Abstract: The properties of a thermosetting polymer emulsion can be improved by irradiation with an ionizing radiation.By adding a specific amount of lipophilic polyfunctional monomer to a thermosetting polymer emulsion and irradiating with an ionizing radiation, the properties of the thermosetting polymer emulsion can be improved regardless of the type of thermosettable polymer constituting the emulsion. The thermosetting polymer emulsion of which properties are improved by this invention can form a film having excellent water-resistance, chemical resistance and toughness.

Abstract: This invention describes novel radiation curable cellulose ester compositions comprising a carboxylated cellulose ester, a glycidyl acrylate or methacrylate, and an effective amount of a photoinitiator. These compositions, when cured, give hard, tough coatings with excellent adhesion to certain metals.

Abstract: A photopolymerizable composition which contains one or more olefinically unsaturated compounds and from 0.2 to 20% by weight (based on the unsaturated compound(s)) of a photoinitiator, with or without conventional additives, the photoinitiator being a mixture of one or more aromatic carbonyl compounds of the general formula (A) ##STR1## where Ar is an ortho-arylene radical which may or may not be substituted by one or more radicals R.sup.1 to R.sup.4, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and each is H, alkyl or 1 to 5 carbon atoms, phenyl, halogen, alkoxy of 1 to 5 carbon atoms, alkaryl of 7 to 11 carbon atoms, aralkyl of 7 to 11 carbon atoms or --CO.sub.2 R.sup.9, where R.sup.9 is alkyl of 1 to 5 carbon atoms, and n is 0 or 1, and an amine, with or without an aromatic carbonyl compound which differs from (A).This photopolymerizable composition is particularly suitable for the manufacture of photopolymer printing plates and UV-curing printing inks.

Abstract: A method of manufacturing shaped articles of cross-linked poly-.alpha.-olefin composition by irradiation of electron beam which comprises the steps of blending a poly-.alpha.-olefin with a compound miscible therewith which is expressed by the general formula:X--Ym(where X is a group free from acetylenic linkage, Y is a group containing acetylenic linkage and m is an integer of 1 or over) and tetrakis-[methylene-(3,5-di-t-butyl-4-hydroxy-hydrocinnamate)]-methane; molding the blended mass into a desired shape; and cross-linking said shaped articles by irradiation of electron beam.

Abstract: A cured adhesive composition possessing excellent cohesive strength at high temperatures along with excellent adhesion, shear strength and solvent resistance is prepared by the radiation initiated curing of an adhesive composition comprising a monoalkenyl arene/conjugated diene block copolymer, tackifying resin and a di-to-tetra-functional acrylate or methacrylate selected from the group consisting of acrylic and methacrylic acid esters of polyols.

Abstract: High solids, low viscosity, radiation curable, aqueous coatings compositions are provided by adding a small proportion of water to a polyethylenically unsaturated resin, preferably a liquid polyester containing acrylate groups and carboxyl functionality enabling improved dispersibility with water in the presence of a base, and a water soluble monoethylenically unsaturated monomer selected from acrylamide and N-methylol acrylamide is added to lower the viscosity of the composition and also to improve the cure. An ultraviolet photosensitizer, such as benzophenone, is added, preferably together with a tertiary amine cosensitizer, to enable ultraviolet cure.

Abstract: A thermoplastic resin composition containing (I) a graft copolymer of a polyphenylene ether with a styrene type compound, containing substantially no homopolymer of polyphenylene ether, and (II) a graft copolymer of an ethylene copolymer of ethylene and not more than 40 mol percent of at least one unsaturated compound of the formula CH.sub.2 .dbd.CH--OCOR.sub.1 or CH.sub.2 .dbd.CR.sub.2 --COOR.sub.3 (wherein R.sub.1 denotes an alkyl group having one to four carbon atoms and R.sub.2 and R.sub.3 each denote a hydrogen atom or an alkyl group having one to four carbon atoms) with a styrene type compound has improved properties such as Izod impact strength, oil resistance and weathering resistance.

Abstract: Acrylate graft copolymers prepared in a two-stage process by first reacting a backbone polymer, such as 1,2-polybutadiene, an alkylidene norbornene polymer or an ethylene/propylene/alkylidene norbornene terpolymer, with, for example, a mixture of dinitrogen tetroxide and oxygen to form a nitrooxidized polymer having incorporated therein nitro and peroxy nitrate functions which serve, in the second stage of the process, as sites for the subsequent graft polymerization of an acrylate monomer are disclosed. The thus-formed graft copolymers comprise from about 5 to about 80 weight percent of the backbone polymer with the balance being furnished by the acrylate monomer.

Abstract: Photopolymerizable coating compositions contain, as the binder, olefinically unsaturated compounds having a boiling point above 50.degree. C, together with from 0.5 to 15% by weight of photoinitiators, based on the binder. The photoinitiators are a mixture of an aromatic carbonyl compound A, which is a derivative of benzoin or benzil, which has at least one carbon-oxygen single bond in the .alpha.-position relative to the carbonyl group, an aromatic carbonyl compound B which is derived from benzophenone, fluorenone, anthraquinone, xanthene, thioxanthone or acridone, and an amine C of the general formula ##STR1## where R', R" and R"' are H, alkyl of 1 to 10 carbon atoms, cycloalkyl of 3 to 10 carbon atoms, aryl, hydroxyalkyl of 1 to 8 carbon atoms or alkoxyalkyl of 2 to 4 carbon atoms, but at most 2 substituents are H and at most 2 substituents are aromatic.These coating compositions may be used for finishing various substrates, as fillers or as printing inks.

Abstract: A curable coating composition contains a polymer having pendant mercaptan groups and a bis-maleimide cross-linking agent. The mercaptan groups of the polymer cross-link with the bis-maleimide upon curing to form a fully cured coating. In a preferred embodiment, the coating composition serves as a cathodic electrocoating composition.

Abstract: Powder paint coatings of this invention are particularly suitable for ultraviolet curing and comprise specific spatial arrangements of ethylenically unsaturated polymers. The polymers contain pendant double bond unsaturation in combination with an epoxy adduct spaced on the polymer chain from a polyester adduct. The powder paint is free of cold flow and can be applied electrostatically or physically to metal substrates, moderately heated to obtain desired flow out, and then cross-linked or cured by ultraviolet irradiation.

Abstract: A radiation curable coating comprising;A. an oligomer of Formula I: ##STR1## wherein: R.sup.1 is hydrogen or methyl;Y is a divalent urethane residue;B. an acrylic ultra-violet light absorber of Formula IV: ##STR2## wherein R.sup.4 is alkyl or hydroxy alkylene. Preferably the coating composition contains a vinyl monomer copolymerizable with the oligomer. The process for curing the coating is also disclosed.

Abstract: This invention provides for improved printing inks which cure upon exposure to ultraviolet radiation and furthermore demonstrate greatly extended shelf lives and stability as compared to prior art inks. The photosensitive component of the ink comprises a mixture of Michler's ketone and an o-halogen substituted hexa-aryl biimidizolyl compound.

Abstract: Impact-resistant polymers having low permeability to gases and vapors and excellent thermal color stability are prepared by polymerizing an olefinic nitrile, such as acrylonitrile, optionally with an olefinic ester, such as methyl acrylate, in an aqueous medium in the presence of an elastomer which is a copolymer of an ester of an olefinically unsaturated monocarboxylic acid, such as ethyl acrylate.

Abstract: A process for preparing a mixture based on a rubberlike copolymer of ethylene, at least one other alpha - alkene and one or more polyenes and tackifying resins which has good building tack.This good building tack can be obtained if the copolymer contains C.dbd.C bonds positioned in the non linear part of the polymer chains, the carbon atoms of which C.dbd.C bonds either have two hydrocarbon groups which are in vicinal cis relative positions and which do not form part of the same cyclic system, or have at least three hydrocarbon groups. In order to obtain the desired high building tack value the mixture must show in unvulcanized state an elongation at break of at least 500% and a tensile strength lying between 1.5 and 50 kg/cm.sup.2. The mixture must be subjected to an artificial light source radiating light with a wave length of between 200 and 300 nm and impacting a radiated energy to the mixture of at least 2 microwatts/cm.sup.2 per nm in the presence of oxygen and a photosensitizer.

Abstract: A multicomponent polymer blend composition is prepared by intimately mixing a nitrile barrier resin, a selectively hydrogenated monoalkenyl arene-diene block copolymer, and at least one dissimilar engineering thermoplastic resin under such conditions that at least two of the polymers form at least partial continuous network phases which interlock with the other polymer networks and therefore results in a desirable balance of properties.

Abstract: A process of polymerizing a monomer mixture containing from 3 to 100% of amines containing two or more allyl groups which method comprises reacting a solution of the monomer mixture in a concentrated mineral acid in the presence of a polymerization initiator and isolating the polymer salt so formed.

Abstract: The surface characteristics of a partially crosslinked polyurethane innerlayer in a bilayer laminate are further improved by treating the polymer film with a small amount of a compound such as tetrahydrofuran, 1,4 dioxane, dimethyl formamide, morpholine, methylene chloride or secondary or tertiary lower alkyl amines in addition to the photoinitiator.

Abstract: A prepolymer for use in preparing photocurable compositions is prepared by reacting an aliphatic diisocyanate having terminal isocyano groups and at least one alkyl side chain with a hydroxy-, mercapto- or amino-containing olefinically unsaturated compound. This prepolymer is compounded with a photosensitizer and, optionally, a polymercaptan to prepare photocurable compositions.

Abstract: A multicomponent polymer blend composition is prepared by intimately mixing a thermoplastic polyester, a selectively hydrogenated monoalkenyl arene-diene block copolymer, and at least one dissimilar engineering thermoplastic resin under such conditions that at least two of the polymers form at least partial continuous network phases which interlock with the other polymer networks and therefore results in a desirable balance of properties. These blends have an unobviously high heat distortion temperature relative to the improved impact strength.