Patents Examined by Lynette T. Umez-Eronini
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Patent number: 7473380Abstract: An etching liquid contains iodine, an iodine compound and alcohol as solute, and solvent such as water. The etching liquid etches a gold or gold alloy layer formed on the surface of a substrate for a semiconductor device or a liquid crystal device evenly. A plurality of gold or gold alloy columns is formed on the layer. The columns are etched scarcely by the etching liquid. The etching liquid etches the gold or gold alloy layer existing between the columns evenly. The etching liquid may further contain a surfactant.Type: GrantFiled: November 22, 2002Date of Patent: January 6, 2009Assignees: Sharp Kabushiki Kaisha, Mitsubishi Chemical CorporationInventors: Yoshihide Suzuki, Keiichi Sawai, Noriyuki Saitou, Masaru Miyoshi, Makoto Ishikawa
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Patent number: 7354861Abstract: Disclosed is a method for polishing a surface of a substrate containing Ru or a Ru compound in a surface region, said method comprising a polishing step with a polishing liquid containing tetravalent cerium ions. The polishing liquid is prepared by adding a compound having a tetravalent cerium ion or its solution to a solvent in or immediately before the polishing step of the substrate.Type: GrantFiled: December 2, 1999Date of Patent: April 8, 2008Assignee: Kabushiki Kaisha ToshibaInventors: Kenro Nakamura, Takeo Kubota, Gaku Minamihaba
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Patent number: 7351660Abstract: A method for fabricating high performance vertical and horizontal electrical connections in a three dimensional semiconductor structure. A dielectric film is imprinted with a stamp pattern at high vacuum and with precise temperature and stamping pressure control. The stamp pattern may be formed on a substrate using semiconductor fabrication techniques. After the dielectric film is stamped, residual dielectric film is removed to allow access to an underlying layer. Via and trench regions formed within the dielectric film by stamping are then metalized to provide the high performance interconnections. Multiple layers of interconnections in the three dimensional structure are provided by stacking layers of stamped and metalized dielectric films on top of each other.Type: GrantFiled: September 26, 2002Date of Patent: April 1, 2008Assignee: HRL Laboratories, LLCInventors: Peter D. Brewer, Carl W. Pobanz
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Patent number: 7341949Abstract: A process for forming a lead-free bump on an electronic component includes preparing the electronic component with at least one bond pad and a passivation layer formed thereon; forming an under bump metallurgy (UBM) structure on the passivation layer and the bond pad; applying a photoresist over the passivation layer, the photoresist having at least one opening corresponding to the bond pad; depositing a thick copper layer (about 1 to 10 ?m thick) in the opening by electroplating; applying a copper-free or low-copper-content solder material on the copper layer; and performing a reflowing procedure under a suitable reflow temperature profile to allow copper ions to diffuse from the copper layer to the solder material so as to form the lead-free bump. This increases the copper content in the solder material but not raising the reflow temperature profile, thereby preventing deterioration of the photoresist due to over heat.Type: GrantFiled: June 4, 2004Date of Patent: March 11, 2008Assignee: Siliconware Precision Industries Co., Ltd.Inventors: Feng-Lung Chien, Huang-Chuan Chang, Chun-Sheng Ho
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Patent number: 7332436Abstract: A composition which includes liquid or supercritical carbon dioxide and an acid having a pKa of less than about 4. The composition is employed in a process of removing residue from a precision surface, such as a semiconductor sample, in which the precision surface is contacted with the composition under thermodynamic conditions consistent with the retention of the liquid or supercritical carbon dioxide in the liquid or supercritical state.Type: GrantFiled: October 15, 2004Date of Patent: February 19, 2008Assignee: International Business Machines CorporationInventors: John Michael Cotte, Dario L. Goldfarb, Pamela Jones, Kenneth John McCullough, Wayne Martin Moreau, Keith R. Pope, John P. Simons, Charles J. Taft
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Patent number: 7329611Abstract: In a formation method for forming a fine structure in a workpiece containing an etching control component, using an isotropic etching process, a mask having an opening is applied to the workpiece, and the workpiece is etched with an etching solution to thereby form a recess, corresponding to a shape of the opening, in a surface of the workpiece. The etching of the workpiece is stopped due to the etching control component eluted out of the workpiece in the etching solution within the recess during the isotropic etching process.Type: GrantFiled: April 10, 2003Date of Patent: February 12, 2008Assignee: NEC CorporationInventors: Shinichi Uehara, Yuko Sato, Ken Sumiyoshi, Setsuo Kaneko, Jin Matsushima
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Patent number: 7311855Abstract: The present invention is directed to a CMP polishing slurry comprising cerium oxide particles, an organic compound having an acetylene bond (triple bond between carbon and carbon) and water, and a method for polishing a substrate which comprises a step of polishing a film to be polished of the substrate with the polishing slurry. In a CMP (chemical mechanical polishing) technique for flattening inter layer dielectrics, insulating films for shallow trench isolation and the like in a manufacturing process of semiconductor devices, the present invention enables the effective and high-speed polishing.Type: GrantFiled: August 6, 2003Date of Patent: December 25, 2007Assignee: Hitachi Chemical Co., Ltd.Inventors: Kouji Haga, Yuto Ootsuki, Yasushi Kurata, Kazuhiro Enomoto
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Patent number: 7311856Abstract: The invention provides a chemical-mechanical polishing system comprising a polishing component, a surfactant, and a liquid carrier. The invention further provides a method of chemically-mechanically polishing a substrate with the polishing system.Type: GrantFiled: March 30, 2005Date of Patent: December 25, 2007Assignee: Cabot Microelectronics CorporationInventors: Renjie Zhou, Steven K. Grumbine, Jian Zhang, Isaac K. Cherian
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Patent number: 7307020Abstract: General purpose methods for the fabrication of integrated circuits from flexible membranes formed of very thin low stress dielectric materials, such as silicon dioxide or silicon nitride, and semiconductor layers. Semiconductor devices are formed in a semiconductor layer of the membrane. The semiconductor membrane layer is initially formed from a substrate of standard thickness, and all but a thin surface layer of the substrate is then etched or polished away. In another version, the flexible membrane is used as support and electrical interconnect for conventional integrated circuit die bonded thereto, with the interconnect formed in multiple layers in the membrane. Multiple die can be connected to one such membrane, which is then packaged as a multi-chip module. Other applications are based on (circuit) membrane processing for bipolar and MOSFET transistor fabrication, low impedance conductor interconnecting fabrication, flat panel displays, maskless (direct write) lithography, and 3D IC fabrication.Type: GrantFiled: December 18, 2003Date of Patent: December 11, 2007Assignee: Elm Technology CorporationInventor: Glenn J Leedy
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Patent number: 7300881Abstract: A plasma etching is performed on a substrate having a pattern wherein an interval between neighboring openings formed on a resist mask is equal to or less than 200 nm, wherein the etching is performed by converting a processing gas comprising an active species generating gas which includes a compound having carbon and fluorine, and a nonreactive gas which includes xenon gas into a plasma. The nonreactive gas further includes argon gas.Type: GrantFiled: September 8, 2004Date of Patent: November 27, 2007Assignee: Tokyo Electron LimitedInventors: Kazuya Kato, Katsuhiko Ono, Hideki Mizuno, Masahiro Ogasawara, Akinori Kitamura, Noriyuki Kobayashi, Yasushi Inata, Shin Okamoto
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Patent number: 7300601Abstract: A CMP composition containing 5-aminotetrazole, e.g., in combination with oxidizing agent, chelating agent, abrasive and solvent. Such CMP composition advantageously is devoid of BTA, and is useful for polishing surfaces of copper elements on semiconductor substrates, without the occurrence of dishing or other adverse planarization deficiencies in the polished copper, even in the presence of substantial levels of copper ions, e.g., Cu2+, in the bulk CMP composition at the copper/CMP composition interface during CMP processing.Type: GrantFiled: December 10, 2002Date of Patent: November 27, 2007Assignee: Advanced Technology Materials, Inc.Inventors: Jun Liu, Peter Wrschka, David Bernhard, MacKenzie King, Michael Darsillo, Karl Boggs
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Patent number: 7300602Abstract: The polishing solution is useful for removing barrier materials in the presence of interconnect metals and dielectrics. The polishing solution comprises, by weight percent, 0.1 to 10 hydrogen peroxide, at least one pH adjusting agent selected from the group consisting of nitric acid, sulfuric acid, hydrochloric acid and phosphoric acid for adjusting a pH level of the polishing solution to less than 3, at least 0.0025 benzotriazole inhibitor for reducing removal rate of the interconnect metals, 0 to 10 surfactant, 0.01 to 10 colloidal silica having an average particle size of less than 50 nm and balance water and incidental impurities. The polishing solution has a tantalum nitride material to copper selectivity of at least 3 to 1 and a tantalum nitride to TEOS selectivity of at least 3 to 1.Type: GrantFiled: January 23, 2003Date of Patent: November 27, 2007Assignee: Rohm and Haas Electronic Materials CMP Holdings, Inc.Inventors: Zhendong Liu, Ross E. Barker, II
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Patent number: 7288212Abstract: An additive composition for a slurry contains a first salt of polymeric acid including a first polymeric acid having a first weight average molecular weight and a first base material, and a second salt of polymeric acid including a second polymeric acid having a second weight average molecular weight and a second base material. A slurry composition is prepared by mixing the additive composition, a polishing particle composition, and water. When implementing a chemical mechanical polishing using the slurry composition, a favorable polishing selectivity is realized.Type: GrantFiled: November 14, 2002Date of Patent: October 30, 2007Assignee: Samsung Electronics Co., Ltd.Inventors: Nam-Soo Kim, Sang-Mun Chon, Young-Sam Lim, Kyoung-Moon Kang, Sei-Cheol Lee, Jae-Hyun So, Dong-Jun Lee
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Patent number: 7285495Abstract: A method for thermally treating a semiconductor layer is described. An embodiment of the technique includes implanting atomic species into a first surface of a donor wafer to form a zone of weakness at a predetermined depth that defines the thickness of a transfer layer, bonding the first surface of the donor wafer to a host wafer, supplying energy to detach the transfer layer from the donor wafer at the zone of weakness, and conducting a recovery operation on the transfer layer. The recovery operation is conducted after detachment but while the layer remains in contact with the donor wafer. The recovery operation includes heat treating the transfer layer for a predetermined duration at a recovery temperature that is lower than a re-adhesion temperature at which the transfer layer would re-adhere to the donor wafer, to improve the crystalline quality and the surface roughness of the transfer layer.Type: GrantFiled: February 16, 2005Date of Patent: October 23, 2007Assignee: S.O.I.Tec Silicon on Insulator TechnologiesInventors: Nicolas Daval, Takeshi Akatsu, Nguyet-Phuong Nguyen
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Patent number: 7282449Abstract: A method for thermally treating a silicon germanium semiconductor layer from a donor wafer is described. An embodiment of the technique includes co-implanting atomic species into a first surface of the donor wafer to form a zone of weakness at a predetermined depth that defines the thickness of a transfer layer, bonding the first surface of the donor wafer to a host wafer, supplying energy to detach the transfer layer from the donor wafer at the zone of weakness, and conducting a recovery operation on the transfer layer. The recovery operation is conducted after detachment but while the layer remains in contact with the donor wafer. The recovery operation includes heat treating the transfer layer for a predetermined duration at a recovery temperature that is lower than a re-adhesion temperature at which the transfer layer would re-adhere to the donor wafer, to improve the crystalline quality and the surface roughness of the transfer layer.Type: GrantFiled: February 17, 2006Date of Patent: October 16, 2007Assignee: S.O.I.Tec Silicon on Insulator TechnologiesInventors: Nicolas Daval, Takeshi Akatsu, Nguyet-Phuong Nguyen
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Patent number: 7273566Abstract: Processes, etchants, and apparatus useful for etching an insulating oxide layer of a substrate without damaging underlying nitride features or field oxide regions. The processes exhibit good selectivity to both nitrides and field oxides. Integrated circuits produced utilizing etching processes of the present invention are much less likely to be defective due to photoresist mask misalignment. Etchants used in processes of the present invention comprise a carrier gas, one or more C2+F gases, CH2F2, and a gas selected from the group consisting of CHF3, CF4, and mixtures thereof. The processes can be performed at power levels lower than what is currently utilized in the prior art.Type: GrantFiled: July 7, 2005Date of Patent: September 25, 2007Assignee: Micron Technology, Inc.Inventor: Kei-Yu Ko
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Patent number: 7268000Abstract: A method and a controller for the chemical mechanical polishing (CMP) of substrates and, in particular, for the chemical mechanical polishing of metallization layers is disclosed. In a linear model of the CMP process, the erosion of the metallization layer to be treated is determined by the overpolish time and possibly by an extra polish time on a separate polishing platen for polishing the dielectric layer, wherein the CMP inherent characteristics are represented by sensitivity parameters derived empirically. Moreover, the control operation is designed so that even with a certain inaccuracy of the sensitivity parameters due to subtle process variations, a reasonable controller response is obtained.Type: GrantFiled: September 30, 2002Date of Patent: September 11, 2007Assignee: Advanced Micro Devices, Inc.Inventors: Dirk Wollstein, Jan Raebiger, Gerd Marxsen
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Patent number: 7262136Abstract: A modified facet etch is disclosed to prevent blown gate oxide and increase etch chamber life. The modified facet etch is a two-stage process. The first stage is a plasma sputter etch to form a facet profile. The first stage etch is terminated prior to reaching the target depth for the etching process. The second stage etch is a reactive ion etch which directionally follows the facet profile to reach the target depth.Type: GrantFiled: July 8, 2004Date of Patent: August 28, 2007Assignee: Micron Technology, Inc.Inventors: William A. Polinsky, Thomas S. Kari, Mark A. Bossler
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Patent number: 7255810Abstract: The invention provides a polishing system and method of its use comprising (a) a liquid carrier, (b) a polymer having a degree of branching of about 50% or greater, and (c) a polishing pad, an abrasive, or a combination thereof.Type: GrantFiled: January 9, 2004Date of Patent: August 14, 2007Assignee: Cabot Microelectronics CorporationInventors: Kevin J. Moeggenborg, Fred F. Sun
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Patent number: 7244680Abstract: A method facilitates generally simultaneously fabricating a number of shallow trench isolation structures such that some selected ones of the shallow trench isolation structures have rounded corners and other selected ones of the shallow trench isolation structures do not have rounded corners. The method includes forming patterned photoresist over a hard mask so that portions of the hard mask are exposed over a portion of a cell region and over a portion of a periphery region, and then removing the exposed hard mask layer in the periphery region while removing a portion of the exposed hard mask layer in the cell region. A trench having rounded corners is then partially formed in the periphery region and more of the hard mask layer is removed in the cell region, before the trench in the periphery region is deepened while a trench in the cell region is formed.Type: GrantFiled: November 14, 2003Date of Patent: July 17, 2007Assignee: Macronix International Co., Ltd.Inventor: Hsu-Sheng Yu