Abstract: A method for using low dielectric SiOF in a process to manufacture semiconductor products, comprising the steps of obtaining a layer of SiOF, and depleting fluorine from a surface of the SiOF layer. In a preferred embodiment, the depleting step comprises the step of treating the surface of the layer of SiOF with a plasma containing ammonia. It is further preferred that the treated surface be passivated by a nitrite plasma. The invention also encompasses a semiconductor chip comprising an integrated circuit with at least a first and second layers, and with a dielective layer of SiOF disposed between the layers, wherein the SiOF dielectric layer includes a first region at one edge thereof which is depleted of fluorine to a predetermined depth.

Abstract: An interlayer dielectric for a damascene structure includes a first etch stop layer formed on a substrate. A first interlayer dielectric layer containing fluorine is formed on the first etch stop layer by deposition. A second etch stop layer is formed on the first interlayer dielectric layer. A second interlayer dielectric layer containing fluorine is formed on the second etch stop layer by deposition. The first and second interlayer dielectric layers and the first and second etch stop layers are etched to form at least one trench and at least one via. The at least one trench and the at least one via are treated with an H2/N2 plasma in-situ, wherein a fluorine-depleted region in the first and second interlayer dielectric layers is formed, and wherein a nitrided region is formed adjacent the fluorine-depleted region, with the nitrided region corresponding to a side surface of the at least one trench and the at least one via.

Abstract: A rapid thermal anneal (>600° C.) in a nitrogen-containing atmosphere is used to form a barrier TiN layer at the bottom of contact openings. To form source and drain contacts, contact openings are etched in a dielectric down to a titanium silicide layer on top of doped regions in the semiconductor (i.e. polysilicon or doped regions in the semiconductor substrate). The barrier TiN layer on the bottom of the contact openings is provided by a rapid thermal anneal in a nitrogen-containing atmosphere which converts the top part of the titanium silicide layer in the contact openings into a barrier TiN layer. This nitrogen-containing atmosphere contains nitrogen-containing species (e.g., N2, NH3, N2O) that react with titanium silicide to form TiN under the conditions provided by the rapid thermal anneal.

Abstract: A cutter element for use in a drill bit, has a substrate comprising a grip portion and an extension and at least a cutting layer affixed to said substrate. The cutting layer has a cutting surface and an interface surface, and the cutting surface includes a region of residual compressive stress, which functions as a preload or prestress so as to offset the effect of localized loading due to contact with the formation during drilling.

Abstract: A semiconductor device formed on a substrate includes at least one metal stack formed on the substrate. A fluorosilicate glass layer is formed on the at least one metal stack, where the fluorosilicate glass layer acts as an interlayer dielectric for the semiconductor device. The fluorosilicate glass layer includes a fluorine-depleted layer at a top portion of the fluorosilicate glass layer that is further away from the substrate. The fluorine-depleted layer is formed by treating the fluorosilicate glass layer with a hydrogen plasma, such as an H2/N2 plasma. The fluorine-depleted layer lessens a likelihood of fluorine atoms in the fluorosilicate glass layer from moving into and thereby corrupting a conducting layer formed above the fluorosilicate glass layer.

Abstract: A process, preferably in a counter-current configuration, for selectively cracking carbon-carbon bonds of naphthenic species using a low acidic catalyst, preferably having a crystalline molecular sieve component and carrying a Group VIII noble metal. The diesel fuel products are higher in cetane number and diesel yield.

Abstract: This invention describes improved apparatus and methods for spin-on deposition of semiconductor thin films. The improved apparatus provides for controlled temperature, pressure and gas compositions within the deposition chamber. The improved methods comprise dispensing of solutions containing thin film precursor via a moveable dispensing device and the careful regulation of the pattern of deposition of the precursor solution onto the wafer. The invention also comprises the careful regulation of deposition variables including dispensation time, wafer rpm, stop time and rates of wafer rotation. In one embodiment, the precursor solution is dispensed from the outer edge of the wafer toward the center. In alternative embodiments, processors regulate the movement of the dispensing arm and the precursor pump to provide an evenly dispensed layer of precursor solution. The invention also describes improved methods for evaporating solvents and curing thin films.

Abstract: An integrated circuit and a method of removing photoresist is described. The process described uses a low oxygen gas or non-oxygen gas plasma that removes the photoresist and provides a protective surface layer over the low-k dielectric material. The low-k dielectric material is part of a dielectric stack. After exposure to the gas plasmas the integrated circuit is subjected to solvent.

Abstract: This invention describes improved apparatus and methods for spin-on deposition of semiconductor thin films. The improved apparatus provides for controlled temperature, pressure and gas compositions within the deposition chamber. The improved methods comprise dispensing of solutions containing thin film precursor via a moveable dispensing device and the careful regulation of the pattern of desposition of the precursor solution onto the wafer. The invention also comprises the careful regulation of deposition variables including dispensation time, wafer rpm, stop time and rates of wafer rotation. In one embodiment, the precursor solution is dispensed from the outer edge of the wafer toward the center. In alternative embodiments, processors regulate the movement of the dispensing arm and the precursor pump to provide an evenly dispensed layer of precursor solution. The invention also describes improved methods for evaporating solvents and curing thin films.

Abstract: Methods and arrangements that increase the process control during the fabrication of the control gate configuration in a non-volatile memory semiconductor device are provided. The methods and arrangements effectively prevent cracks from developing within a tungsten suicide layer that is part of a control gate structure within a non-volatile memory cell. Cracks within the tungsten silicide layer can affect the performance of the memory cell by increasing the resistance of the control gate configuration. The methods and arrangements prevent cracking of the tungsten silicide layer by minimizing the relative difference between temperatures associated with the deposition of the tungsten suicide layer and deposition of a subsequent overlying cap layer.

Abstract: A process is provided for selectively producing diesel fuel with increased cetane number from a hydrocarbon feedstock. The process includes contacting the feedstock with a catalyst which has a large pore crystalline molecular sieve material component having a faujasite structure and alpha acidity of less than 1, preferably about 0.3 or less. The catalyst also contains a dispersed Group VIII noble metal component which catalyzes the hydrogenation/hydrocracking of the aromatic and naphthenic species in the feedstock.

Abstract: This invention comprises improvements in the ways in which spin-on dielectric layers are cured. A semiconductor wafer is coated with a precursor for a spin-on dielectric material, and after the solution is thinned and evened, the wafer is placed in a curing oven, optionally containing an inert gas, and pre-heated to a temperature below which excessive thermomechanical stresses and/or oxidation are not created in the semiconductor wafer. The temperature within the curing oven is then raised to a curing temperature, and thereafter the temperature is slowly lowered to prevent the formation of stress cracks and the loss of dielectric function of the thin film. The curing method of this invention is useful for the manufacture of semiconductor devices employing a variety of spin-on materials.

Abstract: An ultra-large scale integrated circuit is manufactured by using silicon-based, low dielectric constant materials which are spin-coated, dried, cured, and capped in-situ in chemical vapor deposition equipment. The low dielectric constant material is spun on, processed in chemical vapor deposition equipment, subject to chemical-mechanical polishing, and then processed by a conventional photolithographic process for depositing conductors. The material is then reprocessed for each successive layer of conductor separated by dielectric.

Abstract: An interlayer dielectric for a damascene structure includes a first etch stop layer formed on a substrate. A first interlayer dielectric layer containing fluorine is formed on the first etch stop layer by deposition. A second etch stop layer is formed on the first interlayer dielectric layer. A second interlayer dielectric layer containing fluorine is formed on the second etch stop layer by deposition. The first and second interlayer dielectric layers and the first and second etch stop layers are etched to form at least one trench and at least one via. The at least one trench and the at least one via are treated with an H2/N2 plasma in-situ, wherein a fluorine-depleted region in the first and second interlayer dielectric layers is formed, and wherein a nitrided region is formed adjacent the fluorine-depleted region, with the nitrided region corresponding to a side surface of the at least one trench and the at least one via.

Abstract: A roller cone drill bit includes a bit body adapted to be rotated about a longitudinal axis. At least one leg depends from the bit body, and a journal is cantilevered from the leg. A roller cone is rotatably mounted on the journal. A cone retention member is disposed between a first slot in the journal and a corresponding second slot in the roller cone. An access hole runs through the journal to the first slot, penetrating the first slot at a location away from the top dead center of the first slot.

Abstract: A method for producing a dielectric layer in a semiconductor product includes two steps. The first step is forming a fluorinated layer (e.g. SiOF or fluorosilicate glass ("FSG")) which includes a material formed in part with fluorine. The second step is forming a fill layer (e.g. SiO.sub.2) above the fluorinated layer. The fill layer is substantially free of materials formed in part with fluorine. A top surface of the fill layer can be planarized. Surface treatments and oxide caps can be applied to the planarized surface to form fluorine barriers if part of the fluorinated layer is exposed to higher layers. Such a method, and a semiconductor device or integrated circuit manufactured according to the method, allow the dielectric constant of an inter-layer dielectric ("ILD") to be lowered while also minimizing the complexity and expense of the manufacturing process.

Abstract: An ultra-large scale integrated circuit is manufactured by using silicon-based, low dielectric materials on a wafer in which the hydrophobic nature of the dielectric materials is improved by relative low temperature heating in a vacuum or inert atmosphere, slowly increasing the wafer temperature to the hard bake temperature at a predetermined ramp rate, and heating the wafer at the hard bake temperature for a predetermine amount of time. As a result, the dielectric material can repel wet etch chemicals and minimize the formation of holes in the dielectric materials due to etching by wet etch chemicals.

Abstract: Outgassing from a dielectric gap fill layer, e.g., a low dielectric constant material such as HSQ, and attendant deformation or delamination of a barrier dielectric layer on an overlying patterned conductive layer during subsequent thermal processing are avoided or significantly reduced by controlling the thickness of the dielectric cap layer on the dielectric gap fill layer. Embodiments include depositing a conformal SiON barrier on a first conductive pattern, depositing a HSQ gap fill layer on the conformal SiON barrier layer, depositing a silicon oxide cap layer and planarizing such that the thickness of the planarized silicon cap layer is at least 2500 .ANG., thereby avoiding deformation and/or delamination of a conformal SiON barrier layer on an overlying patterned conductive layer during subsequent thermal processing.

Abstract: An inter-level dielectric (ILD) is formed from a lower barrier layer comprising a conformal silicon oxynitride layer, a gap fill layer comprising a high-density plasma (HDP) oxide and a cap layer. The use of HDP oxide as a gap fill layer enables better control of the ILD thickness, avoids outgasing problems, facilitates via formation and reduces planarization.

Abstract: An integrated circuit having semiconductor devices is connected by a first conductive channel damascened into a first oxide layer above the devices. A stop nitride layer, a via oxide layer, a via nitride layer, and a via resist are sequentially deposited on the first channel and the first oxide layer. The via resist is photolithographically developed with rectangular cross-section vias greater than the width of the channels and the via nitride layer is etched to the rectangular cross-section. A second channel oxide layer and a second channel resist are sequentially deposited on the via nitride layer and the exposed via oxide layer. The second channel resist is photolithographically developed with the second channels and an anisotropic oxide etch etches the second channels and rectangular box vias down to the stop nitride layer.