A) a nitrile monomer including methacrylonitrile, (B) a carboxyl-group-containing monomer and (C) a monomer having a functional group reactive with the carboxyl group. The polymerizable component satisfies the following conditions 1 and 2: Condition 1: The weight fraction of the monomers (A), (B) and (C) in the polymerizable component satisfy the inequality shown below. Weight fraction of the monomer (C)<Weight fraction of the monomer (A)?Weight fraction of the monomer (B)??Inequality (I) Condition 2: The ratio by weight of the monomer (B) to the monomer (C) ranges from 600:1 to 3:1.

Abstract: In certain non-limiting, aspects, the present invention relates to storage stable premixes of a polyol suitable for polyurethane or polyisocyanurate foam preparation having, at least, 1,1,1,4,4,4-hexafluoro-2-butene (1336mzzm) as the blowing agent and optional one or more additional additives and/or auxillary blowing agents in amounts suitable for polyurethane or polyisocyanurate foam preparation.

Abstract: Provided herein is a process for producing viscoelastic polyurethane foams having a density of from 100 g/dm3 to 300 g/dm3, in which (a) polyisocyanate is mixed with (b) polymeric compounds having groups that are reactive toward isocyanates, (d) a catalyst, and (e) a blowing agent including water at an isocyanate index of from 50 to 95 to give a reaction mixture. The reaction mixture is placed in a mold and reacted to give the flexible polyurethane foam, wherein the polyisocyanate (a) is obtainable by mixing 4,4?-MDI and oligomers of propylene oxide having from 2 to 8 propylene oxide units. The polymeric compounds (b) include at least one polyalkylene oxide having a hydroxyl number of from 20 to 50 mg KOH/g derived from a trifunctional starter molecule and a proportion of ethylene oxide, based on the content of alkylene oxide, of from 0 to 10% by weight.

Abstract: The invention relates to flame-retardant flexible polyurethane foams with phosphazene and to methods for producing PUR flexible foams by reacting a component A containing: A1, an isocyanate-reactive component, A2, a propellant containing water, A3, optionally auxiliary agents and additives, and A4, a flame retardant, with B, an isocyanate component. The invention is characterized in that the flame retardant A4 contains a phosphazene according to the formula (I): [PmNmXk] (I), where X independently of one another represents O-aryl or NR-aryl, at least one aryl group is substituted, X can represent a bridge, R is selected from the group of H, C1-C4 alkyl, and aryl, and m represents a number from 1 to 5, particularly preferably 3 or 4, k depends on m and represents a number from 0 to 2m, and the phosphazene does not have any groups which are reactive towards isocyanates.

Abstract: A buffer material including a skinned polyurethane foam including a foam layer and a skin layer formed on the surface of the foam layer, wherein the skinned polyurethane foam essentially contains no silicone compound, the foam layer is polyurethane foam, the skin layer is a polyurethane resin layer produced by reaction of a skin-isocyanate component containing an aliphatic and/or an alicyclic polyisocyanate with a skin-active hydrogen group-containing component, the skin layer has a storage modulus at 23° C. (E?coat) of 1×107 Pa or more and 3×108 Pa or less, the foam layer has a storage modulus at 23° C. (E?foam) of 1×105 Pa or more and 5×106 Pa or less, and the ratio (E?coat/E?foam) of the storage modulus at 23° C. (E?coat) of the skin layer relative to the storage modulus at 23° C. (E?foam) of the foam layer is 10 or more and 500 or less.

Abstract: The invention relates to a method for producing polyurethane foams by reacting the following components A a polyol component containing A1 40 to 100 parts by weight of polyether carbonate polyol with a hydroxyl number according to DIN 53240-1 June 2013 of 20 mg KOH/g to 120 mg KOH/g, A2 0 to 60 parts by weight of polyether polyol with a hydroxyl number according to DIN 53240-1 June 2013 of 20 mg KOH/g to 250 mg KOH/g and an ethylene oxide content of 0 to 60 wt. %, wherein polyether polyol A2 is free from carbonate units, B B1 a catalyst and B2 optionally auxiliary and additional materials, C water and/or physical blowing agents with D di- and/or polyisocyanates, wherein the production occurs at a characteristic value of 90 to 120, characterised in that the component A contains a component A5 of 0.05 to 10.00 parts by weight of polyester polyol, in relation to the sum of the parts by weight of the components A1+A2=100 parts by weight, said polyester polyol containing units derived from malonic acid.

Abstract: The present invention is concerned with expanded beads of thermoplastic polyurethane in which a water-soluble anionic surfactant is attached at 50 mg/m2 to 1,000 mg/m2 onto the surfaces of expanded beads of thermoplastic polyurethane having a dispersant attached thereto; and a method for producing an expanded beads molded article, including filling the expanded beads of thermoplastic polyurethane in a mold for molding and heating with a water vapor to mutually fuse the expanded beads with each other. The present invention provides expanded beads from which an expanded TPU beads molded article having excellent tensile strength and a method for producing an expanded TPU beads molded article.

Abstract: A polyisocyanurate foam insulation product includes polyisocyanurate foam produced from reacting an isocyanate and a polyol blend having a functionality of at least 2.2. The isocyanate and the polyol blend are reacted so that the polyisocyanurate foam has an isocyanate index equivalent with or greater than 300. The polyisocyanurate foam includes a fire retardant and includes between 0.02 and 0.45 weight percent of a zinc salt compound. The foam insulation board exhibits a flame spread of no greater than 25 and a smoke index of no greater than 50 when exposed to flame conditions in accordance with an ASTM E-84 test.

Abstract: A method of forming a polyurethane foam article includes the step of forming a resin composition. The resin composition includes a polyol component, an amine catalyst, and a blowing component. The blowing component includes a hydrofluoroolefin and formic acid. The method also includes the steps of combining the resin composition, a recycled resin composition, and an isocyanate component to form a reaction mixture and discharging the reaction mixture to form the polyurethane foam article.

Abstract: A polyurethane catalyst comprises a sodium compound, the sodium compound being 1 to 60 wt % of the polyurethane catalyst by the mass percent, and further comprises a tertiary amine and/or pyridine compound. The sodium compound and the tertiary amine and/or pyridine compound achieve a synergistic effect; during the catalysis of the polymerization of isocyanate and polyalcohol, the speed of the polymerization reaction is increased; and the prepared polyurethane material has excellent physical properties, does not contain any heavy metal element at all, is an environment-friendly catalyst, solves the technical problem of ensuring environmental protection, safety and the catalytic efficiency of the polyurethane catalyst, and is particularly applicable to the preparation of polyurethane synthetic leather resin slurry, a polyurethane elastomer (prepolymer), a polyurethane coating, a polyurethane adhesive, a polyurethane composite material, flexible polyurethane foam, and a rigid polyurethane material.

Abstract: A foaming process for converting fibrous material into a cellular foam structure includes mixing fibrous material and a solvent-based binding agent to form a mixture; saturating the mixture with a pressurized gas to form a gas-saturated mixture; expanding the gas-saturated mixture by reducing the pressure of the pressurized gas to form an expanded mixture with voids in the fibrous material; and curing the expanded mixture to set the fibrous material and drive off the solvent to provide a stable network of fibrous material having cushioning properties.

Abstract: Compositions suitable for production of polyurethane foams, comprising at least one OH-functional compound (OHC) obtainable by the partial or complete hydrogenation of ketone-aldehyde resins, wherein the OH-functional compound contains at least one structural element of the formula (1a) and optionally of the formulae (1b) and/or (1c), with R=aromatic with 6-14 carbon atoms, (cyclo)aliphatic with 1-12 carbon atoms, R1=H, CH2OH, R2=H, or a radical of the formula —(CH2—CH(R?)O—)y—H where R? is hydrogen, methyl, ethyl or phenyl and y=1 to 50, k=2 to 15, preferably 3 to 12, more preferably 4 to 11, m=0 to 13, preferably 0 to 9, l=0 to 2, where the sum of k+l+m is from 5 to 15, preferably from 5 to 12, and k>m, are described.

Abstract: The present invention provides a soft polyurethane foam molded atticle which has a mounting surface (1A) can be obtained by foaming and molding a raw foaming liquid, and has a constitution which a ratio of a diameter of a foaming cell in the horizontal direction X along the mounting surface (1A) to a diameter of the foaming cell in the vertical direction Y orthogonal to the mounting surface (1A) increases toward the mounting surface (1A) in the vertical direction (Y).

Abstract: A spray foam formulation used to form a spray foam insulation layer in a wall structure is described. The formulation may include the reaction product of a polyisocyanate compound and a polyol compound; a fire retardant chosen from at least one of a non-halogenated fire retardant; and a reactive halogen-containing fire retardant, and a carbohydrate. The spray foam insulation layer has an insulative R value of 3.0 to 7.2 per inch, and a density of between about 0.3 to about 4.5 pcf. Further, spray foam insulation made from the spray foam formulation may have fire retardant characteristics that are equivalent to or better than a similar spray insulation foam insulation using non-reactive halogenated fire retardants such as tris(1-chloro-2-propyl)phosphate (TCPP).

Abstract: Embodiments of the present disclosure are directed towards semi-flexible foam formulations that can be utilized to form semi-flexible foams. As an example, a semiflexible foam formulation can include a first polyether polyol having an average nominal hydroxyl functionality from 2 to 4 and a number average equivalent weight from 120 to 1500, a second polyether polyol having a having an average nominal hydroxyl functionality from 4 to 8 and a number average equivalent weight from 120 to 800, and a third polyether polyol having an average nominal hydroxyl functionality from 2 to 4 a number average equivalent weight from 200 to 500 and toluene diisocyanate.

Abstract: Disclosed are ethylenically unsaturated macromers produced using a residue of an isocyanate manufacturing process. Also disclosed are preformed stabilizers produced using such macromers, polymer polyols produced using such preformed stabilizers, foam-forming compositions produced using such polymer polyols, and foam produced using such compositions.

Abstract: Disclosed are a process of producing a polyurethane foam product, a polyurethane foam product pre-mix, polyurethane foam product formulation, and a polyurethane foam product. The process of producing the polyurethane foam product includes contacting a halohydrin component with a polyurethane foam product pre-mix. The polyurethane foam product pre-mix includes the halohydrin component. The polyurethane foam product formulation includes a polyol component, an isocyanate component, and a halohydrin component. The polyurethane foam product is formed by the pre-mix having the halohydrin component.

Abstract: This invention relates to a process for preparing viscoelastic flexible polyurethane foam comprising reacting an isocyanate component with an isocyanate-reactive component that comprises a polyol blend having a hydroxyl number of 56 to 250 and an average functionality of greater than 2, and a hydroxyl-terminated prepolymer. The invention also relates to viscoelastic flexible polyurethane foams.