Patents by Inventor Heinrich Hartmann

Heinrich Hartmann has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5662781
    Abstract: Nitrile impurities are eliminated from polymers which contain acyclic N-vinyl-carboxamide and/or vinylamine units by treating the polymers with at least one oxidizing agent a) with exposure to light and/or b) in the presence of heavy metal ions.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: September 2, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Denzinger, Heinrich Hartmann, Michael Kroener, Claudia Nilz
  • Patent number: 5661220
    Abstract: Reaction products which are suitable as demulsifiers for crude oil emulsions, comprise olefinically unsaturated carboxylic acids and polyetherols and are obtainable byA) condensation of one or more unsaturated C.sub.3 -C.sub.10 -carboxylic acids or their derivatives of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.4 -alkyl or carboxyl, R.sup.3 is hydrogen or methyl and R.sup.1 together with the carboxyl group may form a 5-membered or 6-membered anhydride ring, with a polyetherol of the general formula II ##STR2## where R.sup.4 is a radical of a monohydric or polyhydric alcohol or of a phenol or of an alkylphenol of 7 to 30 carbon atoms or a radical of an alkylphenol/formaldehyde or alkylphenol/acetaldehyde condensate, R.sup.5 is a branched or straight-chain C.sub.2 -C.sub.4 -alkylene group, where different units [R.sup.
    Type: Grant
    Filed: February 7, 1996
    Date of Patent: August 26, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Dieter Faul, Joachim Roser, Heinrich Hartmann, Hans-Henning Vogel, Wilhelmus Slotman, Gerd Konrad
  • Patent number: 5656646
    Abstract: Mixtures of(I)polymers of monoethylenically unsaturated dicarboxylic acids having a molecular weight of from 200 to 5,000 and(II)(1) copolymers having a molecular weight of from 10,000 to 150,000 and comprising(a) from 10 to 70% by weight of monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acids or the salts thereof and(b) from 30 to 90% by weight of monoethylenically unsaturated C.sub.3 -C.sub.10 -monocarboxylic acids and/or the salts thereof,(2) graft polymers having a molecular weight of from 5,000 to 150,000, which are obtainable by free radical graft polymerization of(A) monoethylenically unsaturated C.sub.3 -C.sub.10 -carboxylic acids or the anhydrides and/or the salts thereof in the presence of(B) mono-, oligo- or polysaccharides and the derivatives thereof in a weight ratio (A) : (B) of (95 to 20) : (5 to 80), and/or(3) polyaminocarboxylic acids and/or polymers containing aminocarboxylic acid groupscontain the components (I) and (II) in a weight ratio of from 10 : 0.5 to 0.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: August 12, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Johannes Perner, Paul Diessel, Helmut Guembel, Walter Denzinger, Heinrich Hartmann, Matthias Kroner
  • Patent number: 5653815
    Abstract: In a process for solid-liquid extraction, in particular of sucrose from beet cossettes, countercurrent extraction in an extraction tower is employed. The tower juice is drawn off together with the small-sized solid constituents obtained in the process, such as sand, essentially exclusively via side screens.
    Type: Grant
    Filed: April 4, 1995
    Date of Patent: August 5, 1997
    Assignee: Braunschweigische Maschinenbauanstalt AG
    Inventors: Heinrich Hartmann, Dieter Hellmig, Siegfried Matusch, Guenter Pohner, Guenther Ross, Florian Sosnitza
  • Patent number: 5639723
    Abstract: Reaction products of polybasic acids and amino-containing compounds, which are obtainable by heating a mixture of (a) a polybasic carboxylic acid selected from the group consisting of citric acid, isocitric acid, aconitic acid, itaconic acid and/or tartaric acid and (b) an amino-containing compound in a molar ratio of (a) to (b) of from 1:0.1 to 1:10 to at least 80.degree. C. are used as additives in low-phosphate and phosphate-free detergents and cleaning agents.
    Type: Grant
    Filed: January 23, 1995
    Date of Patent: June 17, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Dieter Boeckh, Richard Baur, Alexander Kud, Volker Schwendemann
  • Patent number: 5630907
    Abstract: Copolymers which are obtained by copolymerization ofa) from 5 to 99 mol % of N-vinylcarboxamides,b) from 95 to 1 mol % of monoethylenically unsaturated carboxylic acids and/or the alkali metal, alkaline earth metal, ammonium or amine salts thereof, and if required,c) up to 30 mol % of other monoethylenically unsaturated compounds, and if required,d) up to 2 mol % of crosslinking agents,and subsequent partial or complete elimination of the acyl groups from the N-vinylcarboxamides polymerized in the copolymer, with formation of amino or ammonium groups, are used as additives to paper stock for increasing the drainage rate and the retention in papermaking, and the dry and wet strength of the paper.
    Type: Grant
    Filed: May 21, 1996
    Date of Patent: May 20, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Claudia Nilz, Walter Denzinger, Heinrich Hartmann, Michael Kroener, Friedrich Linhart, Rudolf Schuhmacher, Dietmar Moench, Andreas Stange
  • Patent number: 5620748
    Abstract: Soft leathers with a pleasant hand are obtained on fatliquoring and filling leather and fur skins with water-soluble or water-dispersible graft polymers of vegetable and animal oils, obtainable by radically initiated polymerizationA) of a monomer or monomer mixture comprising(a) from 20 to 100% by weight of monoethylenically unsaturated carboxylic acids and/or monoethylenically unsaturated sulfonic acids and/or monoethylenically unsaturated phosphonic acids or their alkali metal, alkaline earth metal or ammonium salts,(b) from 0 to 80% by weight of other monoethylenically unsaturated monomers which are copolymerizable with the monomers (a), and(c) from 0 to 5% by weight of at least doubly ethylenically unconjugatedly unsaturated monomersin the presence ofB) vegetable and/or animal oils in a weight ratio of A:B of (80-1):(20-99).
    Type: Grant
    Filed: March 3, 1994
    Date of Patent: April 15, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Hermann Birkhofer, Peter Danisch, Walter Denzinger, Heinrich Hartmann, Michael Kneip
  • Patent number: 5599898
    Abstract: Abstract of the Disclosure: Insoluble, only slightly swellable polymers containing amino groups, which can be obtained from popcorn polymers containing units of the structure ##STR1## where R and R.sup.1 are H or C.sub.1 -C.sub.4 -alkyl, by eliminating the group R--CO-- from at least 2% of the incorporated units of the structure I, with the formation of units of the structure II ##STR2## a process for the preparation of the amino-containing popcorn polymers by polymerizing N-vinylcarboxamides and, if desired, other monoethylenically unsaturated monomers copolymerizable therewith with from 0.
    Type: Grant
    Filed: April 25, 1995
    Date of Patent: February 4, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinrich Hartmann, Walter Denzinger, Michael Kroener, Claudia Nilz
  • Patent number: 5578678
    Abstract: Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule,in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.
    Type: Grant
    Filed: April 19, 1994
    Date of Patent: November 26, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinrich Hartmann, Walter Denzinger, Michael Kroener, Claudia Nilz, Friedrich Linhart, Andreas Stange
  • Patent number: 5576407
    Abstract: Copolymers of hydroxyalkyl vinyl ethers are obtainable by cationic or free radical copolymerization of(a) from 99 to 1% by weight of a hydroxyalkyl vinyl ether,(b) from 1 to 99% by weight of an adduct of a C.sub.2 -C.sub.4 -alkylene oxide with a hydroxyalkyl vinyl ether and(c) from 0 to 98% by weight of other copolymerizable monomers,and the stated copolymer and hydroxyalkyl vinyl ethers polymerized by cationic or free radical polymerization, which contain the monomers (a) or (b) as sole monomers or as a mixture with other copolymerizable monomers in the form of polymerized units, are used as additives for detergents and cleaning agents in amounts of from 0.1 to 50% by weight.
    Type: Grant
    Filed: February 10, 1994
    Date of Patent: November 19, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Gerhard Wolf, Richard Baur, Paul Diessel, Hans-Ulrich Jaeger, Volker Schwendemann, Johannes Perner
  • Patent number: 5548036
    Abstract: Process for the preparation of polymers of aspartic acid by reacting (a) maleic anhydride and (b) ammonia and/or primary or secondary amines without diluent in the (a):(b) molar ratio of 1:0.1 to 1:3 to give monoamides of maleic acid, fumaric acid or their ammonium salts at up to 100.degree. C. and subsequent condensation of the reaction products, with or without compounds capable of cocondensation, at above 100.degree. C. and, where appropriate, hydrolysis of the condensates and use of the polymers as scale inhibitor, as dispersants for pigments and as additive to detergents and cleaners.
    Type: Grant
    Filed: June 26, 1995
    Date of Patent: August 20, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Gunnar Schornick, Richard Baur, Birgit Potthoff-Karl, Volker Schwendemann, Alexander Kud
  • Patent number: 5543459
    Abstract: Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free moneothylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule,in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.
    Type: Grant
    Filed: March 9, 1995
    Date of Patent: August 6, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinrich Hartmann, Walter Denzinger, Michael Kroener, Claudia Nilz, Friedrich Linhart, Andreas Stange
  • Patent number: 5520834
    Abstract: Soluble polyacetals containing acetaldehyde acetal units are obtainable by cationically initiated addition polymerization of(a) compounds containing at least 3 hydroxyl groups, and(b) divinyl ethers containing terminal vinyl ether groups, or mixtures of such divinyl ethers and monovinyl ethers, in the presence or absence of(c) dihydroxy compounds and/or monohydroxy compounds, and are useful as admixture in phosphate-reduced and phosphate-free detergents and cleaners and as dispersant for finely divided minerals.
    Type: Grant
    Filed: March 20, 1995
    Date of Patent: May 28, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Heinrich Hartmann, Johannes Perner, Hans-Ulrich Jaeger, Paul Diessel, Richard Baur, Volker Schwendemann
  • Patent number: 5508394
    Abstract: Esters of citric acid or acetylcitric anhydride with compounds of at least 3 OH groups selected from the group consisting of polyglycerol, sugarcarboxylic acids, alkyl glucosides, derivatives of oligosaccharides, aminosorbitol, aminodisorbitol, glucosamine, triethanolamine and trishydroxyethylmelamine, each OH group of the alcohol component of the esters being esterified on average with from 0.15 to 1 molecule of citric acid or acetylcitric anhydride, are useful as additives in low-phosphate or phosphate-free detergents.
    Type: Grant
    Filed: September 16, 1993
    Date of Patent: April 16, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Elisabeth Kappes, Alfred Oftring, Richard Baur, Alexander Kud, Dieter Boeckh, Heinrich Hartmann, Volker Schwendemann
  • Patent number: 5506332
    Abstract: A process for preparing polyacetals by copolymerization of glyoxylic esters with other copolymerizable monomers in the presence of anionic or cationic polymerization initiators, with or without the introduction of stable end groups and with or without hydrolysis of the copolymerized units of glyoxylic ester present in the copolymer comprises using as monomers cyclic formals derived from diols, homopolymers of formaldehyde, trioxepane or mixtures thereof, although up to 50% by weight of this group of monomers may be replaced by other customary copolymerizable monomers, and the poly(acetal-carboxylate)s thus obtainable are useful as additives in reduced-phosphate and phosphate-free detergents and cleaners, as water treatment agents and as dispersants for finely divided substances.
    Type: Grant
    Filed: February 2, 1995
    Date of Patent: April 9, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Angelika Funhoff, Graham E. McKee, Heinrich Hartmann, Richard Baur, Alexander Kud, Volker Schwendemann
  • Patent number: 5506315
    Abstract: Copolymers are prepared from monoethylenically unsaturated monomers containing acid groups and N-vinyllactams and, if required, other monoethylenically unsaturated monomers by copolymerization of monomers in the presence of free radical polymerization initiators by a solution polymerization method in water at a pH of at least 6, by a process in which an alkali metal base or an alkaline earth metal base or a mixture thereof is used for establishing the pH of the aqueous reaction solution.
    Type: Grant
    Filed: September 12, 1994
    Date of Patent: April 9, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Harald Meyer, Walter Denzinger, Axel Sanner, Heinrich Hartmann
  • Patent number: 5488095
    Abstract: Condensation products that contain N,O-acetal or carboxamide structures and are useful as detergent and cleaner additives are obtainable by condensation of(a) compounds that contain at least one unit of the structural elements ##STR1## where X is OH or NHR and R is C.sub.1 -C.sub.6 -alkyl or --CH.sub.2 --COOH, with(b) aldehydes, ketones or aldehyde- or keto-carboxylic acids to form acetal-lactones, and subsequent cleavage of the acetal-lactones with(c) aminocarboxylic acids, primary or secondary amines and/or polyethyleneimines.
    Type: Grant
    Filed: January 18, 1995
    Date of Patent: January 30, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Dieter Boeckh, Angelika Funhof, Matthias Kroner, Heinrich Hartmann, Richard Baur, Alexander Kud, Volker Schwendemann
  • Patent number: 5466762
    Abstract: There are described block copolyacetals obtainable by cationically initiated polyaddition of(A) polyacetals containing acetaldehyde acetal units and having at least 2 OH groups in the molecule and(B) polyacetals containing acetaldehyde acetal units and having at least 2 vinyl ether groups in the molecule.in a molar ratio of (A):(B) of from 2:1 to 1:2, processes for preparing the block copolyacetals by cationically initiated polyaddition of (A) and (B), and the use of the block polyacetals as additament to reduced-phosphate and phosphate-free detergents and cleaners and as low-foam surfactants in dishwashing compositions.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: November 14, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick, Richard Baur, Volker Schwendemann, Heinrich Hartmann
  • Patent number: 5433752
    Abstract: Products useful for fatliquoring and filling leather and fur skins are obtained on reactingA) homo- or copolymers based on monoethylenically unsaturated dicarboxylic anhydrides and obtainable by free-radically initiated polymerization ofa) from 30 to 100 mol % of one or more monoethylenically unsaturated dicarboxylic anhydrides of from 4 to 10 carbon atoms,b) from 0 to 70 mol % of one or more aromatic vinyl compounds of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, methyl or ethyl and k is 1 or 2,(c) from 0 to 70 mol % of one or more vinyl esters of C.sub.1 - to C.sub.8 -carboxylic acids,(d) from 0 to 50 mol % of one or more C.sub.2 - to C.sub.6 -olefins, and(e) from 0 to 30 mol % of one or more monoethylenically unsaturated C.sub.3 - to C.sub.5 -carboxylic acids,which mixture of monomers (a) to (e) may additionally contain up to 10% by weight of further copolymerizable monomers, withB) amines of the general formula R.sub.4 R.sub.5 NH, where R.sup.4 is hydrogen, C.sub.
    Type: Grant
    Filed: August 26, 1994
    Date of Patent: July 18, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Hermann Birkhofer, Peter Danisch, Walter Denzinger, Heinrich Hartmann, Norbert Greif, Knut Oppenlaender
  • Patent number: 5425784
    Abstract: Water-soluble graft polymers of monosaccharides, oligosaccharides, polysaccharides and derivatives thereof, obtainable by free radical polymerization ofA) a monomer selected from, or a monomer mixture of,(a) from 20 to 100% by weight of acrylic acid or methacrylic acid or of a mixture thereof or of the alkali metal, alkaline earth metal or ammonium salts thereof,(b) from 0 to 80% by weight of other monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers having at least 2 ethylenically unsaturated, nonconjugated double bonds in the molecule,in the presence ofB) monosaccharides, oligosaccharides, polysaccharides, oxidatively, hydrolyrically or enzymatically degraded polysaccharides, oxidized hydrolyrically degraded or oxidized enzymatically degraded polysaccharides, chemically modified mono-, oligo- or polysaccharides or a mixture of the stated compounds in a weight ratio A:B of from 95:5 to 20:80, are used as a tanning agent for the self-
    Type: Grant
    Filed: June 27, 1994
    Date of Patent: June 20, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Denzinger, Heinrich Hartmann, Brigitte Wegner