Abstract: Methods of direct growth of high quality group III-V and group III-N based materials and semiconductor device structures in the form of nanowires, planar thin film, and nanowires-based devices on metal substrates are presented. The present compound semiconductor all-metal scheme greatly simplifies the fabrication process of high power light emitters overcoming limited thermal and electrical conductivity of nanowires grown on silicon substrates and metal thin film in prior art. In an embodiment the methods include: (i) providing a metal substrate; (ii) forming a transition metal dichalcogenide (TMDC) layer on a surface of the metal substrate; and (iii) growing a semiconductor epilayer on the transition metal dichalcogenide layer using a semiconductor epitaxy growth system. In an embodiment, the semiconductor device structures can be compound semiconductors in contact with a layer of metal dichalcogenide, wherein the layer of metal dichalcogenide is in contact with a metal substrate.

Abstract: A device comprising: at least one first layer, such as a graphene layer, at least one second layer of transition metal dichalcogenide, wherein the at least one first layer and the at least one second layer of transition metal dichalcogenide form at least one heterojunction. The first and second layers are laterally displaced but may overlap over a length of 0 nm to 500 nm. A low-resistance contact is formed. The device can be a transistor including a field effect transistor. The layers can be formed by chemical vapor deposition. The graphene can be heavily p-doped. Transistor performance data are described.

Abstract: A method for forming a semiconductor device having a lateral semiconductor heterojunction involves forming a first metal chalcogenide layer of the lateral semiconductor heterojunction adjacent to a first metal electrode on a substrate. The first metal chalcogenide layer includes a same metal as the first metal electrode and at least some of the first metal chalcogenide layer includes metal from the first metal electrode. A second metal chalcogenide layer of the lateral semiconductor heterojunction is formed adjacent to the first metal chalcogenide layer. A second metal electrode is formed adjacent to the second metal chalcogenide layer. The second metal chalcogenide layer includes a same metal as the second metal electrode.

Abstract: In a method of forming a two-dimensional material layer, a nucleation pattern is formed over a substrate, and a transition metal dichalcogenide (TMD) layer is formed such that the TMD layer laterally grows from the nucleation pattern. In one or more of the foregoing and following embodiments, the TMD layer is single crystalline.

Abstract: A device comprising: at least one first layer, such as a graphene layer, at least one second layer of transition metal dichalcogenide, wherein the at least one first layer and the at least one second layer of transition metal dichalcogenide form at least one heterojunction. The first and second layers are laterally displaced but may overlap over a length of 0 nm to 500 nm. A low-resistance contact is formed. The device can be a transistor including a field effect transistor. The layers can be formed by chemical vapor deposition. The graphene can be heavily p-doped. Transistor performance data are described.

Abstract: The present disclosure provides for methods of phosphidation, catalysts formed from phosphidation, and methods of producing H2.

Abstract: A battery comprising: at least one cathode, at least one anode, at least one battery separator, and at least one electrolyte disposed in the separator, wherein the anode is a lithium metal or lithium alloy anode or an anode adapted for intercalation of lithium ion, wherein the cathode comprises material adapted for reversible lithium extraction from and insertion into the cathode, and wherein the separator comprises at least one porous, electronically conductive layer and at least one insulating layer, and wherein the electrolyte comprises at least one polysulfide anion. The battery provides for high energy density and capacity. A redox species is introduced into the electrolyte which creates a hybrid battery. Sodium metal and sodium-ion batteries also provided.

Abstract: Oxygen evolution reaction (OER) catalysts and uses thereof are described. An OER catalyst can include a carbon support, a discontinuous catalytic cobalt (II,III) oxide (Co3O4) nanolayer in direct contact with the carbon support, and an amorphous continuous carbon layer. The Co3O4 nanolayer is positioned between the carbon support and an amorphous continuous carbon layer.

Abstract: A slurry for manufacturing a graphene sheet combining graphite flake structure includes a solvent, a graphite nanoplatelet material and a graphene material. The graphite nanoplatelet material includes a plurality of graphite nanoplatelets. The graphene material comprising a plurality of graphenes. The graphite nanoplatelet material and the graphene material is mixed in the solvent, a weight percentage of the graphite nanoplatelet material is between 0.1% and 10%, and the content of the graphene material is between 1% and 80% of the graphite nanoplatelet material.

Abstract: The present disclosure provides for a lithium-sulfur battery with a dual blocking layer between the anode and cathode, providing for high storage capacity and improved performance.

Abstract: Prelithiation of a battery anode carried out using controlled lithium metal vapor deposition. Lithium metal can be avoided in the final battery. This prelithiated electrode is used as potential anode for Li-ion or high energy Li—S battery. The prelithiation of lithium metal onto or into the anode reduces hazardous risk, is cost effective, and improves the overall capacity. The battery containing such an anode exhibits remarkably high specific capacity and a long cycle life with excellent reversibility.

Abstract: Various embodiments relate to a method of modifying the electrical properties of carbon nanotubes. The method may include providing a substrate having carbon nanotubes deposited on a surface of the substrate, and depositing on the carbon nanotubes a coating layer comprising a mixture of nanoparticles, a matrix in which the nanoparticles are dissolved or stabilized, and an ionic liquid. A field-effect transistor including the modified carbon nanotubes is also provided.

Abstract: A graphene sheet combining graphite flake structure includes a graphite nanoplatelet material and a graphene material. The graphene material is mixed in the graphite nanoplatelet material, and the content of the graphene material is between 1% and 80% of the graphite nanoplatelet material. A slurry for manufacturing the graphene sheet combining graphite flake structure and a manufacturing method for the graphene sheet combining graphite flake structure are also disclosed.

Abstract: The present disclosure provides for methods of phosphidation, catalysts formed from phosphidation, and methods of producing Hz.

Abstract: The present invention provides a method of preparing a battery electrode, comprising: (a) providing electroactive particles; (b) mixing the electroactive particles with a graphene-based material to form a composite; and (c) spray coating the composite onto a substrate to form the battery electrode; wherein the percentage of the electroactive particles to the graphene-based material is 40-95 wt %. Furthermore, the present invention provides a high performance battery electrode and lithium sulfur battery or Lithium Metal Oxide-Sulfur battery.

Abstract: Aromatic molecules are seeded on a surface of a growth substrate; and a layer (e.g., a monolayer) of a metal dichalcogenide is grown via chemical vapor deposition on the growth substrate surface seeded with aromatic molecules. The seeded aromatic molecules are contacted with a solvent that releases the metal dichalcogenide layer from the growth substrate. The metal dichalcogenide layer can be released with an adhered transfer medium and can be deposited on a target substrate.

Abstract: A graphene sheet combining graphite flake structure includes a graphite nanoplatelet material and a graphene material. The graphene material is mixed in the graphite nanoplatelet material, and the content of the graphene material is between 1% and 80% of the graphite nanoplatelet material. A slurry for manufacturing the graphene sheet combining graphite flake structure and a manufacturing method for the graphene sheet combining graphite flake structure are also disclosed.

Abstract: A battery includes a first electrode including a plurality of particles containing lithium, a layer of carbon at least partially coating a surface of each particle, and electrochemically exfoliated graphene at least partially coating one or more of the plurality of particles. The battery includes a second electrode and an electrolyte. At least a portion of the first electrode and at least a portion of the second electrode contact the electrolyte.

Abstract: The invention relates to a method of modifying electrical properties of carbon nanotubes by subjecting a composition of carbon nanotubes to one or more radical initiator(s). The invention also relates to an electronic component such as field-effect transistor comprising a carbon nanotube obtained using the method of the invention. The invention also relates to the use of the modified carbon nanotubes in conductive and high-strength nanotube/polymer composites, transparent electrodes, sensors and nanoelectromechanical devices, additives for batteries, radiation sources, semiconductor devices (e.g. transistors) or interconnects.

Abstract: Disclosed is a method of producing thin graphene nanoplatelets, and the method includes the steps of providing a carbon precursor and a filling material, using the carbon precursor as a binding agent to mix with the filling material thoroughly, producing a composite material through a forming process, performing a heat treatment of the composite material under an atmosphere and at different temperatures to improve the electrical conductivity and adjust to an appropriate binding strength, perform a carbon conversion of the composite material with a good graphite cyrstallinity to produce a layered graphite structure of a thin graphene nanoplatelet precursor, while obtaining high quality graphene by performing an electrochemical process of the thin graphene nanoplatelet precursor, so as to achieve the mass production of the high quality thin graphene nanoplateletes with a low cost.